1、Designation: A518/A518M 99 (Reapproved 2012)Standard Specification forCorrosion-Resistant High-Silicon Iron Castings1This standard is issued under the fixed designation A518/A518M; the number immediately following the designation indicates the yearof original adoption or, in the case of revision, th
2、e year of last revision. A number in parentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This specification covers h
3、igh-silicon cast iron castingsintended for corrosion-resistant service.1.2 This specification covers three grades as shown in Table1. Selection of grade depends on the corrosive service to beexperienced by the casting. All three grades are suited forapplication in severe corrosive environments. Howe
4、ver, Grade2 is particularly suited for application in strong chlorideenvironments, and Grade 3 is recommended for impressedcurrent anodes.1.3 The values stated in either SI units or inch-pound unitsare to be regarded separately as standard. The values stated ineach system may not be exact equivalent
5、s; therefore, eachsystem shall be used independently of the other. Combiningvalues from the two systems may result in non-conformancewith the standard.1.4 The following safety hazards caveat pertains only to thetest method portion, Section 9, of this specification: Thisstandard does not purport to a
6、ddress all of the safety concerns,if any, associated with its use. It is the responsibility of the userof this standard to establish appropriate safety and healthpractices and determine the applicability of regulatory limita-tions prior to use.2. Referenced Documents2.1 ASTM Standards:2A438 Test Met
7、hod for Transverse Testing of Gray Cast Iron(Withdrawn 2003)3E350 Test Methods for Chemical Analysis of Carbon Steel,Low-Alloy Steel, Silicon Electrical Steel, Ingot Iron, andWrought IronE351 Test Methods for Chemical Analysis of Cast IronAllTypes3. Ordering Information3.1 Orders for material under
8、this specification shall includethe following information:3.1.1 ASTM designation and year of issue.3.1.2 Grade of high-silicon cast iron (see Section 5).3.1.3 Number of castings.3.1.4 Approximate weight of the casting.3.1.5 Drawing showing the size, shape, dimensions, andfinishing details. The drawi
9、ng should indicate any criticaldimensions and should give the allowable tolerances on alldimensions and on the accumulation of dimensions. If thepurchaser supplies the pattern, the dimensions of the castingshall conform to those predicted by the pattern.3.1.6 Options in this specification, including
10、:3.1.6.1 The status of the heat treatment of the castings whenshipped by the manufacturer (see Section 7).3.1.6.2 If the chemical analysis and mechanical test resultsare to be reported to the purchaser (see Section 14).3.1.6.3 If a transverse test is required (see 8.1).3.1.6.4 If hydraulic testing i
11、s required, and, if required, thetest pressure and the leakage permitted (see 8.2).3.1.6.5 Any special packing, markings, etc.4. Method of Manufacture4.1 The alloy may be produced by any melting and castingprocess, or combination of processes, capable of meeting thechemical composition and mechanica
12、l properties specified.5. Chemical Composition5.1 High-silicon iron castings are produced in one of threegrades, as given in Table 1 of this specification.6. Chemical Analysis6.1 Heat AnalysisChemical analysis of each heat (or eachtap, if from a continuous melting operation) shall be made bythe manu
13、facturer to determine the percentages of the elementsspecified in Table 1. The analysis shall be made from a testsample cast during the pouring of the heat (or tap). Thechemical composition thus determined shall conform to therequirements specified for that grade in Table 1.1This specification is un
14、der the jurisdiction of ASTM Committee A04 on IronCastings and is the direct responsibility of Subcommittee A04.01 on Grey and WhiteIron Castings.Current edition approved Oct. 1, 2012. Published November 2012. Originallyapproved in 1964. Last previous edition approved in 2008 as A518/A518M 99(2008).
