1、Designation: F2931 17Standard Guide forAnalytical Testing of Substances of Very High Concern inMaterials and Products1This standard is issued under the fixed designation F2931; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the ye
2、ar of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This guide contains a list of potential test methods forthe analysis of Substances of Very High Concern (SVHC) a
3、sdesignated by ECHA, the European Chemicals Agency. Infor-mation on the test methods cited is publicly available and isdrawn from a variety of sources. The guide is intended to assistin the selection of test methods that are applicable for theSVHCs identified.1.2 The specific SVHCs covered within th
4、is guide arecompiled from the ECHACandidate List of Substances of VeryHigh Concern. This list is also referred to as the REACHCandidate List.1.3 This guide specifically addresses methods for the analy-sis of SVHCs in products. It is not intended to cover the manyand varied analysis challenges associ
5、ated in the manufacturingenvironment.1.4 Limitations:1.4.1 This guide is intended to provide a compilation ofavailable test methods for the SVHCs listed on the ECHACandidate list and is not intended to be exhaustive. The testmethods within this guide are not the only ones available forany specific s
6、ubstances and this guide does not recommend anyspecific test method.1.4.2 Test methods for specific substances at the detectionlimits required for REACH reporting are not always available.In some cases, it is necessary to deduce the quantity ofsubstance present through the analysis and quantificatio
7、n of itselements. Although this approach is routinely used somedegree of uncertainty exists in the final result due to thereduced specificity of the test method.1.4.3 Although this guide is intended to be updated on aperiodic basis to capture new developments in the field, thereis no assurance that
8、the information provided is the mostcurrent.1.5 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.6 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of
9、 the user of this standard to establish appro-priate safety, health and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accor-dance with internationally recognized principles on standard-ization establis
10、hed in the Decision on Principles for theDevelopment of International Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standards:2D1257 Specification for High-Gravity GlycerinD1385 Test Method for
11、 Hydrazine in WaterD1971 Practices for Digestion of Water Samples for Deter-mination of Metals by FlameAtomicAbsorption, GraphiteFurnace Atomic Absorption, Plasma EmissionSpectroscopy, or Plasma Mass SpectrometryD3335 Test Method for Low Concentrations of Lead,Cadmium, and Cobalt in Paint by Atomic
12、AbsorptionSpectroscopyD3545 Test Method for Alcohol Content and Purity ofAcetate Esters by Gas ChromatographyD4309 Practice for Sample Digestion Using Closed VesselMicrowave Heating Technique for the Determination ofTotal Metals in WaterD5831 Test Method for Screening Fuels in SoilsD7065 Test Method
13、 for Determination of Nonylphenol,Bisphenol A, p-tert-Octylphenol, Nonylphenol Monoeth-oxylate and Nonylphenol Diethoxylate in EnvironmentalWaters by Gas Chromatography Mass SpectrometryD7485 Test Method for Determination of Nonylphenol,1This guide is under the jurisdiction of ASTM Committee F40 on
