1、Designation: D5363 16Standard Specification forAnaerobic Single-Component Adhesives (AN)1This standard is issued under the fixed designation D5363; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number
2、 in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of Defense.1. Scope1.1 This specification covers single-component anaerobicadh
3、esives suitable for locking, sealing, and retaining threadedor cylindrical assemblies. The adhesives are cured to a solidstate when confined between closely fitting active metalsurfaces.1.2 This specification is intended to be a means of classify-ing anaerobic adhesives. It is not intended for engin
4、eeringdesign purposes.1.3 This specification is intended to replace Military Speci-fications MIL-S-22473, MIL-S-46163, and MIL-R-46082.1.4 The values stated in SI units are to be regarded as thestandard.1.5 The following safety hazards caveat pertains only to thetest methods portion, Section 7, of t
5、his specification. Thisstandard does not purport to address all of the safety concerns,if any, associated with its use. It is the responsibility of the userof this standard to establish appropriate safety and healthpractices and determine the applicability of regulatory limita-tions prior to use.2.
6、Referenced Documents2.1 ASTM Standards:2A109/A109M Specification for Steel, Strip, Carbon (0.25Maximum Percent), Cold-RolledB36/B36M Specification for Brass Plate, Sheet, Strip, AndRolled BarB209 Specification for Aluminum and Aluminum-AlloySheet and PlateB633 Specification for Electrodeposited Coat
7、ings of Zinc onIron and SteelD56 Test Method for Flash Point by Tag Closed Cup TesterD439 Specification for Automotive Gasoline (Withdrawn1990)3D445 Test Method for Kinematic Viscosity of Transparentand Opaque Liquids (and Calculation of Dynamic Viscos-ity)D770 Specification for Isopropyl AlcoholD90
8、7 Terminology of AdhesivesD1084 Test Methods for Viscosity of AdhesivesD1193 Specification for Reagent WaterD2693 Specification for Ethylene GlycolD3951 Practice for Commercial PackagingD4562 Test Method for Shear Strength of Adhesives UsingPin-and-Collar SpecimenD4800 Guide for Classifying and Spec
9、ifying AdhesivesD5648 Test Method for Torque-Tension Relationship ofAdhesives Used on Threaded Fasteners (Lubricity)D5649 Test Method for Torque Strength of Adhesives Usedon Threaded FastenersD5657 Test Method for Fluid TightnessAbility ofAdhesivesUsed on Threaded FastenersE122 Practice for Calculat
10、ing Sample Size to Estimate, WithSpecified Precision, the Average for a Characteristic of aLot or Process2.2 Military Standards:MIL-STD-105 Sampling Procedures and Tables for Inspec-tion by Attributes4MIL-STD-129 Marking for Shipment and Storage4MIL-STD-810 Environmental Test Methods and Engineer-in
11、g Guides4MIL-STD-118 Commercial Packaging of Supplies andEquipment42.3 Federal Standards:FED-STD-313 Material Safety Data Sheets, Preparation andSubmission of42.4 Federal Specifications:FF-N-836 Nut: Square, Hexagon, Cap, Slotted, Castle,Knurled, Welding and Single Ball Seat41This specification is u
12、nder the jurisdiction of ASTM Committee D14 onAdhesives and is the direct responsibility of Subcommittee D14.60 on AdhesiveMaterial Classification System.Current edition approved April 1, 2016. Published May 2016. Originallyapproved in 1993. Last previous edition approved in 2008 as D5363 03 (2008).
