1、FIRE PROTECTION GUIDE TOEdited byGuy R. ColonnaHazardous Chemicals/Materials Division ManagerHAZARDOUS MATERIALS14THEDITIONNational Fire Protection AssociationOne Batterymarch Park, Quincy, MA 02169ForewordInformation on the hazardous properties of chemicals is essential for those using thechemicals
2、 and for those confronted with chemical emergencies such as fires, accidentalspills, and transportation accidents. The information in this Guide can be used to identifythe hazardous properties of most of the chemicals in commercial use today, as well as manythat are available only in laboratory samp
3、le quantities.With the data and recommendations in this Guide, one can take the proper steps to preventfires and other emergencies during the use, storage, and transportation of chemicals andcan make informed decisions on the procedures to follow in an emergency involving chemi-cals. The Guide will
4、be particularly useful to fire and police department personnel and toothers with responsibility for protection of life and property.Preplanning is a well-proven means of increasing the effectiveness of fire-fighting opera-tions; it will be useful in minimizing the effects of fire and other emergenci
5、es involvingchemicals. The Guide provides essential information for preplanning activities. However, theexact plan of attack to be used at a chemical emergency cannot be decided until theemergency occurs and the properties of the chemicals involved have been identified. Withthe urgency of prompt ide
6、ntification in mind, the Guide has been arranged so that the usercan get to the necessary information with a minimum of delay.The Topic Finder, page v, is an alphabetical listing of the key topics to refer to in anemergency. These topics are printed in large type for easy reading under poor light co
7、ndi-tions.The three chemical matrixes assist the user in finding chemical information in this Guide.Matrix 1 lists the major chemical entries and references the appropriate document withinthe Guide. Matrix 2 lists common synonyms and references official chemical names and theappropriate document wit
8、hin the Guide. Matrix 3 is a numerically ordered list of ChemicalAbstracts Service (CAS) numbers and references the chemical name and the appropriatedocument within the Guide.While every effort has been made to make this Guide useful and complete, there are sureto be additional entries that should b
9、e included. Anyone wishing to recommend an additionor a correction, or wishing to comment, is encouraged to do so. Additional chemical entriesto the Hazardous Chemicals Data Compilation may be suggested using the sample data sheetincluded in Appendix B of that document.AcknowledgmentsThe editor woul
10、d like to thank those individuals who put in extra effort to ensure thequality of this revision of the Guide. First and foremost, I note the members of the TechnicalCommittee on Classification and Properties of Hazardous Chemical Data. I would like tothank Amy Cronin for her efforts to manage the ov
11、erall chemical data base that enablesNFPA to determine sources for specific values.I also wish to acknowledge the overall project management by Ann Coughlin.iiContentsRather than by chapter, the Guide is arranged by documents, each of which has acorresponding numerical designation. Each of the docum
12、ents is preceded by importantexplanatory information. This front matter should be studied before the text is utilized.The following listing describes each of the documents as they appear in this Guide.MatrixesFor quick and easy reference, all chemicals contained in the Guide are listed in 3 cross-re
