NAVY MIL-DTL-16884 M-2012 FUEL NAVAL DISTILLATE.pdf

1、Comments, suggestions, or questions on this document should be addressed to: Commander, Naval Sea Systems Command, ATTN: SEA 05S, 1333 Isaac Hull Avenue, SE, Stop 5160, Washington Navy Yard, DC 20376-5160 or emailed to CommandStandardsnavy.mil, with the subject line “Document Comment”. Since contact

2、 information can change, you may want to verify the currency of this address information using the ASSIST Online database at https:/assist.dla.mil. AMSC N/A FSC 9140 METRIC MIL-DTL-16884M 14 August 2012 SUPERSEDING MIL-DTL-16884L 23 October 2006 DETAIL SPECIFICATION FUEL, NAVAL DISTILLATE This speci

3、fication is approved for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers one grade of Naval distillate fuel: NATO symbol F-76. 2. APPLICABLE DOCUMENTS 2.1 General. The documents listed in this section are specified in sections 3, 4, or

4、5 of this specification. This section does not include documents cited in other sections of this specification or recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users are cautioned that they must meet all spec

5、ified requirements of documents cited in sections 3, 4, or 5 of this specification, whether or not they are listed. 2.2 Government documents. 2.2.1 Specifications, standards, and handbooks. The following specifications, standards, and handbooks form a part of this document to the extent specified he

6、rein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. INTERNATIONAL STANDARDIZATION AGREEMENTS NATO STANAG-1135 - Interchangeability of Fuels, Lubricants and Associated Products used by the Armed Forces of the North Atlantic Treaty Nations N

7、ATO STANAG-1385 - Guide Specification (Minimum Quality Standards) for Naval Distillate Fuels (F-75 and F-76) DEPARTMENT OF DEFENSE STANDARDS MIL-STD-290 - Packaging and Marking of Petroleum and Related Products (Copies of these documents are available online at https:/assist.dla.mil/quicksearch/ or

8、https:/assist.dla.mil.) 2.3 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. ASTM INTERNATIONAL ASTM D86 - Standard Test Method

9、for Distillation of Petroleum Products at Atmospheric Pressure Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-16884M 2 ASTM D93 - Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester ASTM D97 - Standard Test Method for P

10、our Point of Petroleum Products ASTM D130 - Standard Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test ASTM D189 - Standard Test Method for Conradson Carbon Residue of Petroleum Products ASTM D287 - Standard Test Method for API Gravity of Crude Petroleum and Petrol

11、eum Products (Hydrometer Method) ASTM D445 - Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity) ASTM D482 - Standard Test Method for Ash from Petroleum Products ASTM D524 - Standard Test Method for Ramsbottom Carbon Residue of Petrol

12、eum Products ASTM D613 - Standard Test Method for Cetane Number of Diesel Fuel Oil ASTM D664 - Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration ASTM D974 - Standard Test Method for Acid and Base Number by Color-Indicator Titration ASTM D976 - Standard Test Metho

13、ds for Calculated Cetane Index of Distillate Fuels ASTM D1141 - Standard Practice for the Preparation of Substitute Ocean Water ASTM D1266 - Standard Test Method for Sulfur in Petroleum Products (Lamp Method) ASTM D1298 - Standard Test Method for Density, Relative Density (Specific Gravity), or API

14、Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method ASTM D1401 - Standard Test Method for Water Separability of Petroleum Oils and Synthetic Fluids ASTM D1500 - Standard Test Method for ASTM Color of Petroleum Products (ASTM Color Scale) ASTM D1552 - Standard Test Method fo

15、r Sulfur in Petroleum Products (High-Temperature Method) ASTM D2274 - Standard Test Method for Oxidation Stability of Distillate Fuel Oil (Accelerated Method) ASTM D2500 - Standard Test Method for Cloud Point of Petroleum Products ASTM D2622 - Standard Test Method for Sulfur in Petroleum Products by

16、 Wavelength Dispersive X-Ray Fluorescence Spectrometry ASTM D2709 - Standard Test Method for Water and Sediment in Middle Distillate Fuels by Centrifuge ASTM D2887 - Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography ASTM D3120 - Standard Test Method for

17、 Trace Quantities of Sulfur in Light Liquid Petroleum Hydrocarbons by Oxidative Microcoulometry Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-16884M 3 ASTM D3605 - Standard Test Method for Trace Metals in Gas Turbine Fuels by Atomic Absorpt

18、ion and Flame Emission Spectroscopy ASTM D3828 - Standard Test Methods for Flash Point by Small Scale Closed Cup Tester ASTM D4052 - Standard Test Method for Density, Relative Density and API Gravity of Liquids by Digital Density Meter ASTM D4057 - Standard Practice for Manual Sampling of Petroleum