13、DOI: 10.1520/D5363-16.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this hist
14、orical standard is referenced onwww.astm.org.4Available from DLA Document Services, Building 4/D, 700 Robbins Ave.,Philadelphia, PA 19111-5094, http:/quicksearch.dla.mil.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1PPP-B-636 Box, S
15、hipping, Fiberboard4QQ-P-416 Plating, Cadmium, Electrodeposited42.5 Military Specifications:MIL-R-46082 Retaining Compounds, Single-Component,Anaerobic4MIL-S-22473 Sealing, Locking, Retaining Compounds;Single-Component4MIL-S-46163 Sealing, Lubricating, and Wicking Com-pounds: Thread-Locking, Anaerob
16、ic, Single-Component4MIL-T-5624 Turbine Fuel, Aviation, Grades JP-4 and JP-542.6 U.S. Department of Transportation (DOT):Code of Federal Regulations, Parts 100 to 199 Departmentof Transportation Rules and Regulations for the Transpor-tation of Explosives and Other Dangerous Articles52.7 Society of A
17、utomotive Engineers:SAE J311 Fluid for Passenger Care Type AutomaticTransmissions, Information Report6SAE J429 Mechanical and Material Requirements for Exter-nally Threaded Fasteners6SAE AMS 2629 Jet Reference Fuel63. Terminology3.1 Definitions:3.1.1 Some terms in this specification are defined in T
18、ermi-nology D907.3.1.2 active metal surface, nrelative to anaerobicadhesives, a metal surface that initiates the formation of freeradicals within anaerobic adhesives.3.1.3 anaerobic adhesive, nan adhesive that is kept in theuncured state by oxygen, as in air, and that cures in the absenceof oxygen w
19、hen exposed to metal ions, especially copper oriron.3.1.4 Newtonian behavior, nthe property of a liquid inwhich its viscosity is constant over a stated range of strainrates. (Compare non-Newtonian behavior.)3.1.5 non-Newtonian behavior, nthe property of a liquidin which its viscosity is not constant
20、 over a stated range ofstrain rates. (Compare Newtonian behavior.)3.1.6 thixotropy, nin a liquid, the property of thinningwhen subjected to strains greater than the yield strain and ofrethickening with time upon subsequent rest.3.1.6.1 DiscussionThe liquid must exhibit yield to bethixotropic. If the
21、 liquid is deformed more than the yield strain,the underlying elastic network is disrupted and its viscosity isreduced. The network reestablishes itself in time when at rest.3.2 Definitions of Terms Specific to This Standard:3.2.1 breakaway torque, nthe initial torque required tobreak the bond, meas
22、ured at the first movement between thenut and the bolt, when unscrewing an unseated assembly.3.2.2 prevailing torque, nthe torque measured at 180rotation of the nut.3.2.2.1 DiscussionPrevailing torque was originally de-fined in MIL-S-46163 and MIL-S-22473 as the average of thefour torques measured a
23、t 90, 180, 270, and 360 rotation of thenut. Studies have shown that the torque measured static at 180rotation of the nut is statistically equivalent to the average ofthe torque measured at the four14 turns. Since measuring thetorque at the one angle of rotation is more efficient, prevailingtorque is
24、 most often defined as the torque measured static at180 rotation of the nut. However, for purposes of thisspecification, the definition of prevailing torque as the averageof the four torques measured at 90, 180, 270, and 360 rotationof the nut is also acceptable.4. Classification4.1 Anaerobic adhesi
25、ves are classified into groups in accor-dance with their performance properties. These groups aresubdivided into classes and grades, as shown in Table 1.NOTE 1For example, the designation AN 0411 would indicate:AN = anaerobic adhesive (from Guide D4800),04 (Group) = retaining compound,1 (Class) = lo
