1、INCH -POUNDDISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimitedMIL-DTL-211Fw/AMENDMENT 13 April 2008SUPERSEDINGMIL-P-211F24 July 2000DETAIL SPECIFICATIONPHOSPHORUS, RED, TECHNICALThis specification is approved for use by allDepartments and Agencies of the Department of De
2、fense.1. SCOPE1.1 Scope. This specification covers three classes of red phosphorus.1.2 Classification. The classes of red phosphorus are specified as follows (see 6.2):Class 1 - DryClass 3 - Dust suppressed with lubricating oilClass 4 - Dust suppressed with aliphatic alcohol alkoxylate2. APPLICABLE
3、DOCUMENTS2.1 General. Thedocumentslistedinthissectionarespecifiedinsections3or4ofthisspeci-fication. This sectiondoes not include documents citedin other sections ofthis specificationorrecommended for additional information or as examples. While every effort has been made toinsurethecompletenessofth
4、islist,documentusersarecautionedthattheymustmeetallspeci-fiedrequirementsofdocumentscitedinsections3or4ofthisspecification, whetherornottheyare listed.AMSC N/A FSC 6810Comments, suggestions, or questions on this document should be addressed to: U.S. Army EdgewoodChemical Biological Center, ATTN: AMS
5、RD-ECB-ENA-S, 5183 Blackhawk Road, Aberdeen ProvingGround, MD 21010-5424 or emailed to SpecsTeamapgea.army.mil. Since contact information canchange, you may want to verify the currency of this address information using the ASSIST Online databaseat http:/assist.daps.dla.mil.Provided by IHSNot for Res
6、aleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-211Fw/AMENDMENT 122.2 Government documents.2.2.1 Specifications, standards, and handbooks. The following specifications, standards,and handbooks form a part of this document to the extent specified herein. Unless otherwi
7、sespecified, the issues of these documents are those cited in the solicitation or contract.FEDERAL STANDARDSFEDERALFED-STD-313 - Material Safety Data, Transportation Data and Disposal Datafor Hazardous Materials Furnished to the Government.(Copies of these documents are available online at http:/ass
8、ist.daps.dla.mil/quicksearch/ orhttp:/assist.daps.dla.mil or from the Standardization Document Order Desk, 700 Robbins Ave-nue, Building 4D, Philadelphia, PA 19111-5094.)2.2.2 Other Government documents, drawings, and publications. The following otherGovernmentdocuments, drawings, and publications f
9、orm a part ofthis documentto the extentspecifiedherein.Unlessotherwisespecified,theissuesofthesedocumentsarethosecitedinthesolicitation.CODE OF FEDERAL REGULATIONS (CFR)49CFR171to199 - DepartmentofTransportationHazardousMaterialsRegulations(TheCodeofFederalRegulationsisavailableonlineatwww.access.gp
10、o.govorfrom theSu-perintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. Or-ders for the above regulation should cite 49 CFR 171 to 199.)2.3 Non-Governmentpublications. Thefollowingdocumentsformapartofthisdocumentto the extent specified herein. Unless otherwise specified
11、, the issues of these documents arethose cited in the solicitation or contract.INTERNATIONAL CIVIL AVIATION ORGANIZATIONTechnical Instructions for the Safe Transport of Dangerous Goods by Air(Application for copies should be addressed to the International Civil Aviation Organiza-tion, 1000 Sherbrook
12、e Street West, Suite 400, Montreal, Quebec, Canada H3A 2R2)INTERNATIONAL MARITIME ORGANIZATIONInternational Maritime Dangerous Goods Code(Application for copies should be addressed to the International Maritime Organization, 101-104Piccadilly, London, WIV OAE, England)Provided by IHSNot for ResaleNo
