1、Designation: D2921 98 (Reapproved 2017)Standard Test Method forQualitative Tests for the Presence of Water Repellents andPreservatives in Wood Products1This standard is issued under the fixed designation D2921; the number immediately following the designation indicates the year oforiginal adoption o
2、r, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers simple qualitative field orlaboratory tests to determi
3、ne water repellency or the presenceof chlorinated phenol2preservative chemicals in wood prod-ucts that are specified to be water repellent preservative treated.1.2 The values stated in SI units are to be regarded asstandard. The values given in parentheses are for informationonly.1.3 This standard d
4、oes not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.1.4 This international standard wa
5、s developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Referenc
6、ed Documents2.1 U.S. Federal Specification:TT-W-572 Wood Preservative Water-Repellant32.2 NIST Standard:262-63 Water Repellent Preservative Non-Pressure Treat-ment for Mill Work43. Significance and Use3.1 Although chlorinated phenol-treated wood has becomeless common due to environmental concerns, r
7、epellent-treatedwood is commonly specified in construction. This test methodprovides a means to verify the presence of a significant level ofwater repellent protection.4. Apparatus4.1 Eyedropper, plastic squeeze bottle or similar means formetering drops of water.4.2 Flame Source, such as bunsen burn
8、er, butane torch, oralcohol burner.4.3 Copper Wire Coil Specimen Holder (or Other SuitableCopper Holder)A suitable copper wire coil can be made byusing a lead pencil as a mandrel to form a helix using copperwire of about 1.6 to 2.4 mm (116 to332 in.) in diameter. Leavea space of approximately the di
9、ameter of the wire between eachloop. The helix should be 19 to 25 mm (34 to 1 in.) in length.Leave a pigtail of about 152 mm (6 in.) of wire at one end ofthe helix and form a loop of approximately 25 mm (1 in.) indiameter to be used as a holder for the coil.4.4 Sharp Knife.5. Water Repellent Test5.1
10、 Place uncut wood items to be tested so that the end grainis exposed as a horizontal surface. If the end grain cannot be sopositioned, comparisons can be made on the flat grain but withless definitive results.5.2 With an eye dropper, or similar device, allow severaldrops of water to fall from about
11、13 mm (12 in.) on the endgrain of the wood. Wait 5 min and then observe the degree ofpenetration. With flat grain or vertical grain surfaces, waitingperiods of 10 to 15 min may be necessary.5.3 Water drops that immediately flatten out, penetrate anddarken the wood, indicate that the wood has not bee
12、n treatedwith a water repellent.5.4 Water drops that “bead-up” and remain as spheres, withlittle or no color change or penetration, indicate that the woodhas been treated with a water repellent. Water repellentpreservatives, meeting Fed. Spec. TT-W-572 and NBS Stan-dard 262-63, impart sufficient wat
13、er repellency to the end grainof wood to cause water drops to bead up and form spheres.6. Preservative Test6.1 Chlorinated phenol based wood preservatives emit acharacteristic green flame upon pyrolysis within a ventilated1This test method is under the jurisdiction of ASTM Committee D01 on Paintand
14、Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.52 on Factory Coated Wood Products.Current edition approved July 1, 2017. Published July 2017. Originally approvedin 1970. Last previous edition approved in 2011 as D2921 98 (2011). DOI:10.1520/D2921-98
15、R17.2Pentachlorophenol, tetrachlorophenol and other chlorinated phenols.3Available from DLA Document Services, Building 4/D, 700 Robbins Ave.,Philadelphia, PA 19111-5094, http:/quicksearch.dla.mil.4Available from National Institute of Standards and Technology (NIST), 100Bureau Dr., Stop 1070, Gaithe
16、rsburg, MD 20899-1070, http:/www.nist.gov.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision
17、 on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.1copper envelope due to the release of chlorine and its conse-quent reaction with copper (Beilsteins test). Untreated woodproduc
18、es a yellow-orange flame but any chlorine containingcompound will give a positive test.6.2 Using the copper wire specimen holder, described in4.3, hold the coil portion in the flame until it burns with acharacteristic yellow-orange color. This preheated coil is thenallowed to cool.6.3 With a knife,
19、cleaned by heating after each use, cut asplinter from the specimen of wood to be tested. Samplesshould be taken near the end of the wood items where end grainis exposed and where normal concentration of the preservativechemicals is greatest. The size of the wood sample should besmaller than the leng
20、th and inner diameter of the coil.6.4 With the copper coil held horizontally, place the splinterin the center of the coil. Put the copper coil with wood splinterin the flame and burn. If chlorinated phenols are present, thecharacteristic green flame is produced. Untreated wood pro-duces the yellow-o
21、range flame.7. Accuracy7.1 The tests are less accurate on flat grain and the heart-wood of some wood species, so that end grain and sapwoodshould be used whenever possible.7.2 Tests on both a known untreated sample and a treatedsample of the same wood species will provide comparisonstandards for the
22、 operator and will improve the accuracy of thetests.7.3 Test results are improved if tests are made with woodsamples taken from the center of a stack or from a protectedarea where the possibility of contamination is least. Untreateditems which come in physical contact with preservative treatedproduc
23、ts during handling and shipping may show slight evi-dence of the preservative chemical.7.4 More than one wood sample obtained from differentareas from the unknown piece should be tested.8. Precision and Bias8.1 PrecisionNo numerical statement of precision is pos-sible in this qualitative test method
24、. One hundred percentagreement was obtained in a round-robin test.8.2 BiasBias has not been determined.9. Keywords9.1 chlorinated phenols; water repellents; wood preserva-tives; wood productsASTM International takes no position respecting the validity of any patent rights asserted in connection with
25、 any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible techni
26、cal committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideratio
27、n at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harb
28、or Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 98 (2017)2
