1、Designation: B111/B111M 18Standard Specification forCopper and Copper-Alloy Seamless Condenser Tubes andFerrule Stock1This standard is issued under the fixed designation B111/B111M; the number immediately following the designation indicates the yearof original adoption or, in the case of revision, t
2、he year of last revision. A number in parentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of Defense.1. Scope*1.1 This specification2e
3、stablishes the requirements forseamless tube and ferrule stock of copper and various copperalloys up to 318 in. 80 mm inclusive, in diameter, for use insurface condensers, evaporators, and heat exchangers. Thefollowing coppers and copper alloys are specified:3Copper or CopperAlloy UNS No.Previously
4、UsedDesignationDescriptionC10100 OFE Oxygen-free electronicC10200 OFAOxygen-free without residual deoxidantsC10300 . . . Oxygen-free, extra low phosphorusC10800 . . . Oxygen-free, low phosphorusC12000 DLPAPhosphorized, low residual phosphorusC12200 DHPAPhosphorized, high residual phosphorusC14200 DP
5、AAPhosphorized, arsenicalC19200 . . . Phosphorized, 1 % ironC23000 . . . Red BrassC28000 . . . Muntz MetalC44300 . . . Admiralty Metals, B, C, and DC44400 . . . . . .C44500 . . . . . .C60800 . . . Aluminum BronzeC61300 . . . . . .C61400 . . . Aluminum Bronze, DC68700 . . . Aluminum Brass, BC70400 .
6、. . 95-5 Copper-NickelC70600 . . . 90-10 Copper-NickelC70620 . . . 90-10 Copper-NickelWelding GradeC71000 . . . 80-20 Copper-NickelC71500 . . . 70-30 Copper-NickelC71520 . . . 70-30 Copper-NickelWelding GradeC71640 . . . Copper-nickel-iron-manganeseC72200 . . . . . .ADesignations listed in Classific
7、ation B224.1.2 UnitsThe values stated in either SI units or inch-pound units are to be regarded separately as standard. Thevalues stated in each system may not be exact equivalents;therefore, each system shall be used independently of the other.Combining values from the two systems may result in non
8、-conformance with the standard.1.3 The following safety hazards caveat pertains only to thetest methods portion, Section 19, of this specification: Thisstandard does not purport to address all of the safety concerns,if any, associated with its use. It is the responsibility of the userof this standar
9、d to establish appropriate safety, health, andenvironmental practices and determine the applicability ofregulatory limitations prior to use. (WarningMercury hasbeen designated by many regulatory agencies as a hazardoussubstance that can cause serious medical issues. Mercury, or itsvapor, has been de
10、monstrated to be hazardous to health andcorrosive to materials. Caution should be taken when handlingmercury and mercury containing products. See the applicableproduct Safety Data Sheet (SDS) for additional information.Users should be aware that selling mercury and/or mercurycontaining products in y
11、our state or country may be prohibitedby law.)1.4 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recom-mendations issued by the
12、 World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Referenced Documents2.1 The following documents in the current issue of theAnnual Book of ASTM Standardsform a part of this specifica-tion to the extent referenced herein:2.2 ASTM Standards:4B153 Test Method for Expansion (Pin T
13、est) of Copper andCopper-Alloy Pipe and TubingB154 Test Method for Mercurous Nitrate Test for CopperAlloys1This specification is under the jurisdiction ofASTM Committee B05 on Copperand Copper Alloys and is the direct responsibility of Subcommittee B05.04 on Pipeand Tube.Current edition approved Mar
14、ch 1, 2018. Published April 2018. Originallyapproved in 1937. Last previous edition approved in 2016 as B111/B111M16. DOI:10.1520/B0111_B0111M-18.2For ASME Boiler and Pressure Vessel Code applications, see related Specifi-cation SB-111 in Section II of the Code.3The UNS system for copper and copper
15、alloys (see Practice E527) is a simpleexpansion of the former standard designation system accomplished by the additionof a prefix “C” and a suffix “00.” The suffix can be used to accommodatecomposition variations of the base alloy.4For referenced ASTM standards, visit the ASTM website, www.astm.org,
16、 orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700,
17、 West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the Worl
18、d Trade Organization Technical Barriers to Trade (TBT) Committee.1B170 Specification for Oxygen-Free Electrolytic CopperRefinery ShapesB224 Classification of CoppersB846 Terminology for Copper and Copper AlloysB858 Test Method for Ammonia Vapor Test for DeterminingSusceptibility to Stress Corrosion
19、Cracking in CopperAlloysB968/B968M Test Method for Flattening of Copper andCopper-Alloy Pipe and TubeE8/E8M Test Methods for Tension Testing of Metallic Ma-terialsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE53 Test Method for Determination of Co
20、pper in UnalloyedCopper by GravimetryE54 Test Methods for Chemical Analysis of Special Brassesand Bronzes (Withdrawn 2002)5E62 Test Methods for Chemical Analysis of Copper andCopperAlloys (Photometric Methods) (Withdrawn 2010)5E75 Test Methods for Chemical Analysis of Copper-Nickeland Copper-Nickel-
