1、MIL-STD-1234CHANGE NOTICE 230 March 1967MILITARY STANDARDPYROTECHNICS: SAMPLING,INSPECTION AND TESTINGTO ALL HOLDERS OF MIL-STD-1234:1. The following pages of MIL-STD-1234 have been revised andsupersede the pages listed:New Page Date Superseded Page Dateii 30 March 1967 ii 18 December 1965iii 30 Mar
2、ch 1967 iii 22 June 1962iv 30 March 1967 iv 18 December 1965v 30 March 1967 v 18 December 1965vi 30 March 1967 vi 22 June 19622. The following methods have been added:Method No. Title Date101.6 Moisture (Electrolytic 30 March 1967Hygrometer Method)506.1 Friction Sensitivity (By 30 March 1967the Roto
3、-Friction Method)3. The following is a cumulative list of earlier changes:a. Superseded pages,New Page Date Superseded Page Dateii 18 December 65 ii 22 June 1962iv 18 December 65 iv 22 June 1962v 18 December 65 v 22 June 1962Provided by IHSNot for ResaleNo reproduction or networking permitted withou
4、t license from IHS-,-,-MIL-STD-123430 March 1967b. Superseded methods.New Method Date101.1.1 18 December 65101.2.1 18 December 65101.3.1 18 December 65101.3.1 18 December 65102.1.1 18 December 65102.2.1 18 December 65c. New methods.Method No. Title Date101.5 Moisture (Karl Fischer Distillation 18 De
5、cember 1965Method)4. Retain this notice and insert before table of contents.5. Holders of MIL-STD-1234 will verify that page changes and additionsindicated have been entered and will destroy the previous notice (notice page only).The latest notice (notice page) will be retained as a check sheet. Thi
6、s issuance,Superseded Method Date101.1 22 June 1962101.2 22 June 1962101.3 22 June 1962101.4 22 June 1962102.1 22 June 1962102.2.1 22 June 1962together with appended pages, is a separate publication.retained by stocking points until the Military Standard iscancelled.Each notice is to becompletely re
7、vised or.Custodians: Preparing ActivityArmy - MU Army - MUNavy - OSAir Force - 11Review Activities:Army - MUNavy - OSAir Force - 70Project No. 1370-0227Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-123430 March 1967DEPARTMENT OF DEFENSEWASH
8、INGTON 25, D. C.Pyrotechnics: Sampling, Inspection and TestingMIL-STD-12341. This Military Standard has been approved by theDepartment of Defense and is manditory for use by allDepartments and Agencies of the Department of Defense.2. Recommended corrections, additions, or deletionsshould be addresse
9、d to Commanding Officer, Picatinny Arsenal,Dover, New Jersey 07801, ATTN: SMUPA-DC7.Supersedes page ii of 18 December 1965Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Provided by IHSNot for ResaleNo reproduction or networking permitted without lic
10、ense from IHS-,-,-MIL-STD-123430 March 1967CONTENTSPageAlphabetical Index of Test Methods . . . . . . . . . . . . . . . . . . . . . . .Numerical Index of Test Methods . . . . . . . . . . . . . . . . . . . .SECTION 1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
11、. . . . . . . . . . . . . . . . . . . . . .SAMPLING AND INSPECTION . . . . . . . . . . . . . . . . . . . . .TESTING . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .TEST METHODS.Group 100 General test methods.Group 200 Physical test methods.Group 300
12、 Sample preparations.Group 400 Chemical test methods.Group 500 Sensitivity brisance and Sta-bility test methods.Group 600 Standard solutions. Group 700 Indicator solution.iiiv123ALPHABETICAL INDEX OF TEST METHODSTitle Method No.Aluminum (Ammonium Hydroxide Method) . . . . . . . . . . . . . . . . . .
13、 . . . . . . . . . . . . .Aluminum (8-Hydroxy-quinoline Method). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Ammonium Thiocyanate Indicator Solution (20-percent) . . . . . . . . . . . . . . Antimony Sulfide (Permanganate Method) . . . . . . . . . . . . . . .