15、 DOI: 10.1520/A0518_A0518M-99R12.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version o
16、f this historical standard is referenced onwww.astm.org.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States16.2 Product AnalysisA product analysis may be made bythe purchaser from material representing each heat, lot, orcasting. The sampl
17、e for such analysis shall be taken as desiredby the purchaser. The chemical composition thus determinedshall meet the requirements for the grade specified.6.3 Routine Analysis MethodsSpectrometric and otherinstrumental methods or wet chemical laboratory methods areacceptable for routine and control
18、determinations, but shall bestandardized against and give essentially the same results as themethods specified in 6.4.6.4 Reference Analysis Methods:6.4.1 Silicon:6.4.1.1 Analyze samples soluble when processed in accor-dance with Test Methods E350, by that method, except asfollows:(a) The sample wei
19、ght shall be 0.3 g with a weighttolerance of 60.1 mg.(b) Pulverize one or more pieces of the sample until theentire material in the piece or pieces passes through a 100-mesh screen.(c) Dissolve the sample in 25 mL of perchloric acid.6.4.1.2 Analyze samples that are not soluble when pro-cessed in acc
20、ordance with 6.4.1.1 in accordance with AnnexA1.6.4.2 Molybdenum:6.4.2.1 Mill, lathe, or pulverize the sample to pass througha 100-mesh sieve. If the sample is soluble when processed inaccordance with Test Methods E350, use this method.6.4.2.2 If the sample is not acid-soluble when processed inaccor
21、dance with 6.4.2.1, proceed as follows:(a) Use the appropriate weight of sample in accordancewith 6.4.2.1 instead of the weight given in A1.2.3 of AnnexA1.(b) Fuse the sample in accordance with A1.2.1 and A1.2.2and A1.2.4-A1.2.12 of Annex A1.(c) Add the amount of dissolving acid(s), specified in the
22、sections in Molybdenum by the Photometric Method in TestMethods E350, heat to fumes of perchloric acid. Proceed inaccordance with Test Methods E350.6.4.3 CarbonDetermine carbon in accordance with sec-tions on Carbon, Total, by the Combustion GravimetricMethod, in Test Methods E350.6.4.4 Manganese:6.
23、4.4.1 Mill, lathe, or pulverize the sample to pass througha 100-mesh sieve.6.4.4.2 Determine manganese in accordance with the sec-tions on Manganese by the Peroxydisulfate-Arsenite Titrimet-ric Method in Test Methods E350. Add hydrofluoric acid asrequired for complete solution of the (HF) sample.6.4
24、.5 Chromium:6.4.5.1 Mill, lathe, or pulverize the sample to pass througha 100-mesh sieve.6.4.5.2 Determine chromium in accordance with the sec-tions on Chromium by the Peroxydisulfate-Oxidation Titrimet-ric Method in Test Methods E350, except dissolve the sampleas follows:(a) Place the appropriate a
25、mount of weighed sample into a600-mL Griffin beaker or 500-mL volumetric flask.Add 20 mLof nitric acid (HNO3) and carefully add HF, dropwise, until thereaction ceases. A TFE-fluorocarbon beaker may be used ifdesired.(b) Add30mLof1+1sulfuric acid (H2SO4),5mLofphosphoric acid (H3PO4), and boil until l
26、ight fumes of H2SO4are present and the sample is completely dissolved.(c) Cool the solution, add 150 mL of water, heat todissolve if necessary, and continue as in Test Methods E350.6.4.6 Copper:6.4.6.1 Mill, lathe, or pulverize the sample to pass througha 100-mesh sieve.6.4.6.2 Determine the copper
27、in accordance with the sec-tions on Copper by the Sulfide Precipitation-ElectrodepositionGravimetric Method in Test Methods E350,or6.4.6.3 Determine the copper in accordance with the sec-tions on Copper by the Neocuproine Photometric Method, inTest Methods E350. Add HF as required for complete solut
28、ionof the sample.7. Heat Treatment7.1 High-silicon iron castings are generally used in theheat-treated (stress-relieved) condition. Small castings ofsimple configuration not conducive to high-residual stressesmay be used in the as-cast condition. If the castings are to besupplied in the stress-relie
29、ved condition, the purchaser must sospecify.7.2 At its option, the foundry may heat treat the castings toremove stresses without the purchaser so specifying.7.3 If used, the stress-relieving heat treatment shall be asfollows:7.3.1 Heat at a rate that will not crack the castings.7.3.2 Hold the castin
30、gs at a minimum temperature of1600F 870C for a minimum period of 1 h/in. mm ofmaximum section thickness, except that in no case shall theholding period be less than 2 h.7.3.3 Cool the castings to 400F 205C maximum at a ratenot faster than 100F 55C/15 min.7.3.4 From 400F 205C to ambient temperature,
31、thecastings may be cooled in still ambient air.8. Mechanical Requirements8.1 Transverse Bend Test:8.1.1 When specified by the purchaser, the silicon-iron alloyshall be given a transverse bend test. The specimen tested shallmeet the test requirements prescribed in Table 2.8.1.2 When transverse bend t
32、ests are specified, test barsshall be made and tested from each heat (or ladle in the case ofcontinuous melting) from which the castings are poured.TABLE 1 Chemical CompositionElement Composition, Weight %Grade 1 Grade 2 Grade 3Carbon 0.651.10 0.751.15 0.701.10Manganese 1.50, max 1.50, max 1.50, max
