SANS 404-2009 Phosphorus deoxidized non-arsenical copper《无砷脱氧磷铜》.pdf

1、 Collection of SANS standards in electronic format (PDF) 1. Copyright This standard is available to staff members of companies that have subscribed to the complete collection of SANS standards in accordance with a formal copyright agreement. This document may reside on a CENTRAL FILE SERVER or INTRA

2、NET SYSTEM only. Unless specific permission has been granted, this document MAY NOT be sent or given to staff members from other companies or organizations. Doing so would constitute a VIOLATION of SABS copyright rules. 2. Indemnity The South African Bureau of Standards accepts no liability for any

3、damage whatsoever than may result from the use of this material or the information contain therein, irrespective of the cause and quantum thereof. ISBN 978-0-626-23184-2 SANS 404:2009Edition 2.2SOUTH AFRICAN NATIONAL STANDARD Phosphorus deoxidized non-arsenical copper Published by SABS Standards Div

4、ision 1 Dr Lategan Road Groenkloof Private Bag X191 Pretoria 0001Tel: +27 12 428 7911 Fax: +27 12 344 1568 www.sabs.co.za SABS SANS 404:2009 Edition 2.2 Table of changes Change No. Date Scope Amdt 1 2008 Amended to change the designation of SABS standards to SANS standards, with no technical changes

5、. Amdt 2 2009 Amended to delete referenced standard methods that have been withdrawn. Foreword This South African standard was approved by National Committee SABS TC 1078, Engineering Materials Non-ferrous metals, in accordance with procedures of the SABS Standards Division, in compliance with annex

6、 3 of the WTO/TBT agreement. This document was published in September 2009. This document supersedes SANS 404:2008 (edition 2.1). A vertical line in the margin shows where the text has been technically modified by amendment No. 2. SANS 404:2009 Edition 2.2 1 Contents Page Foreword 1 Scope . 3 2 Defi

7、nition 3 3 Requirements . 3 4 Sampling and compliance with the specification . 5 5 Inspection and methods of test 5 Appendix A Applicable standards 8 Appendix B Notes to purchasers . 8 SANS 404:2009 Edition 2.2 2 This page is intentionally left blank SANS 404:2009 Edition 2.2 3 Phosphorus deoxidized

8、 non-arsenical copper 1 Scope 1.1 This specification covers non-arsenical deoxidized copper for general use. NOTE a) The titles of standards referred to by number in the specification are given in appendix A. b) Requirements that must be specified by the purchaser, or that must be agreed between man

9、ufacturer and purchaser, are listed in appendix B. 2 Definition 2.1 For the purposes of this specification the following definition shall apply: cast or lot the product of one furnace or crucible melt, or the product of a number of furnace, or crucible melts where these are combined and mixed prior

10、to casting, or the product of a continuous melting furnace where the amount of metal tapped from the furnace without any further additions of metal to the charge exceeds one-third of the furnace capacity 3 Requirements 3.1 Chemical composition The material shall comply with the chemical requirements

11、 laid down in table 1. SANS 404:2009 Edition 2.2 4 Table 1 Chemical requirements 1 2 3 Element %, min. %, max. Copper including silver Nickel Phosphorus 99,85 0,015 0,10 0,080 Arsenic 0,05 Total impurities, excluding silver, nickel, phosphorus, and arsenic, but including the following: 0,060 Antimon

12、y Bismuth Iron 0,005 0,003 0* 0,03 Lead Tellurium Selenium plus tellurium Tin 0,010 0,010 0,020 0,01 * The purchaser shall specify whether the copper is required to withstand severe working operations in the temperature range 400-700 C (e.g repeated hot hammering with intermediate reheating), in whi

13、ch case the maximum bismuth content shall be 0,001 5 %. 3.2 Certificate of analysis The manufacturer or supplier shall, if so specified by the purchaser, supply to the purchaser a copy of the analysis certificate of the copper in the lot. 3.3 Form The copper shall be supplied in cakes, slabs, billet

14、s, or other form as specified by the purchaser. 3.4 Freedom from defects The copper supplied shall be substantially free from physical defects such as shrink holes, cracks, cold sets, pits, raised edges, and other defects in set or casting. 3.5 Nominal dimensions and tolerances The purchaser shall s

15、pecify the nominal dimensions and the following tolerances shall then apply: In the case of cylindrical billets, the permissible variations from the nominal dimensions shall be as follows: Length : 3 % Diameter : up to 25 mm: 5 % Over 125 mm: 6 mm In cases of cakes or slabs horizontally or verticall

16、y cast, the permissible variations from the nominal dimensions shall be as follows: Up to and including 200 mm : 6 mm Over 200 mm : 3 % SANS 404:2009 Edition 2.2 5 3.6 Gassing test When tested in accordance with 5.2, the copper shall show no edge or surface cracking. 4 Sampling and compliance with t

17、he specification1)4.1 Sampling The following sampling procedure shall be applied in determining whether a lot complies with the requirements of the specification. The sample(s) so drawn shall be deemed to represent the lot: a) Sample for inspection. From the lot take at random a number of complete c

