1、| | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BRITISH STANDARD BS 6290-3:1999 Incorporat
2、ing Corrigendum No. 1 ICS 29.220.20 NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW Lead-acid stationary cells and batteries Part 3: Specification for the flat positive plate typeThis British Standard, having been prepared under the direction of the Electrotechnical Sector Com
3、mittee, was published under the authority of the Standards Committee and comes into effect on 15 October 1999 BSI 02-2000 First published, November 1986 Second edition, October 1999 The following BSI references relate to the work on this standard: Committee reference PEL/21 Draft for comment 96/2010
4、03 DC ISBN 0 580 33040 0 BS 6290-3:1999 Amendments issued since publication Amd. No. Date Comments 10838 Corrigendum No. 1 February 2000 Supersession details added to foreword Committees responsible for this British Standard The preparation of this British Standard was entrusted to Technical Committ
5、ee PEL/21, Secondary cells and batteries, upon which the following bodies were represented: British Industrial Truck Association British Telecommunications plc Electricity Association Electric Vehicle Association of Great Britain Lighting Industry Federation Ltd. Ministry of Defence Society of Briti
6、sh Battery Manufacturers Society of Motor Manufacturers and Traders Ltd. Co-opted membersBS 6290-3:1999 BSI 02-2000 i Contents Page Committees responsible Inside front cover Foreword ii 1 Scope 1 2 Normative references 1 3 Terms and definitions 1 4 Materials and components 2 5 Performance 2 6 Type t
7、ests 3 7 Identification marks 3 Annex A (informative) Applications 4 Annex B (informative) Electromagnetic compatibility 4 Annex C (informative) Operational recommendations 4 Annex D (informative) Recharge characteristics 5 Annex E (informative) Operating characteristics 7 Annex F (normative) Additi
8、onal capacity tests 7 Bibliography 8 Figure D.1 Typical recharge characteristics of flat-plate cells using constant-current charging following a discharge at the 3 h rate 5 Figure D.2 Typical recharge characteristics of flat-plate cells using limited-voltage charging following a discharge at the 3 h
9、 rate 6 Table F.1 Final voltages at discharge rates between 1 h and 10 h 7 Table F.2 Final voltages at discharge rates faster than 1 h 7ii BSI 02-2000 BS 6290-3:1999 Foreword This part of BS 6290 has been prepared by Technical Committee PEL/21. This British Standard is part 3 of a series of standard
10、s. It specifies requirements for flat-plate cells and batteries with pasted positive plates. It supersedes BS 6290-3:1986 which is withdrawn. BS 6290-1 has been withdrawn, having been superseded jointly by BS 6290-2:1999, BS 6290-3:1999, BS 6290-4:1997 and BS EN 60896-1:1992. BS 6290-2 specifies req
11、uirements for lead-acid high-performance Plante plate cells and batteries. BS 6290-4 specifies the criteria for classifying lead-acid valve-regulated cells and batteries. BS EN 60896-1 specifies general requirements for all free-venting types of stationary lead-acid cells and batteries. Guidance on
12、safety and health aspects of the handling, installation, usage and maintenance of lead-acid stationary cells and batteries is given in BS 6133. Annexes designated normative are part of the body of the standard. A British Standard does not purport to include all the necessary provisions of a contract
13、. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, pages i and ii, pages 1 to 8, an inside back cover
14、and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. BSI 02-2000 1 BS 6290-3:1999 1 Scope This part of BS 6290 specifies requirements for the materials and performance of stationary cells and batteries comprising either individual lead-ac
15、id cells or monobloc units of the flat-plate type. NOTE Information on applications is given in annex A. Annex B clarifies the position of these cells and batteries with respect to electromagnetic compatibility. 2 Normative references The following normative documents contain provisions which, throu
16、gh reference in this text, constitute provisions of this part of this British Standard. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. For undated references, the latest edition of the publication referred to applies. BS 6133:1995, Code of pr
17、actice for safe operation of lead-acid stationary batteries. BS 6334:1983, Methods of test for the determination of the flammability of solid electrical insulating materials when exposed to an igniting source. BS EN 60896-1, Stationary lead-acid batteries General requirements and methods of test Par
18、t 1: Vented types. 3 Terms and definitions For the purposes of this part of BS 6290, the terms and definitions given in BS 6133:1995, 1.3.2 apply, together with the following. 3.1 stationary cell cell that is installed on a fixed site and is not intended to be moved continually during its life 3.2 s
