1、DRAFT FOR DEVELOPMENTDD CEN/TS 13130-18:2005Materials and articles in contact with foodstuffs Plastics substances subject to limitation Part 18: Determination of 1,2-dihydroxybenzene, 1,3-dihydroxybenzene, 1,4-dihydroxybenzene, 4,4-dihydroxybenzophenone and 4,4dihydroxybiphenyl in food simulantsICS
2、67.250g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58Licensed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy, (c) BSIDD CEN/TS
3、 13130-18:2005This Draft for Development was published under the authority of the Standards Policy and Strategy Committee on 31 May 2006 BSI 2006ISBN 0 580 46061 4National forewordThis Draft for Development is the official English language version of CEN/TS 13130-18:2005.This publication is not to b
4、e regarded as a British Standard.It is being issued in the Draft for Development series of publications and is of a provisional nature because the method was not evaluated using recognized ring trial procedures. As a consequence there is no reproducibility data for the method. It should be applied o
5、n this provisional basis, so that information and experience of its practical application may be obtained.Comments arising from the use of this Draft for Development are requested so that UK experience can be reported to the European organization responsible for its conversion to a European standard
6、. A review of this publication will be initiated 2 years after its publication by the European organization so that a decision can be taken on its status at the end of its 3-year life. Notification of the start of the review period will be made in an announcement in the appropriate issue of Update S
7、tandards.According to the replies received by the end of the review period, the responsible BSI Committee will decide whether to support the conversion into a European Standard, to extend the life of the Technical Specification or to withdraw it. Comments should be sent in writing to the Secretary o
8、f BSI Subcommittee CW/47/1, Migration from plastics, at 389 Chiswick High Road, London W4 4AL, giving the document reference and clause number and proposing, where possible, an appropriate revision of the text.A list of organizations represented on this subcommittee can be obtained on request to its
9、 secretary.Cross-referencesThe British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Ca
10、talogue or of British Standards Online.Summary of pagesThis document comprises a front cover, an inside front cover, the CEN/TS title page, pages 2 to 24, an inside back cover and a back cover.The BSI copyright notice displayed in this document indicates when the document was last issued.Amendments
11、issued since publicationAmd. No. Date CommentsLicensed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy, (c) BSITECHNICAL SPECIFICATIONSPCIFICATION TECHNIQUETECHNISCHE SPEZIFIKATIONCEN/TS 13130-18February 2005ICS 67.250English versionMaterials and articles in contact with foodstuf
12、fs - Plasticssubstances subject to limitation - Part 18: Determination of 1,2-dihydroxybenzene, 1,3-dihydroxybenzene, 1,4-dihydroxybenzene, 4,4-dihydroxybenzophenone and4,4dihydroxybiphenyl in food simulantsMatriaux et objets en contact avec les denresalimentaires - Substances dans les matires plast
13、iquessoumises des limitations - Partie 18 : Dtermination des1,2-dihydroxybenzne, 1,3-dihydroxybenzne, 1,4-dihydroxybenzne, 4,4-dihydroxybenzophnone et 4,4-dihydroxybiphnil dans les simulants dalimentsWerkstoffe und Gegenstnde in Kontakt mit Lebensmitteln- Substanzen in Kunststoffen, die Beschrnkunge
14、nunterliegen - Teil 18: Bestimmung von 1,2-Dihydroxybenzol, 1,3-Dihydroxybenzol, 1,4-Dihydroxybenzol, 4,4-Dihydroxy-benzophenon und 4,4-Dihydroxybiphenyl in PrflebensmittelnThis Technical Specification (CEN/TS) was approved by CEN on 16 December 2004 for provisional application.The period of validit
15、y of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit theircomments, particularly on the question whether the CEN/TS can be converted into a European Standard.CEN members are required to announce the existence of this CEN/TS in the same
16、way as for an EN and to make the CEN/TS availablepromptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS)until the final decision about the possible conversion of the CEN/TS into an EN is reached.CEN members are
17、the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdo
18、m.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2005 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. CEN/TS 13130-18:2005: ELicen