19、and Petroleum Products ASTM D4176 - Standard Test Method for Free Water and Particulate Contamination in Distillate Fuels (Visual Inspection Procedures) ASTM D4177 - Standard Practice for Automatic Sampling of Petroleum and Petroleum Products ASTM D4294 - Standard Test Method for Sulfur in Petroleum

20、 and Petroleum Products by Energy-Dispersive X-ray Fluorescence Spectrometry ASTM D4530 - Standard Test Method for Determination of Carbon Residue (Micro Method) ASTM D4808 - Standard Test Methods for Hydrogen Content of Light Distillates, Middle Distillates, Gas Oils, and Residua by Low-Resolution

21、Nuclear Magnetic Resonance Spectroscopy ASTM D5291 - Standard Test Methods for Instrumental Determination of Carbon, Hydrogen, and Nitrogen in Petroleum Products and Lubricants ASTM D5304 - Standard Test Method for Assessing Middle Distillate Fuel Storage Stability by Oxygen Overpressure ASTM D5452

22、- Standard Test Method for Particulate Contamination in Aviation Fuels by Laboratory Filtration ASTM D5453 - Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence ASTM D5771 - Standard

23、Test Method for Cloud Point of Petroleum Products (Optical Detection Stepped Cooling Method) ASTM D5772 - Standard Test Method for Cloud Point of Petroleum Products (Linear Cooling Rate Method) ASTM D5773 - Standard Test Method for Cloud Point of Petroleum Products (Constant Cooling Rate Method) AST

24、M D5949 - Standard Test Method for Pour Point of Petroleum Products (Automatic Pressure Pulsing Method) ASTM D5950 - Standard Test Method for Pour Point of Petroleum Products (Automatic Tilt Method) ASTM D5985 - Standard Test Method for Pour Point of Petroleum Products (Rotational Method) ASTM D6045

25、 - Standard Test Method for Color of Petroleum Products by the Automatic Tristimulus Method ASTM D6079 - Standard Test Method for Evaluating Lubricity of Diesel Fuels by the High-Frequency Reciprocating Rig (HFRR) ASTM D6217 - Standard Test Method for Particulate Contamination in Middle Distillate F

26、uels by Laboratory Filtration Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-16884M 4 ASTM D6450 - Standard Test Method for Flash Point by Continuously Closed Cup (CCCFP) Tester ASTM D6890 - Standard Test Method for Determination of Ignition

27、 Delay and Derived Cetane Number (DCN) of Diesel Fuel Oils by Combustion in a Constant Volume Chamber ASTM D7039 - Standard Test Method for Sulfur in Gasoline and Diesel Fuel by Monochromatic Wavelength Dispersive X-ray Fluorescence Spectrometry ASTM D7111 - Standard Test Method for Determination of

28、 Trace Elements in Middle Distillate Fuels by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) ASTM D7170 - Standard Test Method for Determination of Derived Cetane Number (DCN) of Diesel Fuel Oils Fixed Range Injection Period, Constant Volume Combustion Chamber Method ASTM D7171 -

29、Standard Test Method for Hydrogen Content of Middle Distillate Petroleum Products by Low-Resolution Pulsed Nuclear Magnetic Resonance Spectroscopy ASTM D7688 - Standard Test Method for Evaluating Lubricity of Diesel Fuels by the High-Frequency Reciprocating Rig (HFFR) by Visual Observation ASTM E29

30、- Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications (Copies of these documents are available from ASTM International, 100 Barr Harbor Dr., P.O. Box C700, West Conshohocken, PA 19428-2959 or online at http:/www.astm.org.) BRITISH STANDARDS INSTIT

31、UTE BS EN14078 - Liquid petroleum products. Determination of fatty acid methyl ester (FAME) content in middle distillates. Infrared spectrometry method. (Copies of this document are available from the British Standards Institute, BSI Customer Services, 389 Chiswick High Road, London, W4 4AL, United

32、Kingdom or online at http:/ INSTITUTE OF PETROLEUM (IP) IP 579/10 - Determination of FAME Content in Middle Distillates Infrared Spectrometry Method (Copies of this document are available from the Energy Institute, 61 New Cavendish Street, London, W1G 7AR, United Kingdom or online at http:/www.energ

33、yinstpubs.org.uk/.) 2.4 Order of precedence. Unless otherwise noted herein or in the contract, in the event of a conflict between the text of this document and the references cited herein, the text of this document takes precedence. Nothing in this document, however, supersedes applicable laws and r

34、egulations unless a specific exemption has been obtained. 3. REQUIREMENTS 3.1 General. Requirements contained herein are not subject to corrections for tolerance of standard test methods. If multiple determinations are made by the inspecting laboratory, average results will be used except for those

