1、Designation: D4067 16Standard Classification System and Basis for Specification forReinforced and Filled Poly(Phenylene Sulfide) (PPS)Injection Molding and Extrusion Materials Using ASTMMethods1This standard is issued under the fixed designation D4067; the number immediately following the designatio
2、n indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agenc
3、ies of the U.S. Department of Defense.1. Scope*1.1 This classification system covers reinforced and filledpoly(phenylene sulfide) materials suitable for injection mold-ing and extrusion.1.2 This classification system is not intended for the selec-tion of materials, but only as a means to call out pl
4、asticmaterials to be used for the manufacture of parts. The selectionof these materials shall be made by personnel with expertise inthe plastics field where the environment, inherent properties ofthe materials, performance of the parts, part design, manufac-turing process, and economics are consider
5、ed.1.3 The properties included in this classification system arethose required to identify the compositions covered. Ifnecessary, other requirements identifying particular character-istics important to specific applications shall be designated byusing the suffixes given in Section 5 or Classificatio
6、n SystemD4000.1.4 The values stated in SI units are to be regarded as thestandard.1.5 This precautionary statement pertains only to the testmethod portion of this classification system, Section 12. Thisstandard does not purport to address all of the safety concernsassociated with its use. It is the
7、responsibility of the user of thisstandard to establish appropriate safety and health practicesand determine the applicability of regulatory limitations priorto use.NOTE 1There is no known ISO equivalent to this standard.2. Referenced Documents2.1 ASTM Standards:2D256 Test Methods for Determining th
8、e Izod PendulumImpact Resistance of PlasticsD618 Practice for Conditioning Plastics for TestingD638 Test Method for Tensile Properties of PlasticsD648 Test Method for Deflection Temperature of PlasticsUnder Flexural Load in the Edgewise PositionD790 Test Methods for Flexural Properties of Unreinforc
9、edand Reinforced Plastics and Electrical Insulating Materi-alsD792 Test Methods for Density and Specific Gravity (Rela-tive Density) of Plastics by DisplacementD883 Terminology Relating to PlasticsD1238 Test Method for Melt Flow Rates of Thermoplasticsby Extrusion PlastometerD1600 Terminology forAbb
10、reviated Terms Relating to Plas-ticsD3418 Test Method for Transition Temperatures and En-thalpies of Fusion and Crystallization of Polymers byDifferential Scanning CalorimetryD3641 Practice for Injection Molding Test Specimens ofThermoplastic Molding and Extrusion MaterialsD3835 Test Method for Dete
11、rmination of Properties ofPolymeric Materials by Means of a Capillary RheometerD3892 Practice for Packaging/Packing of PlasticsD4000 Classification System for Specifying Plastic Materi-alsD5630 Test Method for Ash Content in PlasticsD5740 Guide for Writing Material Standards in the Classi-fication F
12、ormat1This classification system is under the jurisdiction ofASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterials.Current edition approved Sept. 1, 2016. Published September 2016. Originallyapproved in 1982. Last previous edition approved in
13、 2011 as D4067 11. DOI:10.1520/D4067-16.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes
14、 section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1D6358 Classification System and Basis for Specification forPoly (Phenylene Sulfide) (PPS) Injection Molding andExtrusion Materials Using ISO M
15、ethodsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE595 Test Method for Total Mass Loss and Collected Vola-tile Condensable Materials from Outgassing in a VacuumEnvironmentE662 Test Method for Specific Optical Density of SmokeGenerated by Solid Ma
16、terials2.2 Military Standards:3MIL-P-46174 (MR) Plastic Molding Material, Polyphe-nylene Sulfide, Glass Fiber ReinforcedMIL-M-24519 Molding Plastics, Electrical, Thermoplastic2.3 ISO Standard:4ISO 5272 PlasticsDetermination of Tensile PropertiesPart 2: Test Conditions for Moulding and ExtrusionPlast
17、ics3. Terminology3.1 Definitions:3.1.1 The definitions used in this classification system are inaccordance with Terminology D883 and Terminology D1600.4. Classification4.1 There is currently no group, class, or grade distinctionand no basic property table is given.NOTE 2Where no basic property table
18、 exists, the generic familydesignation will be followed by four zeros, for example: PPS 0000.4.1.1 Table A shall be used to specify the physical propertyrequirements that shall be shown by a six-character designa-tion. The designation shall consist of the letter A and the fivedigits comprising the c
