1、_ SAE Technical Standards Board Rules provide that: “This report is published by SAE to advance the state of technical and engineering sciences. The use of this report is entirely voluntary, and its applicability and suitability for any particular use, including any patent infringement arising there
2、from, is the sole responsibility of the user.” SAE reviews each technical report at least every five years at which time it may be reaffirmed, revised, or cancelled. SAE invites your written comments and suggestions. Copyright 2008 SAE International All rights reserved. No part of this publication m
3、ay be reproduced, stored in a retrieval system or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of SAE. TO PLACE A DOCUMENT ORDER: Tel: 877-606-7323 (inside USA and Canada) Tel: 724-776-4970 (outside USA)
4、 Fax: 724-776-0790 Email: CustomerServicesae.org SAE WEB ADDRESS: http:/www.sae.org ARP9536 AEROSPACE RECOMMENDED PRACTICE Issued 2008-03 Declarable Substances Recommended Practice RATIONALE This Declarable Substances List is intended to be used in conjunction with AS9535 to address, in a consistent
5、 way, the collection of information on chemicals throughout the supply chain. This information is key for compliance with numerous regulatory requirements as well as to meet customer and other stakeholders expectations and obligations. The aerospace and defense sectors manufacture long life cycle pr
6、oducts. They consider it essential to know whether any of the substances inscripted in the Declarable Substances List are incorporated within the products they manufacture or in the manufacturing processes in order: - to anticipate, at the earliest design stage, any potential regulatory or business
7、risks that might occur, associated to these substances, - to ease compliance with appropriate applicable regulatory frameworks, - to facilitate end of life management, - to implement an efficient tracking process and anticipate any possible supply chain or business disruption. This is not necessaril
8、y a list of substances that should be removed from the aerospace and defense industries. Despite the fact that some of the substances contained on this list are not currently used within the aerospace and defense industries, they may be used at some point in the future. This use will be of interest
9、to customers or the sector to be tracked for appropriate management. Some of the substances within this list are either currently regulated or may be regulated when the assessments on the substances are completed. SAE International, in partnership with Aerospace Industries Association (AIA) and the
10、Aerospace and Defence Industries Association of Europe (ASD) compiled the list of all the substances that are known as being officially classified as: Carcinogens, Mutagens or Reproductive Toxins CMRs category 1 and 2, according to Annex 1 of Directive 67/548/EEC (as amended) Carcinogens, class 1 an
11、d 2A, according to IARC (International Agency for Research on Cancer) Persistent, Bioaccumulative and Toxic PBT, per the Convention for the Protection of the Marine Environment of the North-East Atlantic (known as the “OSPAR Convention“) - Chemicals for Priority Action (Marine Pollutants of the Nort
12、h-East Atlantic) (as amended through HSC(1) 2007) Substances defined as Persistent, Bioaccumulative and Toxic PBT or very Persistent, very bioaccumulative vPvB according to REACH regulation N1907/2006 Annex XIII; List obtained from ESIS (European chemical Substances Information System) SAE ARP9536 -