26、w strength, and1 (Grade) = viscosity of 100500 mPa.5. Requirements5.1 General RequirementsGeneral requirements are prop-erties that are inherent in every lot of adhesive produced, butmay be tested in accordance with Table 1 at a frequency agreedon by the purchaser and the manufacturer in order to ve
27、rifyspecification conformance.5.1.1 Ultraviolet FluorescenceThe uncured adhesive shallfluoresce under ultraviolet illumination when tested in accor-dance with 7.1.5.1.2 Color and WorkmanshipThe color supplied shall bethe color for the given group, class, and grade, as specified inTable 1. The uncure
28、d adhesive shall be smooth and homoge-neous after shaking, free from lumps, caked material, andparticles of foreign matter when examined in accordance with7.2.5.1.3 Flash PointThe uncured adhesive shall have a flashpoint above 93C when tested in accordance with 7.3.5.1.4 Storage StabilityThe strengt
29、h shall conform to theproperties specified for the given class in Table 1. The viscosityshall increase no more than 50 % above the uppermost limit forthe given grade in Table 1 when tested in accordance with 7.12.5.1.5 ToxicityThe supplier shall furnish a Safety DataSheet (SDS) in accordance with FE
30、D-STD-313 so that the usercan evaluate the safety of the material for the proposed use.5.1.6 Solvent ResistanceThe average strength of eachadhesive, after solvent immersion testing in accordance with7.11, shall meet the requirements specified for the given classin Table 1.5.1.7 Hot StrengthThe avera
31、ge strength of each adhesive,after hot-strength testing in accordance with 7.8, shall meet therequirements specified for the given class in Table 1.5.1.8 Heat AgingThe average strength of each adhesive,after heat-aging testing in accordance with 7.9, shall meet therequirements specified for the give
32、n class in Table 1.5Available from U.S. Government Printing Office Superintendent of Documents,732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401, http:/www.access.gpo.gov.6Available from Society of Automotive Engineers (SAE), 400 CommonwealthDr., Warrendale, PA 15096-0001, http:/www.sae.o
33、rg.D5363 162TABLE1ANBasicPropertiesAnaerobicAdhesivesGroup1ProductsGroupDescriptionClassDescriptionGradeColor(5.1.2)StrengthatStandardConditions,PrevailingTorqueStrength(5.2.3.1),NmViscosity(5.2.1),mPasSolventResistance(5.1.6),PrevailingTorque,Nm,minHotStrength(5.1.7),PrevailingTorque,Nm,minHeatAgin
34、g(5.1.8),PrevailingTorque,Nm,minColdStrength(5.1.9),PrevailingTorque,Nm,minSpeedofCure(5.2.2),PrevailingTorque,Nm,min01Threadlockingandretainingadhesives;slowcuring;Newtonianflowproperties110green17.042.4102517.010.2A8.5A17.08.521red11.328.2102511.36.8A5.6A11.35.62orange11.328.2408011.36.8A5.6A11.35
35、.63red11.328.210025011.36.8B5.6A11.35.64red11.328.210001000011.36.8B5.6A11.35.6031yellow7.919.81002007.94.7B3.9A7.93.9041blue4.511.310254.52.7A2.3A4.52.32blue4.511.31002504.52.7B2.3A4.52.33blue4.511.31000100004.52.7A2.3A4.52.3051purple2.35.610252.31.3A1.1A2.31.12purple2.35.61002502.31.3B1.1A2.31.106
36、1brown1.12.810251.10.7A0.6A1.10.62brown1.12.81002501.10.7B0.6A1.10.63brown1.12.81000100001.10.7A0.6A1.10.6071yellow0.81.51002500.80.4A0.4A0.80.400other0D5363 163TABLE1ANGroups2and3Products(continued)GroupDescriptionClassDescriptionGradeColor(5.1.2)StrengthatStandardConditions,TorqueStrength(5.2.3.1)
37、,NmViscosity(5.2.1),mPasSolventResistance(5.1.6),Nm,minSteelHotStrength(5.1.7),Nm,minASteelSteelPlatedBreakPrevailBreakPrevailBreakPrevailBreakPrevail02Threadlockingadhesives; fastcuring;Newtonianflowproperties110red16.939.516.956.55.639.54.556.5600080008.48.48.48.4C21red16.939.516.956.54.539.54.556
