1、 MIL-PRF-32359 23 August 2012_ PERFORMANCE SPECIFICATION CLEANER, GENERAL, FOR GROUND VEHICLES AND GROUND SUPPORT EQUIPMENT, HAP-FREE This specification is approved for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers general cleaners (e
2、xcludes petroleum products) that are hazardous air pollutant (HAP) free and many of which contain either a low content of volatile organic compounds (VOC) or are composed entirely of exempt VOCs, for use on military systems. The word cleaners throughout the specification means both general cleaners
3、and cleaning compounds (more than one component). All classifications and requirements refer to the cleaner at the concentration for which it is to be used. 1.2 Classification. The cleaners are of the following classes, types, and grades, as specified (see 6.2). 1.2.1 Classes. The classes of cleaner
4、s are based on containing or not containing water and are as follows: Class 1 - Aqueous (contains water). Class 2 - Non-aqueous (does not contain water). 1.2.2 Types. The types of cleaners are based on VOC and vapor pressures and are as follows: Type I - VOC exempt/VOC free. Type II - A maximum vapo
5、r pressure 1 mm Hg at 20 C (68 F). Comments, suggestions, or questions on this document should be addressed to: Director, U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Materials and Manufacturing Technology Branch, Specifications and Standards Office, Attn: RDRL-WMM-D, A
6、berdeen Proving Ground, MD 21005-5069 or emailed to richard.j.squillacioti.civmail.mil. Since contact information can change, you may want to verify the currency of this address information using the ASSIST Online database at https:/assist.dla.mil. AMSC N/A FSC 6850 DISTRIBUTION STATEMENT A: Approve
7、d for public release; distribution is unlimited. METRIC Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32359 2 Type III - A maximum vapor pressure 7 mm Hg at 20 C (68 F). Type IV - A VOC level 25g/L and a maximum vapor pressure 7 mm Hg at 20
8、C (68 F). Type V - No limit on VOC level or vapor pressure. 1.2.3 Grades. The cleaners and cleaning compounds are of the following grades based on evaporation rate. Grade A - An evaporation rate 1.0 (where n-butyl acetate = 1.0). Grade B An evaporation rate 1.0 and 0.1 (where n-butyl acetate = 1.0).
9、 Grade C - An evaporation rate 1.0 GRADE: B - Evaporation rate 1.0 and 0.1 GRADE: C - Evaporation rate 60oC (140oF) pH of Aqueous Solutions ASTM E70 3.0 and 10.0 N/A VOC content, g/L SCAQMD Method 313 See type classifications for requirements (see 1.2.2). Vapor pressure, mm Hg 40 CFR 63.750 See type
10、 classifications for requirements (see 1.2.2). Nonvolatile Matter in Volatile Solvents ASTM D1353 8 mg/100 mL Cleaning Efficiency 4.9.3 The cleaning efficiency shall be greater than 75%. Low Temperature Stability 4.9.4 The undiluted cleaning compound shall be homogeneous and shall not separate, laye
11、r, or visibly deteriorate. Accelerated Storage Stability 4.9.5 No separation or effect on steel strip. Cleaning efficiency shall be no less than freshly made control formula. Shelf-life See 6.2 (b) one copy Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS
12、-,-,-MIL-PRF-32359 14 of the MSDS (see 6.5); (c) certification that the manufacturers material meets the HAP and VOC content requirement (see Table I, 1.2.2 and 3.2.2). 6.3.1.1 Qualification inspection sample identification. Qualification inspection samples are to be forwarded to the laboratory desi
13、gnated in the letter of authorization (see 6.3) and identified as follows: QUALIFICATION TEST SAMPLES Specification MIL-PRF-32359; Class 1 or 2; Type I, II, II, IV, or V; Grade A, B, or C (as applicable) CLEANER, GENERAL, FOR GROUND VEHICLES AND GROUND SUPPORT EQUIPMENT, HAP-FREE Manufacturers name
14、and product number Submitted by (name and date) for qualification testing in accordance with authorization (reference authorizing letter) 6.3.2 Testing facilities. The testing facilities identified below can each do some of the required tests, however, all the tests can be performed by a combination
15、 of those facilities listed below. Please note that this list is not an exclusive list. The list was prepared for your convenience only. There are other facilities that are capable of performing the required tests. The South Coast Air Quality Management District (SCAQMD) can perform only the combine
16、d VOC Content and Vapor Pressure tests. SMI, Inc. 12219 SW 131 Avenue Miami, FL 33186-6401 USA Ph: 305-971-7047 Attn: Patricia D. Viani, President Petro-Lube Test Labs. 116 Sunset Inn Road P.O. Box 300 Lafayette, NJ 07848 Ph: 973-579-3448 Attn: Josiah Wintermute South Coast Air Quality Management Di
17、strict 21865 Copley Dr. Diamond Bar, CA 91765 Ph: 909-396-2000 6.3.2.1 Test methods estimated quantity and costs. The quantity and costs for the specific tests required by this document are given below in Table VII. These costs are typical and may be somewhat different from those found in new quotes
18、. The approximate time to complete all tests is ten weeks. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32359 15 TABLE VII. Quantity and costs for required tests SPECIFIC TEST TEST METHOD QUANTITY (mL) APPROXIMATE COST Total Immersion Corr
19、osion Test ASTM F483 (5 specimens) 1000 $900 Corrosion of Low-Embrittling Cadmium Plate ASTM F1111 400 $200 Sandwich Corrosion Test ASTM F1110 200 $500 Hydrogen Embrittlement ASTM F519 (type 1a specimens) 400 $600 Effect of Cleaners on Unpainted Surfaces ASTM F485 800 $200 Stress Corrosion of Titani
