1、Designation: D 3844 02Standard Guide forLabeling Chlorinated Hydrocarbon Solvent Containers1This standard is issued under the fixed designation D 3844; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A nu
2、mber in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 This guide is intended to provide industrial health andsafety labeling for the following chlorinated hydrocarbonsolvents: methylene chlo
3、ride, perchloroethylene, and trichlo-roethylene. Additional labeling may be required if otherchemicals are mixed with these solvents, or if special contain-ers (for example, aerosol packages) are employed.2. Referenced Documents2.1 ASTM Standards:D 4276 Practice for Confined Area Entry22.2 ANSI Stan
4、dard:ANSI Z 129.1-2000 American National Standard for Haz-ardous Industrial Chemicals-Precautionary Labeling32.3 Code of Federal Regulations:29 CFR 1910.146 OSHA Occupational Safety and HealthStandard for Permit-required Confined Spaces429 CFR 1910.1052 OSHA Occupational Health Standardfor Methylene
5、 Chloride429 CFR 1910.1200 OSHA Hazard Communication Stan-dard449 CFR 172 DOT Hazardous Materials Regulations416 CFR 1500 Consumer Product Safety Commission Regu-lations42.4 Other Publications:ACGIH Threshold Limit Values (TLVs) for Chemical Sub-stances and Physical Agents53. Significance and Use3.1
6、 Chemical product labeling is required by the OSHAHazard Communications Standard 29 CFR 1910.1200. ANSIStandard Z129.1 establishes specific guidelines for preparationof labeling consistent with the OSHA Standard. This guide isintended as an interpretation of these standards as they apply tothese spe
7、cific products and grades.3.2 This guide is intended to provide suggestions for theminimum required labeling for these chlorinated solvents. It isnot intended to replace labeling determinations made bymanufacturers or packagers.3.3 This guide applies to commercially available grades ofthese specific
8、 products. For solvent blends, or formulationswith other materials, consult ANSI Z129.1.4. Requirements4.1 These materials may also be subject to applicablefederal, state and local laws and regulations.5. Labeling5.1 Sections 6-8 describe typical warning statements to beincluded in warning labels fo
9、r the appropriate solvents.5.2 Special grades of these solvents are available. Thesesuggested statements may not be complete, or appropriate inevery case. Solvent suppliers should be consulted beforelabeling containers of these products.5.3 Some states require identification of any componentspresent
10、 in concentrations of 1 % or greater, or of listedcarcinogens in concentrations of 0.1 % or greater. Certaingrades of these products may contain stabilizers in suchconcentrations. Consult the supplier for more information.5.4 Some regulatory districts also require listing of VOCcontent. Methylene ch
11、loride and perchloroethylene are exemptin many jurisdictions, however stabilizers (where present) areconsidered as VOCs, and may need to be labeled as such.5.5 Products packaged for consumer uses may requirelabeling that differs from the recommendations set forth in thisguide. Consult Consumer Produ
12、ct Safety Commission regula-tions (16 CFR Part 1500)6. Suggested Label for Methylene Chloride6.1 Identification:Company NameCompany AddressEmergency Telephone NumberCompany LogoLot NumberNet WeightSolvent Name: Methylene Chloride (dichloromethane)1This guide is under the jurisdiction of ASTM Committ
13、ee D26 on HalogenatedOrganic Solvents and Fire Extinguishing Agents and is the direct responsibility ofSubcommittee D26.05 on Industrial Hygiene.Current edition approved Dec. 10, 2002. Published February 2003. Originallyapproved in 1979. Last previous edition approved in 1996 as D 3844 96.2Annual Bo
