1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN ISO 105-E04:2013Textiles Tests for colourfastnessPart E04: Colour fastness to perspiration(ISO 105-E04:2013)BS EN ISO 105-E04:2013 BRITISH STANDARDNational forewordThis Bri
2、tish Standard is the UK implementation of EN ISO 105-E04:2013. It supersedes BS EN ISO 105-E04:2009 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee TCI/81, Colour fastness and colour measurement oftextiles.A list of organizations represented on this com
3、mittee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2013. Published by BSI StandardsLimited 2013ISBN 978 0 580 74140 1ICS 59.080.0
4、1Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 April 2013.Amendments issued since publicationDate T e x t a f f e c t e dEUROPEAN STANDARD NORME EUROPENNE EUR
5、OPISCHE NORM EN ISO 105-E04 March 2013 ICS 59.080.01 Supersedes EN ISO 105-E04:2009English Version Textiles - Tests for colour fastness - Part E04: Colour fastness to perspiration (ISO 105-E04:2013) Textiles - Essais de solidit des coloris - Partie E04: Solidit des coloris la sueur (ISO 105-E04:2013
6、) Textilien - Farbechtheitsprfungen - Teil E04: Farbechtheit gegen Schwei (ISO 105-E04:2013) This European Standard was approved by CEN on 14 January 2013. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the s
7、tatus of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French,
8、 German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cr
9、oatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
10、 United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 105
11、-E04:2013: EBS EN ISO 105-E04:2013EN ISO 105-E04:2013 (E) 3 Foreword This document (EN ISO 105-E04:2013) has been prepared by Technical Committee ISO/TC 38 “Textiles“ in collaboration with Technical Committee CEN/TC 248 “Textiles and textile products” the secretariat of which is held by BSI. This Eu
12、ropean Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2013, and conflicting national standards shall be withdrawn at the latest by September 2013. Attention is drawn to the possibility that some of t
13、he elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 105-E04:2009. According to the CEN-CENELEC Internal Regulations, the national standards organizations of t
14、he following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Nether
15、lands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 105-E04:2013 has been approved by CEN as EN ISO 105-E04:2013 without any modification. BS EN ISO 105-E04:2013ISO 105-E04:2013(E) ISO 2013 All ri
16、ghts reserved iiiContents PageForeword iv1 Scope . 12 Normative references 13 Principle 14 Apparatus and materials 25 Test specimen 36 Procedure. 37 Test report . 5BS EN ISO 105-E04:2013ISO 105-E04:2013(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of n
17、ational standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. Inter
18、national organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.International Standards are drafted in accordance with the
19、rules given in the ISO/IEC Directives, Part 2.The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by a
20、t least 75 % of the member bodies casting a vote.Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights.ISO 105-E04 was prepared by Technical Committee ISO/T
21、C 38, Textiles, Subcommittee SC 1, Tests for coloured textiles and colorants.This sixth edition cancels and replaces the fifth edition (ISO 105-E04:2008), of which it constitutes a minor revision.ISO 105 consists of many parts designated by a part letter and a two-digit serial number (e.g. A01), und
22、er the general title Textiles Tests for colour fastness. A complete list of these parts is given in ISO 105-A01.iv ISO 2013 All rights reservedBS EN ISO 105-E04:2013INTERNATIONAL STANDARD ISO 105-E04:2013(E)Textiles Tests for colour fastness Part E04: Colour fastness to perspiration1 ScopeThis part
