1、Designation: C373 14aStandard Test Method forWater Absorption, Bulk Density, Apparent Porosity, andApparent Specific Gravity of Fired Whiteware Products,Ceramic Tiles, and Glass Tiles1This standard is issued under the fixed designation C373; the number immediately following the designation indicates
2、 the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This test method covers procedures for determi
3、ningwater absorption, bulk density, apparent porosity, and apparentspecific gravity of fired unglazed whiteware products, glazedor unglazed ceramic tiles, and glass tiles.1.2 The values stated in metric units are normative. Thevalues given in parentheses are mathematical conversions toinch-pound uni
4、ts that are provided for information only and arenot normative.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applic
5、a-bility of regulatory limitations prior to use.2. Significance and Use2.1 Measurement of density, porosity, and specific gravity isa tool for determining the degree of maturation of a ceramicbody, or for determining structural properties that may berequired for a given application.3. Apparatus and
6、Materials3.1 Balance, of adequate capacity, suitable to weigh accu-rately to 0.01 g (0.00002 lb).3.2 Oven, capable of maintaining a temperature of 150 65C (302 6 9F).3.3 Wire Loop, Halter, or Basket, capable of supportingspecimens under water for making suspended mass measure-ments.3.4 Suspended Mas
7、s Container (if Determination of Sus-pended Mass is Desired)A glass beaker or similar containerof such size and shape that the sample, when suspended fromthe balance by the wire loop, specified in 3.3, is completelyimmersed in water with the sample and the wire loop com-pletely free of contact with
8、any part of the container.3.5 Stainless Steel Boiling Container, suitable for boilingwater and with sufficient capacity to hold the test specimensand quantity of water specified in 5.2. The container shall beequipped with a loose removable cover which does not allowpressure to build.3.6 Deionized (D
9、I) or Distilled Water.3.7 Leather Chamois.3.8 Heat Source, such as a hot plate, burner, or equivalent toheat the water to boiling.3.9 Desiccatora sealed chamber containing desiccantswhich is of sufficient size and capacity to allow specimens tocool while preventing the specimens from absorbing moist
10、urefrom ambient air.4. Test Specimens:4.1 Ceramic Whitewares:4.1.1 At least five representative test specimens shall beselected that have not been previously tested. The specimensshall be unglazed and shall have as much of the surface freshlyfractured as is practical. Sharp edges or corners shall be
11、removed. The specimens shall contain no cracks. The indi-vidual test specimens shall weigh at least 50 g.4.2 Ceramic Tiles and Glass Tiles:4.2.1 The specimens shall contain no visible damage orcracks prior to testing. At least five representative test speci-mens shall be selected that have not been
12、previously tested.Cutting of specimens, as described in the following sections,shall consist of scoring and snapping, or sawing when impos-sible to score and snap with conventional tile scoring equip-ment (as can be the case with some glass tiles and highlytextured and structured porcelain tiles).4.
