ASTM D5927-2003 Standard Specification for Thermoplastic Polyester (TPES) Injection and Extrusion Materials Based on ISO Test Methods《基于ISO试验方法的热塑性聚酯注塑和压塑材料的标准规范》.pdf

1、Designation: D 5927 03Standard Specification forThermoplastic Polyester (TPES) Injection and ExtrusionMaterials Based on ISO Test Methods1This standard is issued under the fixed designation D 5927; the number immediately following the designation indicates the year oforiginal adoption or, in the cas

2、e of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.INTRODUCTIONThis material specification is intended to provide a callout system for thermoplastic poly

3、estermaterials based on ISO test methods.1. Scope*1.1 This specification covers thermoplastic polyester mate-rials suitable for molding or extrusion.1.2 This specification allows for the use of recycled ther-moplastic polyester materials provided that the requirements asstated in this specification

4、are met. The proportions of recycledmaterial used, as well as the nature and amount of anycontaminant, however, cannot be covered practically in thisspecification.1.3 The properties included in this specification are thoserequired to identify the compositions covered. There may beother requirements

5、necessary to identify particular character-istics important to specialized applications. These may bespecified by using the suffixes as given in Section 5.1.4 This classification system and subsequent line callout(specification) are intended to provide a means of calling outplastic materials used in

6、 the fabrication of end items or parts.It is not intended for the selection of materials. Materialselection should be made by those having expertise in theplastic field after careful consideration of the design andperformance required of the part, the environment to which itwill be exposed, the fabr

7、ication process to be used, the costsinvolved, and the inherent properties of the material other thanthose covered by this specification.1.5 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.1.6 The following hazards caveat perta

8、ins only to the testmethods portion, Section 11, of this specification: This stan-dard does not purport to address all of the safety concerns, ifany, associated with its use. It is the responsibility of the userof this standard to establish appropriate safety and healthpractices and determine the ap

9、plicability of regulatory limita-tions prior to use.NOTE 1This specification is similar to ISO 7792-1:1995 and ISO7792-2:1988, although the technical content is significantly different.2. Referenced Documents2.1 ASTM Standards:D 883 Terminology Relating to Plastics2D 1600 Terminology for Abbreviated

10、 Terms Relating toPlastics2D 3892 Practice for Packaging/Packing of Plastics3D 4000 Classification System for Specifying Plastic Mate-rials3E 29 Practice for Using Significant Digits in Test Data toDetermine Conformance with Specifications42.2 IEC and ISO Standards:5IEC 112 Recommended Method for De

11、termining the Com-parative Tracking Index of Solid Insulation MaterialsIEC 243 Recommended Methods of Test for ElectricalStrength of Solid Insulating Materials at Power Frequen-ciesISO 62 PlasticsDetermination of Water AbsorptionISO 75-1:1993 PlasticsDetermination of Temperature ofDeflection Under L

12、oadPart 1: General Test MethodsISO 75-2:1993 PlasticsDetermination of Temperature ofDeflection Under LoadPart 2: Plastics and EboniteISO 179-1:1993 PlasticsDetermination of Charpy ImpactStrengthISO 291:1997 PlasticsStandard Atmospheres for Condi-tioning and Testing1This specification is under the ju

13、risdiction of ASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterials.Current edition approved March 10, 2003. Published April 2003. Originallyapproved in 1996. Last previous edition approved in 2000 as D 5927 00.2Annual Book of ASTM Standards,

14、 Vol 08.01.3Annual Book of ASTM Standards, Vol 08.02.4Annual Book of ASTM Standards, Vol 14.02.5Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 1

15、00 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.ISO 294-1:1996 PlasticsInjection Moulding of TestSpecimens of Thermoplastic MaterialsPart 1: GeneralPrinciples, Multipurpose-Test Specimens (ISO MouldType A) and Bars (ISO Mould Type B)ISO 527-1:1993 PlasticsDetermina

