1、Designation: B111/B111M 11Standard Specification forCopper and Copper-Alloy Seamless Condenser Tubes andFerrule Stock1This standard is issued under the fixed designation B111/B111M; the number immediately following the designation indicates the yearof original adoption or, in the case of revision, t
2、he year of last revision. A number in parentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification2establ
3、ishes the requirements forseamless tube and ferrule stock of copper and various copperalloys up to 318 in. 80 mm inclusive, in diameter, for use insurface condensers, evaporators, and heat exchangers. Thefollowing coppers and copper alloys are specified:3(Warn-ingMercury is a definite health hazard
4、in use and disposal.(See 12.1.)Copper orCopperAlloyUNS No.PreviouslyUsedDesignation DescriptionC10100 OFE Oxygen-free electronicC10200 OFAOxygen-free without residual deoxidantsC10300 . . . Oxygen-free, extra low phosphorusC10800 . . . Oxygen-free, low phosphorusC12000 DLPAPhosphorized, low residual
5、 phosphorusC12200 DHPAPhosphorized, high residual phosphorusC14200 DPAAPhosphorized, arsenicalC19200 . . . Phosphorized, 1 % ironC23000 . . . Red BrassC28000 . . . Muntz MetalC44300 . . . Admiralty Metals, B, C, and DC44400C44500C60800 . . . Aluminum BronzeC61300 . . . . . .C61400 . . . Aluminum Bro
6、nze, DC68700 . . . Aluminum Brass, BC70400 . . . 95-5 Copper-NickelC70600 . . . 90-10 Copper-NickelC70620 . . . 90-10 Copper-NickelWelding GradeC71000 . . . 80-20 Copper-NickelC71500 . . . 70-30 Copper-NickelC71520 . . . 70-30 Copper-NickelWelding GradeC71640 . . . Copper-nickel-iron-manganeseC72200
7、 . . . . . .ADesignations listed in Classification B224.1.2 UnitsThe values stated in either SI units or inch-pound units are to be regarded separately as standard. Thevalues stated in each system may not be exact equivalents;therefore, each system shall be used independently of the other.Combining
8、values from the two systems may result in non-conformance with the standard.1.3 The following safety hazards caveat pertains only to thetest methods portion, Section 19, of this specification: Thisstandard does not purport to address all of the safety concerns,if any, associated with its use. It is
9、the responsibility of the userof this standard to establish appropriate safety and healthpractices and determine the applicability of regulatory limita-tions prior to use.2. Referenced Documents2.1 The following documents in the current issue of theAnnual Book of ASTM Standards form a part of this s
10、pecifi-cation to the extent referenced herein:2.2 ASTM Standards:4B153 Test Method for Expansion (Pin Test) of Copper andCopper-Alloy Pipe and TubingB154 Test Method for Mercurous Nitrate Test for CopperAlloysB170 Specification for Oxygen-Free Electrolytic CopperRefinery ShapesB224 Classification of
11、 CoppersB846 Terminology for Copper and Copper Alloys1This specification is under the jurisdiction ofASTM Committee B05 on Copperand Copper Alloys and is the direct responsibility of Subcommittee B05.04 on Pipeand Tube.Current edition approved Oct. 1, 2011. Published November 2011. Originallyapprove
12、d in 1937. Last previous edition approved in 2009 as B111/B111M 09.DOI: 10.1520/B0111_B0111M-11.2For ASME Boiler and Pressure Vessel Code applications, see related Specifi-cation SB-111 in Section II of the Code.3The UNS system for copper and copper alloys (see Practice E527) is a simpleexpansion of
13、 the former standard designation system accomplished by the additionof a prefix “C” and a suffix “00.” The suffix can be used to accommodatecomposition variations of the base alloy.4For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.or
