1、Designation: D 1644 01 (Reapproved 2006)Standard Test Methods forNonvolatile Content of Varnishes1This standard is issued under the fixed designation D 1644; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision
2、. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 These test methods determine the fraction of a va
3、rnishthat is nonvolatile at the temperature of the test while volatilesolvents are driven off. It is sometimes an approximatemeasure of the film-forming matter in a varnish.1.2 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.1.
4、3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use. For a specificst
5、atement, see Section 3.2. Significance and Use2.1 These test methods are applicable to varnish and areuseful to producers and users in determining nonvolatilecontent and are sometimes an appropriate measure of thefilm-forming matter in varnish.3. Hazards3.1 Since the flash points of some of the solv
6、ents used incoatings and related products are below the temperature of thetest, care should be exercised that the lower explosive limits ofthe solvents are not exceeded. The amount of solvent in theoven atmosphere at any one time will depend on the number oftests (pans) in the oven, the percent nonv
7、olatile of the samples,the size of the oven, the type of oven (mechanical or gravityconvection) and the air changes per hour.TEST METHOD A3 h AT 105C4. Procedure4.1 Place a portion of the thoroughly mixed sample in astoppered bottle, or alternatively, in a weighing pipet or a10-mL syringe without a
8、needle, and from this weigh bydifference 1.2 6 0.1 g into a tared flat-bottomed metal or glassdish (Note 1), 80 to 100 mm in diameter and 5 to 10 mm indepth, such as friction-top can covers, ointment boxes, or petridishes.NOTE 1The term “tared, flat-bottomed dish” implies that the emptydish has no m
9、easurable weight change when subjected to the same heatschedule as prescribed for the dish containing the specimen. If this isfound to be not so, then more suitable vessels must be found, orcorrections applied.4.2 By gentle tilting, spread the specimen over the bottom ofthe dish and heat for3hinaven
10、tilated oven maintained at 1056 2C. If necessary, a piece of stout wire can be included in thetare of the dish and used at intervals to break up skins bystirring during the heating period. Cool in a desiccator andweigh the dish.5. Calculation5.1 Calculate the percent of nonvolatile matter NV asfollo
11、ws (Note 2):NV 5 C 2 A!/S 3 100 (1)where:A = weight of dish, g,S = weight of specimen used, g, andC = weight of dish and contents after heating, g.NOTE 2Determinations of nonvolatile matter by this test method maygive high results due either to incomplete elimination of volatile matter orto absorpti
12、on of oxygen by oxidizing-type varnishes.6. Report6.1 Report the nonvolatile matter of the sample to thenearest 0.1 %.TEST METHOD B10 min at 150C7. Apparatus7.1 Sample Transfer Device,a2or5-mL Luer syringe.7.2 Solids Dish, made from metal foil of such design as toensure reasonably good contact of th
13、e bottom surface whenplaced on the hot plate. Condition the dish for at least 10 minat 150C or higher; then store in a desiccator.1These test methods are under the jurisdiction of ASTM Committee D01 onPaint and Related Coatings, Materials, and Applications and are the directresponsibility of Subcomm
14、ittee D01.21 on Chemical Analysis of Paints and PaintMaterials.Current edition approved June 1, 2006. Published June 2006. Originallyapproved in 1959. Last previous edition approved in 2001 as D 1644 01.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-29
15、59, United States.7.3 Hot-Plate, capable of maintaining a surface temperatureof 150 6 3.5C (302 6 6F).8. Procedure8.1 Weigh by difference from the syringe into a tared solidsdish, sufficient sample to form a 65 to 125m (2.5 to 5.0mil)thick nonvolatile residue. Use a minimum of toluene todistribute t
16、he specimen, by gentle swirling uniformly, over thebottom of the dish.NOTE 3Specimen size limits may be estimated from the followingtable, which was calculated for a material having nonvolatile matter witha specific gravity of 1.3:Weight of Nonvolatile ResidueDiameter of Dish 45 mm 100 mmFor a 2.5-m
17、il varnish film 0.12 g 0.60 gFor a 5-mil varnish film 0.25 g 1.20 g8.2 Place the dish on the hot plate at 150 6 3.5C for 10min. Cool to room temperature in a desiccator, then reweigh.9. Calculation9.1 Calculate the nonvolatile matter as described in Section5.10. Report10.1 Report the nonvolatile mat
18、ter of the sample to thenearest 0.1 %.11. Keywords11.1 nonvolatile matter content; varnishesASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determinatio
19、n of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdra
20、wn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your c
21、omments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).D 1644 01 (2006)2