13、 2 - Substances called out in REACH Annex XVII “Other” chemicals of concern to the aviation sector (Ozone Depleting Substances ODS as defined by Montreal Protocol and Persistent Organic Pollutants POP as defined by the Stockholm Convention Many of the substances called out in the reference regulatio
14、ns are actually families of substances, rather than discreet chemicals. The list included in this standard is directly derived from the above sources. However, to facilitate the identification of those substances which fall into these families being used in the suppply chain, SAE E-1 Committee has f
15、urther populated the list with the detailed CAS numbers of the substances belonging to these referenced families. These CAS numbers were derived from several sources, included the N-Class database and the CAS Registry database. This detailed list appears in SA 9535 Substance Declaration Microsoft Ex
16、cel form. This compilation represents a good faith effort by the industry to accurately and completely compile a substance list based on regulations or stakeholders concerns. This list will be subject to change as new information becomes available, and we encourage users to refer to the latest versi
17、on of this recommended practice. 1. SCOPE This standard applies to the aerospace and defense industries and their supply chain. 1.1 Purpose This list of substances was developed for use by members of the aerospace and defense industries in order to assist in making product and process decisions to s
18、upport compliance with regulatory requirements, as well as to meet customers and other third party obligations. In addition, this list will assist aerospace industry member companies with managing business risks, such as supply chain disruption. 2. APPLICABLE DOCUMENTS This Recommended Practice will
19、 consist of a list of substances which are of interest to the sector to know whether any of these substances are used within aerospace products or manufacturing processes used to make these products. It is intended to be used in conjunction with ARP9536. SAE thanks Aerospace Industries Association (
20、AIA) and the Aerospace and Defence Industry Association of Europe (ASD) for their cooperation in the planning of this document. This document is being published simultaneously in the U.S. and in Europe. The European version carries the same number and is published by ASD-STAN. 2.1 SAE Publications A
21、vailable from SAE International, 400 Commonwealth Drive, Warrendale, PA 15096-0001, Tel: 877-606-7323 (inside USA and Canada) or 724-776-4970 (outside USA), www.sae.org. AS9535 Substance Declaration Standard 2.2 ASD-Stan Publications Available from ASD-STAN, 270, Avenue de Tervuren 2ndfloor, B-1150
22、Brussels, Belgium, Tel: +32 2 775 81 26 - Fax: +32 2 775 81 31, www.asd-stan.org. ASD-Stan 9535 SAE ARP9536 - 3 - 3. DISCLAIMER While due diligence is being exercised in creating the Declarable Substances list, this list should not be considered to be exhaustive and will be periodically reviewed and
23、 updated. Application of this standard is the sole responsibility of its users. 4. ARP9536 DECLARABLE SUBSTANCES LIST 4a. Glossary of Chemical Family Identifier Abbreviations used in ARP9536 Declarable Substances List CMRs: Carcinogens, Mutagens or Reproductive Toxins CAS Number: A CAS registry numb
24、er is a unique numeric identifier that can contain up to 10 digits, divided by hyphens into three parts, to designate only one chemical substance. The CAS number is assigned by the Chemical Abstract Service EINECS: European Inventory of Existing Chemical Substances) is a registry number given to eac
25、h chemical substance commercially available in the European Union between 1 January 1971 and 18 September 1981. The inventory was created by Directive 67/548/EEC concerning the labeling of dangerous substances. ELINCS: European List of Notified Chemical Substances HSC: Hazardous Substances Committee
