NAVY MIL-I-17433 C-1986 INHIBITOR HYDROCHLORIC ACID DESCALING AND PICKLING SOLUTIONS《盐酸除锅垢和酸洗溶液抑制剂》.pdf

1、I MIL-I-L7433C 68 m 7777706 OLL7082 4 m H- 13-25 2 MIL-I-l7433C(SH) 4 June 1986 SUPERSEDING MIL-I-l7433B(SHIPS) 22 May 1969 (See 6.5) MILITARY SPECIFICATION INHIBITOR, HYDROCHLORIC ACID DESCALING AND PICKLING SOLUTIONS This specification is approved for use within the Naval Sea Systems Command, Depa

2、rtment of the Navy, and is available for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 - Scope. This specification covers liquid inhibitors for minimizing the deleterious effects of hydrochloric (muriatic) acid on metal, while not interfering with the removal of eith

3、er waterside deposits or corrosion products present on the surface. 2. APPLICABLE DOCUMENTS 2.1 Government documents. 2.1.1 Specifications and standards. The following specifications and standards form a part of this specification to the extent specified herein. Unless otherwise specified, the issue

4、s of these documents shall be those listed in the issue of the Department of Defense Index of Specifications and Standards (DoDISS) and supplement thereto, cited in the solicitation. SPECIFICATIONS FEDERAL PPP-C-96 - Cans, Metal 28 Gage and Lighter. PPP-P-704 - Pails, Metal: (Shipping, Steel, 1 thro

5、ugh 12 Gallons). Beneficial comments (recommendations, additions, deletions) and any pertinent data which may be of use in improving this document should be addressed to: Commander, Naval Sea Systems Command, SEA 5523, Department of the Navy, Washington, DC 20362-5101 by using the self-addressed Sta

6、ndardization Document Improvement Proposal (DD Form 1426) appearing at the end of this document or by letter. AMSC NIA FSC 6850 DISTRIBUTION STATEMENT A Approved for public release; distribution unlimited /THIS DOCUMENT CONTAINS - B- - PAGES. Licensed by Information Handling ServicesProvided by IHSN

7、ot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-I- 17 43 3C( SH) MILITARY MIL-T-16286 - Tubes, Steel, Seamless, Marine Boiler MIL-B-26701 - Bottles, Screw Cap and Carboys Polyethylene Application. Plastic. STANDARDS FEDERAL FED-STD-313 - Material Safety Data She

8、ets Preparation and the Submission of. MILITARY MIL-STD-105 - Sampling Procedures and Tables for Inspection MIL-STD-129 - Marking for Shipment and Storage. MIL-STD-147 - Palletized Unit Loads. by Attributes. 2.1.2 Other Government document. The following other Government document forms a part of thi

9、s specification to the extent specified herein. Unless other- wise specified, the issue shall be that in effect on the date of the solicitation. DEPARTMENT OF TRANSPORTATION Code of Federal Regulations, Title 49 (Application for copies should be addressed to the Superintendent of Documents, U.S. Gov

10、ernment Printing Office, Washington, DC 20402.) (Copies of specifications, standards and other Government documents required by contractors in connection with specific acquisition functions should be obtained from the contracting activity or as directed by the contracting activity.) 2.2 Other public

11、ations. The following documents form a part of this speci- fication to the extent specified herein. Unless otherwise specified, the issues of the documents which are DoD adopted shall be those listed in the issue of the DoDISS specified in the solicitation. Unless otherwise specifed, the issues of d

12、ocuments not listed in the DoDISS shall be the issue of the nongovernment docu- ments which is current on the date of the solicitation. NATIONAL MOTOR FREIGHT TRAFFIC ASSOCIATION, INC., AGENT National Motor Freight Classification (Application for copies should be addressed to the National Motor Frei

13、ght Traffic Association, Inc., ATA TRAFFIC Dept., 2200 Mill Road, Alexandria, VA 223 14.) 2 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-e 1 MIL-I-L7433C 68 77777Ob OLL7084 UNIFORM CLASSIFICATION COMMITTEE AGENT Uniform Freight Classification Rati

14、ngs, Rules and Regulations (Application for copies should be addressed to the Uniform Classification Committee Agent, Tariff Publication Officer, Room 1106, 222 South Riverside Plaza, Chicago, IL 60606.) (Nongovernment standards and other publications are normally available from the organizations wh

15、ich prepare or which distribute the documents. These documents also may be available in or through libraries or other informational services.) 2.3 Order of precedence. In the event of a conflict between the text of this specification and the references cited herein (except for associated detail spec