13、ference matrixes, listing the document(s) where the chemical can be found by chemicalname, synonym, and Chemical Abstracts Service (CAS) number.Full Document Texts49 Hazardous Chemicals Data CompilationLists data on the fire hazard properties in MSDS format for approximately 325chemicals. Includes r
14、ecommendations on storage and fire fighting and NFPA 704diamond hazard ratings.325 Fire Hazard Properties of Flammable Liquids, Gases, and Volatile SolidsLists data on the fire hazard properties in table format of more than 1,300 flammablesubstances including, but not limited to, flashpoint, boiling
15、 point, flammable limits,the NFPA 704 diamond hazard ratings, NFPA 30/OSHA flammable and combustibleliquids classifications, as well as CAS numbers.491 Compilation of Hazardous Chemical ReactionsIncludes 3,600 mixtures of two or more chemicals reported to be potentially danger-ous in that they may c
16、ause fires, explosions, or detonations at ordinary or moderatelyelevated temperatures. Arranged alphabetically by chemical name. Reactions refer-enced.497 Recommended Practice for the Classification of Flammable Liquids, Gases, or Vapors and ofHazardous (Classified) Locations for Electrical Installa
17、tions in Chemical Process Areas, 2008edition.Includes parameters to determine degree and extent of hazardous locations forliquids, gases, and vapors including NEC groups for approximately 264 chemicals. Alsoprovides data on the properties of chemicals enabling proper selection of electricalequipment
18、 for use in these atmospheres.704 Standard System for the Identification of the Hazards of Materials for Emergency Response,2007 edition.Provides criteria for determining the degree of health, flammability, and instabilityhazard of materials that make up the diamond hazard ratings, as well as identi
19、ficationof special hazards (usually water reactivity and oxidizers). Provides guidance on howto apply the system.iiiData AnnexesEach of the annexes contains extracted data from existing current NFPA codes, standards,or recommended practices. This data should be used in conjunction with the associate
20、ddocument to fully understand the applicable requirements. The following summary state-ments identify the contents of the annexes that make up this Guide. Annexes include materialextracted from the following documents:77 Data from Recommended Practice on Static Electricity, 2007 edition.Data extract
21、ed from Annex B of NFPA 77 for numerous commercially significantmaterials. The data are relevant to static electricity, including combustibility parametersfor approximately 75 gases and vapors, and static electric characteristics for approxi-mately 155 conductive liquids, 21 semiconductive liquids,
22、and 33 nonconductive liq-uids.Also included are additional new Annexes C-F giving information on flash point,vapor pressure charge relaxation, and conductivity.400 Data from Hazardous Materials Code, 2010 edition.Table 5.2.1.1.3 for determining, for all industrial occupancies, the maximum allow-able
23、 quantities of hazardous materials per control area. In addition, Annexes B, F,and G provide supplementary information on chemical data, organic peroxides, andoxidizers.484 Data from Standard for Combustible Metals, 2009 edition.Data provided relating to electrically conductive floors and the combus
24、tibility andexplosibility of magnesium, tantalum, titanium, zirconium, and lithium.499 Data from Recommended Practice for the Classification of Combustible Dusts and of Hazardous(Classified) Locations for Electrical Installations in Chemical Process Areas, 2008 edition.The parameters to determine th
25、e degree and extent of hazardous locations fordusts, including CAS number, NEC group, and layer or cloud ignition temperatureare provided for approximately 220 combustible materials.ivTopic FinderSee document No.Boiling Points . 49, 325Chemicals Causing Hazardous Reactions When Mixed 491Clothing Con
