1、852B2018( )( )11. 1 mol 0 1 MPa2 Q W U H S A G12.471 J.K-1mol-113J.K-1mol-1(15 )2. 338K( 101.325kPa)35.32 kJ.mol-1338 K80 dm3150 kPaQ U H S A G (15 )3. () ( )4. ( )xBxOT/K xB/10-6xO/10-5298.15 7.01 6.12315.15 4.34 8.05(1) KOB(2) 2(3) (15 )5. C2H4(g) + H2O(g)= C2H5OH(g)Tr mG$/ (J.mol-1) =-3.47 104+26
2、4(T/K) ln(T/K) +45.2 (T/K)(1) r mH$T(2) 573K K(3) 573Kr mS$(15 )6. N2(g)+3 H2(g) = 2 NH3(g) 298K-46.11 kJ.mol-1(1) (2) ( )7. (Cu) (La)(1) ( )3(2) (3) 0.2 1000(4) 0.8 ?(15 )8. CaCO3(s) CaO(s) CO2(s) T( )9. A1kB A2kC BC(1) 800K A 138.6s A99.9%(2) ( ) 800K A 99.9%1837s (k1+k2)(3) 800K k12.71 10-3s-1k2cB/cC(4) 800K Ea1=70 kJ.mol-1Ea2(5) (15 )10. 298K Zn(s) | ZnCl2(a) | Hg2Cl2(s) | Hg(l)1.2272 V ( E /T)p-4.52 10-4V.K-1E (Zn2+|Zn)=-0.7630V E (Cl-|Hg2Cl2|Hg)=0.2676V(1) (2) ZnCl2a(3) 298 KrGm rSm rHmQr(15 )11. 291 K c=0aln(1+bc)0a b(1) c4(2) ( bc1)a=0.0130 N.m-1(3) (1) ? (4) (15 )12. ( )
