1、 STD-BSI BS EN 720-1-ENGL 1999 I 1624667 O90b2 UT3 II BRITISH STANDARD Tkansportable gas cylinders - Gases and gas mixtures - Part 1: Properties of pure gases The European Standard EN 720-1: 1999 has the status of a Briish Standad ICs 23.020.30; 71.100.20; 75.160.30 BS EN 720-hl999 NO COPYING WITHOU
2、T ES1 PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW STD-BSI BS EN 720-3-ENGL L999 3624bb9 07eIcDb83 T35 sl been prepared under the Sector Committee, was published under the authority of the Standards Committee and comes into effect on 15 August 1999 direction of the Engineering Amd. No. O BSI 08-1
3、999 ISBN O 580 32138 X BS EN 720-11999 Date Comments National foreword This British Standard is the English language version of EN 720-1: 1999. The UK participation in its preparation was entrusted by Technical Committee PvE/3, Gas containers, to Subcommittee pvE1/3/1, Valve fittings for gas cylinde
4、rs, which has the responsibility to: - aid enquirers to understand the text; - present to the responsible intemationaJ/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; - monitor related intemationai and European developments and pro
5、mulgate them in the UK A iist of organizations represented on this subcommittee an be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Standards Catalogue under the
6、 section entitled “International standards Correspondence Index”, or by using the “Find” facility of the BSI Stan* Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application
7、. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 8, an inside back cover and a back cover. The BSI copyright notice displayed throughout this do
8、cument indicates when this document was last issued. STD.BSI BS EN 720-1-ENGL 1799 I Lb24bb7 0790684 771 R EUROPEAN WANDARD NO= EUR0PEE”E RTROP NORM EN 720.1 April 1999 ICs 23.020.30; 71.100.20; 75.160.30 English version Vansportable gas cyljndem - Gases and gas mixtures - Part 1: Properties of pure
9、 gases Bouteilles gaz transportables - Gaz et mlanges de gaz- Gasgemkche - Parie 1: Pmpri6th des gaz purs Ortsbeweghche Gasnaschen - Gase und Teil 1: Eigenschatten von %el - Gasen This European standard was approved by CEN on 20 December 1998. CEN members are bound to comply with the CENKENELEC Inte
10、rnal Regulations which stipdate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtajned on application to the Central Secretariat or to any CEN member
11、. This European Standard exists in three official versions (English, French, German). A version in any other ianguage made by translation under the responsibility of a CEN member into its own language and notified to the Centsal Secretariat has the same status as the official versions. CEN members a
12、re the national standasds bodies of Awb5a, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, IW, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom. European Committee for Standardization Camit6 Europen de Normalisation Europi
13、sches Komitee fr Normung Central Secretariat: rue de Stassart 36, B-1060 Brussels O 1999 CEN AU rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 720-11999 E STD-BSI BS EN 720-L-ENGL 3999 W Lb24bb9 0790b05 806 Page 2 EN 720-1:1999 Foreword T
14、his European Standard has been prepared by khnicd Committee CENmC 23, Ii-ansportable gas cylinders, the Secretanat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by October
15、1999, and conflicting national standards shall be withdrawn at the latest by October 1999. Accorduig to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European standard: Austria, Belgium, Czech Republic, Denmark, Finl
16、and, France, Germany, Greece, Iceland, Ireland, Ita - compressed; - dissolved 3.4 corrosiveness ability of the gas to damage or to destroy extemal living tissues (eyes and skin). Gases are assigned a corrosiveness category This is not to be confused with corrositivity of gases with metallic makriais
17、 (see EN IS0 111141) 4 Properties of gas mixtures From the properties of the Vanous components given in clause 6, the properties of the gas mixtures may be determined by using the appropriate standard on gas mixtures concerning each of the physicochemical criteria indicated in clause 1 (see EN 720-2
