1、BRITISH STANDARD BS EN ISO 10363:1995 Hot-melt adhesives Determination of thermal stability The European Standard EN ISO 10363:1995 has the status of a British Standard ICS 83.180 UDC 665.93:620.193.94BSENISO10363:1995 This British Standard, having been prepared under the directionof the Sector Boar
2、d forMaterials and Chemicals, waspublished under the authorityof the Standards Boardand comes into effect on 15 December 1995 BSI 12-1999 The following BSI references relate to the work on this standard: Committee reference STI/52 Draft for comment 91/54357 DC ISBN 0 580 24494 6 Committees responsib
3、le for this BritishStandard The preparation of this British Standard was entrusted to Technical Committee STI/52, Adhesives, upon which the following bodies were represented: British Adhesives and Sealants Association British Plastics Federation British Steel Industry Centre for Adhesive Technology
4、Chemical Industries Association Contract Flooring Association Department of the Environment (Building Research Establishment) Department of Trade and Industry (National Physical Laboratory) European Resin Manufacturers Association Federation of the Electronics Industry Institute of Materials Ministr
5、y of Defence Society of Motor Manufacturers and Traders Timber Research and Development Association University of Bristol Welding Institute Amendments issued since publication Amd. No. Date CommentsBSENISO10363:1995 BSI 12-1999 i Contents Page Committees responsible Inside front cover National forew
6、ord ii Foreword 2 1 Scope 3 2 Normative references 3 3 Principle 3 4 Apparatus 3 5 Procedure 3 6 Expression of results 4 7 Precision 4 8 Test report 4 Annex A (informative) Example of expression of results 5BSENISO10363:1995 ii BSI 12-1999 National foreword This British Standard has been prepared by
7、 Technical Committee STI/52 and is the English language version of EN ISO 10363:1995 Hot-melt adhesives Determination of thermal stability, published by the European Committee for Standardization (CEN). EN ISO 10363 was produced as a result of international discussion in which the United Kingdom par
8、ticipated. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document
9、 comprises a front cover, an inside front cover, pagesi andii, theENISO title page, pages2 to5 and a back cover. This standard has been updated (see copyright date) and may have had amendments incorporated. This will be indicated in the amendment table on the inside front cover.EUROPEAN STANDARD NOR
10、ME EUROPENNE EUROPISCHE NORM EN ISO 10363 June 1995 ICS 83.180 Descriptors: Plastics, adhesives, thermofusible materials, tests, determination, thermal stability English version Hot-melt adhesives Determination of thermal stability (ISO 10363:1992) Adhsifs thermofusibles Dtermination de la stabilit
11、thermique (ISO 10363:1992) Schmelzklebstoffe Bestimmung der thermischen Bestndigkeit (ISO 10363:1992) This European Standard was approved by CEN on 1995-05-11. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard t
12、he status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, Germa
13、n). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Denmark, Finland, France, Ge
14、rmany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom. CEN European Committee for Standardization Comit Europen de Normalisation Europisches Komitee fr Normung Central Secretariat: rue de Stassart 36, B-1050 Brussels 1995 Cop
15、yright reserved to CEN members Ref. No. EN ISO 10363:1995 EENISO10363:1995 BSI 12-1999 2 Foreword The text of the International Standard from ISO/TC 61 “Plastics” of the International Organization for Standardization (ISO) has been taken over as a European Standard by the Technical Committee CEN/TC
16、193 “Adhesives”. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by December 1995 and conflicting national standards shall be withdrawn at the latest by December 1995. According to the CEN/CENELEC In
17、ternal Regulations, the following countries are bound to implement this European Standard: Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the United Kingdom.ENISO10363:1995 BSI 12-1999 3
18、1 Scope This International Standard specifies a method for determining the thermal stability of non-reactive hot-melt adhesives at temperatures up to 260 C. 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this Internat
19、ional Standard. At the time of publication, the editions indicated were valid. All standards are subject to revision, and parties to agreements based on this International Standard are encouraged to investigate the possibility of applying the most recent editions of the standards indicated below. Me
20、mbers of IEC and ISO maintain registers of currently valid International Standards. ISO 1770:1981, Solid-stem general purpose thermometers. ISO 2555:1989, Plastics Resins in the liquid state or as emulsions or dispersions Determination of apparent viscosity by the Brookfield Test method. ISO 4625:19