14、ok of ASTM Standards, Vol 15.05.3Available from American National Standards Institute, 25 West 43rd Street, 4thFloor, New York, NY 10036.4Available from the Superintendent of Documents, U.S. Government PrintingOffice, Washington, DC 20402.5Available from American Conference of Governmental Industria
15、l Hygienists,1330 Kemper Meadow Dr., Cincinnati, OH 45240.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.CAS No.: 75-09-2UN No.: UN 1593DOT Label: PoisonOSHA PEL: 25 ppm (ACGIH TLV: 50 ppm)Reportable Quantity: 1000 lb6.2 READ MATERI
16、AL SAFETY DATA SHEET BE-FORE HANDLING OR USING THIS PRODUCT.6.3 Health and Safety Information:WARNING! Harmful if inhaled. May cause skin and eyeirritation. May cause liver and kidney damage based on animaldata. Possible cancer hazard. May cause cancer based onanimal data.6.4 Precautions:AVOID BREAT
17、HING OF VAPOR OR MIST. Exposureto high vapor concentrations can cause unconsciousness anddeath.USE ONLY WITH ADEQUATE VENTILATION. Venti-lation must be sufficient to limit exposures in accordance withOSHA Occupational Health Standard for methylene chloride.Eye irritation and dizziness are indication
18、s of overexposure.DO NOT TASTE OR SWALLOW. Swallowing can causeinjury, illness, and death.AVOID CONTACT WITH SKIN AND CLOTHING.Prolonged or repeated contact with liquid can cause skinirritation and dermatitis.DO NOT GET IN EYES. Contact will cause discomfortand irritation.WASH THOROUGHLY AFTER HANDL
19、ING.DO NOT EAT, DRINK, OR SMOKE IN WORK AR-EAS.SEE CURRENT OSHA REGULATIONS.6.5 First Aid:IF INHALEDRemove patient to fresh air. If not breath-ing, give artificial respiration. If breathing is difficult, giveoxygen. Call a physician.IF SWALLOWEDDo not induce vomiting. Contact phy-sician or emergency
20、 medical facility immediately. Never giveanything by mouth to an unconscious person.IF IN EYESImmediately flush eyes thoroughly with largeamounts of water for at least 15 min. Call a physician.IF ON SKINRemove contaminated clothing and shoes.Wash skin with warm water and soap. Wash clothes and air o
21、utshoes before reuse.NOTE TO PHYSICIANAvoid use of adrenalin (or otherheart-stimulating drugs) in any case where a person has beenovercome by methylene chloride. Increased sensitivity of theheart can be caused by overexposure to methylene chloride.6.6 Handling and Storage:DO NOT USE IN POORLY VENTIL
22、ATED OR CON-FINED SPACES. Vapors are heavier than air and will collectin low areas such as pits, degreasers, storage tanks, and otherconfined areas. Do not enter where vapors are suspected inhigh concentrations unless air-supplied positive pressurebreathing apparatus is used and a trained observer i
23、s presentand equipped with rescue gear. See Practice D 4276 and 29CFR 1910.146.Avoid prolonged contact with aluminum. Do not use inaluminum equipment or containers. Contact of methylenechloride with aluminum parts in a pressurizable fluid systemcan cause violent reaction. Consult the equipment suppl
24、ier forfurther information.Avoid contact of this material or its vapors with flames, hotglowing surfaces, welding operations or electric arcs. Suchcontact can form toxic and corrosive acid fumes.Liquid oxygen or other strong oxidants can form explosivemixtures with methylene chloride.Vapors of methy
25、lene chloride in confined or poorly venti-lated areas can form flammable mixtures in the air.Store methylene chloride in a cool, dry, well-ventilated areaout of sunlight. Open slowly to relieve pressure. Do not storein open, unlabeled or mislabeled containers. Keep containerstightly closed when not
