ASME STP-TS-012-1-2012 THERMOPHYSICAL PROPERTIES OF WORKING GASES USED IN WORKING GAS TURBINE APPLICATIONS《燃气轮机使用的工作燃气的热物理特性》.pdf
《ASME STP-TS-012-1-2012 THERMOPHYSICAL PROPERTIES OF WORKING GASES USED IN WORKING GAS TURBINE APPLICATIONS《燃气轮机使用的工作燃气的热物理特性》.pdf》由会员分享,可在线阅读,更多相关《ASME STP-TS-012-1-2012 THERMOPHYSICAL PROPERTIES OF WORKING GASES USED IN WORKING GAS TURBINE APPLICATIONS《燃气轮机使用的工作燃气的热物理特性》.pdf(150页珍藏版)》请在麦多课文档分享上搜索。
1、STP-TS-012-1THERMOPHYSICAL PROPERTIES OF WORKING GASES USED IN WORKING GAS TURBINE APPLICATIONSSTP-TS-012-1 THERMOPHYSICAL PROPERTIES OF WORKING GASES USED IN GAS TURBINE APPLICATIONS Prepared by: ASME Standards Technology, LLC Air Properties Committee Date of Issuance: March 5, 2012 This report was
2、 prepared as an account of work sponsored by the ASME Standards Technology, LLC (ASME ST-LLC) Air Properties Committee. Neither ASME, ASME ST-LLC, nor others involved in the preparation or review of this report, nor any of their respective employees, members, or persons acting on their behalf, makes
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5、ons of the authors, contributors, reviewers of the report expressed herein do not necessarily reflect those of ASME ST-LLC or others involved in the preparation or review of this report, or any agency thereof. ASME ST-LLC does not take any position with respect to the validity of any patent rights a
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8、the registered trademark of the American Society of Mechanical Engineers. No part of this document may be reproduced in any form, in an electronic retrieval system or otherwise, without the prior written permission of the publisher. ASME Standards Technology, LLC Three Park Avenue, New York, NY 1001
9、6-5990 ISBN No. 978-0-7918-3403-9 Copyright 2012 by ASME Standards Technology, LLC All Rights Reserved Thermophysical Properties of Working Gases Used in Gas Turbine Applications STP-TS-012-1 iii Summary of Changes March 5, 2012 STP-TS-012-1 THERMOPHYSICAL PROPERTIES OF WORKING GASES USED IN GAS TUR
10、BINE APPLICATIONS The following changes have been made to the first revision of STP-TS-012. Rev. 1 Page Location Change iv-viii Table of Contents Updated to reflect changes 14 Table 18, row 3 Corrected from “1.50” to “-1.50” 14 Table 18, row 4 Corrected from “1.25” to “-1.25” 14 Table 18, row 5 Corr
11、ected from “0.75” to “-0.75” 14 Table 18, row 6 Corrected from “0.50” to “-0.50” 14 Table 18, row 7 Corrected from “0.25” to “-0.25” 79 Annex F Inserted NASA Tables Referenced to 77F STP-TS-012-1 Thermophysical Properties of Working Gases Used in Gas Turbine Applications iv TABLE OF CONTENTS Forewor
12、d ix Abstract . x 1 OBJECTIVE . 1 2 SCOPE 1 3 NOMENCLATURE . 1 3.1 Symbols . 1 3.2 Greek Symbols . 2 3.3 Superscripts 2 3.4 Subscripts . 2 4 GUIDING PRINCIPLES 2 4.1 Ideal Gas 2 4.1.1 NASA Approach . 3 4.1.2 VDI Approach . 3 4.1.3 Reference Temperature and Pressure 4 4.2 Real Gas . 4 4.3 Fundamental
13、 Constants, Relative Atomic Weights and Enthalpies of Formation . 4 5 IDEAL GAS . 5 5.1 Thermodynamic Properties of Mixtures of Ideal Gases 5 5.1.1 Definitions and Conversion Rules 5 5.1.2 Calculation of Density 6 5.1.3 Calculation of Isobaric Heat Capacity 7 5.1.4 Calculation of Enthalpy 7 5.1.5 Ca