14、DeclarableSubstances in Materials and is the direct responsibility of Subcommittee F40.02 onManagement Practices and Guides.Current edition approved Aug. 1, 2017. Published September 2017. Originallyapproved in 2011. Last previous edition approved in 2016 as F2931 161. DOI:10.1520/F2931-17.2For refe
15、renced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandardsvolume information, refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West
16、Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trad
17、e Organization Technical Barriers to Trade (TBT) Committee.1p-tert-Octylphenol, Nonylphenol Monoethoxylate andNonylphenol Diethoxylate in Environmental Waters byLiquid Chromatography/Tandem Mass SpectrometryD7823 Test Method for Determination of Low Level, Regu-lated Phthalates in Poly (Vinyl Chlori
18、de) Plastics byThermal DesorptionGas Chromatography/Mass Spec-trometryD7968 Test Method for Determination of PolyfluorinatedCompounds in Soil by Liquid Chromatography TandemMass Spectrometry (LC/MS/MS)E1621 Guide for Elemental Analysis by Wavelength Disper-sive X-Ray Fluorescence SpectrometryF2576 T
19、erminology Relating to Declarable Substances inMaterials2.2 European Commission:3Article 57 of the European Union Regulation #1907/20062.3 International Electrotechnical Commission TC111:4IEC 62321 Electrotechnical Products Determination ofLevels of Six Regulated Substances (Lead, Mercury,Cadmium, H
20、exavalent Chromium, PolybrominatedBiphenyls, Polybrominated Diphenyl Ethers)2.4 Joint Industry Guide (JIG):5JIG-101 Material Composition Declaration for Electrotech-nical Products. Ed 4.0, 20113. Terminology3.1 Definitions:3.1.1 Terms and definitions related to declarable substancesin materials may
21、be found in Terminology F2576.3.1.2 Terms and definitions in the guide not found inTerminology F2576 are found in a common dictionary or otherreference documents such as the ASTM Dictionary of Engi-neering Science usedinthemanufacturerofpyrotechnicproducts.BenzylbutylphthalatePhthalicacid,benzylbuty
22、lester85-68-7201-622-7C19H20O4PlasticizerinflooringmaterialsuchasPVCfoam.Otherusesareasaplasticizerintrafficcones,foodconveyorbelts,artificialleather,etc.Bis(2-ethylhexyl)phthalateDioctylphthalate117-81-7204-211-0C24H38O4CommonlyusedasaplaticizerinmanufacturingofarticlesmadeofPVC,resins,rubbers,pack
23、agingmaterials,somepaperproducts,andvariousmedicaldevices,includingthebloodbags.Itcanalsobefoundinsomehydraulicfluidsordielectricfluidsincapacitors.Itisoftenfoundincoatings,pigments,textiles,orusedasasolventinlightsticks.Bis(tributyltin)oxideDistannoxane, hexabutyl-56-35-9200-268-0C24H54OSn2Primaril
24、yusedasabiocideforboats,mildewproofingforleatherwork.CobaltdichlorideCobaltousChloride7646-79-9231-589-4CoCl2Thissubstancecanbeusedfor(1)humidityindicator,(2)absorbentofammoniagas,(3)gasmask,(4)productionforvitaminB12,(5)traceamountofnutrientfactorforfood,(6)traceamountofelementfornitric-acidpestici
25、des,(7)solventinpurifyingmagnesium.Additionally,itmaybeusedforpackaging.DiarsenicpentaoxideDiarsenicPentoxide1303-28-2215-116-9As2O5Thissubstancecanbeusedfor(1)colorants,(2)metalrefining,(3)specialglassproduction,and(4)antisepticagentforwood.DiarsenictrioxideArsenicTrioxide1327-53-3215-481-4As2O3Thi
26、ssubstancecanbeusedfor(1)decolorantsforglassesandenamel,(2)purifyingandoxidizingagentinproductionofspecialglassesandleadcrystal,(3)antisepticagentforwood,and(4)medicineforleukemia.Dibutylphthalate1,2-Benzenedicarboxylic aciddi-n-butylester84-74-2201-557-4C16H22O4Commonplasticizerusedinvariouspolymer
27、stokeepcrystalsfromforming.Itisalsousedinpaints,pigments,orprintinginksasanadhesiveagent.Itissolubleinvariousorganicsolvents.Thispropertyallowsittobeusedasfixativesinperfumesorasanectoparasiticide.HexabromocyclododecaneCyclododecane, hexabromo-isomers25637-99-4247-148-4C12H18Br6Usedasabrominatedflam