19、sed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy, (c) BSI2 Contents page Foreword .3 Introduction.5 1 Scope6 2 Normative references7 3 Method A Determination of 1,2-dihydroxybenzene, 1,3-dihydroxybenzene and/or 1,4-dihydroxybenzene in food simulants7 4 Method B Determination o
20、f 4,4-dihydroxybenzophenone and 4,4dihydroxybiphenyl in food simulants.16 Bibliography24 DD CEN/TS 13130-18:2005Licensed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy, (c) BSI3 Foreword This document (CEN/TS 13130-18:2005) has been prepared by Technical Committee CEN/TC 194 “Ut
21、ensils in contact with food”, the secretariat of which is held by BSI. This part of EN 13130 has been prepared within the Standards, Measurement and Testing project, MAT1-CT92-0006, “Development of Methods of Analysis for Monomers” and has been prepared by Subcommittee (SC 1) of TC 194 “Utensils in
22、contact with food“ as one of a series of test methods for plastics materials and articles in contact with foodstuffs. This standard is intended to support Directives 2002/72/EC 1, 89/109/EEC 2, 82/711/EEC 3 and its amendments 93/8/EEC 4 and 97/48/EC 5, and 85/572/EEC 6. At the time of preparation an
23、d publication of this part of EN 13130 the European Union legislation relating to plastics materials and articles intended to come into contact with foodstuffs is incomplete. Further Directives and amendments to existing Directives are expected which could change the legislative requirements which t
24、his standard supports. It is therefore strongly recommended that users of this standard refer to the latest relevant published Directive(s) before commencement of a test or tests described in this standard. This part of EN 13130 should be read in conjunction with EN 13130-1. Further parts of EN 1313
25、0, under the general title Materials and articles in contact with foodstuffs - Plastics substances subject to limitation, have been prepared, and others are in preparation, concerned with the determination of specific migration from plastics materials into foodstuffs and food simulants and the deter
26、mination of specific monomers and additives in plastics. The parts of EN 13130 are as follows. Part 1: Guide to test methods for the specific migration of substances from plastics to foods and food simulants and the determination of substances in plastics and the selection of conditions of exposure
27、to food simulants Part 2: Determination of terephthalic acid in food simulants Part 3: Determination of acrylonitrile in food and food simulants Part 4: Determination of 1,3-butadiene in plastics Part 5: Determination of vinylidene chloride in food simulants Part 6: Determination of vinylidene chlor
28、ide in plastics Part 7: Determination of monoethylene glycol and diethylene glycol in food simulants Part 8: Determination of isocyanates in plastics Part 9: Determination of acetic acid, vinyl ester in food simulants Part 10: Determination of acrylamide in food simulants Part 11: Determination of 1
29、1-aminoundecanoic acid in food simulants Part 12: Determination of 1,3-benzenedimethanamine in food simulants Part 13: Determination of 2,2-bis(4-hydroxyphenyl)propane (Bisphenol A) in food simulants DD CEN/TS 13130-18:2005Licensed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy,
30、 (c) BSI4 Part 14: Determination of 3,3-bis(3-methyl-4-hydroxyphenyl)-2-indoline in food simulants Part 15: Determination of 1,3-butadiene in food simulants Part 16: Determination of caprolactam and caprolactam salt in food simulants Part 17: Determination of carbonyl chloride in plastics Part 18: D
31、etermination of 1,2-dihydroxybenzene, 1,3-dihydroxybenzene, 1,4-dihydroxybenzene, 4,4-dihydroxybenzophenone and 4,4dihydroxybiphenyl in food simulants Part 19: Determination of dimethylaminoethanol in food simulants Part 20: Determination of epichlorohydrin in plastics Part 21: Determination of ethy
32、lenediamine and hexamethylenediamine in food simulants Part 22: Determination of ethylene oxide and propylene oxide in plastics Part 23: Determination of formaldehyde and hexamethylenetetramine in food simulants Part 24: Determination of maleic acid and maleic anhydride in food simulants Part 25: De
33、termination of 4-methyl-pentene in food simulants Part 26: Determination of 1-octene and tetrahydrofuran in food simulants Part 27: Determination of 2,4,6-triamino-1,3,5-triazine in food simulants Part 28: Determination of 1,1,1-trimethylolpropane in food simulants Parts 1 to 8 are European Standard
34、s. Parts 9 to 28 are Technical Specifications. WARNING All chemicals are hazardous to health to a greater or lesser extent. It is beyond the scope of this Technical Specification to give instructions for the safe handling of all chemicals, that meet, in full, the legal obligations in all countries i
