1、Designation: B658/B658M 111Standard Specification forSeamless and Welded Zirconium and Zirconium Alloy Pipe1This standard is issued under the fixed designation B658/B658M; the number immediately following the designation indicates the yearof original adoption or, in the case of revision, the year of
2、 last revision. A number in parentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.1NOTEThe Nominal Outside Diameter heading in Table 4 was corrected editorially in March 2012.1. Scope1.1 This specification2cover
3、s three grades of seamless andwelded zirconium pipe.1.2 Unless a single unit is used, for example corrosion massgain in mg/dm2, the values stated in either inch-pound or SIunits are to be regarded separately as standard. The valuesstated in each system are not exact equivalents; therefore eachsystem
4、 must be used independently of the other. SI valuescannot be mixed with inch-pound values.1.3 The following precautionary caveat pertains only to thetest methods portions of this specification: This standard doesnot purport to address all of the safety concerns, if any,associated with its use. It is
5、 the responsibility of the user of thisstandard to establish appropriate safety and health practicesand determine the applicability of regulatory limitations priorto use.2. Referenced Documents2.1 ASTM Standards:3B614 Practice for Descaling and Cleaning Zirconium andZirconium Alloy SurfacesE8/E8M Te
6、st Methods for Tension Testing of MetallicMaterialsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE2626 Guide for Spectrometric Analysis of Reactive andRefractory Metals2.2 ANSI Standard:B36.19 Stainless Steel Pipe42.3 ASME Standard:ASME Boiler and
7、Pressure Vessel Code, Section VIII5ASME Boiler and Pressure Vessel Code, Section IX53. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 annealed, nfor purposes of this specification “an-nealed” denotes material that exhibits a recrystallized grainstructure.3.2 Lot Definitions:3.2.
8、1 pipe, na lot shall consist of a material of the samesize, shape, condition, and finish produced from the same ingotor powder blend by the same reduction schedule and the sameheat treatment parameters. Unless otherwise agreed betweenmanufacturer and purchaser, a lot shall be limited to theproduct o
9、f an 8 h period for final continuous anneal, or to asingle furnace load for final batch anneal.4. Classification4.1 The pipe is furnished in three grades as follows:4.1.1 Grade R60702Unalloyed zirconium.4.1.2 Grade R60704Zirconium-tin alloy.4.1.3 Grade R60705Zirconium-niobium alloy.5. Ordering Infor
10、mation5.1 Orders for materials under this specification shouldinclude the following information:5.1.1 Quantity (weight or total length),5.1.2 Name of material (zirconium pipe),5.1.3 Grade number (see 4.1),5.1.4 Nominal pipe size and schedule (Table X1.1),5.1.5 Lengths (random or specified cut length
11、s),5.1.6 Method of manufacture (Section 6),5.1.7 Workmanship and quality level requirements (Section10),5.1.8 ASTM designation and year of issue, and1This specification is under the jurisdiction of ASTM Committee B10 onReactive and Refractory Metals and Alloys and is the direct responsibility ofSubc
12、ommittee B10.02 on Zirconium and Hafnium.Current edition approved April 1, 2011. Published April 2011. Originallyapproved in 1979. Last previous edition approved in 2006 as B658/B658M 06.DOI: 10.1520/B0658_B0658M-11E01.2For ASME Boiler and Pressure Vessel Code Applications, see related Specifi-catio
13、n SB-658 in Section II of that Code.3For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.4Available from American
14、National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036, http:/www.ansi.org.5Available from American Society of Mechanical Engineers (ASME), ASMEInternational Headquarters, Three Park Ave., New York, NY 10016-5990, http:/www.asme.org.1Copyright ASTM International, 100 Barr
15、Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.5.1.9 Additions to the specification and supplementary re-quirements, if required. See 7.3, 14.1, 15.1, and 18.1 foradditional optional requirements for the purchase order.NOTE 1A typical ordering description is as follows: 2
16、40-ft 70-mmzirconium pipe, seamless, descaled 3.0-in. 75-mm Schedule 40 by 12-ft3-m lengths, ASTM B658/B658M - 05, Grade R60702.6. Materials and Manufacture6.1 Seamless pipe shall be made from any seamless methodthat will yield a product meeting this specification.6.2 Pipe containing welded seams or
17、 other joints made bywelding shall comply with the following provisions:6.2.1 Welded by welders, welding operators, and weldingprocedures qualified under the provisions of Section IX of theASME Boiler and Pressure Vessel Code.6.2.2 Filler metal, when used, shall be the same grade as thebase metal.6.
