1、Designation: C602 13Standard Specification forAgricultural Liming Materials1This standard is issued under the fixed designation C602; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parenthese
2、s indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification covers agricultural liming materials,such as quicklime
3、 (burnt lime), hydrated lime, limestone,(calcitic and dolomitic), marl, shells, and by-products includ-ing slag, lime kiln dust and other materials.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 This standard does not p
4、urport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2
5、C25 Test Methods for Chemical Analysis of Limestone,Quicklime, and Hydrated LimeC50 Practice for Sampling, Sample Preparation, Packaging,and Marking of Lime and Limestone ProductsC110 Test Methods for Physical Testing of Quicklime,Hydrated Lime, and LimestoneC125 Terminology Relating to Concrete and
6、 Concrete Ag-gregatesC1271 Test Method for X-ray Spectrometric Analysis ofLime and LimestoneC1301 Test Method for Major and Trace Elements in Lime-stone and Lime by Inductively Coupled Plasma-AtomicEmission Spectroscopy (ICP) and Atomic Absorption(AA)D3176 Practice for Ultimate Analysis of Coal and
7、CokeE11 Specification for Woven Wire Test Sieve Cloth and TestSieves3. Terminology3.1 Definitions:3.1.1 agricultural liming materiala product whose cal-cium and magnesium compounds are capable of neutralizingsoil acidity.3.1.2 air-cooled blast-furnace slag and granulated blast-furnace slagair-cooled
8、 blast-furnace slag and granulatedblast furnace slag as defined in Terminology C125.3.1.3 calcium carbonate equivalent (C.C.E.)the acid-neutralizing capacity (of an agricultural liming material) of thematerial expressed as weight percent of calcium carbonate.4. Chemical Classifications4.1 Agricultur
9、al liming materials shall be classified in termsof calcium carbonate equivalent (C.C.E.), as shown in Table 1.NOTE 1Marl and some by-product liming materials are used forneutralizing soil acidity, but due to their varying composition, theirchemical limits are not included. In some economic circumsta
10、nceslimestone, lime kiln dust, slag, and shells of less than 80 % C.C.E. may beused.5. Sieve Analysis Classifications for AgriculturalLimestone5.1 Agricultural limestone shall be classified according tothe minimum percentages passing the 2.36-mm (No. 8) and250-m (No. 60) sieves conforming to Specifi
11、cation E11,asshown in Table 2.NOTE 2These classifications apply where the agricultural limestone isobtained by the normal crushing procedure and the product contains thefines of fracture. In some economic circumstances, coarser products areused. The 250-m (No. 60) sieve was selected because research
12、 has shownthat this sieve gives a more accurate representation of the particle sizedistribution of most agricultural limestones presently produced than a fineror coarser sieve. The 2.36-mm (No. 8) sieve is used to control the upperlimit on the amount of coarse limestone particles that may be in thep
13、roduct.6. Sieve Analysis Classifications for Agricultural Slag6.1 Air-Cooled Blast-Furnace SlagAir-cooled blast-furnace slag shall be classified the same as agriculturallimestone as described in Section 5.1This specification is under the jurisdiction of ASTM Committee C07 on Limeand is the direct re
14、sponsibility of Subcommittee C07.02 on Specifications andGuidelines.Current edition approved June 1, 2013. Published July 2013. Originally approvedin 1967. Last previous edition approved in 2012 as C602 12. DOI: 10.1520/C0602-13.2For referenced ASTM standards, visit the ASTM website, www.astm.org, o
15、rcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, W
16、est Conshohocken, PA 19428-2959. United States16.2 Granulated Blast-Furnace SlagGranulated blast-furnace slag shall be classified the same as agriculturallimestone as described in Section 5.7. Sieve Analysis Classifications for Agricultural LimeKiln Dust7.1 Lime kiln dust sieve analysis shall be cla
17、ssified the sameas agricultural limestone as described in Section 5.8. Particle Size Requirements for Hydrated Lime andQuicklime8.1 Hydrated lime and quicklime for agricultural use shallbe classified in accordance with the minimum percentagespassing the 2.36-mm (No. 8) and 250-m (No. 60) sieves, asf
18、ollows:Min. %Passing Sieve No. Hydrated Lime Quicklime8 (2.36 mm) 100 9560 (250 m) 97 359. Regulatory Requirements9.1 Agricultural liming materials shall be evaluated for theregulatory considerations using the required local, state, andfederal test methods in effect at the time of use.9.2 Agricultur
19、al liming materials shall meet all applicablelocal, state, and federal requirements in effect at the time ofuse.10. Sampling10.1 Sampling shall be conducted using the proceduresspecified in Practice C50.11. Chemical Methods11.1 Reagent grade chemicals or equivalent and waterpurity shall be used as s
20、pecified in Test Methods C25.11.2 The analytical sample for chemical methods relative tothis standard shall be pulverized to pass a 60 mesh sieve.11.3 The following chemical parameters are to be deter-mined using the methods as specified.11.3.1 Calcium carbonate equivalent by the method in C25and11.