33、Silicon 14.2014.75 14.2014.75 14.2014.75Chromium 0.50, max 3.255.00 3.255.00Molybdenum 0.50, max 0.400.60 0.20, maxCopper 0.50, max 0.50, max 0.50, maxA518/A518M 99 (2012)28.1.3 The test bars shall be heat treated in the productionfurnaces to the same procedure as the castings.8.1.4 Each test bar sh
34、all be permanently marked with theheat or ladle number from which it was poured. Marking shallbe accomplished with cast digits, with a vibratory markingtool, or with a felt-point pen using indelible ink.8.2 Hydrostatic TestWhen specified by the purchaser,subject the castings for critical application
35、s involving pressureor vacuum conditions to a hydrostatic pressure test at aminimum of 40 psig 275 kPa. Any leak revealed by this testshall be cause for rejection of the casting.9. Transverse Bend Test Method9.1 When a requirement for transverse bend tests has beenagreed upon between the purchaser a
36、nd the manufacturer, themanufacturer shall test transverse bend bar(s) from each heat.9.2 Conduct the transverse bend test in accordance withMethod A438, except as follows:9.2.1 Do not machine the specimen.9.2.2 The specimen shall be sufficiently smooth, round, andstraight to permit testing without
37、machining.9.2.3 Produce the specimen in accordance with Fig. 1.9.2.4 The specimen shall conform to the dimensions shownin Fig. 2.9.2.5 Report the actual breaking load without use of acorrection factor. The requirements of Table 2 allow fordeviation due to variations in test bar diameter. In the same
38、sense, measure and report the deflection at fracture withoutcorrection.9.2.6 Apply the load at a rate such that a 0.025-in. 0.65-mm deflection is produced in 50 to 70 s. Continue loading atthe same head-movement rate until the specimen fractures.10. Workmanship, Finish, and Appearance10.1 The workma
39、nship and finish shall be as agreed uponbetween the manufacturer and the purchaser.11. Number of Tests and Retests11.1 If a valid test specimen fails to conform to thisspecification, two retests shall be made. If either retest fails toconform to this specification, the castings represented by theset
40、est bars shall be rejected.TABLE 2 Transverse Bend Test Minimum RequirementsNOTE 1Test bars are to be tested on supports 12 in. 3.5 mm apart.Load at center, min, lbf N 930 4090Deflection at center, min, in. mm 0.026 0.66FIG. 1 Suggested Pattern for Transverse Bend Test Bar, Cast Horizontally, 1.20 i
41、n. 30.5 mm in DiameterA518/A518M 99 (2012)311.2 If after testing, a test specimen shows evidence of adefect, the results of the test may be regarded as invalid andanother test made.11.3 In the absence of further separately cast test bars, themanufacturer shall have the option of submitting test bars
42、sectioned from an agreed-upon position in the castings.11.4 If reheat treatment is required to meet the specification,castings and their representative test bars shall be reheat treatedtogether. Testing will then proceed as in 11.1, 11.2, and 11.3.12. Inspection12.1 When specified in the purchase or
43、der, the inspectorrepresenting the purchaser shall have access to the materialsubject to inspection for the purpose of witnessing the selectionof the samples, the preparation of the test pieces, and theperformance of the test(s). For such tests, the inspector shallhave the right to indicate the piec
44、es from which the sampleswill be taken in accordance with the provisions of thisspecification.12.2 The manufacturer shall inspect the material covered bythis specification prior to shipment and, upon request, shallfurnish the purchaser with a certification of test(s).13. Rejection and Rehearing13.1
45、RejectionAny rejection based on test reports shall bereported to the manufacturer within 30 days from the receipt ofthe test report by the purchaser. The manufacturer shall beadvised within one week of purchasers discovery of materialthat contains injurious defects. The purchaser shall hold themater
46、ial a minimum of 30 days pending action by the manu-facturer.13.2 RehearingSamples tested in accordance with thisspecification that represent rejected material shall be preservedfor two weeks from the date of the test report. In case ofdissatisfaction with the results of the test, the manufacturerma
47、y make a claim for a rehearing within that time.14. Certification14.1 When specified by the purchaser, the manufacturershall provide the purchaser with a certification stating that thecastings meet the specified requirements. The certification shallinclude the results of any chemical analyses and me
48、chanicaltests.15. Product Marking15.1 The trademark of the manufacturer shall be legibly caston each casting.ANNEX(Mandatory Information)A1. SILICON BY THE FUSION-HYDROCHLORIC ACID DEHYDRATION METHODA1.1 This method may be used for the referee determinationof silicon in high-silicon cast irons. All
49、reagents are to bereagent grade. All water is to be deionized or triple-distilled.A1.2 Procedure:A1.2.1 Preparation of SamplePulverize a representativeportion of the sample until the entire portion will pass a No.100 sieve.A1.2.2 Weigh8gofanhydrous sodium carbonate into a50-mL nickel crucible.A1.2.3 Weigh 0.5 g of pulverized sample and place on topof the sodium carbonate in the nickel crucible.A1.2.4 Weigh4gofsodium peroxide and place on top ofthe sample in the nickel crucible.A1.2.5 Stir carefully with a glass rod until the mi