14、lculation of Entropy 7 5.1.6 Calculation of Speed of Sound . 8 5.2 Ideal Gas Equations According to the NASA Scheme 8 5.3 Ideal Gas Equations According to the VDI Scheme 13 6 REAL GAS. 17 6.1 Thermodynamic Properties of Ideal Mixtures of Real Gases 18 6.2 Water Content at Saturation . 23 7 IDEAL AND
15、 REAL GAS PROPERTY DATA TABLES 25 7.1 Diatomic Oxygen (O2) . 25 7.2 Diatomic Nitrogen (N2) 28 7.3 Diatomic Hydrogen (H2) 32 7.4 Water/Steam (H2O) 34 7.5 Carbon Monoxide (CO) . 38 7.6 Carbon Dioxide (CO2) . 40 7.7 Ammonia (NH3) . 43 7.8 Methanol (CH3OH) 45 7.9 Argon (Ar) . 48 7.10 Air 51 Thermophysic
16、al Properties of Working Gases Used in Gas Turbine Applications STP-TS-012-1 v 7.11 Oxygen (O) 55 7.12 Hydrogen (H) . 56 7.13 Nitrogen (N). 58 7.14 Hydroxide (OH) . 60 7.15 Nitric Oxide (NO) 62 References 65 Acknowledgments 68 In Memory of Bonnie J. McBride 69 Abbreviations and Acronyms . 70 Annex A
17、 - Verification of Programs Using Ideal Gas Equations . 71 Annex B - Uncertainty of the Ideal Gas Equations 72 Annex C - Sulfuric Acid Dew-Points . 75 Annex D - Impact of Dissociation 76 Annex E - Sample Calculations of Gas Mixtures . 78 Annex F - NASA Tables Referenced to 77F 79 List of Tables Tabl
18、e 1 - Enthalpies of Formation 5 Table 2 - NASA Coefficients for Diatomic Oxygen (O2) 9 Table 3 - NASA Coefficients for Diatomic Nitrogen (N2) . 9 Table 4 - NASA Coefficients for Diatomic Hydrogen (H2) . 9 Table 5 - NASA Coefficients for Gaseous Water / Steam (H2O) . 10 Table 6 - NASA Coefficients fo
19、r Carbon Monoxide (CO) 10 Table 7 - NASA Coefficients for Carbon Dioxide (CO2). 10 Table 8 - NASA Coefficients for Ammonia (NH3) 11 Table 9 - NASA Coefficients for Methanol (CH3OH) . 11 Table 10 - NASA Coefficients for Argon (Ar). 11 Table 11 - NASA Coefficients for Standard Dry Air(1)11 Table 12 -
20、Composition of NASA Standard Dry (Air) 12 Table 13 - NASA Coefficients for Atomic Oxygen (O) 12 Table 14 - NASA Coefficients for Atomic Hydrogen (H) . 12 Table 15 - NASA Coefficients for Atomic Nitrogen (N) . 12 Table 16 - NASA Coefficients for Hydroxide (OH) 13 Table 17 - NASA Coefficients for Nitr
21、ic Oxide (NO) . 13 Table 18 - Temperature Exponents of the Polynomial Equations (24, 25, 27) 14 STP-TS-012-1 Thermophysical Properties of Working Gases Used in Gas Turbine Applications vi Table 19 - Substance Specific Coefficients Ak,I J.mol1.K1 of Eq. (24) for the Ideal Gas Heat Capacity According
22、to the VDI Scheme . 14 Table 20 - Substance Specific Coefficients Ck,I J.mol1 of Eq. (25) for the Ideal Gas Enthalpy According to the VDI Scheme 15 Table 21 - Substance Specific Coefficients Dk,I J.mol1.K1 of Eq. (27) for the Ideal Gas Entropy According to the VDI Scheme 16 Table 22 - O2Ideal Gas Pr
23、operties 25 Table 23 - O2Real Gas Properties 27 Table 24 - N2Ideal Gas Properties 28 Table 25 - N2Real Gas Properties 30 Table 26 - H2Ideal Gas Properties 32 Table 27 - H2O Ideal Gas Properties . 34 Table 28 - H2O Real Gas Properties . 36 Table 29 - CO Ideal Gas Properties 38 Table 30 - CO2Ideal Gas
24、 Properties . 40 Table 31 - CO2Real Gas Properties 42 Table 32 - NH3Ideal Gas Properties . 43 Table 33 - CH3OH Ideal Gas Properties . 45 Table 34 - Ar Ideal Gas Properties 48 Table 35 - Ar Real Gas Properties 50 Table 36 - Air Ideal Gas Properties 51 Table 37 - Air Real Gas Properties . 53 Table 38
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