13、 reproduction or networking permitted without license from IHS-,-,-MIL-DTL-211Fw/AMENDMENT 13ASTM STANDARDSB 527 - Standard Test Method for Determination of Tap Density of MetallicPowders and CompoundsD 92 - Flash and Fire Points by Cleveland Open CupD 97 - Pour Point of Petroleum OilsD 130 - Detect
14、ion of Copper Corrosion from Petroleum Products by the CopperStrip Tarnish TestD 445 - Kinematic Viscosity of Transparent and Opaque Liquids (and theCalculation of Dynamic Viscosity)D 974 - Acid and Base Number by Color-Indicator TitrationD 1193 - Reagent WaterD 1500 - ASTM Color of Petroleum Produc
15、ts (ASTM Color Scale)D 2270 - Calculating Viscosity Index from Kinematic Viscosity at 40 and 100 _CC 117 - Standard Test Method for Minerals Finer than 75-mm (No. 200) Sieve inMineral Aggregates by WashingE 11 - Wire-Cloth Sieves for Testing Purposes(Copiesofthisdocumentareavailablefromwww.astm.orgo
16、rASTMInternational,100BarrHarbor Drive, West Conshohocken, PA 19428-2959.)2.4 Order of precedence. In the event of a conflict between the text of this document and thereferences cited herein, the text of this document takes precedence. Nothing in this document, howev-er, supersedes applicable laws a
17、nd regulations unless a specific exemption has been obtained.3. REQUIREMENTS3.1 Physical characteristics. Each class of red phosphorus shall conform to the applicablechemical and physical characteristics of table I when tested as specified therein. Class 3 redphosphorus shall be coated with lubricat
18、ing oil conforming to the chemical and physicalcharacteristicsoftableIIwhentestedasspecifiedtherein. Class4hydrophilicdustsuppressantshallbe a straight chain, primary aliphatic alcohol alkoxylate added during manufactureprior todrying;the contractor shall certify that this requirement has been met (
19、see 6.3).3.2 Material Safety Data Sheets. Material Safety Data Sheets for red phosphorus shall beprepared and submitted by the contractor in accordance with FED-STD-313 (see 6.4).Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-211Fw/AMENDMENT
20、 14TABLEI.ChemicalandphysicalcharacteristicsParticlesize:RetainedonNo.200(75mm)sieveRetainedonNo.400(38mm)sieveTapDensity(g/cm)Iron CopperAcidity(asHPO)DustSuppressant/OilVolatilesRedPhosphorusWhitePhosphorusCHARACTERISTICClass1Class3Class4Para.TestMinMaxMinMaxMinMax99.097.097.04.2.4.34.2.4.14.2.4.6
21、4.2.4.24.2.4.44.2.4.34.2.4.34.2.4.74.2.4.5340.020.250.100.060.0051.20.020.250.101.30.060.0050.80.81.21.20.020.250.101.50.060.005530530530306030603060PERCENTBYWEIGHT3Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-211Fw/AMENDMENT 15TABLE II. L
22、ubricating oil chemical and physical characteristicsCharacteristic Requirement ASTMtest methodViscosity, kinematic (centistokes) at 37.8_CFlash point, minimum, _CPour point, maximum, _CASTM Color, maximumNeutralization number, maximumCopper corrosion, ASTM classification,maximum at 100_CViscosity in
23、dex, minimum17 to 20149-3430.10130D 445D92D97D 1500D 974D 130D 22704. VERIFICATION4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchaseorder, the contractor is responsible for the performance of all inspection requirements (ex-aminations and tests) as specified he
24、rein. Except as otherwise specified in the contract or pur-chase order, the contractor mayuse his ownor anyother facilities suitable for the performanceof the inspection requirements specified herein, unless disapproved by the Government. TheGovernment reserves the right to perform any of the inspec
25、tions set forth in this specificationwhere such inspections are deemed necessary to ensure supplies and services conform to pre-scribed requirements.4.1.1 Responsibilityforcompliance. Allitemsshallmeetallrequirements ofsections 3and5. The inspection set forth in this specification shall become a par