35、n which this Technical Specification may be followed. Therefore, specific warnings are not given and users of this Technical Specification should ensure that they meet all the necessary safety requirements in their own country. According to the CEN/CENELEC Internal Regulations, the national standard
36、s organizations of the following countries are bound to announce this CEN Technical Specification: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portug
37、al, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. DD CEN/TS 13130-18:2005Licensed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy, (c) BSI5 Introduction 1,2-dihydroxybenzene (1,2-DHB), (pyro)catechol, C6H4(OH)4, PM/Ref. No 15880, 1,3-dihydroxybenzene (1,3-DHB
38、), resorcinol, C6H4(OH)2, PM/Ref. No 15910, 1,4-dihydroxybenzene (1,4-DHB), hydroquinone, C6H4(OH)2, PM/Ref-No. 15940, 4,4-dihydroxybenzophenone (DHBphen), HOC6H4COC6H4OH, PM/Ref. No 15970 and 4,4-dihydroxybiphenyl (DHBiph), HOC6H4C6H4OH, PM/Ref. No 16000, are monomers used in the manufacture of cer
39、tain plastics materials and articles intended to come into contact with foodstuffs. After manufacture, residual monomer(s) can remain in the polymer and may migrate into foodstuffs coming into contact with the plastics material or article. Method A describes the determination of 1,2-DHB, 1,3-DHB, 1,
40、4-DHB in food simulants. Method B describes the determination of DHBphen and DHBiph in food simulants. However, in cases where migration occurs, pay attention to the clear identification of the analyte, since under the conditions described in the method DHBphen and DHBiph have the same retention tim
41、e. NOTE The following should be taken into account when carrying out a migration test (see EN 13130-1). From migration experiments carried out for 10 d at 40 C it was recognized that 1,2-DHB, 1,3-DHB and 1,4-DHB are subject to losses due to chemical decomposition. The loss observed for 1,2-DHB was u
42、p to 20 % in aqueous simulants, that for 1,3-DHB was 5 % to 12 % in olive oil and that for 1,4-DHB was 14 % to 68 %, in both aqueous food simulants and olive oil. For DHBiph a small loss of 5 % to 12 % due to chemical decomposition was observed when using 15 % v/v aqueous ethanol as food simulant. T
43、he methods described have been pre-validated by collaborative trials with two laboratories. DD CEN/TS 13130-18:2005Licensed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy, (c) BSI6 1 Scope This document, part of EN 13130, specifies two methods as follows. Method A is an analytic
44、al procedure for the determination of the monomers 1,2-DHB, 1,3-DHB and 1,4-DHB in the food simulants water, 3 % w/v aqueous acetic acid, 15 % v/v aqueous ethanol and olive oil. The levels of monomer determined are expressed in milligrams of monomer per kilogram of food simulant. The method is appro
45、priate for the quantitative determination of 1,2-DHB and 1,3-DHB at a minimum level of 0,15 mg/kg in food simulants and, of 1,4-DHB at a minimum level of 0,10 mg/kg in food simulants. Method B is an analytical procedure for the determination of DHBphen and DHBiph in the food simulants water, 3 % w/v
46、 aqueous acetic acid, 15 % v/v aqueous ethanol and olive oil. The method is appropriate for the quantitative determination of DHBphen or DHBiph at minimum levels of 0,2 mg/kg and 0,25 mg/kg, respectively, in food simulants. NOTE The methods should also be applicable to other aqueous food simulants a
47、s well as to the other fatty food simulants e.g. sunflower oil, corn oil or a mixture of synthetic triglycerides. DD CEN/TS 13130-18:2005Licensed Copy: Wang Bin, na, Tue Aug 08 03:28:46 BST 2006, Uncontrolled Copy, (c) BSI7 2 Normative references The following referenced documents are indispensable
48、for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 13130-1:2004, Materials and articles in contact with foodstuffs Plastics substances subject to limi
49、tation Part 1: Guide to test methods for the specific migration of substances from plastics to foods and food simulants and the determination of substances in plastics and the selection of conditions of exposure to food simulants. 3 Method A Determination of 1,2-dihydroxybenzene, 1,3-dihydroxybenzene and/or 1,4-dihydroxybenzene in food simulants 3.1 Principle The aqueous simulant test samples are analyzed directly by high performance liquid chromatography (HPLC) with ultra violet (UV) detection. The olive oil test samples are extra
