1、 API PUBL*4bL3 94 0732290 0533383 754 1993 Study of Refinery Fugitive Emissions from Equipment Leaks Volume 111: Appendices Prepared for: American Petroleum Institute Health and Environmental Sciences Department and Western States Petroleum Association API PUBLICATION NUMBER 461 3 PREPARED UNDER CON
2、TRACT BY: RADIAN CORPORATION SACRAMENTO, CALIFORNIA APRIL 1994 American Petroleum Institute API PUBL*4613 94 0732290 0533384 b0 = FOR E WOR D API PUBLICATIONS NECESSARILY ADDRESS PROBLEMS OF A GENERAL NATURE. WITH RESPECT TO PARTICULAR CIRCUMSTANCES, LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS SH
3、OULD BE REVIEWED. API IS NOT UNDERTAKING TO MEET THE DUTIES OF EMPLOYERS, MANUFAC- TURERS, OR SUPPLIERS TO WARN AND PROPERLY TRAIN AND EQUIP THEIR EMPLOYEES, AND OTHERS EXPOSED, CONCERNING HEALTH AND SAFETY RISKS AND PRECAUTIONS, NOR UNDERTAKING THEIR OBLIGATIONS UNDER LOCAL, STATE, OR FEDERAL LAWS.
4、 NOTHING CONTAINED IN ANY API PUBLICATION IS TO BE CONSTRUED AS GRANTING ANY RIGHT, BY IMPLICATION OR OTHERWISE, FOR THE MANU- FACTURE, SALE, OR USE OF ANY METHOD, APPARATUS, OR PRODUCT COV- ERED BY LETTERS PATENT. NEITHER SHOULD ANYTHING CONTAINED IN ITY FOR INFRINGEMENT OF LETTERS PATENT. THE PUBL
5、ICATION BE CONSTRUED AS INSURING ANYONE AGAINST LIABIL- NOTE: This is to advise the reader that these studies are now under review by the U.S. Environmental Protection Agency. The Agencys review may be complete by summer 1994. Copyright 8 1994 Amencan Pctroleum Insuiurc II API PUBL+4bL3 94 0732290 0
6、533385 527 ACKNOWLEDGMENTS THE FOLLOWING PEOPLE ARE RECOGNIZED FOR THEIR CONTRIBUTIONS OF TIME AND EXPERTISE DURING THIS STUDY AND IN THE PREPARATION OF THIS REPORT API STAFF CONTACTS: Karin Ritter, Health and Environmental Affairs Department Paul Wakim, Statistics Department MEMBERS OF THE AIR TOXI
7、CS MULTIYEAR STUDY WORKGROUP : Julian Blomlcy, UNOCAL Miriam Lev-On, ARCO Products Company Richard Russell, API Consultant Hal Taback, MI Consultant Daniel VanDcrZandcn, Chevron Research and Technology Company This study was Co-funded by the Wcstem States Petroleum Association (WSPA). The following
8、membcrs of the WSPA Fugitivc Emissions Project Steering Committee are recognized for their contributions of timc and expertise: Frank Giles, Ultramar Mau Marusich, Tosco Refining Company Julian Blomley, UNOCAL Miriam Lev-On, ARCO Products Company Daniel Van Dcr Zanden, Chevron Research and Technolog
9、y Company In addition thc U.S. EPA Officc of Air Quality Planning and Standards, Emission Inventory Branch, Research Triangle Park, North Carolina; South Coast Air Quality Management District; Bay Arca Air Quality Management District; and, California Air Resources Board are gntcfully recognized for
10、providing oversight, additional review of draft reports and concurrcnt QA/QC of final measurements during this study. iii API PUBL*Lib13 94 = 0732290 0533386 4b3 LIST OF APPENDICES Appendix Page 1 Introduction 1-1 A Raw Data from Field and Emissions Calculations A-1 A.l WSPA Emission Rate Calculatio
11、n Spreadsheet . A-1 A.2 Emission Correlation Equations Data . A-123 A.3 Zero Component Emissions Data A-130 A.4 Pegged Component Emissions Data A-134 Comparison of Vapor Leak Composition to Liquid Stream Composition Data and Calculations . B-1 Statistical Evaluations and Correlation Details . C-1 De