19、tationary battery two or more stationary cells electrically connected in series 3.3 lead-acid cell cell in which the electrolyte is dilute sulfuric acid, and which is fitted with plates in which the active materials are: a) positive electrode: lead dioxide; b) negative electrode: spongy lead 3.4 fre
20、e-venting enclosed cell cell that is fitted with a vent plug which allows free venting of electrolysis gas NOTE Provision is made for the addition of water and for measurement of the level and density of electrolyte. The cover is not intended to be readily removable. 3.5 flat-plate cell free-venting
21、 enclosed cell containing flat pasted positive and negative plates 3.6 container box in which plate groups and separators are assembled 3.7 group bar bar to which a plate or group of plates is attached 3.8 vent plug plug, provided with a gas vent or vents and baffled to arrest acid spray, that is fi
22、tted in the vent hole in the cover of an enclosed cell NOTE A vent plug normally also provides access for filling. 3.9 monobloc battery in which the cells are fitted in a multi-compartment container 3.10 float operation of a cell or battery in parallel with a load and a charging source at constant v
23、oltage 3.11 discharge taking out of a quantity of electricity from a cell by connecting it to an external circuit in such a way that the current flows through the cell in the reverse direction to that for charging NOTE The quantity of electricity taken out is usually measured in ampere hours. 3.12 c
24、apacity quantity of electricity that can be taken from a cell (or battery) at a particular rate of discharge, under specified conditions of voltage and temperature NOTE Capacity is usually measured in ampere hours. 3.13 rated capacity designation, by the manufacturer, of the capacity of a cell (or b
25、attery) under specified conditions of discharge2 BSI 02-2000 BS 6290-3:1999 4 Materials and components 4.1 Positive plates Positive plates shall be of the pasted, open-grid type. The grid shall be made of lead alloys giving low water loss characteristics. NOTE Suitable lead alloys include lead-calci
26、um or low-antimony lead with 3 % antimony. 4.2 Negative plates Negative plates shall be of the pasted, open-grid type. The grid shall be made of lead alloys as specified in 4.1. 4.3 Separators Separators shall be made of a microporous material in combination with a porous fibre mat. The fibre mat sh
27、all be in contact with the face of the positive plate. 4.4 Group bars Group bars shall be made of a lead alloy compatible with the grid material. For example, group bars of antimony-free lead shall be used with a grid of antimony-free lead alloy, and group bars of antimonial lead shall be used with
28、a grid of antimonial lead alloy. 4.5 Terminal pillars Terminal pillars shall be cast in lead alloy. The cast pillars shall have a smooth surface finish, free from porosity and other defects. They shall be compatible with the electrochemical conditions within the cell and shall be suitable for mechan
29、ical connections. If copper inserts are used, the covering of lead around the insert shall be at least 3.0 mm thick. The terminal pillars shall not carry any part of the weight of either plate group 4.6 Containers Containers shall be made of a plastics material, e.g. styrene acrylonitrile. 4.7 Cell
30、lids Cell lids shall be sealed to the container. Terminal pillars shall be sealed where they pass through the lid. NOTE The sealing should be designed to prevent corrosion of the pillar above the lid. Apart from the vent holes, the complete cell shall be sufficiently sealed to withstand an internal
31、pressure of 1 961 Pa (200 mmH 2 O). 4.8 Vent plugs Vent plugs shall allow no visible wetting of the cell lid when the cell is being overcharged at the 0.09C r3 rate at 208C ambient temperature, where C r3 is the rated capacity in amperes for a 3 h discharge time. 4.9 End springs or packing pieces En
32、d springs or packing pieces shall be provided to hold the plate groups in position. NOTE The end springs or packing pieces should be designed to hold the plate groups in position throughout the anticipated life of the cell. 5 Performance NOTE Operational recommendations relating to performance are g
33、iven in annex C. Information on recharge characteristics and operating characteristics is given in annexes D and E. 5.1 Capacity 5.1.1 The rated capacity shall be stated by the manufacturer in terms of a discharge time of 3 h, as detailed in BS EN 60896-1:1992, clause 6, i.e. C r3 . The fully charge
34、d electrolyte density that applies for the rated capacity shall be stated by the manufacturer. 5.1.2 When the actual capacity of a cell is measured as a laboratory type test in accordance with BS EN 60896-1:1992, clause 13, the cell shall achieve the rated value stated, C r3 , on the first discharge