16、ifications, specification sheets or MS standards), the text of this specifi- cation shall take precedence. Nothing in this specification, however, shall supersede applicable laws and regulations unless a specific exemption has been obtained. 3. REQUIREMENTS 3.1 Weight loss. When tested as specified

17、in 4.5.2, the weight loss shall not exceed 0.0020 pound per square foot per hour. 3.2 Staining and filming of metal. The inhibited hydrochloric acid solu- tion shall not cause filming, staining, or deposit on metal surfaces. These effects will be ascertained from visual observation of specimens foll

18、owing the test as specified in 4.5.2.2. 3.3 Arsesiic. The inhibitor shall contain not more than 0.01 percent of arsenic when tested as specified in 4.5.3. 3.4 Inhibitor strength. Inhibitor use concentrations shall not exceed 0.2 percent by weight (see 4.5.1.1) and must limit metal loss as specified

19、in 3.1. 3.4.1 Compatibility. The inhibitor at concentrations required as specified in 3.4 must be compatible with the acid solution as formulated and as specified in 4.5.1.1. No adherent deposits shall form on the metal surfaces and copper plating shall not occur. 3.5 Precautionary labeling. Complet

20、e, concise instructions for use of the inhibitor, as well as safety precautions, shall be legibly labeled in a durable manner on the container (see 5.3). 3.6 Material safety data sheet. The contracting activity shall be provided a material safety data sheet (MSDS) at the time of contract award. The

21、MSDS form and requirements for its preparation are found in FED-STD-313. The MSDS shall be included with each shipment of the material covered by this specification. The MSDS shall provide available pertinent toxicity information, and delineate accep- table personal protective measures for use when

22、applying the product (see 6.3). Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-I-37433C b 7977706 0337085 T r, -= 3.7 The material shall have no adverse effect on the health of personnel when used for its intended purpose and when handled as rec

23、ommended. Questions pertinent to this effect shall be referred by the contracting activity to the appropriate departmental medical service who will act as an advisor to the contracting agency. 3.8 Workmanship. The product shall be manufactured in a manner to produce an inhibitor that is completely m

24、iscible in hydrochloric acid to provide maximum metal protection. 4. QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchase order, the contractor is responsible for the performance of all inspection requirements as specified herein. Exc

25、ept as otherwise specified in the contract or purchase order, the contractor may use his own or any other facilities suitable for the performance of the inspection requirements specified herein, unless disapproved by the Government. The Government reserves the right to perform any of the inspections

26、 set forth in the specification where such inspections are deemed necessary to assure supplies and services conform to prescribed requirements. 4.1.1 Responsibility for compliance. Al1 items must meet all requirements of sections 3 and 5. The inspection set forth in this specification shall become a

27、 part of the contractors overall inspection system or quality program. The absence of any inspection requirements in the specification shall not relieve the contractor of the responsibility of assuring that all products or supplies submitted to the Government for acceptance comply with all requireme

28、nts of the contract. Sampling in quality conformance does not authorize submission of known defective material, either indicated or actual, nor does it commit the Government to acceptance of defective material. 4.1.2 The contractor shall have the toxicological formulations and associated information

29、 available for review by the contracting activity to evaluate the safety of the material for the proposed use. 4.2 Quality conformance inspection. 4.2.1 Sampling for quality conformance. 4.2.1.1 - Lot. For purposes of sampling, a lot shall consist of all material manufactured as one batch and offere

30、d for delivery at one time. 4.2.1.2 Sampling for tests. From each inspection lot, the inspector shall select two containers at random. From each of the two containers, 1-pint samples shall be taken and placed in separate clean, dry, metal or glass containers, sealed and marked. 4.2.1.3 Sampling for

31、examination of filled containers. A random sample of filled containers shall be selected from each lot in accordance with MIL-STD-105, at inspection level I, with an acceptable quality level (AQL) of 2.5 percent defective to verify compliance with this specification regarding fill, closure, marking

32、and other requirements not involving tests. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-_ MIL-I-17433C 68 W 7777706 OLL7086 L W i- 5 MIL-1-1 7 433C( SH) 4.3 Examination of filled containers. Each sample filled containers shall be examined for def

33、ects of construction of the container and the closure, for evidence of leakage, and for unsatisfactory markings; each filled container shall also be weighed to determine the amount of contents. Any container in the sample having one or more defects, or under required fill, shall be rejected, and if

34、the number of defective containers in any sample exceeds the acceptance number for the appropriate sampling plan in accordance with MIL-STD-105, the lot represented by the sample shall be rejected. mitted for acceptance tests, provided the manufacturer has removed or repaired all nonconforming conta