38、.54006008.48.48.48.4A031blue11.322.65.617.03.422.62.322.61101505.62.85.62.8C04wicking1blue2.311.32.311.31.111.31.111.310301.11.11.11.1C05wicking1blue2.311.311.322.61.722.61.722.610301.15.61.15.6C06wicking1green2.316.917.056.51.111.38.556.510301.18.51.18.5A00other003Threadlockingadhesives; fastcuring
39、;thixotropicflowproperties;lubricating110purple3.411.31.111.31.111.30.611.3at2rpm$5000at20rpm80016001.70.51.70.5C21blue7.922.62.322.61.122.60.622.6at2rpm$5000at20rpm80016003.91.13.91.1B031red11.328.211.333.95.628.25.628.2at2rpm$5000at20rpm120024005.65.65.65.6A00other0D5363 164TABLE1ANGroups2and3Prod
40、ucts(continued)GroupDescriptionClassDescriptionGradeColor(5.1.2)HeatAging(5.1.8),Nm,minASteelColdStrength(5.1.9),Nm,minSteelSpeedofCure(5.2.2),Nm,minSteelBreakPrevailBreakPrevailBreakPrevail02Threadlockingadhesives; fastcuring;Newtonianflowproperties110red8.48.4C8.48.48.48.421red8.48.4A8.48.48.48.40
41、31blue5.62.8C5.62.85.62.804wicking1blue1.11.1C1.11.11.11.105wicking1blue1.15.6C1.15.61.15.606wicking1green1.18.5A1.18.51.18.500other003Threadlockingadhesives; fastcuring;thixotropicflowproperties;lubricating110purple1.70.5C1.70.51.70.521blue3.91.1B3.91.13.91.1031red5.65.6A5.65.65.65.600other0D5363 1
42、65TABLE1ANGroup4Products(continued)GroupDescriptionClassDescriptionGradeColor(5.1.2)StrengthatStandardConditions,ShearStrength(5.2.3.2),ASTMD4562MPa,minViscosity(5.2.1),mPasSolventResis-tance(5.1.6),MPa,minHotStrength(5.1.7),MPa,minHeatAging(5.1.8),MPa,minColdStrength(5.1.9),MPa,minSpeedofCure(5.2.2
43、),MPa,min04retainingadhesives11green13.810050010.36.9A10.3A13.82green13.840080010.310.3A12.4A13.8021green24.11500250010.36.9A10.3A17.200other000otherB,C0other0ATesttemperature=150C.BTesttemperature=93C.CTesttemperature=121C.D5363 1665.1.9 Cold StrengthThe average strength of eachadhesive, after cold
44、-strength testing in accordance with 7.10,shall meet the requirements specified for the given class inTable 1.5.1.10 LubricityGroup 03 products shall show lubricityon the thread flanks to within 610 % of an as-receivedphosphate and oil,38 in.-16 grade 5 bolt, when tested inaccordance with 7.14.5.1.1
45、1 Fluid TightnessGroups 01, 02, and 03 productsshall be capable of making leak-tight assemblies when tested inaccordance with 7.15.5.1.12 WickingThe average breakaway and prevailingtorque strength for Group 02, Class 4, 5, and 6 products, whentested in accordance with 7.16, shall meet the requiremen
46、tsspecified in Table 2.5.2 Detail RequirementsDetail requirements are proper-ties which are adjusted in each lot of adhesive produced toprovide different groups, classes, and grades, and are tested onevery lot in accordance with Table 1 to verify specificationconformance.5.2.1 ViscosityThe uncured a
47、dhesive shall have a viscos-ity within the range given in Table 1 for the grade specifiedwhen tested in accordance with 7.4.5.2.2 Speed of CureThe average strength of eachadhesive, when tested in accordance with 7.7, shall meet therequirements specified for the given class in Table 1.5.2.3 Strength
48、at Standard ConditionsStandard conditionsare 21 to 25C (69.8 to 77F) and 45 to 55 % relative humidity.5.2.3.1 Groups 01, 02, and 03 ProductsThe averagestrength of each adhesive, when tested in accordance with 7.5,shall meet the requirements specified for the given class inTable 1.5.2.3.2 Group 04 Pr
49、oductsThe minimum strength of eachadhesive, when tested in accordance with 7.6, shall meet therequirements specified for the given class in Table 1.6. Other Requirements6.1 SuffxesWhen requirements are needed that supersedeor supplement Table 1, they shall be specified through the useof suffixes.6.2 When using the callout for materials covered by thisspecification, the suffixes that are found in Annex A1 may beused for the specific req