16、tion of TensilePropertiesPart 1: General PrinciplesISO 527-2:1993 PlasticsDetermination of TensilePropertiesPart 2: Testing ConditionsISO 604 PlasticsDetermination of Compressive Proper-tiesISO 1133:1997 PlasticsDetermination of the Melt Mass-Flow Rate (MFR) and the Melt Volume-Flow Rate (MVR)of The

17、rmoplasticsISO 1183:1987 PlasticsMethods for Determining theDensity and Relative Density of Non-Cellular PlasticsISO 3451-2:1984 PlasticsDetermination of AshPart 2:Polyalkylene TerephthalatesISO 7792-1:1995 PlasticsSaturated Polyester (SP) Moul-ding and Extrusion MaterialsPart 1: Designation Sys-tem

18、 and Basis for SpecificationISO 7792-2:1988 PlasticsPolyalkylene TerephthalatesPart 2: Preparation of Test Specimens and Determinationof Properties2.3 Underwriters Laboratories (UL):6UL 94 Test for Flammability of Plastic Materials for Partsin Devices and Appliances2.4 National Technical Information

19、 Service (NTIS):7AD297457 Procedure and Analytical Method for Determin-ing Toxic Gases Produced by Synthetic Compounds3. Terminology3.1 DefinitionsThe terminology used in this specificationis in accordance with Terminologies D 883 and D 1600.4. Classification4.1 Thermoplastic polyester materials are

20、 classified intogroups according to their composition. These groups aresubdivided into classes and grades, as indicated in the basicproperty table (Table TPES).NOTE 2An example of this classification system is as follows. Thedesignation TPES 0113 would indicate:TPES = thermoplastic polyester as foun

21、d in Terminology D 1600,01 (group) = PBT,1 (class) = general purpose, and3 (grade) = requirements given in Table TPES.4.1.1 Grades of reinforced or filled versions, or both, of thebasic materials are identified by a single letter that indicates thereinforcement or filler used and two digits, in mult

22、iples of five,that indicate the nominal quantity in percent by weight. Thus,a letter designation G for glass reinforced and 35 for percent orreinforcement, G35, specifies a material with a nominal glasslevel of 35 %. The reinforcement letter designations andassociated tolerance levels are shown as t

23、abulated as follows:Symbol Material ToleranceC carbon- and graphite-fiber-reinforced62%G glass-reinforced 62%L lubricants (such as PTFE,graphite, silicone, and mo-lybdenum disulfide)depends on material and pro-cessto be specifiedM mineral-reinforced 62%R combinations of reinforce-ments or fillers, o

24、r both63%NOTE 3An example of this classification system for reinforcedthermoplastic polyester is given as follows. The designation TPES021G30 indicates the following:TPES = thermoplastic polyester as found in TerminologyD 1600,02 (group) = PET,1 (class) = unmodified, andG30 (grade) = nominal 30 % gl

25、ass with the requirements given inTable TPES.NOTE 4This part of the classification system uses the percent ofreinforcements or fillers, or both, in the callout of the modified basematerial. The types and percentages of reinforcements and fillers shouldbe shown on the suppliers technical data sheet u

26、nless they are proprietaryin nature. If necessary, additional callout of these reinforcements andadditives can be accomplished by use of the suffix part of the system (seeSection 5).NOTE 5Materials containing reinforcements or fillers, or both, atnominal levels not in multiples of five are included

27、in the nearest TPESdesignation. For example, a material with a nominal glass content of 28 %is included with Grade G30.NOTE 6The ash content of filled or reinforced materials may bedetermined using ISO 3451-2:1984.4.2 Variations of thermoplastic polyester materials that arenot included in Table TPES

28、 are classified in accordance withTable TPES and Table A or B. Table TPES is used to specifythe group of thermoplastic polyester, and Table A or B is usedto specify property requirements.4.2.1 Specific requirements for variations of thermoplasticpolyester materials shall be indicated by a six-charac

29、ter desig-nator. The designation will consist of the letter “A” or “B” andthe five digits comprising the cell numbers for the propertyrequirements in the order as they appear in Table A or B.4.2.1.1 Although the values listed are necessary to includethe range of properties available in existing mate

