NAVY MIL-DTL-24441 D-2009 PAINT EPOXY-POLYAMIDE GENERAL SPECIFICATION FOR《环氧树脂聚酰胺油漆一般规范》.pdf

1、Comments, suggestions, or questions on this document should be addressed to: Commander, Naval Sea Systems Command, ATTN: SEA 05M2, 1333 Isaac Hull Avenue, SE, Stop 5160, Washington Navy Yard DC 20376-5160 or emailed to CommandStandardsnavy.mil, with the subject line “Document Comment”. Since contact

2、 information can change, you may want to verify the currency of this address information using the ASSIST Online database at http:/assist.daps.dla.mil. AMSC N/A FSC 8010 METRIC MIL-DTL-24441D(SH) 27 August 2009 SUPERSEDING MIL-DTL-24441C(SH) 19 May 1999 DETAIL SPECIFICATION PAINT, EPOXY-POLYAMIDE, G

3、ENERAL SPECIFICATION FOR This specification is approved for use by the Naval Sea Systems Command, Department of the Navy, and is available for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers a series of two component epoxy-polyamide pai

4、nts designed to protect surfaces from environmental attack (see 6.1). 1.2 Classification. Paints covered by this specification will be of the following types, as specified (see 6.2): Type III Three-coat system for use where air pollution regulations restrict volatile organic compound (VOC) content t

5、o less than 340 grams per liter (2.8 pounds per gallon) of paint. Type IV Two-coat system for use where air pollution regulations restrict VOC content to less than 340 grams per liter (2.8 pounds per gallon) of paint. Type V Two coat system for use where air pollution regulations restrict VOC conten

6、t to less than 250 grams solvent per liter (2.08 pounds per gallon) of paint. 2. APPLICABLE DOCUMENTS 2.1 General. The documents listed in this section are specified in sections 3, 4, or 5 of this specification. This section does not include documents cited in other sections of this specification or

7、 recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users are cautioned that they must meet all specified requirements of documents cited in sections 3, 4, or 5 of this specification, whether or not they are liste

8、d. 2.2 Government documents. 2.2.1 Specifications, standards, and handbooks. The following specifications, standards, and handbooks form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract.

9、Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-24441D(SH) FEDERAL SPECIFICATIONS QQ-S-698 - Steel Sheet and Strip, Low Carbon FEDERAL STANDARDS FED-STD-141 - Paint, Varnish, Lacquer, and Related Materials; Methods of Inspection, Sampling and

10、 Testing DEPARTMENT OF DEFENSE SPECIFICATIONS (See Supplement 1 for list of specification sheets.) (Copies of these documents are available online at http:/assist.daps.dla.mil/quicksearch/ or from the Standardization Document Order Desk, 700 Robbins Avenue, Building 4D, Philadelphia, PA 19111-5094.)

11、 2.2.2 Other Government documents, drawings, and publications. The following other Government documents, drawings, and publications form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract.

12、CODE OF FEDERAL REGULATIONS (CFR) 29 CFR 1910 - Occupational Safety and Health Standards 29 CFR 1910.1000 - Subpart Z - Toxic and Hazardous Substances 29 CFR 1910.1200 - Hazard Communication 29 CFR 1990 - Identification, Classification, and Regulation of Potential Occupational Carcinogens 40 CFR 60,

13、 Ch. 1, Appendix A, Method 24 - Determination of Volatile Matter Content, Water Content, Density, Volume Solids, and Weight Solids of Surface Coatings 40 CFR Part 63, Appendix A, Method 311 HAPS in Paints and Coatings 40 CFR 82 - Protection of Stratospheric Ozone 40 CFR 261, Appendix 11, Method 1311

14、 - Toxicity Characteristic Leaching Procedure (TCLP) 40 CFR 355, Appendixes A and B - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities 40 CFR 372.65 - Specific Toxic Chemical Listings 49 CFR 171-178 - Hazardous Materials Regulations (Copies of these documents are av

15、ailable from the Superintendent of Documents, U.S. Government Printing Office, Washington DC 20401 or online at www.gpoaccess.gov/index.html.) 2 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-24441D(SH) UNITED STATES ENVIRONMENTAL PROTECTION

16、 AGENCY (EPA) EPA SW-846 - Test Methods for Evaluating Solid Waste Physical/Chemical Methods EPA 600/4-020 - Methods for Chemical Analysis of Water and Waste (Copies of these documents are available from the Environmental Protection Agency, Ariel Rios Building, 1200 Pennsylvania Avenue, N.W., Washin

17、gton DC 20460 or online at www.epa.gov.) 2.3 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. ASTM INTERNATIONAL ASTM D185 - Sta

