1、Designation: D3030 17Standard Test Method forVolatile Matter (Including Water) of Vinyl Chloride Resins1This standard is issued under the fixed designation D3030; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last rev
2、ision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This test method covers the quantitative determinationof the volatile matter (including water) present in vinylchloride resin
3、s.1.2 The values stated in SI units are to be regarded asstandard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety, health, and environmental practices and d
4、eter-mine the applicability of regulatory limitations prior to use.NOTE 1This test method is identical ISO 1269.1.4 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of
5、International Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standards:2D618 Practice for Conditioning Plastics for TestingD883 Terminology Relating to PlasticsD1600 Terminology forAbbreviated T
6、erms Relating to Plas-ticsE145 Specification for Gravity-Convection and Forced-Ventilation OvensE456 Terminology Relating to Quality and StatisticsE2935 Practice for Conducting Equivalence Testing inLaboratory Applications2.2 ISO Standard:ISO 1269 Homopolymer and Copolymer Resins of VinylChlorideDet
7、ermination of Volatile Matter IncludingWater33. Terminology3.1 Definitions: Definitions are in accordance with Defini-tions D883 and Terminology D1600, unless otherwise indi-cated.4. Summary of Test Method4.1 This test method consists of heating at 110C a knownquantity of powdered resin to constant
8、mass. The calculatedmass loss defines quantitatively the volatile matter present inthe sample.5. Significance and Use5.1 The quantity of volatile components in a vinyl chlorideresin can be established by this test method. This test methoddoes not identify the components.6. Apparatus6.1 OvenA forced-
9、ventilation oven conforming to therequirements for Type IIA in Specification E145. The ovenshould be capable of maintaining a temperature of 110 6 1Cwhen the damper is half open and the vent is wide open.6.1.1 The oven shall be equipped with a calibrated ASTMthermometer and the proper stem correctio
10、n shall be applied tothe temperature measurement.6.1.2 The oven temperature shall be controlled by anaccurate, reliable thermoregulator, maintaining the set pointwithin 61.0C or better.6.1.3 The inside of the oven shall be free of contaminationor surface deposits. Stainless steel oven liners should
11、be usedto reduce corrosion due to continued exposure to decomposi-tion gases.6.2 Sample ContainerA weighing vessel of low shapedesign in glass, aluminum, or stainless steel of sufficient size tohold a 10-g resin sample.1This test method is under the jurisdiction of ASTM Committee D20 on Plasticsand
12、is the direct responsibility of Subcommittee D20.15 on Thermoplastic Materials(Section D20.15.08).Current edition approved Dec. 1, 2017. Published January 2018. Originallyapproved in 1972. Last previous edition approved in 2011 as D3030 - 11. DOI:10.1520/D3030-17.2For referenced ASTM standards, visi
13、t the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York,
14、 NY 10036, http:/www.ansi.org.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationally recognized prin
15、ciples on standardization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.107 NOTE 2An aluminum weighing dish, 57 mm in diameter and 18 mmin depth, i
16、s suitable.6.3 BalanceAweighing balance with a precision to within0.001 g.7. Preparation of Apparatus7.1 Maintain the oven at the temperature of the test for atleast 1 h prior to insertion of the specimens.7.2 Prior to test operation, verify the uniformity of tempera-ture within the oven according t
17、o Specification E145. Theairflow in the oven should be greater than 0.3 m3/min (10ft3/min).NOTE 3The temperature uniformity can also be verified by placing 5or more portions of the same resin sample in the oven, distributed over thetest area, following Section 8. Calculate the percent of volatile lo
18、ss(Section 9). If the differences in the volatile loss of the samples exceed thetest reproducibility, the temperature in the oven is not uniform and mustbe corrected before proceeding with the test.8. Procedure8.1 Dry the weighing vessel in the oven at 110 6 1C for 30min and cool to room temperature
19、 in a desiccator. Tare theweighing vessel to the nearest 0.001 g.8.2 Spread approximately 10 g of sample resin evenly overthe bottom of the weighing vessel and weigh to the nearest0.001 g. Record the sample mass.8.3 Place the resin-filled weighing dish in the oven con-trolled at 110 6 1C and close t
20、he oven.8.4 After 1 h, remove the weighing dish, cool to roomtemperature in a desiccator, and weigh to the nearest 0.001 g.Return the weighing dish to the oven and heat for an additional15 min, cool to room temperature in the desiccator, andre-weigh. Constant mass is reached when the successiveweigh
21、ing differs by 0.001 g or less; if the mass variation isgreater than 0.001, continue the 15 min heating-weighing cycleuntil constant mass is obtained.NOTE 4Prompt weighing after removal of the dish from desiccatorwill improve accuracy.8.5 Test a minimum of two samples, and average the results.9. Cal
22、culation9.1 For each determination calculate the mass percent ofvolatile matter present as follows:M 2 M!/M# 3100where:M and M = respectively, the mass before and after heatingof the resin determined at room temperature (atemperature in the range from 20 to 30C (68 to85F), as defined in Methods D618
23、).10. Report10.1 Report the following information:10.1.1 The arithmetic average of the determinations to thenearest 0.01 mass %.11. Precision and Bias11.1 The following should be used for judging the accept-ability of results (95 % confidence limits):11.2 Reproducibility Limit, RThe value below whic
24、h theabsolute difference between two test results obtained underreproducibility conditions is likely to be expected to occur witha probability of approximately 0.95 (95 %).11.3 Repeatability Limit, rThe value below which theabsolute difference between two individual test results obtainedunder repeat
25、ability conditions is likely to be expected to occurwith a probability of approximately 0.95 (95 %).11.4 Equivalence testing on numerical data from twosources shall be conducted in accordance with Practice E2935or any known method for judging the equivalence of twomeans.NOTE 5Example: a t-test.11.5
26、BiasNo justifiable statement of bias can be made forthis test method, since the true value of the property cannot beestablished by an accepted referee method.NOTE 6Other techniques of volatile determinations may be substi-tuted at the option of the purchaser and seller, such as the use of asemi-auto
27、matic moisture tester or a procedure employing an infrared lampas a heating source. With such methods, the temperature of the heatedsample must be maintained at 110 6 1C.12. Keywords12.1 moisture content; test method; vinyl chloride resins;volatile matterD3030 17207 SUMMARY OF CHANGESCommittee D20 h
28、as identified the location of selected changes to this standard since the last issue (D3030 - 11)that may impact the use of this standard. (December 1, 2017)(1) Added E456 and E2935 references to 2.1.(2) Changed the set point accuracy to 61C in 6.1.2 to agreewith test oven accuracy, 6.1.(3) Added ne
29、w Note 2: Aluminum pan dimensions.(4) Renumbered Note 2 to 3.(5) Renumbered Note 3 to 4.(6) Reworded 11.2 and 11.3.(7) Added new 11.4.(8) Added new Note 5.(9) Renumbered old 11.4 to 11.5.(10) Renumbered Note 4 to 6.ASTM International takes no position respecting the validity of any patent rights ass
30、erted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time b
31、y the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will rece
32、ive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM Inte
33、rnational, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 17307