26、tamination Hazard . 49Description of Hazardous Chemicals . 49Electrical Equipment for Hazardous Chemical Locations. 49, 497,499Explosives. 491Extinguishing Methods Recommended . 49, 325Fighting Fire in Hazardous Chemicals . 49Fire Fighting Procedures and Methods 49, 325Flammability Hazard Identifica
27、tion Method . 704Flammability Hazards Identified . 49, 325, 400Flammable Limits (Explosive Limits). 49, 325, 497Flash Point. 49, 325, 497Hazard Index Applied . 49, 325, 400Hazard Index Described 704Hazardous Chemical Reactions 491Hazardous Chemicals Data 49, 325Hazardous Chemicals, Description of 49
28、Health Hazard Identification Method . 704Health Hazards Identified 49, 325, 400Ignition Temperatures . 49, 325, 497Instability Hazard Identification Method 704Instability Hazards Identified. 49, 325, 400Marking System for Hazardous Material. 704Melting Point . 325Organic Peroxides 400Oxidizer, Speci
29、al Hazard Symbol 704Oxidizing Materials . 49, 400Personal Protective Equipment. 49Physical Properties . 49Polymerization Hazards Identified . 49Propagation of Flame 49Protective Clothing Defined 49Reactions of Two Chemicals Causing a Hazard 491Reactions with Water, Hazardous 49, 325Reactions with Wa
30、ter, Marking Symbol 704Respiratory Protective Requirements . 49Shipping Containers . 49Specific Gravity . 325Static Electricity Characteristics 77Storage Recommendations . 49Toxicity 49Vapor Density 49, 325, 497Vapor-Air Density, Defined . 49Water Reactivity Identification Symbol 704Water Reaction o
31、f Hazardous Chemicals . 49Water Solubility . 49, 325vMatrixesArranged by PageChemical Name 1Synonym 31CAS Number 63Chemical MatrixCHEMICAL Doc. No.CHEMICAL Doc. No.acrylamide 49, 491abalyn 325acetal 325 acrylamide polymer 499acetal, linear 499 acrylic acid 491, 497acetaldehyde 49, 77, 325, 491, 497
32、acrylic acid, glacial 325acetaldehyde (15H11034C) 77 acrylic acid, inhibited 49acetaldehydediethylacetal 325 acrylic aldehyde 325acetaldol 325 acrylonitrile 77, 325, 491, 497acetamide 77 acrylonitrile, inhibited 49acetanilide 49, 325 acrylonitrile polymer 499acetic acid 491, 497 acrylonitrile-vinyl
33、chloride- 499vinylidenechloride copolymeracetic acid (0H11034C) 77(70-20-10)acetic acid (25H11034C) 77acrylonitrile-vinyl pyridine 499acetic acid, glacial 49, 325copolymeracetic acid, isopropyl ester 325adipic acid 325, 499acetic acid, methyl ester 325adipic ketone 325acetic acid, n-propyl ester 325
34、adiponitrile 49, 325, 497acetic acid, water solutions 325adipoyl chloride 325acetic acid-tert-butyl ester 497alcohol 325acetic aldehyde 325aldol 325acetic anhydride 49, 325, 491, 497alfalfa meal 499acetic anhydride (25H11034C) 77alkyl ketone dimer sizing compound 499acetic ester 325all inorganic nit
35、rites 400acetic ether 325allene 491o-acetoacet anisidide 325allyl acetate 325m-acetoacet xylidide 325allyl alcohol 49, 77, 325, 491, 497acetoacet-ortho-toluidide 325allyl alcohol derivative (CR-39) 499acetoacet-p-phenetidide 325, 499allyl bromide 49, 325acetoacetanilide 325, 499allyl caproate 325ace
36、toacetic acid, ethyl ester 325allyl chloride 49, 77, 325, 491, 497acetoethylamide 325allyl chlorocarbonate 325acetone 77, 325, 491, 497allyl chloroformate 49, 325acetone cyanohydrin 49, 325, 491, 497allyl diglycol carbonate 325acetonitrile 49, 77, 325, 491, 497allyl ether 325acetonyl acetone 325ally
37、l glycidyl ether 497acetophenone 77, 325allyl isothiocyanate 325p-acetotoluidide 325allyl trichloride 325acetyl acetone 325allyl trichlorosilane 325acetyl bromide 77, 491allyl vinyl ether 325acetyl chloride 49, 77, 325, 491allylamine 49, 325n-acetyl ethanolamine 325allylene 325n-acetyl morpholine 32
