1、BS EN 1076:2009ICS 13.040.30NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDWorkplace exposure Procedures formeasuring gasesand vapours usingpumped samplers Requirements and testmethodsLicensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Unco
2、ntrolled Copy, (c) BSIThis British Standardwas published under theauthority of the StandardsPolicy and StrategyCommittee on 31 March2010. BSI 2010ISBN 978 0 580 58633 0Amendments/corrigenda issued since publicationDate CommentsBS EN 1076:2009National forewordThis British Standard is the UK implement
3、ation of EN 1076:2009. Itsupersedes BS EN 1076:1997 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee EH/2/2, Work place atmospheres.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not
4、 purport to include all the necessary provisionsof a contract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunityfrom legal obligations.Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Uncontrolled Copy, (c) BSIBS EN 10
5、76:2009EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 1076 December 2009 ICS 13.040.30 Supersedes EN 1076:1997English Version Workplace exposure - Procedures for measuring gases and vapours using pumped samplers - Requirements and test methods Exposition sur les lieux de travail - Procdures po
6、ur le mesurage des gaz et vapeurs laide de dispositifs de prlvement par pompage - Exigences et mthodes dessaiExposition am Arbeitsplatz - Messung von Gasen und Dmpfen mit pumpenbetriebenen Probenahmeeinrichtungen - Anforderungen und Prfverfahren This European Standard was approved by CEN on 1 Novemb
7、er 2009. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obta
8、ined on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Manage
9、ment Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norw
10、ay, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2009 CEN All rights of exploitation in any form
11、and by any means reserved worldwide for CEN national Members. Ref. No. EN 1076:2009: ELicensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Uncontrolled Copy, (c) BSIBS EN 1076:2009EN 1076:2009 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative references 53 Terms a
12、nd definitions .54 Symbols and abbreviated terms 55 Types of samplers .76 Requirements .76.1 General 76.2 Sampler requirements .76.3 Measuring procedure requirements . 107 General test conditions 127.1 Reagents 127.2 Apparatus 127.3 Independent method 137.4 Generation of the calibration gas mixture
13、. 138 Test methods . 148.1 General . 148.2 Sampler test methods 148.3 Measuring procedure test methods 158.4 Uncertainty of measurement . 229 Test report . 23Annex A (informative) Examples for the determination of the breakthrough volume 24A.1 Direct method 24A.2 Chromatographic method 24Annex B (in
14、formative) Estimation of uncertainty of measurement . 26B.1 General . 26B.2 Uncertainty associated with sampled air volume . 26B.3 Uncertainty associated with sampling efficiency 28B.4 Uncertainty associated with sample storage and transportation 28B.5 Uncertainty associated with method recovery 28B
15、.6 Uncertainty associated with method variability 32B.7 Calculation of combined standard uncertainty . 35Annex C (informative) Example of estimation of expanded uncertainty 37Bibliography . 41Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Uncontrolled Copy, (c) BSIBS EN 107
16、6:2009EN 1076:2009 (E) 3 Foreword This document (EN 1076:2009) has been prepared by Technical Committee CEN/TC 137 “Assessment of workplace exposure to chemical and biological agents”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, e
17、ither by publication of an identical text or by endorsement, at the latest by June 2010, and conflicting national standards shall be withdrawn at the latest by June 2010. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or
18、CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 1076:1997. The major technical changes between this European Standard and the previous edition are as follows: a) adaptation of the framework for assessing the performance of procedures f
19、or measuring gases and vapours against the general requirements for the performance of procedures for measuring chemical agents in workplace atmospheres as specified in EN 482; b) revision of the calculation model for the uncertainty of measurement to comply with EN 482 and ENV 13005; c) modificatio
20、n of the classification scheme for sampler types; d) deletion of the informative annexes on the evaluation of pumped samplers by means of field tests. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this Europe
21、an Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United K
22、ingdom. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Uncontrolled Copy, (c) BSIBS EN 1076:2009EN 1076:2009 (E) 4 Introduction This European Standard provides a framework for assessing the performance of procedures for measuring gases and vapours against the general requir
23、ements for the performance of procedures for measuring chemical agents in workplace atmospheres as specified in EN 482. It enables manufacturers and users of pumped samplers and developers and users of procedures for measuring gases and vapours to adopt a consistent approach to method validation. Li
24、censed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Uncontrolled Copy, (c) BSIBS EN 1076:2009EN 1076:2009 (E) 5 1 Scope This European Standard specifies performance requirements and test methods under prescribed laboratory conditions for the evaluation of pumped samplers used in c
25、onjunction with an air sampling pump and of procedures using these samplers for the determination of gases and vapours in workplace atmospheres. This European Standard is applicable to pumped samplers and measuring procedures using these samplers in which sampling and analysis are carried out in sep
26、arate stages. This European Standard is not applicable to: pumped samplers which are used for the direct determination of concentrations, for example, length-of-stain detector tubes; samplers which rely on sorption into a liquid, and subsequent analysis of the solution (bubblers). 2 Normative refere
27、nces The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 482:2006, Workplace atmospheres General r
28、equirements for the performance of procedures for the measurement of chemical agents EN 838, Workplace atmospheres Diffusive samplers for the determination of gases and vapours Requirements and test methods EN 1232:1997, Workplace atmospheres Pumps for personal sampling of chemical agents Requiremen