23、of ISO 105 specifies a method for determining the resistance of the colour of textiles of all kinds and in all forms to the action of human perspiration.2 Normative referencesThe following referenced documents are indispensable for the application of this document. For dated references, only the edi
24、tion cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 105-A01:2010, Textiles Tests for colour fastness Part A01: General principles of testingISO 105-A02, Textiles Tests for colour fastness Part A02: Grey scale for assessing
25、change in colourISO 105-A03, Textiles Tests for colour fastness Part A03: Grey scale for assessing stainingISO 105-A04, Textiles Tests for colour fastness Part A04: Method for the instrumental assessment of the degree of staining of adjacent fabricsISO 105-A05, Textiles Tests for colour fastness Par
26、t A05: Instrumental assessment of change in colour for determination of grey scale ratingISO 105-F01, Textiles Tests for colour fastness Part F01: Specification for wool adjacent fabricISO 105-F02, Textiles Tests for colour fastness Part F02: Specification for cotton and viscose adjacent fabricsISO
27、105-F03, Textiles Tests for colour fastness Part F03: Specification for polyamide adjacent fabricISO 105-F04, Textiles Tests for colour fastness Part F04: Specification for polyester adjacent fabricISO 105-F05, Textiles Tests for colour fastness Part F05: Specification for acrylic adjacent fabricISO
28、 105-F06, Textiles Tests for colour fastness Part F06: Specification for silk adjacent fabricISO 105-F10, Textiles Tests for colour fastness Part F10: Specification for adjacent fabric: MultifibreISO 3696, Water for analytical laboratory use Specification and test methods3 PrincipleSpecimens of the
29、textile in contact with adjacent fabrics are treated in two different solutions containing histidine, drained and placed between two plates under a specified pressure in a test device. The specimens and the adjacent fabrics are dried separately. The change in colour of each specimen and the staining
30、 of the adjacent fabrics are assessed by comparison with the grey scales or instrumentally. ISO 2013 All rights reserved 1BS EN ISO 105-E04:2013ISO 105-E04:2013(E)4 Apparatus and materials4.1 Test devices, each consisting of a frame of stainless steel into which a weight-piece of mass approximately
31、5 kg and base 60 mm 115 mm is closely fitted, so that a pressure of (12,5 0,9) kPa can be applied on test specimens measuring (40 2) mm (100 2) mm, placed between glass or acrylic-resin plates measuring approximately 60 mm 115 mm 1,5 mm. The test device shall be constructed so that, if the weight-pi
32、ece is removed during the test, the pressure remains unchanged.If the dimensions of the composite specimen differ from the size of (40 2) mm (100 2) mm, the weight-piece used shall be such that a nominal pressure of (12,5 0,9) kPa is applied to the specimen.Other devices may be used provided that eq
33、uivalent results are obtained.4.2 Oven, maintained at (37 2) C.4.3 Alkaline solution, freshly prepared, using grade 3 water complying with ISO 3696, containing, per litre: 0,5 g of l-histidine monohydrochloride monohydrate (C6H9O2N3HClH2O); 5 g of sodium chloride (NaCl);and either 5 g of disodium hy
34、drogen orthophosphate dodecahydrate (Na2HPO412H2O)or 2,5 g of disodium hydrogen orthophosphate dihydrate (Na2HPO42H2O).The solution is brought to pH 8 (0,2) with 0,1 mol/l sodium hydroxide solution.4.4 Acid solution, freshly prepared, using grade 3 water complying with ISO 3696, containing, per litr
35、e: 0,5 g of l-histidine monohydrochloride monohydrate (C6H9O2N3HClH2O); 5 g of sodium chloride (NaCl); 2,2 g of sodium dihydrogen orthophosphate dihydrate (NaH2PO42H2O).The solution is brought to pH 5,5 (0,2) with 0,1 mol/l sodium hydroxide solution.4.5 Adjacent fabrics (see ISO 105-A01).Either:4.5.