19、ell numbers for the property require-ments in the order as they appear in Table A.4.1.1.1 The values listed are necessary to include the rangeof properties available in existing materials. However, thisdoes not imply that every possible combination of propertiesexists or can be obtained with the cur
20、rent state of technology.4.2 A single letter shall be used to indicate the majorcategory of the reinforcement, along with two numbers thatindicate the percentage of additive(s) by mass, with thetolerances as tabulated in Table 1:TABLE 1 Reinforcement-Filler Symbols and TolerancesCategory Material To
21、lerance (Based on thetotal mass)C Carbon and graphite fiber-reinforced 2 percentage pointsG Glass-reinforced #15 % glass content 2 percentage points15 % glass content 3 percentage pointsL Lubricants (such as PTFE, graphite,silicone, and molybdenum disulfide) orlubricants with fillers/reinforcementsD
22、epends upon the materialand processto bespecified.M Mineral-reinforced 2 percentage pointsR Reinforced-combination/mixtures ofreinforcements or other fillers/reinforcements.3 percentage points basedon the total reinforcement.NOTE 3This part of the system uses the type and percentage ofadditive to de
23、signate the modification of the basic material. To facilitatethis designation, the type and percentage of additive can be shown on thesuppliers technical data sheet unless it is proprietary in nature. Ifnecessary, additional requirements shall be indicated by the use of thesuffix part of the system,
24、 as given in Section 5. Special agreements ontolerances may be needed below 5 % levels.NOTE 4An example of this classification system for a poly(phenylenesulfide) material is as follows: The designation ASTM D4067PPS0000G40A42043 would indicate the following material requirementsfrom Table A:PPS0000
25、 = poly(phenylene sulfide) material,G40 = glass-reinforced at 40 % nominal level,A = Table A physical property requirements,4 = tensile strength, min 120 MPa,2 = flexural modulus, min 10 000 MPa,0 = Izod impact strength, unspecified,4 = flexural strength, min 165 MPa, and3 = density, min 1.60 g/cm3.
26、If no properties are specified, the designation would be ASTM D4067PPS0000G40A00000.5. Suffixes5.1 When additional requirements are needed that are notcovered by the basic requirements or cell table requirements,they shall be indicated through the use of suffixes. Electrical,flammability or other re
27、quirements shall be designated by theappropriate suffix from Table 3 of Classification SystemD4000.5.1.1 If applicable, heat deflection temperature shall bedesignated using the following suffix:Y = Heat deflection temperature as designated by the follow-ing digits:First Digit1 = Test Method D648, 18
28、20 kPaSecond Digit1 = minimum of 260C2 = other minimum temperature (C) - specifyNOTE 5Heat treating the test specimens at 260C for4hispermittedto achieve high heat deflection temperatures.6. Basic Requirements6.1 Basic requirements from Table A, as they apply, arealways in effect unless superseded b
29、y specific suffixrequirements, which always take precedence.3Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http:/dodssp.daps.dla.mil.4Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor
30、, New York, NY 10036, http:/www.ansi.org.D4067 162TABLE A Physical Property RequirementsDesignationOrderProperty/ASTM TestMethodUnits01234567891 Tensile strength, min D638AMPaBC60 80 110 120 130 160 180 200D2 Flexural modulus, min D790EMPaBC7 000 10 000 12 000 14 000 17 000 20 000 23 000 26 000D3 Iz
31、od impact strength, min D256FJ/mGC28 40 52 70 80 90 100 110D4 Flexural strength, min D790EMPaBC85 105 135 165 195 225 255 285D5 Density, min D792 g/cm3 C1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.10DAType I specimens, 3.18 mm thickness, crosshead speed of 5 mm/min.BMPa 145 = psi.CUnspecified.DSpecific val
32、ue (must be shown).ETangent modulus of elasticity. Test specimens are 3.18 by 12.7 mm and tested with a crosshead speed of 1.3 mm/min 50 % with a span to depth ratio of 16:1.FTest specimens are 3.18 mm thick with a notch radius of 0.25 mm and tested by Method A.GJm18.73103= ftlbf in.7. General Requi
33、rements7.1 The plastics composition shall be uniform and shallconform to the requirements specified herein. The color andform of the material shall be as agreed upon between thesupplier and the user.8. Detail Requirements8.1 Test specimens for the various materials shall conformto the requirements p
34、rescribed in Table A and suffix require-ments as they apply.8.2 For the purpose of determining conformance with thisclassification system, all specified limits in this classificationsystem are absolute limits, as defined in Practice E29.8.2.1 In the absolute method, an observed value or acalculated