38、5allylidene diacetate 325acetyl oxide 325allylpropenyl 325acetyl peroxide 325, 491almond shell 499acetylamino-t-nitrothiazole 499alpha methyl pyridine 325acetylene 77, 325, 491, 497alpha-methyl styrene 497acetylene dichloride-cis 325aluminum, A422 flake 499acetylene dichloride-trans 325aluminum alky
39、ls 49acetylene, dissolved 49aluminum, atomized collector fines 499acetylene in oxygen 77aluminum carbide 491acetylphenol 325aluminum chloride 491acrolein 77, 325, 491aluminum chloride, anhydrous 49acrolein dimer 325aluminum fluoride 491acrolein, inhibited 49, 4971CHEMICAL Doc. No.CHEMICAL Doc. No.am
40、monium perchlorate 49, 400, 491aluminum hydride 491ammonium permanganate 49, 400, 491aluminum hydroxide 491ammonium persulfate 400, 491aluminum oxide 491ammonium phosphate, 491aluminum phosphide 49, 491monoammonium phosphatealuminum powder, uncoated 49ammonium picrate 491aluminumcobalt alloy (6040)
41、499ammonium sulfate 491aluminumcopper alloy (5050) 499ammonium thiocyanate 491aluminumlithium alloy (15% Li) 499ammonium thiosulfate 491aluminummagnesium alloy 499(dowmetal) amoxybenzene 325aluminumnickel alloy (5842) 499 amyl acetate 77, 325aluminumsilicon alloy (12% Si) 499 sec-amyl acetate 325, 4
42、97amino ethane 325 n-amyl acetate 4972-amino-1-butanol 325 amyl alcohol 325, 4912-amino-2-methyl-1-propanol 325 sec-amyl alcohol 3251-amino-2-propanol 325 amyl bromide 3251-amino-4-ethoxybenzene 325 amyl butyrate 3252-amino-4-methylpentane 325 amyl carbinol 325amino-5-nitrothiazole 499 amyl chloride
43、 325aminobenzene 325 tert-amyl chloride 3252-aminobiphenyl 325 amyl chlorides (mixed) 3251-aminobutane 325 amyl ether 325aminocyclohexane 325 amyl formate 3251-aminodecane 325 t-amyl hydroperoxide 4002-aminoethanol 325, 491 amyl lactate 325H9252-aminoethyl alcohol 325 amyl maleate 3254-(2-aminoethyl
44、)morpholine 325 n-amyl mercaptan 3251-(2-aminoethyl)piperazine 325 amyl mercaptans 49, 325n-aminoethyl piperazine 77 amyl naphthalene 325aminoethyl-ethanolamine 77 amyl nitrate 49, 3252-aminoethylethanolamine 325 amyl oleate 325aminoguanidine nitrate 491 amyl oxalate 3251-aminoheptane 325 t-amyl per
45、oxy-2-ethylhexanoate 400H9251-aminoisopropyl alcohol 325 t-amyl peroxyacetate 4001-aminooctane 325 t-amyl peroxybenzoate 4002-aminopentane 325 t-amyl peroxyneodecanoate 400p-aminophenetole 325 t-amyl peroxypivalate 400(m-aminophenyl) methyl carbinol 325 o-amyl phenol 3253-aminopropanol 325 p-tert-am
46、yl phenol 325n-(3-aminopropyl) cyclohexylamine 325 amyl phenyl ether 325n-(3-aminopropyl) morpholine 325 amyl phthalate 3252-aminothiazole 491 amyl propionate 325ammonia 77, 497 amyl salicylate 325ammonia, anhydrous 49, 325, 491 amyl stearate 325ammonium acetate 491 amyl sulfides (mixed) 325ammonium
47、 carbonate 491 amyl toluene 325ammonium azide 491 amyl trichlorosilane 325ammonium bromide 491 amyl xylyl ether 325ammonium dichromate 49, 400, 491 amylamine 325ammonium chloride 491 sec-amylamine 325ammonium fluoride 49 amylamines 49ammonium hydroxide 491 p-tert-amylaniline 325ammonium iodide 491 a
48、mylbenzene 325ammonium nitrate 49, 491 amylcyclohexane 325ammonium oxalate 491 amylene 3252CHEMICAL Doc. No.CHEMICAL Doc. No.asphalt, liquid-slow curing (grade SC- 325amylene chloride 325250)H9252-amylene-cis 325asphalt, liquid-slow curing (grade SC- 325H9252-amylene-trans 3253000)p-sec-amylphenol 3
49、25asphalt, liquid-slow curing (grade SC- 3252-(p-tert-amylphenoxy)ethanol 32570)2-(p-tert-amylphenoxy) ethyl laurate 325asphalt, liquid-slow curing (grade SC- 325p-tert-amylphenyl acetate 325800)p-tert-amylphenyl butyl ether 325asphalt (typical) 325p-tert-amylphenyl methyl ether 325aspirin acetol (2) 499aniline 49, 77, 325, 491, 497azelaic acid 499aniline hydrochloride 325aziridine 3252-anilinoethanol 325azo-bis-butyronitrile 499H9252-anilinoethanol ethoxyaniline 325azobisisobutyronitrile 325o-anisaldehyde 325 H9251, H9251H11032-azodiisobutyronitrile 491o-anisidine 3