18、akes (or the other shapes in the lot) such that their combined mass is at least 1% of the total mass of the lot. b) Sample for testing. Obtain the sample for test in the form of a test bar or ingot cast while pouring the lot. Obtaining such a test sample shall be a matter of agreement between the pu

19、rchaser and the manufacturer or supplier, and where such a sample cannot be obtained the sample taken in accordance with (a) above shall be used as the test sample. 4.2 Compliance The lot shall be deemed to comply with the requirements of the specification if after inspection and testing the samples

20、 drawn in accordance with 4.1 are found to comply with the appropriate requirements of the specification. 5 Inspection and methods of test 5.1 Inspection Inspect the samples drawn in accordance with 4.1 for compliance with the relevant requirements of 3.3, 3.4, and 3.5. NOTE If the purchaser wishes

21、to inspect the material at the manufacturers works, he shall notify the manufacturer to that effect at the time of placing the order. In such cases the manufacturer shall afford the purchaser all reasonable facilities to satisfy himself that the material complies with the requirements of the specifi

22、cation. 5.2 Gassing test 5.2.1 Preparation of test specimens Cut a piece or pieces of suitable size from each sample ingot or other shape taken in accordance with 4.1, and cold-roll or draw them (after preliminary forging or hot-rolling if necessary) into strip or wire of thickness not greater than

23、3,25 mm and not less than 2,0 mm. Cut test specimens of convenient length from the strip or wire, draw-file or other-wise smooth the edges, and anneal them in hydrogen for half an hour at 800 C. 5.2.2 Close bending After cooling, bend the test specimen AB (see figure 1) by steadily applied pressure

24、or a succession of blows at right angles to the length AC and flatten it close until A assumes the position indicated by D. 1) This section applies to the sampling for inspection and testing before acceptance or rejection of single lots in cases where no information about the implementation of quali

25、ty control or testing during manufacture is available to help in assessing the quality of the lot. It is also used as the procedure for adjudicating in cases of dispute. SANS 404:2009 Edition 2.2 6 5.3 Sample for chemical analysis a) So take the sample for chemical analysis by drilling completely th

26、rough each sample ingot or other shape, taken in accordance with 4.1, that the drillings are representative of its average cross-section. Where the thickness is too great to permit drilling right through, drill the pieces from either side to a depth equal to half their thickness. Thoroughly clean th

27、e drill used for taking the sample. Do not use a lubricant in the operation, and keep the drillings as fine as possible. Treat the drillings carefully with a magnet to remove any particles of iron which may have been introduced in taking the sample. b) The thoroughly mixed drillings shall constitute

28、 the sample for chemical analysis and shall be taken as being representative of the lot. 5.4 Methods of test NOTE Any reliable method of chemical analysis may be used for determining the individual constituents of the alloy(s). Suitable methods2)are listed below and shall be the methods used in case

29、s of dispute. 5.4.1 Deleted by amendment No. 2. 5.4.2 Nickel3): ASTM E 62 Amdt 2 5.4.3 Phosphorus3): ASTM E 62 Amdt 2 5.4.4 Arsenic3): ASTM E 62 Amdt 2 5.4.5 Antimony3): ASTM E 62 Amdt 2 5.4.6 Deleted by amendment No. 2. 5.4.7 Iron3): ASTM E 62 Amdt 2 5.4.8 Deleted by amendment No. 2. 5.4.9 Deleted

30、by amendment No. 2. 5.4.10 Deleted by amendment No. 2. 5.4.11 Tin3): ASTM E 62 with the following modifications: Amdt 2 a) Use a 20 g sample and dissolve in 150 ml of nitric acid (1:1) b) Reduce specifically with nickel c) Titrate using potassium iodate solution (1 mL = 0,000 5 g Sn) 2) These method

31、s are revised from time to time. In all cases the latest edition of the individual method must be used. 3) Deleted by amendment No. 2. SANS 404:2009 Edition 2.2 7 Figure 1 Close bend test piece SANS 404:2009 Edition 2.2 8 Appendix A Applicable standards Reference is made to the latest issues of the

32、following standards: ASTM E 62, Standard test methods for chemical analysis of copper-nickel and copper alloys (photometric methods). ASTM E 75, Standard test methods for chemical analysis of copper-nickel and copper-nickel-zinc alloys. SANS 5563 (SABS SM 563), Determination of copper (plus silver)

33、in copper. Amdt 2 SANS 5564 (SABS SM 564), Determination of bismuth in copper. Amdt 2 SANS 5565 (SABS SM 565), Determination of lead in copper. Amdt 2 SANS 5566 (SABS SM 566), Determination of selenium in copper. Amdt 2 SANS 5567 (SABS SM 567), Spectrographic analysis of copper. Amdt 2 Appendix B No

34、tes to purchasers B.1 The following requirements must be specified in tender invitations and in the order or contract: a) whether the copper is required to withstand severe working operations in the temperature range 400-700 C (see table 1); b) whether a certificate of analysis is required (see 3.2)

35、; c) the form required (see 3.3); d) the nominal dimensions of the pieces to be supplied (see 3.5); e) whether inspection facilities are required at the manufacturers works (see 5.1). B.2 The following requirements must be agreed upon between the manufacturer and the purchaser: the casting of a test

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