35、value is not rounded off, but is to be compareddirectly to the specified limiting value. Conformance or non-conformance with the specification is based on this compari-son.9. Sampling9.1 Sampling shall be statistically adequate to satisfy therequirements of 13.4.9.2 A batch or lot is construed as a
36、unit of manufacture asprepared for shipment and can consist of a blend of two ormore “production runs.”PhaseLiquidCell thickness0.025 mmSamplePyrolyzatePrismNaClFIG. 1 Infrared Spectrum of Poly(phenylene sulfide) PyrolyzateD4067 16310. Specimen Preparation10.1 The test specimens shall be prepared by
37、 injectionmolding in accordance with Practice D3641. Processing con-ditions are:Drying 2 h at 135CPlastic melt temperature 305 - 335CMold temperature 140C minimumAverage injection velocity 200 100 mm/sPlastic Hold Pressure 600 bar minimum11. Conditioning11.1 ConditioningBefore performing the require
38、d tests,condition test specimens for a minimum of4hinthestandardlaboratory atmosphere of 23C and 50 % relative humiditywith standard tolerances as specified in Section 7 of PracticeD618.11.2 Test ConditionsConduct those tests influenced by theambient conditions in the standard laboratory atmosphere
39、of23C and 50 % relative humidity as defined in 3.1.2 of PracticeD618.12. Test Methods12.1 Determine the properties of the material according tothe test methods in 2.1, using the specimens and protocolsspecified in Table A and applicable Suffixes, as required.12.1.1 The number of tests shall be consi
40、stent with therequirements of Section 9 and paragraph 13.4.12.2 Reinforcement ConcentrationsTest Method D5630,using a temperature of 815C for inorganic fillers/reinforcements. Carbon fiber, graphite fiber, and other organicreinforcements require special methods that shall be agreedupon between the s
41、upplier and the user.13. Inspection and Certification13.1 Inspection and certification of the material suppliedwith reference to a specification based on this classificationsystem shall be for conformance to the requirements specifiedherein.13.2 Lot-acceptance inspection shall be the basis on whicha
42、cceptance or rejection of the lot is made. The lot-acceptanceinspection shall consist of apparent shear viscosity (TestMethod D3835) or flow rate (Test Method D1238, 315/5.0);reinforcement or filler content (Test Method D5630); and,tensile strength (Test Method D638, Type 1 bar or ISO 527-2,Type 1A
43、bar).13.3 Periodic check inspection with reference to a specifi-cation based upon this classification system shall consist of thetests for all requirements of the material under the specifica-tion. Inspection frequency shall be adequate to ensure thematerial is certifiable in accordance with 13.4.13
44、.4 Certification shall be that the material was manufac-tured by a process in statistical control; sampled, tested, andinspected in accordance with this classification system; andthat the average values for the lot meet the requirements of thespecification (line callout).13.5 A report of test result
45、s shall be furnished when re-quested. The report shall consist of results of the lot-acceptanceinspection for the shipment; the results of the most recentperiodic-check inspection; and the percent by weight of re-cycled plastic, as defined in 3.1.47 of Guide D 7209, ifrequested.14. Packaging and Mar
46、king14.1 Provisions of Practice D3892 apply for packaging,packing, and marking of containers for plastic materials. Otherpackaging or marking, or both, is acceptable when agreed uponby the purchaser and the supplier.15. Keywords15.1 plastic materials; poly(phenylene sulfide)SUPPLEMENTARY REQUIREMENT
47、SThe following supplementary items shall become part of this classification system when applicable,as agreed upon between the user and the supplier.S1. ApprovalMaterial submitted by a new supplier shallbe approved by the user. Material or test specimens submittedby the supplier and intended for eval
48、uation, shall be accompa-nied by the suppliers laboratory test report.S1.1 New SourcesThe user can elect to accept shipmenttemporarily on the suppliers certification.S2. Infrared Spectrophotometry or Thermal Analysis, orBothIf requested by the user, infrared or thermal analysis, orboth, shall be con
49、ducted on materials supplied to this classifi-cation system. The curves established for initial approval shallconstitute the reference standard and shall be kept on file at theusers laboratory. All samples shall produce curves that corre-spond to the reference standard when tested under the sameconditions as those specified on the master set of curves.S2.1 In the event such analyses are to be designated asrequired of the supplier, this must appear on the part drawingor purchase contract, or both, as agreed upon between user andsup