28、eretardantforpolystyrenematerials,forexample,HIPScasematerialandpackaging.LeadhydrogenarsenateLeadAcidArsenate7784-40-9232-064-2(AsO4H)PbInsecticideorpesticideSodiumdichromatedihydrateSodiumBichromate7789-12-0234-190-3Na2Cr2O7.2H2OUsedfor:(1)productionofotherchromiumcompounds,(2)productionofinorgani
29、cchromatepigments,(3)preservativesupplement,finishingofmetalplating,(4)productionofvitaminK.TriethylarsenateArsenicacidTriethylEster15606-95-8427-700-2(C2H5O)3AsOUsedforintegratedcircuitmanufacturingasanintermediateforn-typedopingofsemiconductors.2,4-Dinitrotoluene1-methyl-2,4-dinitrobenzene121-14-2
30、204-450-0C7H6N2O42,4-dinitrotolueneisusedintheproductionoftoluenediisocyanate,whichisusedforthemanufactureofflexiblepolyurethanefoams.Thesubstanceisalsousedasgelatinizing-plasticizingagentforthemanufactureofexplosivemixtures(forexample,forairbagsincars).AluminosilicateRefractoryCeramicFibresVITREOUS
31、142844-00-6Refractoryceramicfibresareusedforhigh-temperatureinsulation,almostexclusivelyinindustrialapplications(insulationofindustrialfurnacesandequipment,equipmentfortheautomotiveandaircraft/aerospaceindustry)andinfireprotection(buildingsandindustrialprocessequipment).AnthraceneoilAnthracenePhenan
32、threneCarbazole90640-80-5292-602-7C14H10C12H9NThesubstancesaremainlyusedinthemanufactureofothersubstancessuchasanthraceneandcarbonblack.Theymayalsobeusedasreducingagentsinblastfurnances,ascomponentsinbunkerfuel,forimpregnating,sealingandcorrosionprotection.F2931 174TABLE1ContinuedSubstanceNameSynony
33、mCASNumberEUNumberChemicalFormulaCommonUsesAnthraceneoil,anthracenepasteAnthracenePhenanthreneCarbazole90640-81-6292-603-2C14H10C12H9NThesubstancesaremainlyusedinthemanufactureofothersubstancessuchasanthraceneandcarbonblack.Theymayalsobeusedasreducingagentsinblastfurnances,ascomponentsinbunkerfuel,f
34、orimpregnating,sealingandcorrosionprotection.Anthraceneoil,anthracenepaste,anthracenefractionAnthracenePhenanthreneCarbazole91995-15-2295-275-9C14H10C12H9NThesubstancesaremainlyusedinthemanufactureofothersubstancessuchasanthraceneandcarbonblack.Theymayalsobeusedasreducingagentsinblastfurnances,ascom
35、ponentsinbunkerfuel,forimpregnating,sealingandcorrosionprotection.Anthraceneoil,anthracenepaste,distn.lightsAnthracenePhenanthreneCarbazole91995-17-4295-278-5C14H10C12H9NThesubstancesaremainlyusedinthemanufactureofothersubstancessuchasanthraceneandcarbonblack.Theymayalsobeusedasreducingagentsinblast
36、furnances,ascomponentsinbunkerfuel,forimpregnating,sealingandcorrosionprotection.Anthraceneoil,anthracene-lowAnthracenePhenanthreneCarbazole90640-82-7292-604-8C14H10C12H9NThesubstancesaremainlyusedinthemanufactureofothersubstancessuchasanthraceneandcarbonblack.Theymayalsobeusedasreducingagentsinblas
37、tfurnances,ascomponentsinbunkerfuel,forimpregnating,sealingandcorrosionprotection.DiisobutylphthalateBis(2-methylpropyl)benzene-1,2-dicarboxylate84-69-5201-553-2C16H22O4Diisobutylphthalateisusedasplasticiserfornitrocellulose,celluloseether,polyacrylateandpolyacetatedispersions,andasagellingaidincomb
38、inationwithotherplasticisers,whicharewidelyusedforplastics,lacquers,adhesives,explosivematerialandnailpolish.LeadchromateLead(2+)chromate7758-97-6231-846-0CrH2O4.PbLeadchromateisusedformanufacturingpigmentsanddyes,asapigmentorcoatingagentinindustrialandmaritimepaintproductsorforembalming/restoringof
