KS M 1995-2009 Determination of organic compounds emitted from plastics-Gas chromatographic method《合成塑料发出的有机化合物分析方法 气体层离法》.pdf

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1、 KSKSKSKSKSKSKSK KSKSKS KSKSK KSKS KSK KS KS M 1995 KS M 1995:2009 2009 11 30 http:/www.kats.go.krKS M 1995:2009 : ( ) ( ) SK R&D center () () () ( ) : (http:/www.standard.go.kr) : :2004 12 9 :2009 11 30 2009-0741 : : ( 02-509-7300) (http:/www.kats.go.kr). 10 5 , . KS M 1995:2009 Determination of or

2、ganic compounds emitted from plastics Gas chromatographic method 1 , ( ) . . 2 . . ( ) . KS A 0006, KS M 0031, 3 3.1 - ( ) . HSS(Headspace sampler) . 4 , 100 1 , 2 . 5 KS M 1995:2009 2 5.1 1) . . 5.2 99.5 % . 5.3 2) . 99.5 % , . 5.4 100 mL 3) n- 100 mL . . 6 6.1 KS M 0031 . ( ) . 6.1.1 4) . 1 . 6.1.

3、2 300 . 10 . ( ) , . 1) (octafluorotoluene) , (anthracene-d10) . 2) n- , n- , . 3) ( ). 4) . (dynamic) . KS M 1995:2009 3 6.1.3 , .5)6.1.4 300 1 . . 6.1.5 ( ) . 6.2 6.2.1 99.999 % 6.2.2 99.999 % 6.2.3 6) 6.2.4 99.999 % 6.3 1 . , . 6.3.1 . , . 6.3.2 5) 0.25 mm 30 m , (5 % / 95 % ) 0.25 m . 6) 2 . KS

4、M 1995:2009 4 . . 2 . 6.3.3 7)2 , 8) . . 6.4 6.4.1 n- . 1: -2: 1 6.4.2 400 2 . 6.5 7) 1 3.1 mm 1.6 mm . 2 0.25 mm0.53 mm . , . 8) , . 300 mL . KS M 1995:2009 5 7 7.1 KS A 0006 (2015) , (6520) % . 7.2 7.2.1 . , . 7.2.2 . 7.2.3 . , . . 7.3 a) 400 2 . b) , . c) 2 9) . d) . 2 9) . . (pin) KS M 1995:2009

5、 6 7.4 7.4.1 1 ( ) a) . b) . c) . 1 2 . d) 1 . e) . f) . g) .10) . 7.4.2 2 ( ) a) 2 . b) 2 . c) 1 . d) 1 2 . e) . 7.4.3 . . 7.5 . 7.6 . .11) , . (mass selective detector) . 7.7 10) , . 11) 3 . 2 % . KS M 1995:2009 7 ( ) . ( ) , (mi) . 7.8 5.4 12) . ( ) . 8 7.7 (mi) , . EiSmi100 Ei : (i) (ng/cm2) mi

6、: (i) (ng) S : (cm2) 9 (Ei, ng/cm2) 1 . 10 . a) ( , , ) b) c) d) e) 12) 0.001 mL 0.01 mL . KS M 1995:2009 8 A ( ) A.1 A.1.1 PVC, LLDPE 1 A.1.2 A.2 7.2 7.3 , . 2 800 mm2 . A.3 100 160 200 , 20 mL/min 10 2 800 mm2(10 mm140 mm) 1 10 , 20 mL/min , 5 2 , 5 , , 1.5 mL/min 250 (: 30 m, : 0.25 mm) : (5 % /

7、95 % ), : 0.25 m , 1.5 mL/min 40 (0 ) 20 / 300 (7 ) (FID) 250 KS M 1995:2009 9 B ( ) B.1 PVC C13C14C15C16C17C18C19C13C15C16C17 B.2 LLDPE Tetramethylbutylphenol NonylphenolDOAEpoxidizedsoybean oil 153787 1 92 3(13) (02)26240114 (02)262401489 http:/ KS M 1995:2009 KSKSKS SKSKS KSKS SKS KS SKS KSKS SKSKS KSKSKS Determination of organic compounds emitted from plastics Gas chromatographic method ICS 71.040 Korean Agency for Technology and Standards http:/www.kats.go.kr

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