35、. 5.1.3 When the actual capacity of a battery is measured as a site test in accordance with BS EN 60896-1:1992, clause 13, the battery shall achieve the rated value stated, C r3 , on the first discharge. No individual cell voltage shall be below 1.75 V after 2.5 h of discharge. NOTE The voltage of i
36、ndividual cells of a battery may fall below 1.80 V (subject to the requirement of 5.1.3). A cell whose voltage falls below 1.75 V after 2.5 h of discharge during site testing of a battery may be replaced and the test repeated. 5.1.4 If an additional test for capacity is required at a different disch
37、arge rate, the final voltages given in annex F shall apply. 5.2 Endurance When tested in accordance with BS EN 60896-1:1992, clause 15, the endurance, in charge/discharge cycles, shall be that stated by the manufacturer. 5.3 Constant-voltage float-charge operation When tested in accordance with BS E
38、N 60896-1:1992, clause 14, the cell, monobloc or battery shall meet the requirements specified in BS EN 60896-1:1992, 7.2. 5.4 Charge retention When tested in accordance with BS EN 60896-1:1992, clause 16, the charge retention shall be that stated by the manufacturer. 5.5 Short-circuit current and i
39、nternal resistance When tested in accordance with BS EN 60896-1:1992, clause 17, the short-circuit current and internal resistance shall be those stated by the manufacturer. BSI 02-2000 3 BS 6290-3:1999 5.6 Flammability of non-metallic parts When tested in accordance with method FV given in BS 6334:
40、1983, the flammability category in accordance with BS 6334:1983, 9.4 shall be that stated by the manufacturer. NOTE The principal non-metallic parts of a battery are the cell containers and lids. The flammability of the portion of the container in contact with electrolyte on its inner surface is red
41、uced considerably by the thermal capacity of the electrolyte. As a consequence, the parts of the containers above the electrolyte level, together with the lid and accessories, are those most vulnerable to fire damage. 6 Type tests NOTE Where individual cell voltages cannot be measured, e.g. in the c
42、ase of monobloc units, the cell voltage should be derived by dividing the voltage of the unit by the number of cells in the unit. Where a sample size is quoted in the test method, the value stated for cells applies to monobloc units. Type tests shall employ the test sequences recommended in BS EN 60
43、896-1:1992, clause 18. The accuracy of measuring instruments used in the tests shall conform to BS EN 60896-1:1992, clause 11. Cells and batteries shall be prepared for testing in accordance with BS EN 60896-1:1992, clause 12. 7 Identification marks Identification marks shall conform to BS EN 60896-
44、1:1992, as amended by Amendment No. 1, clause 19 to 22 (section six).BS 6290-3:1999 4 BSI 02-2000 Annexes Annex A (informative) Applications Electrical performance characteristics indicate that the pasted positive plate cell has a better energy density in ampere hours per cubic metre (Ah/m 3 ) than
45、the Plante cell at the 3 h rate of discharge. Whilst there is no reliable test to confirm the service endurance of the product, experience has shown that, under well maintained float-charge conditions, a product life of 10 years or more can be expected. However, product life depends upon plate desig
46、n, electrolyte density and operating parameters. The pasted positive plate cell used for stand-by purposes can be cycled, but its design is not appropriate to regular deep discharges. The pasted positive plate cell is particularly recommended for power systems where space for the battery is limited,
47、 and where a shorter service life, relative to the Plante cell, is acceptable. Typical applications are stand-by engine starting, uninterruptible power supplies and emergency lighting. NOTE When considering the size of a battery for a particular application, it should be recognized that service life
48、 is normally considered to have expired when the capacity falls to 0.8C r3 . The user should define the required level of performance at the end of service life and size the battery accordingly. Annex B (informative) Electromagnetic compatibility Rechargeable cells or batteries within the scope of t
49、his standard are not sensitive to normal electromagnetic disturbances, and therefore no immunity tests are required under the terms of Directive 89/336/EEC (EMC Directive) 1. Free-standing rechargeable cells or batteries electrically isolated from any associated electrical system are for all practical purposes electromagnetically inert, and therefore any requirement for conformity with Directive 89/336/EEC 1 in respect of electromagnetic emission is deemed to be satisfied. It should be noted that the electrical system in which rechargeable cells or batter