13、2.2 For tiles less than or equal to 205 205 mm (8 8 in.), specimens shall be cut in half, within 10 mm (0.4 in).Specimens shall be cut perpendicular to the longest side if thespecimen has unequal sides. Select one half at random fromeach specimen for testing (see Fig. 1a and Fig. 1b).1This test meth
14、od is under the jurisdiction ofASTM Committee C21 on CeramicWhitewares and Related Products and is the direct responsibility of SubcommitteeC21.03 on Methods for Whitewares and Environmental Concerns.Current edition approved Dec. 1, 2014. Published December 2014. Originallyapproved in 1955. Last pre
15、vious edition approved in 2014 as C373 2014. DOI:10.1520/C0373-14A.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States14.2.3 For tiles greater than 205 205 mm (8 8 in.) and
16、lessthan or equal to 410 410 mm (16 16 in.), each specimenshall be cut into four equal quadrants, within 10 mm (0.4 in).Select one quadrant at random from each specimen for testing(see Fig. 2).4.2.4 For tiles greater than 410 410 mm (16 16 in.), a205 205 mm (8 8 in.) portion, within 10 mm (0.4 in),
17、shallbe cut from one corner of each specimen for testing (see Fig.3.4.2.5 For non-square tiles which have a side less than orequal to 205 mm (8 in.) and a side greater than 205 mm (8 in.),each specimen shall be cut once perpendicular to the longestside, such that a 205 mm (8 in.) portion, within 10
18、mm (0.4 in),from the end remains for testing (see Fig. 4).4.2.6 For non-square tiles which have a side greater than205 mm (8 in.) and less than or equal to 410 mm (16 in.), anda side greater than 410 mm (16 in.), each specimen shall be cutonce perpendicular to the longest side, such that a 205 mm (8
19、in.) portion, within 10 mm (0.4 in.), from the end remains. The205 mm (8 in.) portion shall be cut a second time, in half,within 10 mm (0.4 in.) perpendicular to the first cut. Select onehalf at random from each specimen for testing (see Fig. 5).4.2.7 If a tile does not weigh at least 50 g (0.11 lb)
20、 prior tocutting, then multiple whole pieces may be used to equal onetest specimen with a mass of at least 50 g (0.11 lb).5. Procedure5.1 Dry the test specimens to constant mass (Note 2)byheating in an oven at 150 6 5C (302 6 9F) for a minimumof 24 h (or such other time as has been established for t
21、he ovenin use and the mass of the tiles being dried), followed bycooling in a desiccator. Determine the dry mass, D,tothenearest 0.01 g (0.00002 lb) (see Note 1).NOTE 1Specimens being tested directly following their manufacturemay be considered fully dried so long as they have not been subjected toa
22、ny process that wets the specimen post firing (such as can occur in cuttingand polishing operations) and are placed in a desiccator sufficientlyquickly (usually within no more than 30 min of exiting the kiln) that nomoisture has been absorbed from ambient air.NOTE 2The drying of the specimens and th
23、e determination of theirmasses may be done either before or after the specimens have beenimpregnated with water. Usually the dry mass is determined beforeimpregnation. However, if the specimens are friable or evidence indicatesthat particles have broken loose during the impregnation, the specimenssh
24、all be dried and weighed after the suspended mass and the saturatedmass have been determined, in accordance with 5.4 and 5.5. In this case,the second dry mass shall be used in all appropriate calculations.5.2 Addition of Specimens to DI or Distilled Water:5.2.1 For Ceramic Whitewares, Glass Tiles, a
25、nd PressedCeramic TilesBring DI or distilled water to a boil in astainless steel boiling container. Place the specimens in the(a.) Equal Sides: x # 205 mm, , a =12 x (within 10 mm)(b.) Unequal Sides: x # 205 mm, y# 205 mm, x y, a =12 x (within 10 mm)FIG. 1FIG. 2205 mm 410mm,y410mm,a=205mm(within10mm
26、)FIG. 4x 205 mm, y # 205mm,a=205mm(within10mm)FIG. 5x 410 mm, 205 mm y # 410 mm, a = 205 mm (within 10 mm),b=12 y (within 10 mm)C373 14a2boiling DI or distilled water, and use setter pins, a rustproofrack, or equivalent to separate the specimens from the bottomand sides of the stainless steel boilin
27、g container and from eachother. The DI or distilled water shall be unused and of sufficientquantity that the test specimens are fully submerged and themass ratio of water to test specimens is at least 3:1.5.2.2 For Extruded Ceramic TilesPlace the specimens in astainless steel boiling container of DI
28、 or distilled water at roomtemperature, and use setter pins, a rustproof rack, or equivalentto separate the specimens from the bottom and sides of thestainless steel boiling container and from each other. The DI ordistilled water shall be unused and of sufficient quantity suchthat the test specimens