21、Zinc Alloys (Withdrawn 2010)5E76 Test Methods for Chemical Analysis of Nickel-CopperAlloys (Withdrawn 2003)5E112 Test Methods for Determining Average Grain SizeE118 Test Methods for Chemical Analysis of Copper-Chromium Alloys (Withdrawn 2010)5E243 Practice for Electromagnetic (Eddy Current) Examina-
22、tion of Copper and Copper-Alloy TubesE255 Practice for Sampling Copper and Copper Alloys forthe Determination of Chemical CompositionE478 Test Methods for Chemical Analysis of Copper AlloysE527 Practice for Numbering Metals and Alloys in theUnified Numbering System (UNS)E2575 Standard Test Method fo
23、r Determination of Oxygenin Copper and Copper Alloys (Withdrawn 2017)53. Terminology3.1 Definitions:3.1.1 For definitions of terms relating to copper and copperalloys, refer to Terminology B846.4. Ordering Information4.1 Include the following specified choices when placingorders for product under th
24、is specification, as applicable:4.1.1 ASTM Designation and year of issue;4.1.2 Copper or Copper Alloy UNS No. Designation (seeTable 1);4.1.3 Temper (Section 7);4.1.4 Dimensions, outside diameter, and wall thickness,whether minimum or nominal (Section 14);4.1.5 How furnished (tube or ferrule stock);4
25、.1.6 Quantitytotal weight or total length or number ofpieces of each size; and4.1.7 Intended application.4.2 The following options are available but may not beincluded unless specified at the time of placing of the orderwhen required:4.2.1 Tension Test per ASME Boiler and Pressure VesselCode (see Se
26、ction 8).4.2.2 Hydrostatic or pneumatic test as an alternative to eddycurrent test (Section 13).4.2.3 If the cut ends of the tubes do not need to be deburred(Section 15).4.2.4 If the product is to be subsequently welded (Table 1,Footnotes G and H).4.2.5 Residual Stress TestAmmonia Vapor Test or Mer-
27、curous Nitrate Test (Section 12).4.2.6 ForAmmonia Vapor Test, risk level (pH value) if otherthan 10.4.2.7 Heat identification or traceability details.4.2.8 Certification (Section 23).4.2.9 Test Report (Section 24).4.2.10 If a subsequent thermal treatment after straighteningis required (Section 7).4.
28、2.11 If product is purchased for agencies of the U.S.Government (see Supplementary Requirements section of thisspecification for additional requirements, if required).5. Materials and Manufacture5.1 Materials:5.1.1 The material of manufacture shall be a form of suchpurity and soundness as to be suit
29、able for processing into theproducts prescribed herein.5.1.2 When specified in the contract or purchase order thatheat identification or traceability is required, the purchasershall specify the details desired.65.2 Manufacture:5.2.1 The product shall be manufactured by such hot-working, cold-working
30、, annealing, straightening, trimming,and other processes as to produce a uniform seamless tube inthe finished product.5.2.2 The product shall be hot- or cold-worked to thefinished size, and subsequently annealed, when required, tomeet the temper properties specified.6. Chemical Composition6.1 The pr
31、oduct shall conform to the chemical compositionrequirements specified in Table 1.6.2 These composition limits do not preclude the presenceof other elements. By agreement between the manufacturer andpurchaser, limits may be established and analysis required forunnamed elements.6.2.1 Copper Alloy UNS
32、No. C19200Copper is the differ-ence between the sum results of all the elements determinedand 100 %. When all the elements in Table 1 are determined,their sum shall be 99.8 % minimum.5The last approved version of this historical standard is referenced onwww.astm.org.6Due to the discontinuous nature
33、of the processing of castings into wroughtproducts, it is not always practical to identify a specific casting analysis with aspecific quantity of finished material.B111/B111M 182TABLE1ChemicalRequirementsCopperorCopperAlloyUNSNo.Composition,%CopperTinAluminumNickel,inclCobaltLead,maxIronZincManganes
34、eArsenicAntimonyPhosphorusChromiumOtherNamedElementsC1010099.99minA0.0002max.0.0010maxB0.0005max0.0010max0.0001max0.00005max0.0005max0.0004max0.0003max0.0001maxCC10200C99.95minD.CC1030099.95minD.0.0010.005.C1080099.95minD.0.0050.012.C12000E99.90minD.0.0040.012.C1220099.9minD.0.0150.040.C1420099.4min
35、D.0.150.50.0.0150.040.C1920098.5min.0.81.20.20max.0.010.04.C2300084.086.0.0.050.05maxremainder.C2800059.063.0.0.090.07maxremainder.C4430070.073.00.91.2.0.070.06maxremainder.0.020.06.C4440070.073.00.91.2.0.070.06maxremainder.0.020.10.C4450070.073.00.91.2.0.070.06maxremainder.0.020.10.C60800remainderD
36、.5.06.5.0.100.10max.0.020.35.C61300remainderD0.200.506.07.50.15max0.012.03.00.10max0.20max.0.015max.F,GC61400remainderD.6.08.0.0.011.53.50.20max1.0max.0.015max.C6870076.079.0D.1.82.5.0.070.06maxremainder.0.020.06.C70400remainderD.4.86.20.051.31.71.0max0.300.8.C70600remainderD.9.011.00.051.01.81.0max
37、1.0max.C7062086.5minD.9.0-11.00.021.0-1.80.50max1.0max.0.02max.C.05maxS.02maxC71000remainderD.19.023.00.05H0.501.01.0maxH1.0max.H.HC71500remainderD.29.033.00.050.401.01.0max1.0max.C7152065.0minD.29.0-33.00.020.40-1.00.50max1.0max.0.02max.C.05maxS.02maxC71640remainderD.29.032.00.05H1.72.31.0maxH1.52.