35、iners. Rejected lots may be resub- 4.4 Quality conformance testing. Each of the samples selected as speci- fied in 4.2.1.2 shall be subjected to the tests as specified in 4.5.1, 4.5.2, and 4.5.3. If a sample fails to comply in any respect to this specification, the lot which it represents shall be r

36、ejected. Rejected lots may be resubmitted for acceptance tests, provided the manufacturer has removed or reworked all non- conforming products. 4.5 Test procedures. 4.5.1 Preparation of inhibited acid solution. 4.5.1.1 The inhibited acid solution shall be formulated as follows: Hydrochloric acid, 23

37、“ Baume (specific gravity (sp. gr.) 1.19, assay 37 percent) 120 milliliters (mL) Ferric chloride (FeC13 . 6H2O) 15 grams Cupric chloride (CuC12 . 2H20) 0.31 grams 1, 3 Diethylthiourea (DETU) 5.2 grams Inhibitor, concentration final concentration not to exceed 0.2 percent by weight Distilled water su

38、fficient amounts to obtain 500 mL of inhibited acid solution 4.5.1.2 Heat solution to 170 + 2 degrees Fahrenheit (OF); (76.6 + 1 degrees Celsius (OC) stir and pour 150 mL into each of two tall form beakers (approxi- mately 2-1/8 inch (54 millimeters (mm) diameter, 3-7/8 inch (98 mm) depth) containin

39、g a 1/8 inch (3 mm) glass rod bent into a V shape to support test specimens during evaluations. 4.5.2 Weight loss. 4.5.2.1 Specimen preparation. A class G boiler tube (2-inch (51 mm) diameter) in accordance with MIL-T-16286 shall be split, cut and machined into l-inch (26-m) lengths of half-tubes. B

40、efore testing, the specimens shall be degreased in acetone and wiped dry. placing the specimen in concentrated hydrochloric acid heated to approximately Corrosion products shall be removed by T Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-125F (51

41、.6“C) until removal is accomplished (usually about 5 minutes). Speci- mens shall then be rinsed with water, dipped in acetone, and wiped dry. Total surface area shall be measured to the nearest 1/64 inch (0.4 mm). Wire brushing is then applied, followed by a momentary exposure to the acid and a wate

42、r rinse. The specimens are then dipped in acetone, air dried and placed in a desiccator prior to weighing. The weight of each specimen shall be determined to the nearest milligram. Stress relieving shall not be applied to the boiler tube specimens. 4.5.2.2 Test specimens shall be placed in beakers c

43、ontaining the descalant solution described and as specified in 4.5.1.1. (76.6“C) and placed in a thermostatically controlled water bath maintained at 170 5 2F (76.6 + 1C). Specimens shall remain in contact with acid for 6 hours, then removed, rinsed with hot (140 to 150F) (60 to 65.5“C) water, dippe

44、d in ace- tone, air dried and weighed. Weight loss in grams per 6 hours shall be converted to pounds per square foot per hour. Determinations shall be run in duplicate and averaged. .Results shall agree within 10 percent of the mean or the test shall be repeated. Acid shall be heated to 170F 4.5.3 A

45、rsenic content. This test shall be conducted as follows: Place 10 grams of the sample in a 200 mL flask. 75 mL HC1 (sp. gr. 1.09). Mix well, insert a thermometer and arrange the flask and condenser for downward distillation. solution into 150 mL of cold water contained in a 400 mL beaker cooled in a

46、n ice or cold-water bath. in the beaker. The temperature of the vapors during distillation, shall remain below 223F (106C); otherwise halt the distillation, cool the flask, and add 34 mL of concen- trated HC1 before continuing the distillation. Neutralize the distillate care- fully with 25 percent N

47、aOH solution, then add 1:l HC1 until just acid. Add 15 mL to 20 mL of cold-saturated NaHC03 solution. Add 1 gram of KI crystals and 5 mL of 1 percent starch solution. Stir until the KI is dissolved and titrate with 0.01N iodine solution. Add 5 grams cuprous chloride and Distill approximately 35 mL o

48、f the (The condenser tip should dip below the surface of the water The distillation should be watched carefully to avoid suck-back.) Percent arsenic = 3.75 AN W Where : A = mL of iodine solution used. N = normality of iodine solution. W = weight of sample. 4.6 Inspection of packaging. Sample package

49、s and packs, and the inspect- ion of the preservation-packaging, packing and marking for shipment and storage shall be in accordance with the requirements of section 5 and the documents specified therein. 5. PACKAGING (The packaging requirements specified herein apply only for direct Government acquisition.) Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-3. i MIL-I- 1 7 433 C ( SH) 5.1 Pres