39、artproducts.Furtherpotentialusesincludeasdetergentsandbleaches,photosensitivematerialsandforthemanufactureofpyrotechnicpowder.Leadchromatemolybdatesulphatered(C.I.PigmentRed104)Lead(2+)chromatelead(2+)sulfatelead(2+)molybdate12656-85-8235-759-9CrH2O4.PbH2O4S.PbPbMoO4Leadchromatemolybdatesulphatered(
40、C.I.PigmentRed104)isusedasacolouring,paintingandcoatingagentinsectorssuchastherubber,plasticandpaints,coatingsandvarnishesindustries.Applicationscomprisetheproductionofagriculturalequipment,vehiclesandaircraftaswellasroadandairstrippainting.Leadsulfochromateyellow(C.I.PigmentYellow34)Lead(2+)chromat
41、elead(2+)sulfate1344-37-2215-693-7CrH2O4.PbH2O4S.PbLeadsulfochromateyellow(C.I.PigmentYellow34)isusedasacolouring,paintingandcoatingagentinsectorssuchastherubber,plasticandpaints,coatingsandvarnishesindustries.Applicationscomprisetheproductionofagriculturalequipment,vehiclesandaircraftaswellasroadan
42、dairstrippainting.Thesubstanceisfurtherusedforcamouflageorammunitionmarkinginthedefencearea.Pitch,coaltar,hightemperatureanodepitch,binderpitch,claypigeonbinder,electrodepitch,hardpitch,impregnatingpitch,softpitch,vacuumpitch65996-93-2266-028-2notapplicablePitch,coaltar,hightemperatureismainlyusedin
43、theproductionofelectrodesforindustrialapplications.Smallervolumesarededicatedtospecificusessuchasheavydutycorrosionprotection,specialpurposepaving,manufactureofothersubstancesandtheproductionofclaytargets.Tris(2-chloroethyl)phosphate115-96-8204-118-5C6H12Cl3O4PTris(2-chloroethyl)phosphateismainlyuse
44、dasanadditiveplasticiserandviscosityregulatorwithflame-retardingpropertiesforacrylicresins,polyurethane,polyvinylchlorideandotherpolymers.Otherfieldsofapplicationareadhesives,coatings,flame-resistantpaintsandvarnishes.ThemainindustrialbranchestouseTCEParethefurniture,thetextileandthebuildingindustry
45、.ZirconiaAluminosilicateRefractoryCeramicFibresRefractoryceramicfibresareusedforhigh-temperatureinsulation,almostexclusivelyinindustrialapplications(insulationofindustrialfurnacesandequipment,equipmentfortheautomotiveandaircraft/aerospaceindustry)andinfireprotection(buildingsandindustrialprocessequi
46、pment).AcrylamideProp-2-enamide79-06-1201-173-7C3H5NOAcrylamideisalmostexclusivelyusedforthesynthesisofpolyacrylamides,whichareusedinvariousapplications,inparticularinwastewatertreatmentandpaperprocessing.Minorusesofacrylamidecomprisethepreparationofpolyacrylamidegelsforresearchpurposesandasgrouting
47、agentsincivilengineering.F2931 175TABLE1ContinuedSubstanceNameSynonymCASNumberEUNumberChemicalFormulaCommonUsesAmmoniumdichromateDiammoniumdichromate,Ammoniumbichromate,ammoniumchromate,chromicacidH2Cr2O7diammoniumsalt,diammoniumdichromate,dichromicaciddiammoniumsalt7789-09-5232-143-1Cr2H2O7.2H3NAmm
48、oniumdichromateismainlyusedasanoxidisingagent.Otherknownusesareinthemanufactureofphotosensitivescreensandasmordantinthemanufactureoftextiles.Minorusesseemtocomprisemetaltreatmentandlaboratoryanalyticalagent.Boricacid10043-35-3 11113-50-1233-139-2 234-343-4BH3O3Boricacidiswidelyusedonaccountofitscons
49、istency-influencing,flame-retarding,antisepticandpreservativeproperties.Itisacomponentofdetergentsandcleaners,adhesives,toys,industrialfluids,brakefluids,glass,ceramics,flameretardants,paints,disinfectants,cosmetics,foodadditives,fertilisers,insecticidesandotherproducts.Disodiumtetraborate,anhydrousDisodiumtetraboratedecahydrate,Disodiumtetraborateanhydrous,Disodiumtetraboratepentahydrate,boraxdecahydrate,boricacid,disodiumsalt,boraxpentahydrate1303-96-4 1330-43-4 12179-04-3215-540-4Na2B4O710H2ONa2B4O7Na2B4O75H2ODisodiumtetraborateandtetraborondisodiumheptaoxideformthesam