36、1 A multifibre adjacent fabric complying with ISO 105-F10.or:4.5.2 Two single-fibre adjacent fabrics, complying with the relevant document selected from ISO 105-F01 to F06.One of the adjacent fabrics shall be made of the same kind of fibre as that of the textile to be tested, or that predominating i
37、n the case of blends, the second piece being made of the fibre indicated in Table 1 or, in the case of blends, of the kind of fibre that is second in order of predominance, or as otherwise specified.2 ISO 2013 All rights reservedBS EN ISO 105-E04:2013ISO 105-E04:2013(E)Table 1 Single-fibre adjacent
38、fabricsIf first piece is: Second piece is to be:cotton woolwool cottonsilk cottonviscose woolpolyamide wool or cottonpolyester wool or cottonacrylic wool or cotton4.5.3 If required, a non-dyeable fabric (for example polypropylene).4.6 Grey scale for assessing change in colour, complying with ISO 105
39、-A02.4.7 Grey scale for assessing staining, complying with ISO 105-A03.4.8 Spectrophotometer or colorimeter for assessing change in colour and staining, complying with ISO 105-A04 and ISO 105-A05.4.9 A set of 11 glass or acrylic resin plates.4.10 Flat-bottomed dish made of inert materials.5 Test spe
40、cimen5.1 If the textile to be tested is fabric, eithera) attach a specimen measuring (40 2) mm (100 2) mm to a piece of the multifibre adjacent fabric (4.5.1), also measuring (40 2) mm (100 2) mm, by sewing along one of the shorter sides, with the multifibre fabric next to the face of the specimen;
41、orb) attach a specimen measuring (40 2) mm (100 2) mm between the two single-fibre adjacent fabrics (4.5.2), also measuring (40 2) mm (100 2) mm, by sewing along one of the shorter sides.5.2 Where yarn or loose fibre is to be tested, take a mass of the yarn or loose fibre approximately equal to one
42、half of the combined mass of the adjacent fabrics, and eithera) place it between a (40 2) mm (100 2) mm piece of the multifibre fabric (4.5.1) and a (40 2) mm (100 2) mm piece of the non-dyeable fabric (4.5.3) and sew them along all four sides (see ISO 105-A01:2010, Subclause 10.3, “Preparation of c
43、omposite specimens”); orb) place it between a (40 2) mm (100 2) mm piece of each of the two specified single-fibre fabrics (4.5.2) and sew along all four sides.6 Procedure6.1 Lay out the composite specimen smoothly in a flat-bottomed dish and cover with alkaline solution (4.3). Thoroughly wet the co
44、mposite specimen in this solution at pH 8 (0,2) at an approximate liquor ratio of 50:1, and allow it to remain in the solution at room temperature for 30 min. Press and move it ISO 2013 All rights reserved 3BS EN ISO 105-E04:2013ISO 105-E04:2013(E)from time to time to ensure good and uniform penetra
45、tion of the liquor. Pour off the solution and wipe the excess liquor off the specimen between two glass rods.Place the composite specimen between two glass or acrylic-resin plates (see 4.9), under a nominal pressure of (12,5 0,9) kPa, and place in a test device (4.1) which has been preheated to the
46、test temperature.By the same procedure, wet a composite specimen in the acid solution at pH to 5,5 (0,2) (4.4) and then test it in a separate pre-heated test device.NOTE Up to 10 test specimens, each separated from the next by one plate, can be tested in one test device simultaneously. If less than
47、10 specimens are prepared, all 11 plates must still be used to maintain the correct nominal pressure.6.2 Place the test device containing the composite specimen in the oven (4.2) for 4 h at (37 2) C, positioning it so that the test specimens are in either the horizontal position (Figure 1) or the ve
48、rtical position (Figure 2) depending on the type of device available.Figure 1Figure 26.3 Open out each composite specimen (by breaking the stitching except on one of the shorter sides, if necessary) and dry it by hanging it in air at a temperature not exceeding 60 C, with the two or three parts in c
49、ontact only at the line of stitching.6.4 Assess the change in colour of each specimen and the staining of the adjacent fabric(s) by comparison with the grey scales (4.6 and 4.7) or instrumentally (see ISO 105-A04 and ISO 105-A05).In many cases of cellulosic fibres dyed with direct dyes containing copper, or after treatment with copper salts, the prescribed tests and natural perspiration bring about a removal of