30、rial, usersshould not infer that every possible combination of theproperties exists or can be obtained.4.2.2 When the grade of the basic material is not known oris not important, the use of “0” grade classification shall beused for materials in this system (see Note 7).NOTE 7An example of a reinforc

31、ed thermoplastic polyester of thisclassification system is as follows. The designation TPES0310G30A22450 would indicate the following material requirementsfrom Table A:TPES0310 = PET copolymer, from Table TPES,G30 = glass-reinforced at 30 % nominal glass content,A = Table A for property requirements

32、,2 = tensile strength, 50 MPa, min,2 = tensile modulus, 2700 MPa, min,4 = Charpy impact, 6.0 kJ/m2, min,5 = deflection temperature, 185C, at 1.8 MPa, min,and0 = unspecified.If no properties are specified, the designation would be TPES0310G30A00000.6Available from Underwriters Laboratories, 333 Pfing

33、sten Rd., Northbrook, IL600622096.7Available from NTIS, 5285 Port Royal Rd., Springfield, VA 22161.D5927032TABLE A Detailed Requirements:AReinforced or Filled Thermoplastic PolyestersDesignationOrderNumberPropertyCell Limits0 123456 7 8 91 Tensile strength, ISO527-1:1993 and ISO527-2:1993, min, MPaB

34、unspecified 35 50 70 95 115 140 175 210 specify valueC2 Tensile modulus, ISO 527-1:1993and ISO 527-2:1993,min, MPaDunspecified 1 400 2 700 4 100 5 500 6 900 8 000 10 000 12 500 specify valueC3 Charpy impact, ISO 179:1993,min, kJ/m2Eunspecified 1.5 3.0 4.5 6.0 8.5 11.0 13.5 17.5 specify valueC4 Defle

35、ction temperature underload at 1.8 MPa, ISO75-1:1993 and ISO75-2:1993, min, CFunspecified 50 100 120 150 185 205 220 235 specify valueC5 To be determined . . . . . . . . . .AIt is recognized that detailed test values, particularly Charpy impact, may not predict nor even correlate with the performanc

36、e of parts molded of these materials.BTensile strength shall be determined using a Type 1A tensile specimen as described in ISO 527-2:1993. Crosshead speed shall be 5 mm/min6 20 %.CIf a specific value is required, it must appear on the drawing or contract, or both.DTensile modulus shall be determine

37、d using a Type 1A tensile specimen as described in ISO 527-2:1993 at a test speed of 1 mm/min 6 20 %.EThe test specimen shall be 80 6 2by106 0.2 by 4 6 0.2 mm, cut from the center of the Type 1A tensile specimen and tested as described in ISO 179:1993, Method1eA.FThe test specimen size shall be 80 6

38、 2by106 0.2 by 4 6 0.2 mm, cut from the center of the Type 1A tensile specimen. The requirements are based on unannealedtest specimens.TABLE B Detailed Requirements:ASpecial Thermoplastic PolyestersDesignationOrderNumberPropertyCell Limits0 12345678 91 Tensile strength, ISO 527-1:1993 and ISO527-2:1

39、993, min, MPaBunspecified 10 30 35 40 45 50 60 80 specify valueC2 Tensile modulus, ISO 527-1:1993 and ISO527-2:1993, min, MPaDunspecified 100 350 1000 1500 2000 2500 3000 4000 specify valueC3 Charpy impact, ISO 179:1993, min, kJ/m2Eunspecified 2.0 3.5 5.0 8.0 13.0 18.0 25.0 50.0 specify valueC4 Defl

40、ection temperature under load at 1.8 MPa,ISO 75-1:1993 and ISO 75-2:1993, min, CFunspecified 30 45 60 70 80 90 100 115 specify valueC5 To be determined . . . . . . . . . .AIt is recognized that detailed test values, particularly Charpy impact, may not predict nor even correlate with the performance

41、of parts molded of these materials.BTensile strength shall be determined using a Type 1A tensile specimen as described in ISO 527-2:1993. Crosshead speed shall be 50 mm/min6 10 %.CIf a specific value is required, it must appear on the drawing or contract, or both.DTensile modulus shall be determined

