1、Designation: D7588 11 (Reapproved 2018)Standard Guide forFT-IR Fingerprinting of a Non-Aqueous Liquid Paint asSupplied in the Manufacturers Container1This standard is issued under the fixed designation D7588; the number immediately following the designation indicates the year oforiginal adoption or,
2、 in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This guide covers the FT-IR fingerprinting of a liquidpaint as supplied in the c
3、ontainer without the need to separatecomponents. Spectra collected using this technique have beenfound useful for paint manufacturers quality control, troubleshooting and to verify that the paint being used is the same asthe paint sample tested. This technique has been found usefulfor both single an
4、d multi-component coatings, the latter ofwhich, where each component is analyzed separately (forexample, amine cured epoxies and polyol/isocyanate ure-thanes).1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 This standard
5、 does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety, health, and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.4 This interna
6、tional standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Com
7、mittee.2. Referenced Documents2.1 ASTM Standards:2D2621 Test Method for Infrared Identification of VehicleSolids From Solvent-Reducible PaintsE131 Terminology Relating to Molecular SpectroscopyE168 Practices for General Techniques of Infrared Quanti-tative AnalysisE204 Practices for Identification o
8、f Material by InfraredAbsorption Spectroscopy, Using the ASTM Coded Bandand Chemical Classification Index (Withdrawn 2014)33. Terminology3.1 DefinitionsFor definitions of terms and symbols, referto terminology in Terminology E131.4. Summary of Guide4.1 Infrared spectra are collected using an FT-IR s
9、pectro-photometer fitted with an ATR crystal, multi or single bounce.Samples are taken directly from the paint container as suppliedby the manufacturer.5. Significance and Use5.1 The ability to collect an infrared spectrum of a liquidpaint as supplied in the container from the manufacturer is ofsign
10、ificant importance when performing qualification testing.Historically, fingerprinting a material for such purpose in-volved separating the components of the paint and collectingan infrared spectrum of one or more of these components(vehicle, pigments, solvent, etc.) with Test Method D2621being used
11、for the identification of the vehicle. This unfortu-nately provides information only on the portion of the liquidpaint analyzed whereas the technique shown in this practiceprovides a more complete picture of what is in the containerprovided. In addition, user expertise and time required tocollect a
12、spectrum is minimal versus traditional standards.6. Apparatus6.1 SpectrophotometerAn FT-IR spectrophotometer witha wavelength range of at least 600 to 4000 cm-1and aresolution no less than 4 cm-1.6.2 Multi or Single Bounce Horizontal Attenuated TotalReflectance (ATR) TroughFor many paint samples, a
13、45degree single bounce Fresnel-type ZnSe crystal has been foundto provide satisfactory results for most liquid paints. Paintsamples unsuitable for this setup will exhibit many 100 %absorptions not to be confused with the 100 % absorptions1This guide is under the jurisdiction of ASTM Committee D01 on
14、 Paint andRelated Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.21 on Chemical Analysis of Paints and Paint Materials.Current edition approved June 1, 2018. Published June 2018. Originallyapproved in 2011. Last previous edition approved in 2001 as D7588 11
15、. DOI:10.1520/D7588-11R18.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this
16、historical standard is referenced onwww.astm.org.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the D
17、ecision on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.1associated with the spectral cutoff of the instrument optics andcrystal material. It should be noted that ATR spectra ar
18、einfluenced by the depth of penetration of the infrared wave intothe sample which can be influenced by the type of crystalmaterial. Two spectra obtained using different crystal materialscan appear different. For finite comparison of like materials itis recommended that only spectra obtained with the
19、 samecrystal material be compared.7. Procedure7.1 Ensure that the contents of the container are homoge-neous.7.2 Collect a background infrared spectrum with the ATRtrough in place. It is recommended that a new background becollected before the analysis of each sample.7.3 Fill the trough with the sam
20、ple and then immediatelycollect an infrared spectrum from 600 to 4000 cm-1at aresolution of no less than 4 cm-1or as agreed upon betweeninterested parties. This step shall be completed within 1 minuteor noted otherwise and sufficient sample shall be used tominimize any effect due to solvent loss and
21、/or reaction withatmospheric components. Very small sample quantities, signifi-cantly less than 1 milliltre for example, may be prone to suchchanges depending on the volatility of any solvents present andreactivity to atmospheric components such as water and/orcarbon dioxide.7.4 Annotate sample infr
22、ared spectrum with all informationnecessary to reproduce the spectrum. This information shallinclude at a minimum:7.4.1 Sample identification including product color and IRcollection date,7.4.2 ATR crystal type and configuration, and7.4.3 Identification of any manipulation of the spectrumsuch as but
23、 not limited to baseline and ATR corrections.7.5 Compare spectrum to reference spectra as needed.8. Report8.1 Properly identify and label the spectrum collected.Identification should include sample name, batch number, dateand time, analyst and/or company name, ATR crystal material,ATR apparatus name
24、, spectral correction applied if any, andany other information necessary to duplicate the samplingand/or spectral collection. Example spectra are shown in Figs.1-59. Keywords9.1 infrared spectra; paint; solventFIG. 1 Liquid Epoxy Part AD7588 11 (2018)2FIG. 2 Liquid Epoxy Part BD7588 11 (2018)3FIG. 3
25、 Liquid AlkydD7588 11 (2018)4FIG. 4 Liquid Urethane Part AD7588 11 (2018)5ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity
26、of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments
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28、eceived a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies
29、) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 5 Liquid Urethane ConverterD7588 11 (2018)6