12、velopment of Emission Correlation Equations Using the Measurement Error Method (MEM) Statistical Analysis Method D-1 B C D E Independent Audit Results E-1 1993 Refinery Study F-1 F Response to Regulatory Agency Comments on the Final Draft of the 8API PUBLr4613 94 W 0732290 0533387 3TT INTRODUCTION T
13、his volume, Volume III of the 1993 Study of Refinery Fugitive Emssionsffom Equipment Leaks, contains the appendices related to the data calculations and independent audit results. Specifically: e Appendix A contains raw data from field and emissions calculations; Appendix B documents the comparison
14、of vapor leak composition to liquid stream composition data and calculations; Appendix C contains statistical evaluations and correlation details; Appendix D discusses the development of emission correlation equations using the Measurement Error Method (MEM) statistical analysis method; Appendix E c
15、ontains independent audit results; and Appendix F reprints the Response to Regulatory Agency Comments on the Final Draft of the 1993 Refinery Study. 1-1 API PUBL*46L3 94 = 0732290 0533388 236 APPENDIX A RAW DATA FROM FIELD AND EMISSIONS CALCULATIONS API PUBL*YbL3 9Y W 0732290 0533389 172 A. 1 WSPA E
16、MISSION RATE CALCULATION SPREADSHEET API PUBL*4bL3 94 O732290 O533390 994 :ODES: ACCY AUDTC AUDTD AUDll BL DINV DUP DZ I NV L N2-# PEG PEGF PEG1 PGAC SINV *DRIP ACTUATION: C M SERVICE: HL LL UNIT: SRU VRU COMPONENT CATEGORY: C OEL PRV Accuracy check Audit gas directly to canister Audit duplicate Aud
17、it gas through tent Blank sampie Determined to be invalid after review Sample duplicate Default zero Invalid Liquid sample Nitrogen flow test Pegged source Final screening value pegged but not initial Initial screening value pegged but not final Pure gas accuracy check Screening values invalid (e, i
18、nitial and final screening values varied by more than a factor of 2) Component dripping; liquids collected and liquid concentration added to emission rates Control Manual Heavy liquid tight liquid Sulfur recovery unit Vapor recovery unit Connector Open-ended line Pressure relief valve A- 1 API PUBL8
19、4613 94 H 0732290 0533393 820 COMPONENT TYPE: BTFf C CENT COUP DIA FL HC MC NEDL OEL PRV TH U vc VERT PRODUCT DB HCO HTGO LCO LPG LVGO OVHG gas Pa B R Diesel Reg UL LABORATORY DATA NA Butterfly valve Connector Centrifugal Coupler Diaphrarn valve mange Horizontal centrifugal Motor control Needle Open
20、-ended line Pressure relief valve Threaded connector Union connector Vertical centrifugal Vertical Debutinized bottoms Heavy cycle oil Hydrotreated gas oil Light cycle oil Uquified petroleum gas Light vacuum gas oil Overhead gas Pa bottoms Recycled diesel Regular unleaded gasoline Not analvzed A-2 A
21、PI PUBL*qb13 94 W 0732290 0533392 7b7 W A-3 API PUBLU4bL3 94 0732290 0533393 bT3 m A-4 API PUBLS4613 94 W 0732270 0533394 53T A-5 API PUBLU4bL3 94 0732290 0533395 47b A-6 t r o w (o ;5 a n (o 2 v) 3 Q c Q U O n a E O t m U t W I LI) n a W U n LI) z 2 3 3 W 5 z LI) 0 s2 w a 3 0 m a m o. i I a m 2 8 P 4 e C O - b 8 x I W a? t H a a s 3 - i s d 9 - U o : A-19 t API PUBLs4bL3 94 0732290 0.533409 890 W e E c C c o U a U I + O O id -8 n 4 - 0 9 I l i I I I i ! 1 1 A-20 API PUBL*:Yb33 94 = 0732290 0533430 502 m A-2 1 API PUBL*4613 74 0732290 0533411 449 A-22