26、in use.Do not reuse drum without recycling or reconditioning inaccordance with any applicable federal, state or local laws.Do not use cutting or welding torches, open flames, orelectric arcs on empty or full containers (including storagetanks) that may contain methylene chloride liquid or vapors.SPI
27、LLS OR LEAKSEvacuate the area, ventilate, andavoid breathing vapors. Dike the area to contain the spill.Personnel wearing proper protective equipment including anair line respirator or a self-contained breathing apparatus witha full facepiece, should clean up the area by mopping withabsorbent materi
28、al, and should place the contaminant in closedcontainers for disposal. Avoid contamination of ground andwater.DISPOSALSend to a permitted waste management facil-ity. Any disposal must be in compliance with federal, state andlocal regulations. Do not flush to the sewer, on the ground, orinto any body
29、 of water.KEEP OUT OF REACH OF CHILDREN.7. Suggested Label for Perchloroethylene7.1 Identification:Company NameCompany AddressEmergency Telephone NumberCompany LogoLot NumberNet WeightSolvent Name: Perchloroethylene (tetrachloroethylene)CAS No.: 127-18-4UN No.: UN 1897DOT Label: PoisonOSHA PEL: 100
30、ppm (ACGIH TLV: 25 ppm)Reportable Quantity: 100 lb7.2 READ MATERIAL SAFETY DATA SHEET BE-FORE HANDLING OR USING THIS PRODUCT.7.3 Health and Safety Information:WARNING! Harmful if inhaled. May cause skin and eyeirritation. May cause liver and kidney damage based on animaldata. Possible cancer hazard.
31、 May cause cancer based onanimal data.7.4 Precautions:D3844022AVOID BREATHING OF VAPOR OR MIST. Exposureto high vapor concentrations can cause unconsciousness anddeath.USE ONLY WITH ADEQUATE VENTILATION. Venti-lation must be sufficient to limit exposure below permissibleexposure limits. Eye irritati
32、on and dizziness are indications ofoverexposure.DO NOT TASTE OR SWALLOW. Swallowing can causeinjury, illness, and death.AVOID CONTACT WITH SKIN AND CLOTHING.Prolonged or repeated contact with liquid can cause skinirritation and dermatitis.DO NOT GET IN EYES. Contact will cause discomfortand irritati
33、on.WASH THOROUGHLY AFTER HANDLING.DO NOT EAT, DRINK, OR SMOKE IN WORK AR-EAS.SEE CURRENT OSHA REGULATIONS.7.5 First Aid:IF INHALEDRemove patient to fresh air. If not breath-ing, give artificial respiration. If breathing is difficult, giveoxygen. Call a physician.IF SWALLOWEDDo not induce vomiting. C
34、ontact phy-sician or emergency medical facility immediately. Never giveanything by mouth to an unconscious person.IF IN EYESImmediately flush eyes thoroughly with largeamounts of water for at least 15 min. Call a physician.IF ON SKINRemove contaminated clothing and shoes.Wash skin with warm water an
35、d soap. Wash clothes and air outshoes before reuse.NOTE TO PHYSICIANAvoid use of adrenalin (or otherheart-stimulating drugs) in any case where a person has beenovercome by perchloroethylene. Increased sensitivity of theheart can be caused by overexposure to perchloroethylene.7.6 Handling and Storage
36、DO NOT USE IN POORLY VENTILATED OR CON-FINED SPACES. Vapors are heavier than air and will collectin low areas such as pits, degreasers, storage tanks, and otherconfined areas. Do not enter where vapors are suspected inhigh concentrations unless air-supplied positive pressurebreathing apparatus is u
37、sed and a trained observer is presentand equipped with rescue gear. See Practice D 4276 and 29CFR 1910.146.Avoid contact of this material or its vapors with flames, hotglowing surfaces, welding operations or electric arcs. Suchcontact can form toxic and corrosive acid fumes.Liquid oxygen or other st
38、rong oxidants can form explosivemixtures of perchloroethylene.Store perchloroethylene in a cool, dry, well-ventilated areaout of sunlight. Do not store in open, unlabeled or mislabeledcontainers. Keep containers tightly closed when not in use.Do not reuse drum without recycling or reconditioning ina