38、5.H.C.06maxS.03maxHC72200remainderD.15.018.00.05H0.501.01.0maxH1.0max.H0.300.70Si.03maxTi.03maxHAThisvalueisexclusiveofsilverandshallbedeterminedbydifferenceof“impuritytotal”from100%.“Impuritytotal”isdefinedasthesumofsulfur,silver,lead,tin,bismuth,arsenic,antimony,iron,nickel,mercury,zinc,phosphorus
39、,selenium,tellurium,manganese,cadmium,andoxygenpresentinthesample.BNotincludingCobalt.CAdditionalimpuritymaximumsinpercentforalloyC10100shallbe:bismuth0.0001,cadmium0.0001,oxygen0.0005,selenium0.0003,sulfur0.0015,tellurium0.0002,mercury0.0001.ForC10200,oxygenshouldbe0.0010max.DCopper(includingsilver
40、).EThisincludesoxygen-freeCuwhichcontainsPinanamountagreedupon.FSiliconshallbe0.10%max.GWhentheproductisforsubsequentweldingapplicationsandissospecifiedbythepurchaser,chromiumshallbe0.05%max,cadmium0.05%max,zinc0.05%max,andzirconium0.05%max.HWhentheproductisforsubsequentweldingapplications,andsospec
41、ifiedbythepurchaser,zincshallbe0.50%max,lead0.02%max,phosphorus0.02%max,sulfur0.02%max,andcarbon0.05%max.B111/B111M 1836.2.2 For alloys in which copper is listed as “remainder,”copper is the difference between the sum results of all theelements determined and 100 %. When all elements in Table 1are d
42、etermined, the sum of the results shall be as follows:Copper Alloy UNS No.Copper Plus NamedElements, % minC60800 99.5C61300 99.8C61400 99.5C70400 99.5C70600 t = thickness of tube wall, in. mm;D = outside diameter of the tube, in. mm; andS = allowable stress of the material, psi MPa.13.1.3 Pneumatic
43、TestEach tube shall be subjected to aninternal air pressure of 60 psig 400 kPa, min, for 5 s withoutshowing evidence of leakage. The test method used shallpermit easy visual detection of any leakage, such as by havingthe tube under water or by the pressure differential method.Any evidence of leakage
44、 shall be cause for rejection.14. Dimensions and Permissible Variations14.1 DiameterThe outside of the tubes shall not varyfrom that specified by more than the amounts shown in Table9 or Table 10 as measured by “go” and “no-go” ring gages.Alternatively, micrometers may be used to ensure outer diam-e
45、ter tolerance at any one point; however, in cases of dispute,ring gauges shall be used for final determination.TABLE 5 Notch DepthInch-Pound ValuesNOTE 1See Table 6 for notch depthSI values.Tube WallThickness,in.Tube Outside Diameter, in.Over14 to34,inclOver34 to 114,inclOver 114to 318,inclOver 0.01
46、70.032 0.005 0.006 0.007Incl 0.0320.049 0.006 0.006 0.0075Incl 0.0490.083 0.007 0.0075 0.008Incl 0.0830.109 0.0075 0.0085 0.0095Incl 0.1090.120 0.009 0.009 0.011B111/B111M 18614.2 Wall Thickness Tolerances:14.2.1 Tubes Ordered to Minimum WallNo tube wall at itsthinnest point shall be less than the s
47、pecified wall thickness.The maximum plus deviation from the specified wall at anypoint shall not exceed twice the values shown in Tables 11 and12.14.2.2 Tubes Ordered to Nominal WallThe maximum plusand minus deviation from the nominal wall at any point shallnot exceed the values shown in Tables 11 a
48、nd 12.14.3 LengthThe length of the tubes shall not be less thanthat specified when measured at room temperature, but mayexceed the specified value by the amounts given in Tables 13and 14.14.4 Squareness of CutThe departure from squareness ofthe end of the tube shall not exceed the following:Tube, OutsideDiameter, in. mmTolerance, in. mmUp to5