21、3.2 Total calcium and magnesium oxidedeterminationcan be made by methods in C25, C1271 or C1301.SIEVE ANALYSIS OF AGRICULTURAL LIMINGMATERIALS12. Preparation of Sample12.1 Dry the sample to constant weight at 110 6 5Candstore in an airtight container. Obtain the sample from a largersample of the mat
22、erial to be tested by the use of a riffle or asample splitter in accordance with Practice D3176,orbythemethod of quartering. The sample for sieve analysis shall havea weight of 100 to 150 g.12.2 Where limestone contains clay, some agglomeration offine particles may occur. The agglomerates must be br
23、oken byrolling the dry sample with a hard rubber roller on a hardrubber mat or by some equally effective means that does notresult in crushing the limestone.13. Procedure13.1 Sieve analysis shall be conducted using the proceduresin Test Methods C110. Sieve the sample through 2.36-mm (No.8) and 250-m
24、 (No. 60) sieves. Determine the weight of limingmaterial passing each sieve on a scale or balance sensitive to atleast 0.1 g. Calculate the amount of liming material passing thesieves to the nearest whole percentage of the total weight of thedry sample.14. Report14.1 Report the following results for
25、 agricultural limingmaterials:14.1.1 Percentage Calcium Carbonate EquivalentThepercentage calcium carbonate equivalent (C.C.E.) shall bereported on the as-received basis. Calculate as follows:C.C.E. as 2 received! 5 1 2 % moisture100!# 3C.C.E. oven2 dry! (1)14.1.2 Percentage MoistureCalculate as fol
26、lows:Moisture, %5 (2)Weight of sample as received! 2 oven 2 dry weightWeight of sample as received!310014.1.3 Percentage Calcium Oxide and Magnesium OxideThe percentages of calcium oxide and magnesium oxide on thebasis of the as-received sample.14.1.4 Sieve AnalysisThe amount of dried sample passing
27、the 2.36-mm (No. 8) and 250-m (No. 60) sieves as apercentage of the total weight of the dried sample with thefigures rounded to the nearest whole percentage point.15. Keywords15.1 aglime; agricultural liming materials; agricultural lime-stone; calcium carbonate equivalent; hydrated lime; limeby-prod
28、ucts; lime kiln dust; limestone; LKD; quicklime; slagTABLE 1 Agricultural Liming MaterialsMaterialCalcium CarbonateEquivalent (C.C.E.),percentQuicklime not less than 140Hydrated lime not less than 110Limestone not less than 80Slag not less than 80Shells not less than 80TABLE 2 Classification for Agr
29、icultural LimestoneClassDesignationPassing No. 8(2.36-mm)Sieve, min,percentPassing No. 60(250-m)Sieve, min,percentS 100 100T9975O95N9040E82C602 132SUMMARY OF CHANGESCommittee C07 has identified the location of selected changes to this standard since the last issue, C602 12,that may impact the use of
30、 this standard. (Approved June 1, 2013.)(1) Revised to clarify sieve classification.(2) Revised Section 1 and Section 4 to include reference tolime kiln dust.(3) Added Section 7 and Section 9.ASTM International takes no position respecting the validity of any patent rights asserted in connection wit
31、h any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible techn
32、ical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful considerati
33、on at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Har
34、bor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).C602 133