29、ts and test methods EN 1540:1998, Workplace atmospheres Terminology EN ISO 8655-2, Piston-operated volumetric apparatus Part 2: Piston pipettes (ISO 8655-2:2002) EN ISO 8655-6, Piston-operated volumetric apparatus Part 6: Gravimetric methods for the determination of measurement error (ISO 8655-6:200
30、2) 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 482:2006 and EN 1540:19981)apply. 4 Symbols and abbreviated terms For the purposes of this document, the following symbols and abbreviations apply. NOTE See 8.4 and Annex B for symbols used in conjunc
31、tion with uncertainty of measurement only. CRM certified reference material 1) EN 1540:1998 is currently subject to revision. Until the revised EN is published the definitions given in EN 482:2006 take precedence. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Uncontrolled
32、Copy, (c) BSIBS EN 1076:2009EN 1076:2009 (E) 6 LV limit value ma1 mass of analyte desorbed from tube blank, in micrograms (g) ma2 mass of analyte desorbed from spiked tube, in micrograms (g) ma,lt maximum mass uptake of analyte in a leak test performed on a sealed sampler used for making measurement
33、s for comparison with a long-term limit value, in milligrams (mg) ma,st maximum mass uptake of analyte in a leak test performed on a sealed sampler used for making measurements for comparison with a short-term limit value, in milligrams (mg) 1m LV,lt is the long-term limit value of the substance giv
34、en as volume concentration, in milligrams per cubic metre (mg/m); 240 is the reference period, in minutes (min); 0,01 is the nominal minimum flow rate for type B samplers, in litres per minute (l/min); 10-3 is a factor applied to convert the nominal minimum flow rate from litres per minute (l/min) t
35、o cubic metres per minute (m/min); 1/3 is a factor applied to calculate the maximum permitted leakage. When tested in accordance with 8.2.2, for substances with a short-term limit value the maximum leakage, i.e. the maximum mass uptake of analyte above the blank value (see 6.3.2.3), shall be less th
36、an ma,stcalculated according to Equation (2), in milligrams (mg), as follows: )100,01155,0(313-sta,stLV,= m (2) where ma,st is the maximum mass uptake of analyte in a leak test performed on a sealed sampler used for making measurements for comparison with a short-term limit value; LV,st is the short
37、-term limit value of the substance given as volume concentration, in milligrams per cubic metre (mg/m); 15 is the reference period, in minutes (min); 0,01 is the nominal minimum flow rate for type B samplers, in litres per minute (l/min); Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/
38、2010 03:47, Uncontrolled Copy, (c) BSIBS EN 1076:2009EN 1076:2009 (E) 9 10-3is a factor applied to convert the nominal minimum flow rate from litres per minute (l/min) to cubic metres per minute (m/min); 1/3 is a factor applied to calculate the maximum permitted leakage. 6.2.3 Shelf life (for impreg
39、nated supports) The manufacturer shall specify the shelf life of the sampler when stored in its original package. During this period the sampler shall fulfil all requirements. 6.2.4 Sample identification (for commercially available sorbent tubes and impregnated filters) The sampler shall have a suit
40、able area for sample identification by the user. 6.2.5 Marking Samplers shall be marked with at least the following: manufacturers name; product identification; indication of the direction of air flow, if necessary; batch identification; shelf life (if applicable); number of this European Standard.
41、If required due to limited space, the marking may be placed on the packaging of the sampler. However, the manufacturers name, product identification and direction of air flow shall be indicated on the sampler. 6.2.6 Instructions for use The instructions for use supplied with the sampler shall be in
42、the language(s) of the country where the sampler is to placed on the market. They shall contain at least the following information: a) designated use (general purpose for a number of gases and vapours or, specific, for a particular gas or vapour, see 6.1); b) blank value (only when used for a partic
43、ular gas or vapour, see 6.1); c) directions for proper handling of the sampler, including opening and closing; d) general information on the principle of use, for example, sorbent type, reaction of the reagent impregnated solid, desorption method; e) information on storage and transport; f) informat
44、ion on health or environmental hazards and method of disposal. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 04/06/2010 03:47, Uncontrolled Copy, (c) BSIBS EN 1076:2009EN 1076:2009 (E) 10 6.3 Measuring procedure requirements 6.3.1 Sampling procedure requirements 6.3.1.1 General Sampling con
45、ditions (sample volume, flow rate and sampling time) shall be established according to the LV assigned to the compounds of interest, e.g. short-term limit value, long-term limit value or both. 6.3.1.2 Sample volume The recommended sample volume shall be less than two-third of the breakthrough volume
46、 measured in accordance with 8.3.1.3. 6.3.1.3 Air flow rate 6.3.1.3.1 Impregnated filters When tested according 8.3.1.4, the maximum air flow rate shall be 90 % of the flow rate at which the breakthrough volume drops by 5 %. 6.3.1.3.2 Thermal desorption samplers (Type B samplers) A minimum air flow
47、rate shall be established according to the test in 8.3.1.5. 6.3.1.4 Storage conditions after sampling The storage conditions after sampling shall be specified. When tested in accordance with 8.3.1.6, the mean value of the recovery after storage shall not differ by more than 10 % from the value befor
48、e storage. 6.3.2 Analytical procedure requirements 6.3.2.1 Analytical quantification limit The quantification limit shall be lower than or equal to the calculated mass of analyte that would be collected for the minimum air sample volume specified in the measuring procedure at the following concentra
49、tions: 0,1 LV for substances with long-term limit value; 0,5 LV for substances with short-term limit value only. 6.3.2.2 Analytical recovery When tested in accordance with 8.3.2.2, the analytical recovery Ranshall be: for Type A samplers: Ran 75 % with v 10 % at each loading; for Type B samplers: Ran 95 % with v 10 % at each loading. 6.3.2.3 Blank value When tested in accordance with
