1、Designation: D4814 16e1Standard Specification forAutomotive Spark-Ignition Engine Fuel1This standard is issued under the fixed designation D4814; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number i
2、n parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of Defense.1NOTEEq 3, Eq 4, Eq X1.6, and Eq X1.7 were corrected editorially in J
3、anuary 2017.1. Scope*1.1 This specification covers the establishment of require-ments of liquid automotive fuels for ground vehicles equippedwith spark-ignition engines.1.2 This specification describes various characteristics ofautomotive fuels for use over a wide range of operatingconditions. It pr
4、ovides for a variation of the volatility and watertolerance of automotive fuel in accordance with seasonalclimatic changes at the locality where the fuel is used. For theperiod May 1 through Sept. 15, the maximum vapor pressurelimits issued by the United States (U.S.) Environmental Pro-tection Agenc
5、y (EPA) are specified for each geographical areaexcept Alaska and Hawaii. Variation of the antiknock indexwith seasonal climatic changes and altitude is discussed inAppendix X1. This specification neither necessarily includesall types of fuels that are satisfactory for automotive vehicles,nor necess
6、arily excludes fuels that can perform unsatisfactorilyunder certain operating conditions or in certain equipment. Thesignificance of each of the properties of this specification isshown in Appendix X1.1.3 The spark-ignition engine fuels covered in this specifi-cation are gasoline and its blends with
7、 oxygenates, such asalcohols and ethers and where gasoline is the primary compo-nent by volume in the blend. The concentrations and types ofoxygenates are not specifically limited in this specification.The composition of both unleaded and leaded fuel is limited byeconomic, legal, and technical consi
8、deration, but theirproperties, including volatility, are defined by this specifica-tion. In many countries, regulatory authorities having jurisdic-tion have set laws and regulations that limit the concentrationof oxygenates and certain other compounds found in spark-ignition engine fuel. In the Unit
9、ed States, oxygenate types andconcentrations are limited to those approved under the U.S.Environmental Protection Agencys (EPA) substantially simi-lar rule (see X3.3.1), waivers, and partial waivers includingsome restrictions on vehicle and equipment use (see X3.3.2).With regard to fuel properties,
10、including volatility, this speci-fication can be more or less restrictive than the EPA rules,regulations, and waivers. Refer to Appendix X3 for discussionsof EPA rules relating to fuel volatility, lead and phosphorouscontents, sulfur content, benzene content, deposit controladditive certification, a
11、nd use of oxygenates in blends withunleaded gasoline. Contact the EPA for the latest versions ofthe rules and additional requirements.1.4 This specification does not address the emission char-acteristics of reformulated spark-ignition engine fuel. Refor-mulated spark-ignition engine fuel is required
12、 in some areas tolower emissions from automotive vehicles, and its character-istics are described in the research report on reformulatedspark-ignition engine fuel.2However, in addition to the legalrequirements found in this research report, reformulated spark-ignition engine fuel should meet the per
13、formance requirementsfound in this specification.1.5 This specification represents a description of automotivefuel as of the date of publication. The specification is undercontinuous review, which can result in revisions based onchanges in fuel, automotive requirements, or test methods, or acombinat
14、ion thereof. All users of this specification, therefore,should refer to the latest edition.NOTE 1If there is any doubt as to the latest edition of SpecificationD4814, contact ASTM International Headquarters.1.6 Tests applicable to gasoline are not necessarily appli-cable to its blends with oxygenate
15、s. Consequently, the type offuel under consideration must first be identified in order toselect applicable tests. Test Method D4815 provides a proce-dure for determining oxygenate concentration in mass percent.Test Method D4815 also includes procedures for calculatingmass oxygen content and oxygenat
16、e concentration in volumepercent. Appendix X4 provides a procedure for calculating the1This specification is under the jurisdiction of ASTM Committee D02 onPetroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility ofSubcommittee D02.A0.01 on Gasoline and Gasoline-Oxygenate Bl
17、ends.Current edition approved Nov. 15, 2016. Published December 2016. Originallyapproved in 1988. Last previous edition approved in 2016 as D4814 16d. DOI:10.1520/D4814-16EE01.2Supporting data have been filed at ASTM International Headquarters and maybe obtained by requesting MONO12, U.S. Reformulat
18、ed Spark-Ignition Engine Fueland the U.S. Renewable Fuels Standard.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance
19、 with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.1mass oxygen content of a fuel using m