14、g. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States
15、.B858 Test Method for Ammonia Vapor Test for Determin-ing Susceptibility to Stress Corrosion Cracking in CopperAlloysE8 Test Methods for Tension Testing of Metallic MaterialsE8M Test Methods for Tension Testing of Metallic Materi-als Metric5E29 Practice for Using Significant Digits in Test Data toDe
16、termine Conformance with SpecificationsE53 Test Method for Determination of Copper in UnalloyedCopper by GravimetryE54 Test Methods for ChemicalAnalysis of Special Brassesand Bronzes5E62 Test Methods for Chemical Analysis of Copper andCopper Alloys (Photometric Methods)5E75 Test Methods for Chemical
17、 Analysis of Copper-Nickeland Copper-Nickel-Zinc Alloys5E76 Test Methods for Chemical Analysis of Nickel-CopperAlloys5E112 Test Methods for Determining Average Grain SizeE243 Practice for Electromagnetic (Eddy-Current) Exami-nation of Copper and Copper-Alloy TubesE255 Practice for Sampling Copper an
18、d Copper Alloys forthe Determination of Chemical CompositionE478 Test Methods for ChemicalAnalysis of CopperAlloysE527 Practice for Numbering Metals and Alloys in theUnified Numbering System (UNS)3. Terminology3.1 Definitions:3.1.1 For definitions of terms relating to copper and copperalloys, refer
19、to Terminology B846.3.2 Definition of Term Specific to This Standard:3.2.1 capable ofthe test need not be performed by theproducer of the material. However, should subsequent testingby the purchaser establish that the material does not meet theserequirements, the material shall be subject to rejecti
20、on.4. Ordering Information4.1 Include the following information when placing ordersfor product under this specification:4.1.1 ASTM Designation and year of approval (for ex-ample, ASTM B111/B111M 04),4.1.2 Copper or Copper Alloy UNS Designation (see Table1),4.1.3 Form (tube or ferrule stock),4.1.4 Te
21、mper (see Temper section),4.1.5 Dimensions, outside diameter, and wall thickness,whether minimum or nominal (Dimensions and PermissibleVariations Section),4.1.6 Quantitytotal weight or total length or number ofpieces of each size, and4.1.7 If product is purchased for agencies of the U.S.Government (
22、see the Supplementary Requirements Section).4.2 The following options are available and should bespecified at the time of placing of the order when required:4.2.1 Tension Test required per ASME Boiler and PressureVessel Code, Mechanical Properties section.4.2.2 Pressure test as an alternative to edd
23、y current test(Nondestructive Testing Section).4.2.3 If the cut ends of the tubes do not need to be deburred(Workmanship, Finish, and Appearance section).4.2.4 If the product is to be subsequently welded (Table 1,Footnotes G and H).4.2.5 Residual Stress TestAmmonia Vapor Test or Mer-curous Nitrate T
24、est (Performance Requirements Section).4.2.6 ForAmmonia Vapor Test, risk level (pH value) if otherthan 10.4.2.7 Heat identification or traceability details (Number oftests and Retests section).4.2.8 Certification (Certification Section).4.2.9 Mill Test Report (Mill Test Report Section).4.2.10 If a s
25、ubsequent thermal treatment after straighteningis required (Temper section).5. Materials and Manufacture5.1 MaterialsThe material shall be of such quality andpurity that the finished product shall have the properties andcharacteristics prescribed in this specification.5.2 ManufactureThe product shal
26、l be produced by pro-cesses such as casting, extrusion, drawing, annealing, straight-ening, trimming, and other processes which may produce aseamless tube in the specified condition.6. Chemical Composition6.1 The product shall conform to the chemical requirementsspecified in Table 1.6.2 These compos
