1、Designation: D1513 05 (Reapproved 2012)Standard Test Method forCarbon Black, PelletedPour Density1This standard is issued under the fixed designation D1513; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision.
2、 A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This test method covers the determination of the po
3、urdensity of pelleted carbon blacks.1.2 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the us
4、er of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D1799 Practice for Carbon BlackSampling PackagedShipmentsD1900 Practice for Carbon BlackSampling Bulk Ship-ment
5、sD4483 Practice for Evaluating Precision for Test MethodStandards in the Rubber and Carbon Black ManufacturingIndustries3. Summary of Test Method3.1 Pour density is determined by measuring the mass ofcarbon black in a known volume.4. Significance and Use4.1 Pour density is a function of the degree o
6、f compactionduring pelletization. It is strongly influenced by and inverselyproportional to structure (OAN). Pour density of carbon blackis useful for estimating the weight-to-volume relationship forcertain applications, such as automatic batch loading systems,and for estimating weights of bulk ship
7、ments.5. Apparatus5.1 Cylindrical Container, 1000 or 624-cm3capacity, hav-ing a uniform height and no pouring lip or deformation of thewall. A stainless steel beaker 100 6 5mm(46 0.2 in.) indiameter is acceptable.NOTE 1A satisfactory container can be made by pouring 1000 or 624cm3of water at 20C int
8、o a 1000 or 1200-cm3stainless steel beaker 1006 5mm(46 0.2 in.) in diameter, marking the water level and then cuttingat the mark after chucking firmly in a lathe.5.2 Straightedge or Spatula, at least 150 mm (6 in.) inlength.5.3 Balance, torsion or trip, with a sensitivity of 0.1 g.6. Sampling6.1 Sam
9、ples shall be taken in accordance with PracticeD1799 or Practice D1900.7. Procedure7.1 Pour the carbon black into the center of the taredcontainer from a height not more than 50 mm (2 in.) above therim. A large enough excess should be used to form a coneabove the rim of the cylindrical container. Le
10、vel the surfacewith a single sweep of the straightedge or spatula heldperpendicular to and in firm contact with the lip of thecontainer. Record the mass of the carbon black to the nearestgram.8. Calculation8.1 Calculate the pour density to the nearest kg/m3asfollows:8.1.1 Using a 1000-cm3container:D
11、 5 W1000(1)8.1.2 Using a 624-cm3container:D 5 W624316!/10 (2)where:D = pour density, kg/m3,W1000= mass of carbon black, g in 1000-cm3container, andW624= mass of carbon black, g in 624-cm3container.1This test method is under the jurisdiction of ASTM Committee D24 on CarbonBlack and is the direct resp
12、onsibility of Subcommittee D24.51 on Carbon BlackPellet Properties.Current edition approved June 1, 2012. Published November 2012. Originallyapproved in 1957. Last previous edition approved in 2005 as D1513 052. DOI:10.1520/D1513-05R12.2For referenced ASTM standards, visit the ASTM website, www.astm
13、.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States18.2 Density
14、 to the nearest lb/ft3can be calculated as follows:8.2.1 Using a 1000-cm3container:d 5 D/165 W1000/16 (3)8.2.2 Using a 624-cm3container:d 5 D/165 W624/10 (4)where:d = pour density, lb/ft3,D = pour density, kg/m3,W624= mass of carbon black, g in 624-cm3container, andW1000= mass of carbon black, g in
15、1000-cm3container.9. Report9.1 Report the following information:9.1.1 Proper identification of the sample, and9.1.2 Result obtained, reported to the nearest kg/m3(0.1lb/ft3).10. Precision and Bias310.1 This precision and bias section has been prepared inaccordance with Practice D4483. Refer to Pract
16、ice D4483 forterminology and other statistical details.10.2 PrecisionThe precision results in this section give anestimate of the precision as described in 10.3-10.5.2. Theprecision parameters should not be used for acceptance/rejection testing of any group of materials without documen-tation that t
17、hey are applicable to those particular materials andthe specific testing protocols that include this test method.10.3 A Type 1 interlaboratory precision program was con-ducted in 1994. Both repeatability and reproducibility repre-sent short-term testing conditions. Nine laboratories testedthree carb
18、on blacks (Materials A, B, and C) twice on twodifferent days. A test result is the value obtained from a singledetermination. Acceptable difference values were not mea-sured.10.4 The results of the precision calculations are given inTable 1, with the materials arranged in ascending “mean level”order
19、.10.5 The precision for the pooled values for pour densitymay be expressed as follows:10.5.1 RepeatabilityThe repeatability, (r), of the pourdensity has been established as 1.7 % (pooled). Two single testresults (or determinations) that differ by more than 1.7 % mustbe considered suspect and dictate
20、 that some appropriate inves-tigative action be taken.10.5.2 ReproducibilityThe reproducibility, (R),ofthepour density has been established as 3.7 % (pooled). Twosingle test results (or determinations) produced in separatelaboratories that differ by more than 3.7 % must be consideredsuspect and dict
21、ate that some appropriate investigative ortechnical/commercial action be taken.10.6 BiasIn test method terminology, bias is the differencebetween an average test value and the reference (true) testproperty value. Reference values do not exist for this testmethod since the value or level of the test
22、property isexclusively defined by the test method. Bias, therefore, cannotbe determined.11. Keywords11.1 carbon black; estimating mass of bulk shipments; massto volume relationships; pelleted carbon black; pour density3Supporting data have been filed at ASTM International Headquarters and maybe obta
23、ined by requesting Research Report RR:D24-1028.TABLE 1 Test Method PrecisionType 1: Pour DensityMaterialMean Levelkg/m3(lb/ft3)Within LaboratoryABetween LaboratoryASrr (r) SRR (R)C 380 (23.8) 2.8 (0.18) 7.9 (0.50) 2.1 4.5 (0.28) 12.9 (0.80) 3.4B 434 (27.1) 2.2 (0.14) 6.2 (0.39) 1.4 6.3 (0.39) 17.7 (
24、1.11) 4.1A 540 (33.7) 3.3 (0.20) 9.2 (0.57) 1.7 6.5 (0.41) 18.5 (1.16) 3.4Pooled orAverage values452 (28.2) 2.8 (0.17) 7.9 (0.50) 1.7 5.9 (0.39) 16.6 (1.03) 3.7ASymbols are defined as follows:Sr= within laboratory standard deviationr = repeatability in measurement units, kg/m3(lb/ft3)(r) = repeatabi
25、lity in percentSR= between laboratory standard deviationR = reproducibility in measurement units, kg/m3(lb/ft3)(R) = reproducibility in percentD1513 05 (2012)2ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this stand
26、ard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be review
27、ed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible
28、 technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Cons
29、hohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D1513 05 (2012)3