18、 for the re potential). O BSI 08-1999 STD.BS1 BS EN 720-1-ENGL 1999 m lb24bb9 0790b87 bBO .I Page 4 EN 720-1:1999 5 Code number ?b be able to recognize the properties of a gas, a code each gas is based on the following four 6.3 State of the gas in the cylinder at 15 OC (category III) 8 subdivisions:
19、 number WC) is given. This code number assign Category I: Category II: Category III: Category IV: fire potentiai, defining the gas behaviour with respect to flammability (see 3.1); toxicity determined by the 50 % lethal concentration (see 3.2): Subdivision 1: liquefied gas at over 35 bw, Subdivision
20、 2: liquid withdrawal - liquefied gas Subdivision 3: dissolved gas; (optionai); II Subdivision 4: 35 bar or less - gas only (including cryogenic gas withdrawal); gas state, defining the physical state of the contents in the cylinder at 15 OC within a given pressure range (see 3.3); corrosiveness (se
21、e 3.4). Subdivision 6: medium pressure range, compressed gases from 35 bar up to and including 250 bar; Subdivision 7: hiah pressure range, above 250 bar Each category is composed of Merent Sub-diWions, a supports combustion (oxidizing gas having an oxidant potential equal to or less than that of ai
22、r); flammable (gas having flammable limits in air) (see 3.1); spontaneously fiammable; highiy oxidizing (see 3.1) (oxidizing gas having an oxidant potential greater than that of air); fiammable and subject to decomposition or polymerization. For corrosiveness, gases are divided into 4 subdivisions:
23、Subdivision O non-corrosive; Subdivision 1: non-halogen acid forming; Subdivision 2: basic; Subdivision 3: halogen acid forming. 6.6 Designation of the code This code is called E“rsc code: F: E fortoxicity; for fire potentia S: for gas state, defining the physical state of the contents in the cylind
24、er at 15 OC with a given pressure range; 5.2 Toxicity (category II) For toxicity, gases are divided into five subdivisions: Subdivision O: Subdivision 1: Subdivision 2: Subdivision 3: Subdivision 9: life supporting; asphyxiant (when LC50 is greater than 15 O00 p.p.m.V); toxic and asphyxiant (when 20
25、0 p.p.m.V I LCM I 5 O00 p.p.m.V); very toxic and asphyxiant (when LC50 5 200 p.p.m.V); harmfui and asphyxiant (when 5 O00 p.p.m.V I LC50 15 O00 p.p.m.V) C for corrosiveness. 6 List of gases NOTE For compressed gases the third digit used in this standard is a 5. Most of these gases may be Nied at hig
26、her pressure and consequently the relevant digit 7 or 8 shall then be used. For liquefied gases the third digit used in this standard is O or 1 (depending on the pressure). Most of these gases may be used with liquid withdrawal and consequently the relevant digit 2 shall then be used (irrespective o
27、f the pressure). where E50 values correspond to 1 h exposure and mortality in 14 days and with p.p.m.V corresponding to the parts per million by volume. O BSI 08-1999 Page 5 EN 720-1:1999 GaS Acetylene Air Aliene Ammonia Antimony pentafluoride Argon Arsine Bistrifluoromethylperoxide Boron trichlorid
28、e Boron Muoride Bromine pentafluoride Bromine trifluoride Bromoacetone Bromochlorodifiuoromethane Bromochloromethane BromoMuoromethane Bromotrjfiuoroethylene 1,SButadiene (inhibited) Butane 1-Butene ZButene Carbon dioxide Carbon monoxide Carbonylfluoride Carbonyl sulfide Chlorine Chlorine pentafluor
29、ide Chlorine trifluoride l-Chloro-1, laifluoroethane l-Chloro-l,2,2,2 tetmfiuoroethane l-Chlor0-2,2,2 tsifuoroethane Chlorodifiuoromethane Chlorofluoromethane Chloroheptafluorocyclobutane Chloromethane Chloropentafluoroethane Chlorotsifiuoromethane Chlorotsifiuoroethylene coal gas cyanogen Cyanogen
30、chloride Cyclopropane Deuterium Deuterium Chloride Deuterium fluoride Deuterium selenide Deuterium sulfide Diborane Dibromodifhoromethane 1,2-Dibromottrafluoroethane Propadiene R717 Boron chloride Boron fluoride R12B1 i-ifiuorobromomethane R13B1 R113B1 Butylene Butylene Carbonic acid R744 anhyrie Ca
31、rbonoxylsulfide R142b R124 R133a Monochlorodifluoromethane R22 C317 Methyl chloride R40 Monochloropentafluoroethane R115 Monochlorotriluoromethane R1113 n”imethy1ene R12B2 R114B2 Code Number 5130 1050 2100 2902 0303 0150 2300 4300 0203 0253 4303 4303 0203 o100 0100 o100 2100 5100 2100 2100 2100 O110
32、 2250 02 13 2201 4203 4303 4203 2100 o100 o100 o100 2100 o100 2900 o100 o100 5200 Mixture 2200 0303 2100 2150 0213 0203 2301 2201 5350 0100 o100 O BSI 08-1999 STD.5SI BS EN 720-1-ENGL 3999 M 1624669 0790689 453 Page 6 EN 720-1:1999 GaS 2,2-Dichloro-l, 1,1 tsifluoroethane Dichloro-2-chlorovinylmine 1