20、um Alloys ASTM F945 400 $500 Effects on Painted Surfaces ASTM F502 (6 specimens) 400 $800 Stress Crazing of Acrylic Plastics ASTM F484 (types A and C) 200 $300 Rubber Property - Effect of Liquids ASTM D471 (11 specimens) 800 $1,500 Flash Point ASTM D56 100 $300 pH of Aqueous Solutions ASTM E70 100 $
21、100 VOC content, g/L SCAQMD Method 313 200 $800 Vapor pressure, mm Hg 40 CFR 63.750 Nonvolatile Matter in Volatile Solvents ASTM D1353 200 $300 Cleaning Efficiency FED-STD-791, Method 7502 (MIL-PRF-680, App A) 1200 $300 Low Temperature Stability MIL-PRF-85570D, section 4.5.8 100 $100 Accelerated Sto
22、rage Stability MIL-PRF-85570D, section 4.5.2 1200 $400 Copper Strip Corrosion ASTM D130 200 $200 Evaporation Rate ASTM E2008 100 $400 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32359 16 6.4 Definitions. 6.4.1 Carcinogens. The Occupationa
23、l Safety and Health Administration (OSHA) definition of carcinogens is those chemicals / processes appearing in lists 1, 2A, and 2B of the International Agency for Research on Cancer (IARC) 1/; substances known to be carcinogenic and occupational exposures associated with a technological process kno
24、wn to be carcinogenic by the National Toxicology Program (NTP) Report on Carcinogens (latest annual report)2/; and OSHA regulated carcinogens3/. 1/Copies of these volumes may be found in medical libraries or through the World Health Organization, 1211 Geneva 27, Switzerland. 2/Copies may be obtained
25、 from the Public Health Service, National Toxicology Program, Public Information Office, P.O. Box 12233, MD B2-04, Research Triangle Park, NC 27709 or at http:/ntp-server.niehs.nih.gov. 3/Copies may be found in 29 CFR part 1910 Subpart Z. 6.4.2 Hazardous Air Pollutant (HAP). HAP is defined as any su
26、bstance listed under Section 112 of the Clean Air Act or its modifications. The text of the Clean Air Act, listed pollutants and modifications are kept by the Environmental Protection Agency (EPA) and are accessible through the website: http:/www.epa.gov. 6.4.3 Volatile organic compound (VOC). VOC i
27、s defined in 40 CFR Part 51.100 (s). Volatile organic compounds (VOC) means any compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, which participates in atmospheric photochemical reactions. For the latest complete de
28、finition of VOC see: http:/www.epa.gov/ttn/naaqs/ozone/ozonetech/def_voc.htm. 6.4.3.1 Exempt VOC. A list of exempt VOC is listed in 40 CFR Part 51.100 (s). For the current list of exempt organic compounds see: http:/www.epa.gov/ttn/naaqs/ozone/ozonetech/def_voc.htm. Compounds that are explicitly exe
29、mpted from regulation by the EPA as VOCs are those compounds of carbon that have negligible photochemical reactivity (they do not produce ozone in atmospheric reactions). 6.4.4 Hand-wipe cleaning. Hand-wipe cleaning operation means the removal of contaminants such as dirt, grease, oil, and coatings
30、from a substrate by physically rubbing with a material such as a rag, paper, or cotton swab that has been moistened with a cleaning solvent. 6.5 Material Safety Data Sheet (MSDS). An MSDS must be prepared and submitted in accordance with FED-STD-313. The MSDS must also meet the requirements of 29 CF
31、R 1910.1200. The 29 CFR 1910.1200 requires that the MSDS for each hazardous chemical used in an operation must be readily available to personnel using the material. Questions pertinent to the effect(s) of these cleaners on the health of personnel using them should be referred by the procuring activi
32、ty to the appropriate medical service, who will act as its adviser. Contracting officers will identify the activities requiring copies of the MSDS. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32359 17 6.6 Shelf-life. This specification co
33、vers items where the assignment of a Federal shelf-life code is a consideration. Specific shelf-life requirements should be specified in the contract or purchase order, and should include, as a minimum, shelf-life code, shelf-life package markings in accordance with MIL-STD-129 or FED-STD-123, prepa
34、ration of a materiel quality storage standard for type II (extendible) shelf-life items, and a minimum of 85 percent shelf-life remaining at time of receipt by the Government. These and other requirements, if necessary, are in DoD 4140.27-M, Shelf-life Management Manual. The shelf-life codes are in
35、the Federal Logistics Information System Total Item Record. Additive information for shelf-life management may be obtained from DoD 4140.27-M, or the designated shelf-life Points of Contact (POC). The POC should be contacted in the following order: (1) the Inventory Control Points that manage the it
36、em and (2) the DoD Service and Agency administrators for the DoD Shelf-Life Program. Appropriate POCs for the DoD Shelf-Life Program can be contacted through the DoD Shelf-Life Management website: https:/www.shelflife.hq.dla.mil/ 6.7 Subject term (key word) listing. Aqueous Environmental Non-aqueous
37、 Non-aviation Non-hazardous Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32359 18 CONCLUDING MATERIAL Custodians: Preparing activity: Army - MR Army MR Navy - SH (Project 6850-2008-003) Air Force - 68 Review activities: Army - AT, EA, GL N
38、avy - AS, CG, MC Air Force - 03, 50, 84, 99 DLA - GS, GS3 GSA - FAS MISC MP NOTE: The activities listed above were interested in this document as of the date of this document. Since organizations and responsibilities can change, you should verify the currency of the information above using the ASSIST Online database at https:/assist.dla.mil. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-