18、ndard Test Methods for Coarse Particles in Pigments, Pastes, and Paint ASTM D522 - Standard Test Method for Mandrel Bend Test of Attached Organic Coatings ASTM D523 - Standard Test Method for Specular Gloss ASTM D562 - Standard Test Method for Consistency of Paints Using the Stormer-Type Viscometer

19、ASTM D714 - Standard Test Method for Evaluating Degree of Blistering of Paints ASTM D1141 - Standard Specification for Substitute Ocean Water ASTM D1210 - Standard Test Method for Fineness of Dispersion of Pigment-Vehicle Systems by Hegman-Type Gage ASTM D1296 - Standard Test Method for Odor of Vola

20、tile Solvents and Diluents ASTM D1308 - Standard Test Method for Effect of Household Chemicals on Clear and Pigmented Organic Finishes ASTM D1364 - Standard Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method) ASTM D1394 - Standard Test Methods for Chemical Analysis of

21、White Titanium Pigments ASTM D1475 - Standard Test Method for Density of Liquid Coatings, Inks, and Related Products ASTM D1640 - Standard Test Methods for Drying, Curing, or Film Formation of Organic Coatings at Room Temperature ASTM D1652 - Standard Test Methods for Epoxy Content of Epoxy Resins A

22、STM D1729 - Standard Practice for Visual Appraisal of Color Differences of Diffusely-Illuminated Opaque Materials ASTM D2244 - Standard Method for Calculation of Color Differences from Instrumentally Measured Color Coordinates ASTM D2369 - Standard Test Method for Volatile Content of Coatings ASTM D

23、2698 - Standard Test Method for Determination of the Pigment Content of Solvent-Reducible Paints by High-Speed Centrifuging ASTM D2805 - Standard Test Method for Hiding Power of Paints by Reflectometry 3 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-

24、,-MIL-DTL-24441D(SH) ASTM D3278 - Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus ASTM D3960 - Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings ASTM D4400 - Standard Test Method for Sag Resistance of Paints

25、Using a Multinotch Applicator ASTM D4417 - Standard Test Methods for Field Measurement of Surface Profile of Blast Cleaned Steel ASTM D4541 - Standard Test Method for Pull-Off Strength of Coatings Using Portable Adhesion Testers ASTM E260 - Standard Practice for Packed Column Gas Chromatography ASTM

26、 E1252 - Standard Practice for General Techniques for Qualitative Infrared Analysis (Copies of these documents are available from ASTM International, 100 Barr Harbor Dr., PO Box C700, West Conshohocken, PA 19428-2959 or online at www.astm.org.) INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) Inte

27、rnational Agency for Research on Cancer (IARC) Monographs (Copies of this document are available from WHO Press, World Health Organization, CH-1211 Geneva 27, Switzerland or online at www.who.int/bookorders.) NATIONAL TOXICOLOGY PROGRAM (NTP) Latest Annual Report on Carcinogens, Summary, National To

28、xicology Program (Copies of this document are available from NIEHS, Public Information Office, MD B2-04, Research Triangle Park, NC 27709 or online at http:/library.niehs.nih.gov.) 2.4 Order of precedence. In the event of a conflict between the text of this document and the references cited herein,

29、the text of this document takes precedence. Nothing in this document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3. REQUIREMENTS 3.1 Specification sheets. The individual item requirements shall be as specified herein and in accordance with the

30、applicable specification sheet. In the event of any conflict between the requirements of this specification and the specification sheet, the latter shall govern. 3.2 Qualification. The paints furnished under this specification shall be products that are authorized by the qualifying activity for list

31、ing on the applicable qualified products list before contract award (see 4.2 and 6.3). 3.3 Manufacturer. The paint shall be manufactured (see 6.5) and supplied as a two-component system formulated in accordance with the applicable specification sheet to produce a uniform, high quality product capabl

32、e of meeting all requirements. 3.4 Composition. The components shall be manufactured using the material specified in the specification sheet and in the proportions as specified in the individual specification sheets. The components shall be completely compatible so, when components A and B are mixed

33、 as specified by volume, the paint shall be suitable for spray applications above 4.4 degrees Celsius (C) (40 degrees Fahrenheit (F), and shall meet all other specified requirements. To achieve specified colors, pigments dispersed in polyamide may be used for tinting provided all requirements of the

34、 specification are met. Added pigment shall not exceed 120 grams for 100 liters (1 pound for 100 gallons). 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-24441D(SH) 3.4.1 Use of alternate (“or equal”) ingredients. Specification sheets allo