33、,2-Dichlorodifluoroethylene Dichlorodifluoromethane Dichlorofluoromethane 1,2-Dichlorohexafluorocyclobutane Dichlorosilane 1,l-Dichlorotetrafuorethane 1,2-Dichlorotetrafluoroethane Diethyhinc 1,l-Difluoroethane 1,l-Difuoroethylene Difluoromethane Dimethyl ether Dimethylmine 2,2-Dimethylpropane Dimet
34、hylshe Diphosgene Mane Ethylchloride (flamable liquid) Ethyl ether Ethylacetylene Ethyldichloromine Ethylene Ethylene oxide Fluorine Fluoroehe Germane Helium Heptafluorobutyronitsiie Hexafluoroacetone Hexafluorocyclobutene Hexafluoroethane Hexafluoropropylene Hydrogen Hydrogen bromide Hydrogen chlor
35、ide Hydrogen cyanide Hydrogen fluoride Hydrogen iodide Hydrogen selenide Hydrogen sulfide Iodotrifluoromethane Iodine pentafluoride Isobutane Isobutylene Krypton Methane Methyl acetylene Methyl bromide Sgnonym R123 Lewisite R1112a R12 R21 C316 R114a R114 Ethylidene fluoride R152a Vilidene fluoride R
36、1132a Methlylene fluoride Methyl ether Neopentane %lxamethylmethane R170 ChiOroethane R160 R1150 1-Butyne Ethene Oxirane Ethyl fluoride Hexafiuoropropan-2; perfluoroacetone Perfiuoroethane R116 Hexafiuoropropene Hydrobromic acid (anhydrous) Hydrochloric acid (anhydrous) Hydrocyanic acid (anhydrous)
37、Hydrofluoric acid (anhydrous) Hydroiodic acid (anhydrous) Wuoromethyl iodide Itimethyhethane R601 Isobutene; 2-methylpropene R50 Allylene; propyne Bromomethane Code Number O100 0303 O100 O100 O100 O100 2203 O100 O100 3300 2100 2110 O110 2100 2902 2100 2100 0303 2100 2100 2100 2100 0303 2150 5200 434
38、3 2 100 2300 0150 2300 0203 2100 O100 O100 2150 0203 0213 5301 0203 0203 2301 2201 O100 4303 2 100 2100 0150 2150 2 100 O200 O BSI 08-1999 STD.BSI BS EN 7ZO-I-ENGL L999 II Lb24bb7 0790b70 375 m Page 7 EN 720-1:1999 GaS Methyl Ethyl Ether Methyl fluoride Methyl mercaptan Methyl-3-Butene Methyldichlor
39、oamine Methylshe Methylvinylether (iMited) Monoethylamiie Monomethylamhe Mustard gas Natural gas Neon Nitric oxide Nickel carbonyl Nitrogen Nitrogen dioxide Nitrogen trioxide Nitrosyl chloride Nitrous oxide Octafuorocyclobutane Octafuoropropane omen Oxygen difluoride Ozone Pentaborane Pentachloroflu
40、oroethane Pentafluoroethane Pentafiuoroethyliodide Pentafluoropropionitrile Perfiuoro-2-butene Perfiuorobutane Phenylcarbylamme Chloride Phosgene Phosphine Phosphonis pentafluoride Phosphorus tdluoride Propane Propylene Propylene oxide Silane Silicon tetrachloride Sicon tetrafluoride Stibine Sulfur
41、dioxide Sulfur hexafluoride Sufur tetsafluoride Synonym Ethyl Methyl Ether Fluoromethane R41 Methanethiol Isoamvlene - Isopropvlethvlene Methoxyethylene Ethylamine R631 Methylamine R630 Nitrogen 0 oxide Nickel tetracarbonyle Liquid dioxide Nitrogen 0 oxide Dinitrogentetramide peroxide Nitrogen tetro
42、xide Nitrogen sesquioxide Dinitrogen trioxide Nitrogen Nitrogen oxide Perfiuorocyclobutane C318 Perfiuoropropane R218 R125 Carbonyl chloride R290 Propene R1270 Methyl Oxirane Silicone tetmhydride Tetrafluorosilane R764 Antimonyhydride Code Number 2100 2110 2201 2100 O30 2100 5100 2102 2902 0303 2150
43、 0150 4351 2300 0150 4301 4301 0303 4110 O100 O100 . 4050 4343 4330 3300 O100 O100 O100 2300 O900 O100 0303 0303 3310 0303 0203 2100 2100 5900 3150 0203 0253 5300 0201 O100 0303 O BSI 08-1999 Page 8 EN 720-1:1999 GiM Sulfuryl fluoride 1,1,1,2-Tehlorodifiuoroethane 1 , 1 , 1,2,2-Teorodifiuoroethane r
44、ntmethyl lead 1,1,1,2-tmfiuoroethane 1,1,2,2-trafluor0-1 chloroethane lktdiuoroethylene Tetrafluoromethane l%tmmethyl lead liichlorofluoromethane l,l,l-i-ichlomuoroethane l,l,l-Mchiorotrifiuoroethane liiethyl aluminium methyl borane Tiifuoroacetonitrile 1 , 1 , 1-?iifluoroethane liifluoroethylene Ti
45、ifuoromethane Wethylamine Weth ylstibme Rkethylsilane limgsten hexafluoride Uranium heduoride Vinyl Bromide (inhibited) Vinyl Chloride (inhibited) Vinyl Fluoride (inhibited) Xenon Synonym R112a R112 R134a Carbon tetrafiuoride R1114 Carbon tetrafluoride R14 ?iichloromonofiuoromethane R11 R113a R113 R
46、143a Fluorofom R23 Chloroethylene R1140 Fluoroethylene R1141 Code Number 0203 O100 O100 2300 O100 O100 O100 0150 2200 O100 O100 O100 3300 3200 2200 2100 2200 o100 2902 3300 2100 0303 0303 5100 5100 5100 0150 O BSI 08-1999 STDmBSI BS EM 720-li-ENGL 1999 O lib24669 079069Z “48 BS EN 720-1:1999 BSI 389
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