14、. . . . . . . . . . . . . . Average Particle Size (Fischer Subsieve Sizer) . . . . . . . . . . . . . . . . . Barium Diphenylamine Sulfonate Indicator Solution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Barium Salts (Chromate Method) . . . . . . . . . . . .
15、 . . . . . . . . . . . . . . . . . . . . Barium Salts (Sulfate Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bromophenol Blue Indicator Solution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chlorate (Ferrous Sulfate Method) . . . . . . . . . . . . . . . .
16、 . . . .Chloride (Silver Nitrate Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dissolution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Dissolution-Extraction . . . . . . . .
17、 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Eriochrome Black T Indicator Solution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Extraction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
18、. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Ferric Ammonium Sulfate Indicator Solution . . . . . . . . . . . . . . . . . . . . . . . . . . . Ferric Ammonium Sulfate (0.1N Standard Solution) . . . . . . . . . . . . . . . . . . . . . 407.1407.2706.1410.1202.1708.
19、1406.2408.1710.1402.1401.1801.1801.2709.1801.8706.1608.1Fricton Sensitivity (by the Roto-Friction Method) . . . . . . . . . . . . . . . . . . . . . . . . . . 506.1Granulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201
20、.1100C. Heat Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 802.1Hexachlorobenzene (Para Bomb Method) . . . . . . . . . . . . . . . . . . . . . . . 404.1Hydrochloric Acid (0.1N Standard Solution) . . . . . . . . . . . . . . . . . . . 604.1iii
21、Supersedes Page iii of 22 June 1962Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-123430 March 1967ALPHABETICAL INDEX OF TEST METHODContinuedTitle Method No.Hygroscopicity (Equilibrium Method) . . . . . . . . . . . . . . . . . . . . .Impact
22、Sensitivity Test (U.S. Bureau of Mines Apparatus) . . . . . . . . . . .75C. International Test . . . . . . . . . . . . . . . . . . . . .Iron (Jones Reductor Method) . . . . . . . . . . . . . . . . . . . . . . . . . .Leaching . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Lead S
23、ulfocyanate (Silver Nitrate Method). . . . . . . . . . . . . .Magnesium (Eudiometer Method) . . . . . . . . . . . . . . . .Methyl Orange Indicator Solution . . . . . . . . . . . . . . .Methyl Red Indicator Solution . . . . . . . . . . . . . . . . . . .Moisture (Desiccation Method) . . . . . . . . .
24、. . . . . . . . . . .Moisture (Karl Fischer Extraction Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . .Magnesium (Pyrophosphate Method) . . . . . . . . . . .Moisture (Karl Fischer Distillation Method). . . . . . . . . . . . . . . . . . . . . . .Moisture, (Electrolytic Hygrometer Metho
25、d) . . . . . . . . . . . . . . . . . . . . . . . . . . .Moisture (Karl Fischer Method) . . . . . . . . . . . . . . . .Moisture (Modified Karl Fischer Method) . . . . . .Multiple Solvent Extraction . . . . . . . . . . . . . . . . . .Nickel (Dimethylglyoxine Method) . . . . . . . . . . . . .Nitro-Comp
26、ounds (Titanous Chloride Method) . . . . . . . . . . . . . . . .Organic Destruction and Sample Dissolution . . . . . . . . . . . .Perchlorate (Ammonium Chloride Method) . . . . . . . . . . . . . . . . . . . . . . .Phenolphthalein Indicator Solution. . . . . . . . . . . . . . . . .Potassium and Bariu
27、m Salts (Flame Spectrophotometric Method) . . . . . . . . . . . . . . Potassium Bichromate (0.1N Standard Solution) . . . . . . . . . . . . . . . . . . . . . . .Potassium Permanganate (0.1N Standard Solution) . . . . . . . . . . . . . . . . . . .Potassium Salts (Tetraphenyl Boron Method) . . . . . .