29、 are fully submerged and the mass ratioof water to test specimens is at least 3:1. Bring the DI ordistilled water with submerged specimens to a boil in one houror less.5.3 Boil the specimens for 5 h 6 5 min. Place a loose coverover the container to minimize water loss through evaporation.Test specim
30、ens shall be completely immersed in the boiling DIor distilled water throughout the duration of the 5 h boil. AddDI or distilled water as needed to ensure the specimens arecompletely immersed at all times. Ensure that the boil ismaintained throughout the test and that the addition of waterdoes not h
31、inder the boil.After the 5-h boil, allow the specimensto continue to soak in the same DI or distilled water in whichthey were boiled for an additional 24 h 6 30 min., ensuringthat the specimens remain completely immersed.5.4 After the 24-h soak of the test specimens, determine tothe nearest 0.01 g (
32、0.00002 lb) the mass, S, of each specimenwhile suspended in water. Perform the weighing by placing thespecimen in a wire loop, halter, or basket that is suspendedfrom one arm of the balance. Before actually weighing,counterbalance the scale with the loop, halter, or basket inplace and immerse in wat
33、er to the same depth as is used whenthe specimens are in place. If it is desired to determine only thepercentage of water absorption, omit the suspended massoperation.5.5 After the determination of the suspended mass, or afterthe 24-h soak, if the suspended mass is not determined, bloteach specimen
34、lightly with a damp leather chamois to removeall visible water droplets from the surface, and determine thesaturated mass, M, to the nearest 0.01 g (0.00002 lb). A dampchamois is defined as one which has been saturated with waterand then pressed only enough to remove water which coulddrip. The blott
35、ing process shall involve patting the specimenlightly on all edges and surfaces with the damp chamois. Takecare not to blot excessively as this could introduce error bywithdrawing water from the pores of the specimen. Weightdetermination shall be performed immediately after the blot-ting process to
36、avoid errors due to evaporation of water fromthe test specimen.6. Calculation6.1 In the following calculations, the assumption is madethat 1 cm3of water weighs 1 g.6.1.1 Calculate the exterior volume, V, in cubic centimetres,as follows:V 5 M 2 S (1)6.1.2 Calculate the volumes of open pores, VOP, and
37、 imper-vious portions, VIP, in cubic centimetres as follows:VOP5 M 2 D (2)VIP5 D 2 S (3)6.1.3 The apparent porosity, P, expresses, as a percent, therelationship of the volume of the open pores of the specimen toits exterior volume. Calculate the apparent porosity as follows:P 5 M 2 D!/V# 3100 (4)6.1
38、.4 The water absorption, A, expresses as a percent, therelationship of the mass of water absorbed to the mass of thedry specimen. Calculate the water absorption as follows:A 5 M 2 D!/D# 3100 (5)6.1.5 Calculate the apparent specific gravity, T, of thatportion of the test specimen that is impervious t
39、o water, asfollows:T 5 D/D 2 S! (6)6.1.6 The bulk density, B, in grams per cubic centimetre, ofa specimen is the quotient of its dry mass divided by theexterior volume, including pores. Calculate the bulk density asfollows:B 5 D/V (7)7. Report7.1 Report the average of all the specimens tested for ea
40、chdesired property (V, VOP,VIP, P, A, T, or B, or combinationsthereof) and also the individual values to one decimal place byrounding to the nearest tenth. For example, 0.44 rounds to 0.4and 0.46 rounds to 0.5. If the calculated property ends inexactly five hundredths, round to the nearest even tent
41、h (forexample, 0.45 rounds to 0.4, 0.55 rounds to 0.6, 0.65 rounds to0.6, and 0.75 rounds to 0.8).8. Precision and Bias8.1 PrecisionNo statement is made about the precision ofthis test method since no test data are available yet to permitsuch a statement to be made. Work is planned to develop thisda
42、ta.8.2 BiasNo statement is made about the bias of this testmethod since no standard samples are available.9. Keywords9.1 apparent porosity; apparent specific gravity; bulk den-sity; ceramic tile; fired whiteware products; glass tile; waterabsorptionC373 14a3SUMMARY OF CHANGESCommittee C21 has identi
43、fied the location of selected changes to this standard since the last issue(C373 88 (2006) that may impact the use of this standard. (Dec. 1, 2014.)(1) Revised subsections 3.6, 5.2 5.3.(2) Revised subsections 4.2.2 4.2.5.(3) Added Figs. 1-5.(4) Revised Section 7.(5) Revised subsection 5.5.ASTM Inter
44、national takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely
45、their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand shou
46、ld be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Stan
47、dards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 14a4