20、easured oxygenate type,oxygenate concentration in volume percent, and measureddensity or relative density of the fuel.1.7 The following applies to all specified limits in thisstandard: For purposes of determining conformance with thesespecifications, an observed value or a calculated value shall ber
21、ounded “to the nearest unit” in the right-most significant digitused in expressing the specification limit, in accordance withthe rounding method of Practice E29. For a specification limitexpressed as an integer, a trailing zero is significant only if thedecimal point is specified. For a specified l
22、imit expressed as aninteger, and the right-most digit is non-zero, the right-mostdigit is significant without a decimal point being specified. Thisconvention applies to specified limits in Tables 1, 3, and X8.1,and it will not be observed in the remainder of this specifica-tion.1.8 The values stated
23、 in SI units are the standard, exceptwhen other units are specified by U.S. federal regulation.Values given in parentheses are provided for information only.NOTE 2Many of the values shown in Table 1 were originallydeveloped using U.S. customary units and were subsequently soft-converted to SI values
24、. As a result, conversion of the SI values willsometimes differ slightly from the U.S. customary values shown becauseof round-off. In some cases, U.S. federal regulations specify non-SI units.1.9 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It
25、 is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:3D86 Test Method for Distillation of Petroleum Products andLiquid Fuels at Atmosp
26、heric PressureD130 Test Method for Corrosiveness to Copper from Petro-leum Products by Copper Strip TestD287 Test Method for API Gravity of Crude Petroleum andPetroleum Products (Hydrometer Method)D381 Test Method for Gum Content in Fuels by Jet Evapo-rationD439 Specification for Automotive Gasoline
27、 (Withdrawn1990)4D525 Test Method for Oxidation Stability of Gasoline (In-duction Period Method)D1266 Test Method for Sulfur in Petroleum Products (LampMethod)D1298 Test Method for Density, Relative Density, or APIGravity of Crude Petroleum and Liquid Petroleum Prod-ucts by Hydrometer MethodD2622 Te
28、st Method for Sulfur in Petroleum Products byWavelength Dispersive X-ray Fluorescence SpectrometryD2699 Test Method for Research Octane Number of Spark-Ignition Engine Fuel3For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For An
29、nual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.4The last approved version of this historical standard is referenced onwww.astm.org.TABLE 1 Vapor Pressure and Distillation Class RequirementsAVapor Pressure/Distillation ClassASTM Test Met
30、hodAA A B C D EVapor Pressure,Bat 37.8 C (100 F) max, kPa (psi) 54 (7.8) 62 (9.0) 69 (10.0) 79 (11.5) 93 (13.5) 103 (15.0) D4953, D5191,D5482,orD6378Distillation Temperatures, C (F), at % EvaporatedCD8610 volume %, max 70. (158) 70. (158) 65 (149) 60. (140.) 55 (131) 50. (122)50 volume %minD77 (170.
31、) 77 (170.) 77 (170.) 77 (170.) 77 (170.)E77 (170.)Emax 121 (250.) 121 (250.) 118 (245) 116 (240.) 113 (235) 110. (230.)90 volume %, max 190. (374) 190. (374) 190. (374) 185 (365) 185 (365) 185 (365)End Point, max 225 (437) 225 (437) 225 (437) 225 (437) 225 (437) 225 (437)Distillation Residue, volum
32、e %, max 2 2 2 2 2 2 D86Driveability Index,Fmax, C (F) 597 (1250.) 597 (1250.) 591 (1240.) 586 (1230.) 580. (1220.) 569 (1200.) DerivedG,HASee 1.7 for determining conformance with specification limits in this table. When using this table to determine the conformance of gasoline volatility, the reade
33、r is advisedto review other applicable national, state, provincial, or local requirements. (For example, in the U.S. these may include the EPA Substantially Similar rule, California AirResources Board (CARB), Clean Burning Gasoline (CBG), other state or local and pipeline specifications). See Append
34、ix X3 for a summary of applicable U.S. EPAregulations for spark-ignition engine fuels.BConsult EPA for approved test methods for compliance with EPA vapor pressure regulations.CAt 101.3 kPa pressure (760 mm Hg).DGasolines that may be blended with 1 % to 15 % by volume ethanol or all other gasolines
35、whose disposition with ethanol blending is not known shall meet a minimum50 % evaporated distillation temperature of 77 C (170. F) prior to blending with ethanol. Gasoline-ethanol blends that contain 1 % to 15 % by volume ethanol shall meeta minimum 50 % evaporated distillation temperature of 66 C (
36、150. F) after blending.EGasolines known from the origin to retail that will not be blended with ethanol may meet a minimum 50 % evaporated distillation temperature of 66 C (150. F) for volatilityclasses D and E only. Gasolines meeting these limits are not suitable for blending with ethanol.FSee 5.2.
37、3 for Driveability Index equations for gasoline and gasoline-ethanol blends containing no more than 15 % by volume ethanol.GThe DI specification limits are applicable at the refinery or import facility as defined by 40 CFR Part 80.2 and are not subject to correction for precision of the test method.