28、 . . . . . . . . . . . . . . . . . . . . . . .Potassium Thiocyanate (0.1N Standard Solution) . . . . . . . . . . . . . . . . . .Reactivity Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Selective Solvent Extraction (Extraction Method) . . . . . . . . . . . .Selective Solvent Extr
29、action (Insoluble Residue Method) . . . . . . .Selective Solvent Extraction (Leaching) . . . . . . . . . . . . . . . . . . . . . . . . . . . .Selective Solvent Extraction (Soxhlet Method) . . . . . . . . . . . . . . . . . . . .Silver Nitrate (0.1N Standard Solution) . . . . . . . . . . . . . . . . .
30、 .Sodium Diphenylbenzidine Sulfonate Indicator Solution . . . . . . . . . . . . . .Sodium Hydroxide (0.1N Standard Solution) . . . . . . . . . . . . . . . .Sodium Oxalate (Potassium Permanganate Method) . . . . . . . . Soxhlet Extraction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
31、. . . . . . . . . .Starch Indicator Solution . . . . . . . . . . . . . . . .Strontium Nitrate (Sulfate Method) . . . . . . . . . . . . .Sulfur (Carbon Disulfide Insoluble) . . . . . . . . . . . . . . . .Sulfur (Carbon Disulfide Soluble) . . . . . . . . . . . . . . . . . . .Titanous Chloride (0.2N St
32、andard Solution) . . . . . . . . . . . . .Titanium and Titanium Dioxide (Jones Reductor Method) . . . . . . . . . . . . . . .Total Lead (Chromate Method) . . . . . . . . . . . . . . .Total Lead (Sulfate Method) . . . . . . . . . . . . . . . . . . . . . . .100C. Vacuum Stability Test . . . . . . . .
33、. . . . . . . . . . . .Volatiles (Oven Method) . . . . . . . . . . . . . . . .Volatiles (Vacuum Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Zinc Oxide . . . . . . . . . . . . . . . . . . . . . . . . .Zirconium or Zirconium Hydride (Cupferron Method) . . . . .
34、 . . . . . .203.1605.1601.1414.1301.4405.1412.1412.2704.1702.1101.1.1101.4.1101.5101.6101.2.1101.3.1301.7411.1420.1301.5403.1703.1421.1605.1606.1416.1608.1504.1204.2204.4204.1204.3607.1707.1602.1416.1301.6701.1418.1409.1409.2601.1413.1408.1408.2603.1102.1102.2.1419.1416.1ivSupersedes Page iv of 18 D
35、ecember 1965Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-123430 March 1967NUMERICAL INDEX OF TEST METHODSGROUP 100GENERAL TEST METHODSMethod No.101.1.1 Moisture (Desiccation Method)101.2.1 Moisture (Karl Fischer Method)101.1.1 Moisture (Mo
36、dified Karl Fischer Method)101.4.1 Moisture (Karl Fischer Extraction Method)101.5 Moisture (Karl Fischer Distillation Method)101.6102.1.1102.2.1201.1202.1203.l204.1204.2204.3204.4301.1301.2301.3301.4301.5301.6301.7401.1402.1403.1404.1405.1406.1406.2407.1407.2408.1408.2409.1409.2410.1411.1412.1412.24
37、13.1414.1415.1416.1417.1418.1419.1420.1421.1Moisture (Electrolytic Hygrometer Method)Volatiles (Oven Method)Volatiles (Vacuum Oven Method)GROUP 200PHYSICAL TEST METHODSGranulationAverage Particle Size ( Fischer Subsieve Sizer)Hygroscopicity (Equilibrium Method)selective Solvent Extraction (Leaching
38、Method)Selective Solvent Extraction (Extraction Method)Selective Solvent Extraction (Soxhlet Method)Selective Solvent Extraction (Insoluble Residue Method)GROUP 300SAMPLE PREPARATIONSDissolutionDissolution ExtractionExtractionLeachingOrganic Destruction and Sample DissolutionSoxhlet ExtractionMultip
