1、Designation: D904 99 (Reapproved 2013)Standard Practice forExposure of Adhesive Specimens to Artificial Light1This standard is issued under the fixed designation D904; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of las
2、t revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This practice covers the basic principles and operatingprocedures for ultraviolet (UV) light aging (with or withoutwater)
3、 of adhesive bonded joints having at least one glass ortransparent adherend, using fluorescent UV (see Method A) orxenon-arc light sources (see Method B).1.2 This practice is limited to the apparatus for obtaining,measuring, and controlling the aging conditions, and to theprocedures for exposure. Sa
4、mple preparation, strength, testconditions, and evaluation of the results are described in otherASTM test methods or specifications.1.3 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.4 This standard does not purport to addres
5、s all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D907 Terminology
6、 of AdhesivesG151 Practice for Exposing Nonmetallic Materials in Accel-erated Test Devices that Use Laboratory Light SourcesG154 Practice for Operating Fluorescent Ultraviolet (UV)Lamp Apparatus for Exposure of Nonmetallic MaterialsG155 Practice for Operating Xenon Arc Light Apparatus forExposure of
7、 Non-Metallic Materials3. Terminology3.1 DefinitionsMany of the terms in this practice aredefined in Terminology D907.3.2 Definitions of Terms Specific to This Standard:3.2.1 irradiance, n(1) the rate at which light energy fallson a unit area of surface (W/m2), or (2) the radiant powerincident upon
8、a unit area of surface.3.2.2 radiant exposure (or light dosage), n(1) the accu-mulated light energy which has fallen on a unit area over time(J/m2), or (2) the irradiance integrated with respect to time.3.2.3 spectral irradiance, nthe distribution of irradiancein accordance with wavelength.3.2.3.1 D
9、iscussionSpectral irradiance is usually shown asa curve relating irradiance (ordinate) and light wavelength(abscissa). Because shorter wavelength UV is usually moredamaging than longer wavelength UV, lamps with differentspectral irradiance curves can cause drastically differentamounts of UV damage,
10、even if they produce the same totalirradiance.3.2.4 spectral power distribution (SPD), nthe amount ofradiation present at each wavelength.3.2.4.1 DiscussionThe SPD can be expressed by power inwatts, irradiance in watts/square metre, or energy in joules. Theshape of the SPD would be identical in all
11、of these units.Fluorescent lamps are frequently described by relative SPDswhich show the amount of radiation at each wavelength as apercentage of the amount of radiation at the peak wavelength.3.2.5 UV-A, nultraviolet light in the wavelength bandbetween 315 and 400 nm.3.2.6 UV-B, nultraviolet light
12、in the wavelength bandbetween 280 and 315 nm.4. Significance and Use4.1 This practice is for determining the effects of UV light,or UV light and water, on adhesive bonded joints undercontrolled but artificial conditions. The results of this practicecan be used for comparing the relative durability o
13、f severaladhesives in a specific laboratory UV exposure.4.2 This practice is not for determining a forecast of the lifeof an adhesive bond in service. It is only for determining therelative durability of different adhesives compared to eachother.4.3 The results obtained may vary between the differen
14、tlight sources (xenon-arc or fluorescent UV), because of thedifferent spectral-irradiance of the lamps.Adhesives should not1This practice is under the jurisdiction of ASTM Committee D14 on Adhesivesand is the direct responsibility of Subcommittee D14.40 on Adhesives for Plastics.Current edition appr
15、oved July 1, 2013. Published July 2013. Originally approvedin 1946. Last previous edition approved in 2008 as D904 99 (2008). DOI:10.1520/D0904-99R13.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStand
16、ards volume information, refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1be compared to each other based on their performance underdifferent types of light sources.4.4 Th
17、e results obtained may vary when operation condi-tions are varied within the limits of a given method. The resultsmay also vary when exposures are performed on instrumentsmade by different manufacturers. Comparisons between mate-rials must only be made when they are tested at the same timein the sam
18、e instrument. Be sure to accurately report theoperating conditions.4.5 The type and UV transmittance characteristics of thetransparent adherend used can have a significant effect on therate and type of degradation of the adhesives being tested.Comparisons between adhesives must only be made whentest