38、HSince DI is an index and has no units, the standard temperature conversion from U.S. customary to SI units is not appropriate. The following equation is to be used tomake the conversion: DIC5sDIF2176d/1.8D4814 16e12D2700 Test Method for Motor Octane Number of Spark-Ignition Engine FuelD2885 Test Me
39、thod for Determination of Octane Number ofSpark-Ignition Engine Fuels by On-Line Direct Compari-son TechniqueD3120 Test Method for Trace Quantities of Sulfur in LightLiquid Petroleum Hydrocarbons by Oxidative Microcou-lometryD3231 Test Method for Phosphorus in GasolineD3237 Test Method for Lead in G
40、asoline byAtomicAbsorp-tion SpectroscopyD3341 Test Method for Lead in GasolineIodine Mono-chloride MethodD3831 Test Method for Manganese in Gasoline By AtomicAbsorption SpectroscopyD4052 Test Method for Density, Relative Density, and APIGravity of Liquids by Digital Density MeterD4057 Practice for M
41、anual Sampling of Petroleum andPetroleum ProductsD4175 Terminology Relating to Petroleum Products, LiquidFuels, and LubricantsD4176 Test Method for Free Water and Particulate Contami-nation in Distillate Fuels (Visual Inspection Procedures)D4177 Practice for Automatic Sampling of Petroleum andPetrol
42、eum ProductsD4306 Practice for Aviation Fuel Sample Containers forTests Affected by Trace ContaminationD4806 Specification for Denatured Fuel Ethanol for Blend-ing with Gasolines for Use as Automotive Spark-IgnitionEngine FuelD4815 Test Method for Determination of MTBE, ETBE,TAME, DIPE, tertiary-Amy
43、l Alcohol and C1to C4Alco-hols in Gasoline by Gas ChromatographyD4953 Test Method for Vapor Pressure of Gasoline andGasoline-Oxygenate Blends (Dry Method)D5059 Test Methods for Lead in Gasoline by X-Ray Spec-troscopyD5188 Test Method for Vapor-Liquid Ratio TemperatureDetermination of Fuels (Evacuate
44、d Chamber and PistonBased Method)D5191 Test Method for Vapor Pressure of Petroleum Prod-ucts (Mini Method)D5453 Test Method for Determination of Total Sulfur inLight Hydrocarbons, Spark Ignition Engine Fuel, DieselEngine Fuel, and Engine Oil by Ultraviolet FluorescenceD5482 Test Method for Vapor Pre
45、ssure of Petroleum Prod-ucts (Mini MethodAtmospheric)D5500 Test Method for Vehicle Evaluation of UnleadedAutomotive Spark-Ignition Engine Fuel for Intake ValveDeposit FormationD5598 Test Method for Evaluating Unleaded AutomotiveSpark-Ignition Engine Fuel for Electronic Port Fuel Injec-tor FoulingD55
46、99 Test Method for Determination of Oxygenates inGasoline by Gas Chromatography and Oxygen SelectiveFlame Ionization DetectionD5842 Practice for Sampling and Handling of Fuels forVolatility MeasurementD5845 Test Method for Determination of MTBE, ETBE,TAME, DIPE, Methanol, Ethanol and tert-Butanol in
47、Gasoline by Infrared SpectroscopyD5854 Practice for Mixing and Handling of Liquid Samplesof Petroleum and Petroleum ProductsD6378 Test Method for Determination of Vapor Pressure(VPX) of Petroleum Products, Hydrocarbons, andHydrocarbon-Oxygenate Mixtures (Triple ExpansionMethod)D6469 Guide for Microb
48、ial Contamination in Fuels and FuelSystemsD6920 Test Method for Total Sulfur in Naphthas, Distillates,Reformulated Gasolines, Diesels, Biodiesels, and MotorFuels by Oxidative Combustion and Electrochemical De-tectionD7039 Test Method for Sulfur in Gasoline, Diesel Fuel, JetFuel, Kerosine, Biodiesel,
49、 Biodiesel Blends, andGasoline-Ethanol Blends by Monochromatic WavelengthDispersive X-ray Fluorescence SpectrometryD7220 Test Method for Sulfur in Automotive, Heating, andJet Fuels by Monochromatic Energy Dispersive X-rayFluorescence SpectrometryD7667 Test Method for Determination of Corrosiveness toSilver by Automotive Spark-Ignition Engine FuelThinSilver Strip MethodD7671 Test Method for Corrosiveness to Silver by Automo-tive SparkIgnition Engine FuelSilver Strip MethodD7757 Test Method for Silicon in Gasoline and RelatedProducts by Monochromatic Waveleng