26、t of the contractors overallinspectionsystemorqualityprogram.The absence ofanyinspectionrequirements inthe speci-ficationshallnotrelievethecontractoroftheresponsibilityofensuringthatallproducts orsup-pliessubmittedtotheGovernmentforacceptancecomplywithallrequirementsofthecontract.Samplinginspection,
27、aspartofmanufacturingoperations,isanacceptablepracticetoascertainconformance torequirements, however, this does notauthorize submissionof knowndefectivematerial,eitherindicatedoractual,nordoesitcommittheGovernmenttoacceptdefectivema-terial.4.1.2 Contractorassuranceofcompliance. Thecontractorsquality
28、programordetailedin-spection systemshall provide assurance ofcompliance ofall characteristicswith the applicableProvided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-211Fw/AMENDMENT 16drawing, special packaging instruction, and specification requir
29、ements using, as a minimum,the conformance criteria specified herein.4.1.3 Alternative inspection provisions. Alternative inspection procedures, methods, orequipment, such as statistical process control, tool control, and other types of samplingproceduresmaybeusedbythecontractorwhentheyprovide,asami
30、nimum,thelevelorqualityassurance required by the inspection provisions specified herein. Prior to applying suchalternative procedures, methods, orequipment, the contractor shall describe them in a writtenproposalsubmittedtotheGovernmentforevaluationandapproval.(See 6.9.) Whenrequired,thecontractorsh
31、alldemonstratethattheeffectivenessofeachproposedalternativeisequaltoorbetter than the quality assurance provisions specified herein. In cases of dispute as towhetherthe contractors proposed alternative provides equal quality assurance, the provisions of thesespecification shall apply. All approved a
32、lternative inspection provisions shall be specificallyincorporatedintothe contractors qualityprogram ordetailedinspectionsystem, asapplicable.4.2 Quality conformance inspection4.2.1 Lotting. A lot shall consist of the red phosphorus of one class produced by onemanufacturer, at one plant, from the sa
33、me materials, and under essentially the samemanufacturing conditions provided the operation is continuous. In the event the process is abatch operation, each batch shall constitute a lot (see 6.5).4.2.2 Sampling.4.2.2.1 For examination of packaging. Sampling shall be as specified in the contract (se
34、e6.2).4.2.2.2 For test (see 6.6). Sampling shall be conducted in accordance with table III. Arepresentativespecimenof4533grams(g)shallberemovedfromeachsamplecontainerandplacedinasuitableclean,drycontainerlabeledtoidentifythelotandcontainerfromwhichitwas taken.Number of containers in batch or lot Num
35、ber of sample containers2to2526 to 150151 to 1,2001,201 to 7,0007,001 to 20,000Over 20,00023581020TABLE III. Sampling for testProvided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-211Fw/AMENDMENT 174.2.3 Inspection procedure.4.2.3.1 Forexaminationo
36、fpackaging. Thesampleunitshallbeonefilledshippingcontainerready for shipment. Sample shipping containers shall be examined for the following defects:(a) Contents per container not as specified(b) Container not as specified(c) Container closure not as specified(d) Container damaged or leaking(e) Mark
37、ing incorrect, missing, or illegible(f) Bagexteriorordruminteriororexteriorcontaminatedwithredphosphorus4.2.3.2 For test (see 6.6). Approximately equal portions of all of the specimens taken in 4.2.2.2shall bethoroughly mixed to form a compositespecimen of no lessthan 450 g. The compositespeci-men s