35、w manufacturers to use alternate (“or equal”) ingredients for named ingredients. When ingredients not listed on the individual specification sheets are proposed for use, manufactures shall conduct complete qualification tests. 3.4.2 Hazardous solvents. When tested as specified in 4.5.20, the content

36、 of hazardous air pollutant solvents (HAPs) in the each individual liquid coating shall not exceed the percent by weight (wt%) values specified in table I. Within these limitations and the requirement that the finished coating meet all requirements of this specification, coating system solvent selec

37、tion shall be in accordance with the individual specification sheets. TABLE I. HAP solvent content limits of coatings using alternate solvents. Hazardous solvent in each individual total paint Maximum, wt% Benzene 0.05 Chlorine or fluorine containing solvents, total 0.05 Class I or Class II ozone-de

38、pleting chemicals as defined in 40 CFR 82. 0.01 Ethyl benzene 0.05 Methyl, ethyl, and butyl mono-ethers of ethylene glycol or the acetates thereof, total (methyl, ethyl, and butyl cellosolves, and methyl, ethyl, and butyl cellosolve acetates) 0.05 Methyl ethyl ketone (MEK) 0.05 Methyl isobutyl keton

39、e (MIBK) 0.05 Toluene 0.Xylene (all forms), total 0.1 3.4.3 Hazardous pigments and additives. When tested as specified in 4.5.21, the content of each soluble metal and the total content of each metal in the coating shall be less than the values specified in table II. In addition, asbestos and asbest

40、os form pigments shall not exceed 0.5 weight per cent of the dry paint film (see 4.5.21). Crystalline silica shall not exceed 100 milligrams per liter (mg/L). TABLE II. Metals content for coatings using alternate pigments. Soluble metal and its compound in each individual dry paint Soluble content,

41、maximum, mg/L Total content, maximum, wt% Antimony 15 0.015 Arsenic 5 0.00Barium (excluding barite) 100 0.10 Beryllium 0.75 0.0002 Cadmium 1 0.0005 Chromium (VI) 1 0.001 Chromium and chromium (III) 560 0.56 Cobalt 50 0.005 5 Provided by IHSNot for ResaleNo reproduction or networking permitted withou

42、t license from IHS-,-,-MIL-DTL-24441D(SH) TABLE II. Metals content for coatings using alternate pigments Continued. Soluble metal and its compound in each individual dry paint Soluble content, maximum, mg/L Total content, maximum, wt% Copper 25 0.01 Fluoride salts 180 0.18 Lead 5 0.005 Mercury 0.2 0

43、.0002 Molybdenum 350 0.35 Nickel 20 0.02 Selenium 1 0.002 Silver 5 0.001 Tantalum 100 0.100 Thallium 7 0.007 Tungsten 100 0.100 Vanadium 24 0.01 Zinc 25 0.25 3.4.4 Toxicity. The materials used in the coating compound, unless specific material maximum levels are cited herein (see 3.4.2 and 3.4.3), sh

44、all have no known carcinogenic or potentially carcinogenic materials identified by OSHA (29 CFR 1990) as regulated carcinogens, or IARC latest monographs, or the latest annual report of the NTP; and shall have no extremely hazardous substances (EHS) or toxic chemicals identified in 29 CFR 1910.1000,

45、 40 CFR 355, and 40 CFR 372, respectively. The manufacturer is responsible for maintaining carcinogenic free, extremely hazardous substance free, and toxic chemical free materials. The manufacturer shall not, unless specific material maximum levels are cited herein, allow the addition of any of thes

46、e prohibited materials to the formulation; and when any of these prohibited materials are/may be present, as a result of being present as a trace or impurity in another ingredient(s), the concentration of the prohibited material shall not equal or exceed 0.1 percent by weight of the coating compound

47、. Questions pertinent to this toxic effect shall be referred by the contracting activity to the qualifying activity. The qualifying activity will act as advisor to the contracting activity. The qualifying activity will arrange for review of questions by the appropriate departmental medical service.

48、3.4.5 Recycled, recovered, or environmentally preferable materials. Recycled, recovered, or environmentally preferable materials should be used to the maximum extent possible provided that the material meets or exceeds the operational and maintenance requirements, and promotes economically advantage

49、ous life cycle costs. 3.5 Conformance requirements. The paint shall conform to all conformance requirements specified in table III. 3.5.1 Qualification requirements. The paint shall conform to all qualification requirements specified in 3.6 and the applicable specification sheets as identified in table III (see 4.2). 3.6 Qualitative requirements. Qualitative requirements shall be as specified in 3.6.1 through 3.6.10: 3.6.1 Brushing pro