27、ition limits do not preclude the presenceof other elements. Limits for unnamed elements may beestablished by agreement between manufacturer or supplierand purchaser.6.2.1 Copper Alloy UNS No. C19200Copper may betaken as the difference between the sum of all the elementsanalyzed and 100 %. When all t
28、he elements in Table 1 areanalyzed, their sum shall be 99.8 % minimum.6.2.2 For copper alloys in which copper is specified as theremainder, copper may be taken as the difference between thesum of all the elements analyzed and 100 %.6.2.2.1 When all the elements in Table 1 are analyzed, theirsum shal
29、l be as shown in the following table:Copper AlloyUNS No.Copper Plus NamedElements, % minC60800 99.5C61300 99.8C61400 99.5C70400 99.5C70600 t = thickness of tube wall, in. mm;D = outside diameter of the tube, in. mm; andS = allowable stress of the material, psi MPa.13.1.3 Pneumatic TestEach tube shal
30、l be subjected to aninternal air pressure of 60 psig 400 kPa, min, for 5 s withoutshowing evidence of leakage. The test method used shallpermit easy visual detection of any leakage, such as by havingthe tube under water or by the pressure differential method.Any evidence of leakage shall be cause fo
31、r rejection.14. Dimensions and Permissible Variations14.1 DiameterThe outside of the tubes shall not varyfrom that specified by more than the amounts shown in Table9 or Table 10 as measured by “go” and “no-go” ring gages.14.2 Wall Thickness Tolerances:14.2.1 Tubes Ordered to Minimum WallNo tube wall
32、 at itsthinnest point shall be less than the specified wall thickness.The maximum plus deviation from the specified wall at anypoint shall not exceed twice the values shown in Tables 11 and12.14.2.2 Tubes Ordered to Nominal WallThe maximumplus and minus deviation from the nominal wall at any pointsh
33、all not exceed the values shown in Tables 11 and 12.14.3 LengthThe length of the tubes shall not be less thanthat specified when measured at a temperature of 20C, butmay exceed the specified value by the amounts given in Tables13 and 14.14.4 Squareness of CutThe departure from squareness ofthe end o
34、f the tube shall not exceed the following:Tube, OutsideDiameter, in. mm Tolerance, in. mmUp to58 16, incl 0.010 in. 0.25Over58 16 0.016 in./in. mm/mm of diameter14.5 For the purpose of determining conformance with thedimensional requirements prescribed in this specification, anyTABLE 5 Notch DepthIn
35、ch-Pound ValuesNOTESee Table 6 for notch depthSI values.Tube Wall Thickness,in.Tube Outside Diameter, in.Over14 to34,inclOver34 to 114,inclOver 114 to 318,inclOver 0.0170.032 0.005 0.006 0.007Incl 0.0320.049 0.006 0.006 0.0075Incl 0.0490.083 0.007 0.0075 0.008Incl 0.0830.109 0.0075 0.0085 0.0095Incl
36、 0.1090.120 0.009 0.009 0.011TABLE 6 Notch DepthSI ValuesNOTESee Table 5 for notch depthinch-pound values.Tube Wall Thickness,mmTube Outside Diameter, mmOver 6 to 19,inclOver 19 to 32,inclOver 32 to 80,inclOver 0.40.8 0.13 0.15 0.18Incl 0.81.3 0.15 0.15 0.19Incl 1.32.1 0.18 0.19 0.20Incl 2.12.8 0.19
37、 0.22 0.24Incl 2.83.0 0.23 0.23 0.28TABLE 7 Diameter of Drilled HolesInch-Pound ValuesNOTESee Table 8 for diameter of drilled holesSI values.Tube Outside Diameter,in.Diameter of DrilledHoles, in.Drill No.14 34 , incl 0.025 72Over34 1, incl 0.031 68Over 1114 , incl 0.036 64Over 114 112 , incl 0.042 5
38、8Over 112 134 , incl 0.046 56Over 134 2, incl 0.052 55TABLE 8 Diameter of Drilled HolesSI ValuesNOTESee Table 7 for diameter of drilled holesinch-pound values.Tube Outside Diameter,mmDiameter of DrilledHoles, mmDrill No.6.019.0, incl 0.65 72Over 19.025.4, incl 0.80 68Over 25.431.8, incl 0.92 64Over