18、2.3 Welds in grade R60705 shall be stress relief annealedwithin 14 days after welding to prevent delayed hydridecracking. The heat treatment shall be as follows:6.2.3.1 The stress-relieving treatment shall consist of hold-ing the pipe at a minimum temperature of 1100F 600C fornot less than 30 min pe
19、r inch 25mm of the maximumthickness in a nonreducing atmosphere. The minimum time atthis temperature is 15 min. All stress-relieved parts shall becleaned subsequently and shall be free of oxide scale contami-nation (see Practice B614).6.3 The pipe shall be furnished in the annealed or stress-relieve
20、d condition.7. Chemical Composition7.1 The material shall conform to the requirements as tochemical composition prescribed in Table 1.7.2 The manufacturers ingot analysis shall be consideredthe chemical analysis for piping, except for hydrogen andnitrogen, which shall be determined on the finished p
21、roduct.7.3 When requested by the purchaser and stated in thepurchase order, a product analysis for any elements listed inTable 1 shall be made on the finished product.7.3.1 The manufacturers analysis shall be considered asverified if the check analysis confirms the manufacturersreported values withi
22、n the tolerances prescribed in Table 2.8. Tensile Requirements8.1 The material, as represented by the test specimens, shallconform to the tensile properties prescribed in Table 3.9. Permissible Variations in Dimensions9.1 Diametric any point (cross section) along the lengthof the pipe, the variation
23、s in outside diameters shall not exceedthose prescribed in Table 4.9.1.1 The tolerances on the outside diameter include ovalityexcept as provided for in 9.1.2.9.1.2 Thin-wall pipe usually develops significant ovality(out-of-roundness) during final annealing, straightening, orTABLE 1 Chemical Require
24、mentsAElementComposition, %UNS Grade DesignationR60702 R60704 R60705Zirconium + hafnium, min 99.2 97.5 95.5Hafnium, max 4.5 4.5 4.5Iron + chromium 0.2 max 0.2 to 0.4 0.2 maxTin . 1.0to2.0 .Hydrogen, max 0.005 0.005 0.005Nitrogen, max 0.025 0.025 0.025Carbon, max 0.05 0.05 0.05Niobium . . . . . . 2.0
25、 to 3.0Oxygen, max 0.16 0.18 0.18ABy agreement between the purchaser and the manufacturer, analysis may be required and limits established for elements and compounds not specified in the tableof chemical compositions.TABLE 2 Permissible Variation in Check Analysis BetweenDifferent LaboratoriesElemen
26、tPermissible Variation in ProductAnalysis, %Hydrogen 0.002Nitrogen 0.01Carbon 0.01Hafnium 0.1Iron + chromium 0.025Tin 0.05Niobium 0.05Oxygen 0.02TABLE 3 Tensile RequirementsUNS Grade DesignationsR60702 R60704 R60705Tensile strength,min, ksi MPa55 380 60 415 80 550Yield strength, min,ksi MPa30 205 35
27、 240 55 380Elongation in 2 in.or 50 mm,min, %A16 14 16AWhen a sub-size specimen is used, the gauge length shall be as specified inTest Methods E8/E8M for that specimen.TABLE 4 Permissible Variations in DiameterANominal Outside Diameter,(NPS)Bin. mmPermissible Variations in OutsideDiameter, in. mmOve
28、r Under18 to 112 3.2 to 40, incl164 .4132 .8Over 112 to 4 40 to 100, incl132 .8132 .8Over 4 to 8 100 to 200, incl116 1.6132 .8Over 8 to 12 200 to 305, incl332 2.4132 .8AFor seamless pipe only. Tolerances on welded pipe shall be as agreed uponbetween the manufacturer and the purchaser.BNPS = nominal
29、pipe size.B658/B658M 1112both. Thin-wall pipe is defined as having a wall thickness of3 % or less of the outside diameter. The diameter tolerances ofTable 4 are not sufficient to provide for additional ovalityexpected in thin-wall pipe and are applicable only to the meanof the extreme (maximum and m
30、inimum) outside diameterreadings in any one cross section. However, for thin-wall pipethe difference in extreme outside diameter readings (ovality) inany one cross section shall not exceed 1.5 % of the specifiedoutside diameter.9.2 ThicknessThe variation in thickness at any point shallnot be more th
31、an 612.5 % of the nominal wall thicknessspecified.9.3 Length:9.3.1 Pipe shall be furnished in lengths as specified in thepurchase order. No pipe shall be under the specified length andnot more than14 in. 6.4 mm over that specified.9.3.2 For pipe ordered to random lengths, the lengths andvariations s
32、hall be agreed upon between the manufacturer andthe purchaser.NOTE 2A system of standard pipe sizes approved by the AmericanNational Standards Institute as ANSI B36.19, reproduced as Table X1.1,shall apply, pending the development of similar standards for zirconium.10. Workmanship, Finish and Appear
33、ance10.1 The finished pipe shall be reasonably straight, shallhave smooth ends, free of burrs, and shall be free of cracks,seams, blisters, and other injurious imperfections in accordancewith standards of acceptability agreed upon between themanufacturer and the purchaser. Minor defects may be re-mo