39、ccordance with any applicable federal, state or local laws.Do not use cutting or welding torches, open flames, orelectric arcs on empty or full containers (including storagetanks) that may contain perchloroethylene liquid or vapors.SPILLS OR LEAKSEvacuate the area, ventilate, andavoiding breathing v
40、apors. Dike the area to contain the spill.Personnel wearing proper protective equipment including anair line respirator or self-contained breathing apparatus, with afull facepiece, should clean up the area by mopping withabsorbent material, and should place the contaminant in closedcontainers for di
41、sposal. Avoid contamination of ground andsurface water.DISPOSALSend to a permitted waste management facil-ity. Any disposal must be in compliance with federal, state andlocal regulations. Do not flush to the sewer, on the ground, orinto any body of water.KEEP OUT OF REACH OF CHILDREN.8. Suggested La
42、bel for Trichloroethylene8.1 Identification:Company NameCompany AddressEmergency Telephone NumberCompany LogoLot NumberNet WeightSolvent Name: TrichloroethyleneCAS No.: 79-01-6DOT Label: PoisonUN No.: UN 1710OSHA PEL: 100 ppm (ACGIH TLV: 50 ppm)8.2 READ MATERIAL SAFETY DATA SHEET BE-FORE HANDLING OR
43、 USING THIS PRODUCT.8.3 Health and Safety Information:WARNING! Harmful if inhaled. May cause skin and eyeirritation. May cause liver and kidney damage based on animaldata. Possible cancer hazard. May cause cancer based onanimal data.8.4 Precautions:AVOID BREATHING OF VAPOR OR MIST. Exposureto high v
44、apor concentrations can cause unconsciousness anddeath.USE ONLY WITH ADEQUATE VENTILATION. Venti-lation must be sufficient to limit exposure below permissibleexposure limits. Eye irritation and dizziness are indications ofoverexposure.DO NOT TASTE OR SWALLOW. Swallowing can causeinjury, illness, and
45、 death.AVOID CONTACT WITH SKIN AND CLOTHING.Prolonged or repeated contact with liquid can cause skinirritation and dermatitis.DO NOT GET IN EYES. Contact will cause discomfortand irritation.WASH THOROUGHLY AFTER HANDLING.DO NOT EAT, DRINK, OR SMOKE IN WORK AR-EAS.SEE CURRENT OSHA REGULATIONS.8.5 Fir
46、st Aid:IF INHALEDRemove patient to fresh air. If not breath-ing, give artificial respiration. If breathing is difficult, giveoxygen. Call a physician.D3844023IF SWALLOWEDDo not induce vomiting. Contact phy-sician or emergency medical facility immediately. Never giveanything by mouth to an unconsciou
47、s person.IF IN EYESImmediately flush eyes thoroughly with largeamounts of water for at least 15 min. Call a physician.IF ON SKINRemove contaminated clothing and shoes.Wash skin with warm water and soap. Wash clothes and air outshoes before reuse.NOTE TO PHYSICIANAvoid use of adrenalin (or otherheart
48、stimulating drugs) in any case where a person has beenovercome by trichloroethylene. Increased sensitivity of theheart can be caused by overexposure to trichloroethylene.8.6 Handling and Storage:DO NOT USE IN POORLY VENTILATED OR CON-FINED SPACES. Vapors are heavier than air and will collectin low
49、areas such as pits, degreasers, storage tanks, and otherconfined areas. Do not enter where vapors are suspected inhigh concentrations unless air-supplied positive pressurebreathing apparatus is used and a trained observer is presentand equipped with rescue gear. See Practice D 4276 and 29CFR 1910.146.Avoid prolonged contact with aluminum. Do not use inaluminum equipment or containers.Avoid contact of this material or its vapors with flames, hotglowing surfaces, welding operations or electric arcs. Suchcontact can form toxic and corrosive acid fumes.Liquid oxygen or o
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