19、ed on transparent adherends of the same type (preferablythe same lot) with the same UV transmission.4.6 This practice is not for determining the effects ofatmospheric pollutants, biological organisms, salt, or freeze/thaw cycles.5. Method AFluorescent UV5.1 ApparatusA fluorescent UV and condensation
20、 cham-ber in accordance with Practices G151 and G154.5.2 Lamp TypeUse fluorescent UV-A lamps, with a peakemission at 343 nm.NOTE 1UV-A lamps are preferable to UV-B lamps, because UV-Awavelengths can pass through the transparent portion of the test specimenwithout being absorbed, whereas most of the
21、UV-B wavelengths arefiltered out by the glass.5.2.1 Other fluorescent UV lamps meeting the size andelectrical characteristics in 5.2 may be used by prioragreement, provided that the lamp and spectral power distri-bution are reported in conformance with Section 7. Use oflamps other than those specifi
22、ed in 5.2 may result in significantdifferences in test results.5.3 Specimen MountingMount the specimens in the speci-men holders so that the UV passes through the transparentadherend to reach the adhesive joint or so that the joint isexposed to the effects of condensation (if applicable). Use asuita
23、ble backing panel to ensure that vapor does not escapefrom the test chamber around the test specimen. When the testspecimens do not completely fill the racks, fill the emptyspaces with blank panels to maintain the test conditions withinthe chamber.5.4 Time/Temperature CyclesProgram the apparatus toa
24、chieve the desired test conditions, as follows:5.4.1 Cycle I4hUVat606 3C followed by 4 hcondensation at 50 6 3C, for applications where the adhesivewill be exposed to moisture.5.4.2 Cycle II24hUVat606 3C with no condensation,for applications where moisture is not a factor.5.4.3 Other temperatures an
25、d time cycles are acceptable, aslong as they are reported in accordance with Section 7.NOTE 2Temperatures are black-panel temperatures measured in thepanel rack.5.5 Operate the apparatus in accordance with PracticesG151 and G154.5.6 Expose the specimens for 168 h or multiples thereof,unless a signif
26、icant change is observed in a shorter time.6. Method BXenon Arc6.1 ApparatusAny xenon arc apparatus in accordancewith Practices G151 and G155.6.2 Filter configuration in accordance with Practices G151and G155.6.3 Irradiance LevelSet the irradiance level to a levelselected by mutual agreement.6.4 Tim
27、e/Temperature CyclesProgram the unit for one ofthe following light/spray cycles:6.4.1 Cycle 140 min of light followed by 20 min of lightand specimen spray followed by 60 min of light followed by 60min of dark. During the light cycle operate at a 63 6 3Cblack-panel temperature and 50 6 5 % relative h
28、umidity.During the dark cycle operate at 38 6 2C black-paneltemperature and 95 6 5 % relative humidity.6.4.2 Cycle IIContinuous light without water at a black-panel temperature of 60 6 3C.6.5 Other filters, irradiance levels, relative humidities,temperatures, and time cycles are acceptable, as long
29、as theyare reported in accordance with Section 7.6.6 Operate the apparatus in accordance with PracticesG151 and G155.6.7 Expose the specimens for either (1) 168 h or multiplesthereof, unless a significant change is observed in a shortertime, or (2) a given amount of radiant exposure.7. Report7.1 Rep
30、ort the following information:7.1.1 Type and model of exposure apparatus and the manu-facturers designation.7.1.2 Type of light source and the manufacturers designa-tion. If a xenon-arc device is used, report the filter combinationand irradiance setting.7.1.3 Specimen temperature setting.7.1.4 Time
31、cycle.7.1.5 Relative humidity if controlled.7.1.6 Number of hours of exposure, or radiant exposure.7.1.7 Type of specimen and property evaluated for changedue to light effects.7.1.8 Type, thickness, and (optionally) UV transmissioncharacteristics of transparent adherend used. If UV transmis-sion is
32、reported, describe how it was measured.7.1.9 Mean and precision of property measured beforeexposure.7.1.10 Mean and precision of property measured afterexposure.7.2 Follow the section on Report contained in PracticesG151 and G154 or Practice G155, as appropriate.8. Precision and Bias8.1 It is not pr
33、acticable to specify the precision and bias ofthis practice because this practice limits itself to the relativedurability of different adhesives compared to each other.D904 99 (2013)29. Keywords9.1 adhesive; artificial light; ultraviolet lightASTM International takes no position respecting the valid
34、ity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subje
35、ct to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquart
36、ers. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard
37、 is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D904 99 (2013)3