34、ved provided the dimensional tolerances in accordance withSection 9 are not exceeded. Unless otherwise specified, thepipe shall be furnished free of scale.11. Significance of Numerical Limits11.1 For the purpose of determining compliance with thespecified limits for requirements of the properties li
35、sted in thefollowing table, an observed value or a calculated value shallbe rounded as indicated in accordance with the roundingmethods of Practice E29.Property Rounded Unit for Observed orCalculated ValueChemical composition and toler-ances (when expressed as deci-mals)Nearest unit in the last righ
36、t-handplace of figures of the specifiedlimitTensile strength and yield strength Nearest 1000 psi 10 MPaElongation Nearest 1 %12. Number of Tests and Retests12.1 One longitudinal tension test shall be made from eachlot, see13.1.12.2 One chemistry test for hydrogen and nitrogen contentshall be made fr
37、om each lot of finished product, see 13.3.12.3 A hydrostatic proof test shall be performed on eachlength of pipe, see 13.2.12.4 Retests:12.4.1 If any sample or specimen exhibits obvious surfacecontamination or improper preparation disqualifying it as atruly representative sample, it shall be discard
38、ed and a newsample or specimen substituted.12.4.2 If the results of any tests of any lot do not conform tothe requirements specified, retests shall be made on additionalpipe of double the original number from the same lot, each ofwhich shall conform to the requirements specified.12.4.3 Retesting aft
39、er failure of initial retests may be doneonly with the approval of the purchaser.13. Test Methods13.1 Tension TestsConduct the tension test in accordancewith Test Methods E8/E8M. Determine the yield strength bythe offset (0.2 %) method. Determine the tensile propertiesusing a strain rate of 0.003 to
40、 0.007 in./in. mm/mm/minthrough the yield strength. After the yield strength has beenexceeded, the cross-head speed may be increased to approxi-mately 0.05 in./in. mm/mm/min to failure.13.2 Hydrostatic TestsPrior to dimensional checks, upset-ting, swaging, expanding, or other forming operations, tes
41、teach pipe18 in. 3.2 mm and larger in outside diameter, andwith wall thickness of 0.015 in. 0.4 mm and over to ahydrostatic pressure sufficient to produce a fiber stress of threefourths of the minimum yield strength of the pipe, providedthat the test pressure does not exceed 5000 psi 35 MPa.Determin
42、e the test pressure as follows:P 5 2St/D (1)where:P = hydrostatic test pressure, psi MPa,S = allowable fiber stress of three fourths of the minimumyield strength (Table 2), psi MPa,t = average wall thickness of the pipe, in. mm, andD = nominal diameter of the pipe, in. mm.13.3 Chemical TestsConduct
43、the chemical analysis by thestandard techniques normally used by the manufacturer. GuideE2626 may be used as a guide for chemical analysis tech-niques.13.4 When specified in the purchase order, all butt weldsshall be 100 % radiographed or x-rayed per ASME CodeSection VIII, paragraph UW-51.14. Inspec
44、tion14.1 The manufacturer shall inspect the material covered bythis specification prior to shipment. If so specified in thepurchase order, the purchaser or his representative may witnessthe testing and inspection of the material at the place ofmanufacture. In such cases, the purchaser shall state in
45、 hispurchase order which tests he desires to witness. The manu-facturer shall give ample notice to the purchaser as to the timeand place of the designated tests. If the purchasers represen-tative does not present himself at the time agreed upon for thetesting, the manufacturer shall consider the req
46、uirement for thepurchasers inspection at the place of manufacture to bewaived.14.2 The manufacturer shall afford the inspector represent-ing the purchaser, without charge, all reasonable facilities tosatisfy him that the material is being furnished in accordancewith this specification. This inspecti
47、on shall be so conducted asnot to interfere unnecessarily with the operation of the works.B658/B658M 111315. Rejection15.1 Rejection for failure of the material to meet therequirements of this specification shall be reported to themanufacturer. Unless otherwise specified, rejected materialmay be ret
48、urned to the manufacturer at the manufacturersexpense, unless the purchaser receives, within three weeks ofthe notice of rejection, other instructions for disposition.16. Certification16.1 A producer or supplier shall furnish the purchaser witha certificate that the material was manufactured, sample
49、d,tested, and inspected in accordance with this specification andhas been found to meet the requirements. The certificate shallinclude a report of the test results.17. Referee17.1 In the event of disagreement between the manufacturerand the purchaser on the conformance of the material to therequirements of this specification or any special test specifiedby the purchaser, a mutually acceptable referee shall performthe tests in question. The results of the referees te