39、31.838.1, incl 1.1 58Over 38.144.4, incl 1.2 56Over 44.450.8, incl 1.3 55B111/B111M 116measured value outside the specified limiting values for anydimensions may be cause for rejection.15. Workmanship, Finish and Appearance15.1 Roundness, straightness, uniformity of the wall thick-ness, and inner an
40、d outer surface of the tube shall be such as tomake it suitable for the intended application. Unless otherwisespecified on the purchase order, the cut ends of the tubes shallbe deburred by use of a rotating wire wheel or other suitabletool.15.2 Annealed-temper or thermally stress-relieved tubesshall
41、 be clean and smooth but may have a superficial, dulliridescent film on both the inside and the outside surface.Drawn-temper tubes shall be clean and smooth, but may havea superficial film of drawing lubricant on the surfaces.16. Sampling16.1 SamplingThe lot size, portion size, and selection ofsampl
42、e pieces shall be as follows:16.1.1 Lot Size600 tubes or 10 000 lb 4550 kg orfraction of either, whichever constitutes the greater weight.16.1.2 Portion SizeSample pieces from two individuallengths of finished product.16.2 Samples taken for the purpose of the tests prescribed inthe specification sha
43、ll be selected in a manner that willrepresent correctly the material furnished and avoid needlessTABLE 9 Diameter TolerancesInch-Pound ValuesNOTESee Table 10 for diameter tolerancesSI values.Wall Thickness, in.Outside Diameter, in. 0.020A0.032 0.035 0.042 0.049 and Over0.0220.0250.028Diameter Tolera
44、nce, Plus and Minus, in.Up to 0.500, incl 0.003 0.0025 0.0025 0.0025 0.0025Over 0.5000.740, incl 0.0040 0.004 0.004 0.0035 0.003Over 0.7401.000, incl 0.0060 0.006 0.005 0.0045 0.004Over 1.0001.250, incl . . . 0.009 0.008 0.006 0.0045Over 1.2501.375, incl . . . . . . . . . 0.008 0.005Over 1.3752.000,
45、 incl . . . . . . . . . . . . 0.006Over 2.0003.125, incl . . . . . . . . . . . . 0.0065ATolerances in this column are applicable to light drawn and drawn tempers only. Tolerances for annealed tempers shall be as agreed upon between the manufacturerand the purchaser.TABLE 10 Diameter TolerancesSI Val
46、uesNOTESee Table 9 for diameter tolerancesinch-pound values.Wall Thickness, mmOutside Diameter, mm 0.508A0.813 0.889 1.07 1.24 and Over0.5590.6350.711Diameter Tolerance, Plus and Minus, mmUp to 12, incl 0.076 0.064 0.064 0.064 0.064Over 1218, incl 0.10 0.10 0.10 0.089 0.076Over 1825, incl 0.15 0.15
47、0.13 0.11 0.10Over 2535, incl . . . . . . . . . 0.20 0.13Over 3550, incl . . . . . . . . . . . . 0.15Over 5079, incl . . . . . . . . . . . . 0.17ATolerances in this column are applicable to light drawn and drawn tempers only. Tolerances for annealed tempers shall be as agreed upon between the manufa
48、cturerand the purchaser.TABLE 11 Wall Thickness Tolerances, Plus and MinusInch-Pound ValuesNOTESee Table 12 for SI values.Wall Thickness,in.Outside Diameter, in.Over18 to58,inclOver58 to 1,inclOver 1 to 2,inclOver 2 to3.125, incl0.020, incl to 0.032 0.003 0.003 . . . . . .0.032, incl to 0.035 0.003
49、0.003 0.004 . . .0.035, incl to 0.058 0.004 0.0045 0.0045 0.0050.058, incl to 0.083 0.0045 0.005 0.005 0.00550.083, incl to 0.120 0.005 0.0065 0.0065 0.00650.120, incl to 0.134 0.007 0.007 0.0075 0.008TABLE 12 Wall Thickness Tolerances, Plus and MinusSI ValuesNOTESee Table 11 for inch-pound values.Wall Thickness,mmOutside Diameter, mmOver 12 to 25,inclOver 25 to 50,inclOver 50 to 80,incl0.50, incl to 0.80 0.08 . . . . . .0.80, incl to 0. 90 0.08 0.10 . . .0.9