26、 Intended Release: A substance is intended to be released, if under normal or reasonably foreseeable conditions of use, the release is essential for the end use function of the article. In other words, without the release of the substances, the article would not work sufficiently or as intended by t
27、he supplier of the article. Additionally, if the release contributes to a quality or minor function of the article, which is not directly connected to the end use function (e.g. perfumed eraser), then it is an intended release. Normal wear during use is not an intended release. MSDS: Material Safety
28、 Data Sheet is a form containing data regarding the properties of a particular substance. An important component of product stewardship and workplace safety, it is intended to provide workers and emergency personnel with procedures for handling or working with that substance in a safe manner, and in
29、cludes information such as physical data (melting point, boiling point, flash point, etc.), toxicity, health effects, first aid, reactivity, storage, disposal, protective equipment, and spill handling procedures. The exact format of an MSDS can vary from source to source from source to source and sh
30、all be provided in compliance with the applicable regulatory framework and in the language of the country where the item is delivered ODS: Ozone Depleting Substances PBT: Persistent, Bioaccumulative and Toxic POP: Persistent Organic Pollutants SAP: Enterprise resource planning software produced by S
31、AP AG, headquartered in Walldorf, Germany. vPvB: very Persistent and very Bioaccumulative SAE ARP9536 - 4 - 4b. Glossary of Chemical Family Identifier Abbreviations used in ARP 9536 Declarable Substances Lists Chemical Family Full Name FAMAs Arsenic Compounds, including arsenic acid and its salts FA
32、MAzoOther Other Azo compounds FAMBe Beryllium Compounds FAMBenzene Compounds based on a single benzene ring FAMBenziAzo Benzidine based azo dyes FAMCd Cadmium Compounds FAMCoWCarbide Cobalt metal with tungsten carbide FAMCr Chrome compounds, other than CrVI FAMCrVI Chromium (VI) compounds arsenic tr
33、ioxide FAMAs 1303-28-2 033-004-00-6 diarsenic pentaoxide; arsenic pentoxide; arsenic FAMAs NOCAS0019 033-005-00-1 arsenic acid and its salts FAMAs 7784-40-9 082-011-00-0 lead hydrogen arsenate; Arsenic acid, lead(2+) salt (1:1) FAMAs 23593-75-1 clotrimazole FAMAzoOther 592-62-1 611-004-00-2 methyl-O
34、NN-azoxymethyl acetate; methyl azoxy meth FAMAzoOther 7440-41-7 004-001-00-7 beryllium FAMBe NOCAS0015 004-002-00-2 beryllium compounds FAMBe 1304-56-9 004-003-00-8 beryllium oxide FAMBe 108-70-3 1,3,5-trichlorobenzene FAMBenzene 108-88-3 TOLUENE FAMBenzene 120-82-1 1,2,4trichlorobenzene; TRICHLOROB
35、ENZENE FAMBenzene 133-49-3 Pentachlorobenzenethiol FAMBenzene 31472-83-0 Tetrachloro(tetrachlorophenyl)benzene FAMBenzene 50-00-0 FORMALDEHYDE FAMBenzene 552-89-6 O-NITROBENZALDEHYDE FAMBenzene 85-22-3 pentabromoethylbenzene* FAMBenzene 87-61-6 1,2,3-trichlorobenzene FAMBenzene 75-28-5 601-004-01-8
36、isobutane (containing 0.1 % butadiene FAMBenzene 71-43-2 601-020-00-8 benzene FAMBenzene 118-74-1 602-065-00-6 hexachlorobenzene (HCB) FAMBenzene 96-09-3 603-084-00-2 styrene oxide; (epoxyethyl)benzene; phenyloxiran FAMBenzene 84777-06-0 607-426-00-1 1,2-benzenedicarboxylic acid, dipentylester, bran
37、ched and linear FAMBenzene 68515-42-4 607-480-00-6 1,2-benzenedicarboxylic acid; di-C7-11-branched a FAMBenzene 79-46-9 609-002-00-1 2-nitropropane FAMBenzene 121-14-2 609-007-00-9 2,4-dinitrotoluene dinitrotoluene, technical grade FAMBenzene 25321-14-6 609-007-00-9 2,4-dinitrotoluene FAMBenzene 92-