42、 using a Type 1A tensile specimen as described in ISO 527-2:1993 at a test speed of 1 mm/min 6 20 %.EThe test specimen shall be 80 6 2by106 0.2 by 4 6 0.2 mm, cut from the center of the Type 1A tensile specimen and tested as described in ISO 179:1993, Method1eA.FThe test specimen size shall be 80 6

43、2by106 0.2 by 4 6 0.2 mm, cut from the center of the Type 1A tensile specimen. The requirements are based on unannealedtest specimens.TABLE 1 Recommended Processing ConditionsMaterialMelt Temperature,CMold Temperature,CAverage Injection Veloc-ity, mm/sHold Pressure Time,sTotal Cycle Time,sPBT, unfil

44、led semicrystalline 260 6 3806 5 200 6 100 20 6 5406 5PBT, filled semicrystalline 260 6 6 5 200 6 100 20 6 6 5PET, unfilled amorphous 285 6 326 5 200 6 100 20 6 6 5PET, unfilled semicrystalline 275 6 3 135 6 5 2006 100 20 6 5406 5PET, filled semicrystalline 285 6 3 135 6 5 2006 100 20 6 6 5PET, fill

45、ed semicrystalline, nucleated 285 6 31106 5 2006 100 20 6 6 5PET, filled semicrystalline, flame-retarded 2756 3 135 6 5 2006 100 20 6 5406 5PET, filled semicrystalline, flame-retarded,nucleated275 6 6 5 2006 100 20 6 6 5PCT, unfilled amorphous 300 6 3206 3 200 6 100 20 6 5406 5PCT, unfilled semicrys

46、talline 300 6 3 120 6 5 2006 100 20 6 6 5PCT, filled semicrystalline 300 6 3 120 6 5 2006 100 20 6 6 5PEN, unfilled amorphous 300 6 3206 3 200 6 100 20 6 5406 5D5927033TABLE TPES Detail Requirements for Thermoplastic PolyestersAGroup Description Class Description Grade DescriptionBFlow Rate,ISO1133:

47、1997,g/10 minDensity,ISO1183:1987,g/cm3TensileStrength, ISO527-1:1993and ISO527-2:1993,Cmin,MPaTensileModulus,ISO527-1:1993and ISO527-2:1993,Dmin, MPaCharpyImpact ISO179:1993,Emin, kJ/m2DeflectionTemperatureat 1.8 MPa,ISO 75-1:1993 and ISO75-2:1993,Fmin, C01 Polybutylene 1 general 1 6 250/2.16G1.28

48、to 1.34 45 1 800 3.0 .terephthalate purpose 2 12 250/2.16G1.28 to 1.34 45 1 800 3.0 .(PBT) 3 20 250/2.16G1.28 to 1.34 45 1 800 3.0 .4 35 250/2.16G1.28 to 1.34 45 1 800 3.0 .5 60 250/2.16G1.28 to 1.34 45 1 800 3.0 .6 100 250/2.16G1.28 to 1.34 45 1 800 3.0 .G10 10 % glass . 1.34 to 1.38 70 4 000 3.0 1

49、45G15 15 % glass . 1.36 to 1.47 75 4 500 3.0 160G20 20 % glass . . 80 6 000 4.5 .G30 30 % glass . 1.50 to 1.59 85 7 000 6.0 190G40 40 % glass . 1.58 to 1.65 115 10 000 6.0 190R40 40 % filler . 1.54 to 1.64 85 9 000 3.0 1800 other2 impact 1 20 250/5.0G1.16 to 1.32 20 1 000 45 .modified G05 5 % glass . 1.26 to 1.36 35 2 300 7.0 55G10 10 % glass . 1.25 to 1.35 35 3 500 3.3 85G15 15 % glass . 1.31 to 1.37 45 3 000 7.0 130G30 30 % glass . 1.42 to 1.53 70 7 000 7.0 145R40 40 % filler . 1.49 to 1.59 60 5 000 7.0 1500 other3 flame-retarded1 unfilled 1.38