35、standard test methods where repeatability data are given. In those cases, the average value derived from the individual results that agree within the repeatability limits given may be used at the discretion of the inspection authority, provided an indication is given of the total number of results o

36、btained and the number falling outside of the repeatability limits. The flash point value is absolute and no value less than 60.0 C is permissible. For purposes of determining conformance with these specifications, an observed value or a calculated value shall be rounded “to the nearest unit” in the

37、 last right-hand digit used in expressing the specification limit, in accordance with the rounding method of ASTM E29. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-16884M 5 3.2 Material. The fuel supplied under this specification shall con

38、sist of refined hydrocarbon distillate fuel, containing no residual fuel. The fuel shall be derived from conventional sources including crude oil, natural gas liquid condensates, heavy oil, shale oil, and oil sands and may contain only those additives specified in 3.2.1 unless otherwise stated. The

39、fuel shall not contain any intentionally blended fatty acid methyl esters (FAME) as specified in 3.2.2. 3.2.1 Additives. The additives listed herein may be used either singularly or in combination, provided the amounts do not exceed those specified herein. Information concerning the type and amount

40、of each additive used shall be made available when requested by the procuring activity or user. 3.2.1.1 Metal deactivator. A metal deactivator, N, N-disalicyclidene-1, 2 propanediamine, may be blended into the fuel in an amount not to exceed 5.8 milligrams of active ingredient per liter of fuel (2.2

41、 grams/100 U.S. gallons, or 2 lb/1,000 barrels). 3.2.1.2 Lubricity additives. Lubricity additives are permitted in accordance with Note 15 of table I. 3.2.2 FAME. The recent mandatory and voluntary introduction of FAME (commonly known as biodiesel) has resulted in the potential for trace amounts of

42、FAME in F-76 fuel. Fuel supplied under this specification shall not be blended with FAME. In the event of contamination with FAME, the fuel supplied under this specification shall not contain more than 0.1 volume percent FAME as determined by EN14078:2009 or IP 579/10. 3.3 Physical and chemical requ

43、irements. The Naval distillate fuel shall conform to the physical and chemical requirements specified in table I. Where more than one test method is allowed for a specific requirement, table I lists the referee test method first and follows it with the notation “(R)”. For sulfur, table II shows the

44、referee test methods for sulfur, the alternate sulfur test methods, and the range over which each test method applies. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-16884M 6 TABLE I. Physical and chemical requirements. PHYSICAL REQUIREMENTS

45、 Characteristic Requirement ASTM Test Method Appearance, at 25 C or ambient, whichever is higher Clear, bright, and free of visible particulates D4176 1/ Demulsification, at 25 C, minutes (max) 10 D1401 2/ Density, at 15 C, kg/m3 (max) 876 D1298 (R), D4052, D287 Distillation: 10% Point, C 50% Point,

46、 C 90% Point, C (max) End Point, C (max) Residue + Loss, % vol. (max) Record Record 357 385 3.0 D86 (R) 3/ D2887 4/ Cloud Point, C (max) -1 D2500 (R), D5771 5/, D5772 5/, D5773 5/ Color, (max) 3 D1500 (R), D6045 Flash Point, C (min) 60.0 D93 (R) 6/, D6450 6/, D3828 6/ Particulate Contamination, mg/l

47、iter (max) 10 D6217 (R), D5452 7/ Pour Point, C (max) -6 D97 (R), D5949, D5950, D5985 8/ Viscosity, at 40 C, mm2/second 1.7 4.3 D445 CHEMICAL REQUIREMENTS Characteristic Requirement ASTM Test Method Acid Number, mg KOH/g (max) 0.30 D974 (R) 9/, D664 Ash, wt. % (max) 0.005 D482 Carbon Residue on 10%

48、bottoms, wt. % (max) 0.20 D524 (R) 10/ 0.14 D189, D4530 10/ Corrosion, at 100 C (max) No. 1 D130 Hydrogen Content, wt. % (min) 12.5 D7171 (R), D4808, D5291 Ignition Quality: Cetane Number, (min) Cetane Index, (min) Derived cetane number (min) 42 43 42 D613 (R) D976 D6890, D7170 Storage Stability, to

49、tal insolubles, mg/ 100 ml (max) 3.0 D5304 (R) 11/ 1.5 D2274 12/ Sulfur Content, wt. % (max) 0.1 D4294 (R) 13/, D1266, D1552, D2622, D3120, D5453 (R) 14/, D7039 Trace Metals, ppm (max): Calcium Lead Sodium plus Potassium Vanadium 1.0 0.5 1.0 0.5 D7111 (R), D3605 Lubricity, at 60 C, micrometers (max) 460 15/ D6079, D7688 Additive Names and Dosages Record Provided by IHSNot for ResaleNo reproduction or netwo