38、93-3 609-039-00-3 4-nitrobiphenyl FAMBenzene 602-01-7 609-050-00-3 2,3-dinitrotoluene FAMBenzene 618-85-9 609-052-00-4 3,5-dinitrotoluene FAMBenzene 81-15-2 609-068-00-1 musk xylene FAMBenzene 25376-45-8 612-151-00-5 methyl-phenylenediamine diaminotoluene, technical product - mixture FAMBenzene of 2
39、 and 3 SAE ARP9536 - 6 - CAS Number EU Index Number Chemical Name Chemical Family 122-66-7 007-021-00-4 hydrazobenzene; 1,2-diphenylhydrazine FAMBenziAzo 60-09-3 611-008-00-4 4-aminoazobenzene; 4-phenylazoaniline FAMBenziAzo NOCAS0023 611-024-00-1 Benzidine based azo dyes; 4,4; -diarylazobiphen FAMB
40、enziAzo 1937-37-7 611-025-00-7 disodium 4-amino-3-4-(2,4-diaminophenyl)azo1 FAMBenziAzo 2602-46-2 611-026-00-2 tetrasodium 3,3-1,1-biphenyl-4,4-diylbis(azo FAMBenziAzo 573-58-0 611-027-00-8 disodium 3,3-1,1-biphenyl-4,4-diylbis(azo)b FAMBenziAzo 108225-03-2 611-058-00-7 (6-(4-hydroxy-3-(2-methoxyphe
41、nylazo)-2-sulfonato-7 FAMBenziAzo 32534-81-9 Pentabrominated diphenyl ether (pentaBDE) FAMBrominatedHC 32536-52-0 Octabrominated diphenyl ether (octaBDE); Diphenyl ether, octabromo FAMBrominatedHC derivative 36355-01-8 Hexabromobipheny l-1,1 -bipheny l FAMBrominatedHC 59536-65-1 Hexa C W . Co; Cobal
42、t metal FAMCoWCarbide with tungsten carbide NOCAS0026 Cobalt metal with tungsten carbide FAMCoWCarbide 7789-09-5 024-003-00-1 ammonium dichromate FAMCr 24613-89-6 024-010-00-X dichromium tris(chromate); chromium III chromate; FAMCr 1333-82-0 024-001-00-0 chromium (VI) trioxide FAMCrVI 7778-50-9 024-
43、002-00-6 potassium dichromate FAMCrVI 10588-01-9 024-004-00-7 sodium dichromate anhydrate FAMCrVI 7789-12-0 024-004-01-4 sodium dichromate, dihydrate FAMCrVI 14977-61-8 024-005-00-2 chromyl dichloride; chromic oxychloride FAMCrVI 7789-00-6 024-006-00-8 potassium chromate FAMCrVI 13765-19-0 024-008-0
44、0-9 calcium chromate FAMCrVI 7789-06-2 024-009-00-4 strontium chromate FAMCrVI NOCAS0018 024-017-00-8 Chromium (VI) compounds FAMCrVI SAE ARP9536 - 7 - CAS Number EU Index Number Chemical Name Chemical Family 7775-11-3 024-018-00-3 sodium chromate FAMCrVI NOCAS0024 611-029-00-9 o-dianisidine based a
45、zo dyes; 4,4-diarylazo-3,3 FAMDianisAzo 88-85-7 609-025-00-7 dinoseb; 6-sec-butyl-2,4-dinitrophenol FAMDinoseb NOCAS0021 609-026-00-2 salts and esters of dinoseb FAMDinoseb 1420-07-1 609-030-00-4 dinoterb (ISO); 2-tert-butyl-4,6-dinitrophenol FAMDinoterb NOCAS0022 609-031-00-X salts and esters of di
46、noterb FAMDinoterb 492-80-8 4,4-CARBONIMIDOYLBIS(N,N-DIMETHYLANILIN); AURAMINE, FAMDye MANUFACTURE OF 632-99-5 MAGENTA, MANUFACTURE OF FAMDye 2475-45-8 611-032-00-5 1,4,5,8-tetraaminoanthraquinone; C.I. Disperse Bl FAMDye 16071-86-6 611-005-00-8 disodium 5-(4-(2,6-hydroxy-3-(2-hydroxy-5-sul FAMDyes
47、1317-95-9 Tripoli FAMFiber/Ceramic 1332-21-4 ASBESTOS FIBRES FAMFiber/Ceramic 14464-46-1 Cristobalite FAMFiber/Ceramic 14808-60-7 Quartz FAMFiber/Ceramic 15468-32-3 Tridymite FAMFiber/Ceramic 12510-42-8 650-012-00-0 erionite FAMFiber/Ceramic 12001-28-4 650-013-00-6 Crocidolite - ASBESTOS FIBRES FAMF
48、iber/Ceramic 12001-29-5 650-013-00-6 Chrysotile - ASBESTOS FIBRES FAMFiber/Ceramic 12172-73-5 650-013-00-6 Amosite (Grunerite); ASBESTOS FIBRES FAMFiber/Ceramic 132207-32-0 650-013-00-6 asbestos, CHRYSOTILE FAMFiber/Ceramic 77536-66-4 650-013-00-6 Actinolite - ASBESTOS FIBRES FAMFiber/Ceramic 77536-67-5 650-013-00-6 Anthophyllite - ASBESTOS FIBRES FAMFiber/Ceramic 77536-68-6 650-013-00-6 Tremolite - ASBESTOS FIBRES FAMFiber/Ceramic NOCAS0025 650-017-00-8 Refractory Ceramic Fibres; Special Purpose Fibres, FAMFiber/Ceramic 106340-44-7 Tetrabromodibenzofuran (TeBDF) FAMFuran/Dioxin 1746-01-6