39、le Solvent ExtractionGROUP 400CHEMICAL TEST METHODSChloride (Silver Nitrate Method)Chlorate (Ferrous Sulfate Method)Perchlorate (Ammonium Chloride Method)Hexachlorobenzene (Parr Bomb Method)Lead Sulfocyanate (Silver Nitrate Method)Barium Salts ( Sulfate Method )Barium Salts (Chromate Method)Aluminum
40、 (Ammonium Hydroxide Method)Aluminum (8-Hydroxy-quinoline Method)Total Lead (Chromate Method )Total Lead (Sulfate Method)Sulfur (Carbon Disulfate Insoluble)Sulfur (Carbon Disulfide Soluble)Antimony Sulfide ( Permanganate Method )Nickel ( Dimethylglyoxime Method )Magnesium (Audiometer Method )Magnesi
41、um ( Pyrophosphate Method)Titanium and Titanium Dioxide (Jones Reductor Method)Iron (Jones Reductor Method)Potassium Salts ( Tetraphenyl Boron Method)Zirconium or Zirconium Hydride (Cupferron Method)Sodium Oxalate (Potassium Permanganate Method)Strontium Nitrate (Sulfate Method)Zinc Oxide (Formic Ac
42、id Method)Nitro-Compounds (Titanous Chloride Method)Potassium and Barium Salts (Flame SpectrophotometricMethod)vSupersedes Page v of 18 December 1965Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-123430 March 1967NUMERICAL INDEX OF TEST METH
43、ODS-ContinuedGROUP 600 SENSITIVITY, BRISANCE AND STABILITYTEST METHODSMethod No.501.1502.1503.1504.1505.1506.1601.1602.1603.1604.1605.1606.1607.1608.1701.1702.1703.1704.1705.1706.1707.1708.1709.1710.1750C. International Test100C. Heat Test100C. Vacuum Stability TestReactivity TestImpact Sensitivity
44、Test (U.S. Bureau of Mines Apparatus)Friction Sensitivity (By the Roto-Friction Method).GROUP 600 STANDARD SOLUTIONSTitanous Chloride (0.2N Standard Solution)Sodium Hydroxide (0.1N Standard Solution)Ferric Ammonium Sulfate (0.15N Standard Solution)Hydrochloric Acid (0.1N Standard Solution)Potassium
45、Bichromate (0.1N Standard Solution)Potassium Permanganate (0.1N Standard Solution)Silver Nitrate (0.1N Standard Solution)Potassium Thiocyanate (0.1N Standard Solution)GROUP 700 INDICATOR SOLUTIONSStarch Indicator SolutionMethyl Red Indicator SolutionPhenolphthalein Indicator SolutionMethyl Orange In
46、dicator SolutionFerric Ammonium Sulfate Indicator SolutionAmmonium Thiocyanate Indicator Solution (20-Percent)Sodium Diphenylbenzidine Sulfonate IndicatorSolutionBarium Diphenylamine Sulfonate Indicator SolutionEriochrome Black T Indicator SolutionBromophenol Blue Indicator SolutionviSupersedes Page
47、 vi 22 June 1962Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-123430 March 1967METHOD 101.6MOISTURE (ELECTROLYTIC HYGROMETER METHOD)This method has been coordinated and approved for use by the Departments ofthe Army and Air Force.1. SCOPE1.
48、1 This method is used for determining the moisture content of small grain orflaked propellants. The principle of the method is measurement of the currentrequired for electrolysis of water that has been volatilized from the specimen.Other volatile compounds such as alcohols, amines and ammonia may in
49、terfere.2. SPECIMEN2.1 The specimen shall consist of 0.2-0.6 gm of propellant weighed to thenearest 0.2 mg.3. APPARATUS3.1 Solids Moisture Analyzer (Consolidated Electrodynamics Corporation,360 Sierra Madre Villa, Pasadena, Cal. , or equivalent) See figure 1.3.2 Nitrogen, extra-dry grade, in a cylinder with a pressure regulator to