21、80, Binders for paints and varnishes Determination of softening point Ring-and-ball method. 3 Principle A quantity of hot-melt adhesive is heated under specified conditions. Samples are taken at regular time intervals and any changes in viscosity and in softening point (determined by the “ring-and-b
22、all” method) during heating are noted. The maximum temperature and the duration of the test are fixed by agreement between the adhesive user and manufacturer. 4 Apparatus 4.1 Stainless-steel or glass vessel, external diameter65 mm, height 95 mm, equipped with a loose-fitting lid. 4.2 Oil bath, stirr
23、ed and capable of being maintained at the operating temperature recommended by the manufacturer of the hot-melt adhesive. Alternatively, a ventilated oven may be used instead of the oil bath. The oven or bath shall be capable of heating the sample to within 2 C of the required temperature. 4.3 Glass
24、 stirring rod 4.4 Apparatus for measuring the softening point by the “ring-and-ball” method as specified in ISO 4625. 4.5 Apparatus for measuring viscosity, in accordance with ISO 2555. 4.6 Thermometer, complying with type T of ISO1770. 4.7 Balance, capable of weighing to the nearest 0,1g. 5 Procedu
25、re WARNING For reasons of health and safety, conduct the tests in a ventilated space with a fume extraction system. 5.1 Place the stainless-steel or glass vessel (4.1) in the oil bath or oven (4.2) regulated to heat the sample to within 2 C of the operating temperature recommended by the manufacture
26、r of the hot-melt adhesive. 5.2 Add a sufficient quantity of the hot-melt adhesive under test to the vessel. Mix well with the glass stirring rod (4.3) until the sample has melted completely. Measure the temperature by inserting the thermometer (4.7) into the sample. Start the timing from this point
27、. Continue to heat the adhesive for 2 h at the operating temperature 2 C to establish thermal equilibrium. 5.3 Measure, at the operating temperature 2 C, the viscosity in accordance with ISO 2555, making the measurement directly in the stainless-steel or glass vessel, or with the aid of the rotary v
28、iscosimeter four measuring viscosity in the molten state. Using the appropriate amount of adhesive, measure the softening point by the “ring-and-ball” method as specified in ISO 4625. 5.4 Repeat all the operations described in 5.3 at regular time intervals of between 4 h and 6 h, until the time, bas
29、ed on pre-determined criteria, for stopping the test is reached. Record the criteria used and the duration of the test in the test report. If skin formation is observed on the surface of the hot-melt adhesive, the skin shall be removed before each subsequent viscosity measurement. If it is not possi
30、ble to carry out the tests every 4 h to6 h, care shall be taken to ensure that any gaps in the timing do not occur towards the end of the useful life, of the adhesive. 5.5 At the time that each measurement is taken, observe and record whether or not a skin has formed on the surface of the adhesive;
31、fumes are being given off; phase separation has occurred; gelation has occurred; sedimentation has occurred; any change in colour has occurred.ENISO10363:1995 4 BSI 12-1999 6 Expression of results Tabulate the viscosity in pascal seconds and the softening point in degrees Celsius measured after each
32、 of a series of heating intervals (in hours) chosen depending on the nature of the hot-melt adhesive and the manufacturers instructions for use. An example of a convenient form of expression of results is shown in Annex A . 7 Precision The precision of this test method is not known because inter-lab
33、oratory data are not available. When inter-laboratory data are obtained, a precision statement will be added at a subsequent revision. 8 Test report The test report shall include the following information: a) a reference to this International Standard; b) all details necessary for complete identific
34、ation of the hot-melt adhesive tested; c) information about sample conditioning; d) the test conditions, test temperature, time intervals between measurements, and conditions of measurement of the viscosity (type of spindle and speed) and of the “ring-and-ball” softening point; e) the criterion (or
35、criteria) selected to indicate when to stop the test; f) the duration of the test; g) the tabulated test results as specified in clause6; h) all procedural details that are optional or not covered by this standard, as well as any incidents that may have affected the results.ENISO10363:1995 BSI 12-19
36、99 5 Annex A (informative) Example of expression of results Identification of the hot-melt adhesive: . Heating temperature: C Test date: . Heating time Viscosity (type of spindle and speed) Softening point (“ring-and-ball”) Remarks in accordance with 5.5 (h) (Pas) ( C) ISO 2555 ISO 4625BS EN ISO 103
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