38、hall be tested as specified in the applicable portions of 4.2.4. Each test shall be conducted induplicate analysis. Failure of either analysis of any test shall be cause for rejection of the lot repre-sented.4.2.4 Tests (see 6.6)(a) InductiveCoupled Plasma (ICP). Besureallglasswareisfreeofmetals. So
39、akglass-ware in 5% HNO3, rinse with distilled water, soak in 5% HCl and rinse with distilled water.RunICPaccordingtomanufacturersspecification. Assurethe ICPhasbeenpurgedwithnitro-gen at 223.008 nm for Cu, 238.204 nm for Fe, and 177.494 nm for P. Calibrate the instrumentusing standards of Cu, Fe, an
40、d P. Run a water blank before running samples.(b) Chemicals. Water, in accordance with ASTM D 1193, and reagent grade chemicalsshallbeusedthroughoutthetests. Whereapplicable,blankdeterminationsandstandardsshallbe run and corrections applied where significant. ICP standards for copper and iron shall
41、be 5mg/ml and standards for phosphorus shall be 50 mg/ml. Tests shall be conducted as follows:4.2.4.1 White Phosphorus. Weigh 10 g of the RP specimen and add 50 milliliters (ml) carbondisulfide. Mix for 60 minutes in a sonicbath or with magneticstirrer. Filter through a Whatman No.42 filter paper or
42、 equal and take a 10 ml aliquot into a 50 ml volumetric flask and allow to evaporatedry in hood with air or nitrogen stream. Add 25 ml water, 2.5 ml concentrated nitric acid and diluteto volume with water. Run ICP on prepared solution.Percent White Phosphorus = 25 x 10- 3AWwhere: A = ICP reading (mg
43、/ml)W = weight of specimen (g)4.2.4.2 AcidityasPhosphoricAcid. Weigh10goftheRPspecimenina50mlflaskanddiluteto volume withwater. Mix insonic bathfor 5 minutes. Filter througha WhatmanNo. 42 filterpaper or equal and run ICP on solution.Provided by IHSNot for ResaleNo reproduction or networking permitt
44、ed without license from IHS-,-,-MIL-DTL-211Fw/AMENDMENT 18Percent Acidity as Phosphoric Acid = 15.8 x 10- 3AWwhere: A = ICP reading (mg/ml)W = weight of specimen (g)4.2.4.3 Red Phosphorus, Copper, Iron.(a) Sampleinsolution. Weigh 0.2+.05g(tonearest0.1mg)ofthe RPintoa400mlflask.Add50mlofdistilledwate
45、r,25mlofconcentratednitricacid,and25mlofconcentratedhydrochloric acid. Heat the sample slowly until there is approximately 30 ml. Remove thesamplefromthe sourceof heatand coverwith awatch glassif thereaction becomesviolent. Ifparticulates are still present, add 10 ml of nitric acid and wash down the
46、 inside of the beakerwith distilled water. Evaporate the contents to approximately 30 ml, cool and filter (with aWhatman 42 or equal) into a 100 ml volumetric flask. Dilute to volume with water.(b) Copper. RunpreparedsolutioninICPPercent Cu = .01AWwhere: A = concentration of Cu from ICP in mg/mlW =
47、weight of sample in grams(c) Iron. RunpreparedsolutioninICPPercent Fe = .01AWwhere: A = concentration of Fe from ICP in mg/mlW = weight of sample in grams(d) Red Phosphorus. Take 5 ml sample from 100 ml flask and dilute to 200 ml with dis-tilledwater. RunsolutioninICP. Blanksarealsoruntodetermineifa
48、djustmentsarenecessary.Percent RP =(.4AW)E0.316Fwhere: A = concentration of P from ICP, in mg/mlW = weight of sample, in gramsE = Percent WP from 4.2.4.1F=PercentH3PO4from 4.2.4.2* See note 6.10 if instrument drift is present.4.2.4.4 Dust Suppressant. Weigh 5.0 g of specimen into a 150 ml beaker and add 50 ml ofmethylene chloride and a 1 inch stirring bar. Cover with a watch glass and stir for 30 minutes.Filter the solution through a Whatman No. 42 or equal filter paper into a clean, tared, glassProvided by IHSNot for ResaleNo reproduction or networking permitted without li
