1、BRITISH STANDARDBS EN 13096:2003Incorporating corrigendum no. 1Transportable gas cylinders Conditions for filling gases into receptacles Single component gasesThe European Standard EN 13096:2003 has the status of a British StandardICS 23.020.30g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g3
2、7g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN 13096:2003This British Standard was published under the authority of the Standards Policy and Strategy Committee on 24 February 2004 BSI 2007ISBN 0 58
3、0 43475 3National forewordThis British Standard was published by BSI. It is the UK implementation of EN 13096:2003, incorporating corrigendum May 2006. It partially supersedes BS 5355:1976.The UK participation in its preparation was entrusted by Technical Committee PVE/3, Gas containers, to Subcommi
4、ttee PVE/3/7, Gas cylinder (receptacle) operations.A list of organizations represented on this subcommittee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application.Complianc
5、e with a British Standard cannot confer immunity from legal obligations.Amendments issued since publicationAmd. No. Date Comments17034 Corrigendum No. 130 April 2007 Replacement of subclause 6.2.3EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 13096December 2003ICS 23.020.30English versionTranspor
6、table gas cylinders - Conditions for filling gases intoreceptacles - Single component gasesBouteilles gaz transportables - Conditions de remplissagedes rcipients - Gaz composant uniqueOrstbewegliche Gasflaschen - Bedingungen fr das Fllenvon Gasen in Gefe - Einzelne GaseThis European Standard was app
7、roved by CEN on 1 October 2003.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationals
8、tandards may be obtained on application to the Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to
9、the Management Centre has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece,Hungary, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Slovakia, Spain, Sweden,
10、Switzerland and UnitedKingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2003 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No.
11、EN 13096:2003 EIncorporating corrigendum May 2006 EN 13096:2003 (E)2ContentsPageForeword. 3Introduction 41 Scope . 52 Normative references . 53 Terms and definitions. 54 Principles and requirements for filling gas receptacles. 74.1 General requirements (all gases and gas receptacles) 74.2 For compre
12、ssed gases. 84.3 For low pressure liquefied gases 84.4 For high pressure liquefied gases 84.5 For dissolved gases . 94.6 In cases where the reference temperatures are to be deliberately exceeded 94.7 For gases not listed in Tables of this standard . 95 Fitting of pressure relief devices. 106 Gas Tab
13、les. 106.1 Key to Tables 1 to 3 106.2 Explanations for the Tables. 116.2.1 Minimum test pressure Ph (column 5) 116.2.2 Classification code (column 8a) 116.2.3 ADR special provisions (column 8b) 116.2.4 Substances and preparations directive classification (column 8c) 14Annex A (informative) Index of
14、gases 34Bibliography . 42EN 13096:2003 (E)3ForewordThis document (EN 13096:2003) has been prepared by Technical Committee CEN/TC 23 “Transportable gascylinders”, the secretariat of which is held by BSI.This European Standard shall be given the status of a national standard, either by publication of
15、an identicaltext or by endorsement, at the latest by June 2004, and conflicting national standards shall be withdrawn atthe latest by June 2004.This European Standard has been submitted for reference into the RID and/or the technical annexes of theADR. Therefore in this context the standards listed
16、in the normative references and covering basicrequirements of the RID/ADR not addressed within the present standard are normative only when thestandards themselves are referred to in the RID and/or the technical annexes of the ADR.Annex A is informative.According to the CEN/CENELEC Internal Regulati
17、ons, the national standards organizations of the followingcountries are bound to implement this European Standard: Austria, Belgium, Czech Republic, Denmark,Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands,Norway, Portugal, Slovakia, Spain, Sweden, S
18、witzerland and the United Kingdom.EN 13096:2003 (E)4IntroductionIt is recognised that higher filling degrees than those specified in this standard have been safely used formany years in certain northern European countries, where ambient temperatures are consistently lower thanmore southern parts of
19、Europe. In these cases, gas receptacles have been filled, transported and usedexclusively within the country concerned in accordance with local National Standards.EN 13096:2003 (E)51 ScopeThis European Standard specifies the general requirements (such as charging pressure, filling factor etc.) forfi
20、lling single gas receptacles, manifolded gas cylinders (bundles) tubes and drums with single componentgases.This standard excludes the specific requirements for filling acetylene cylinders, cryogenic gases are alsoexcluded.For the requirements for filling with gas mixtures EN 13099 should be consult
21、ed.This standard is primarily for industrial gases other than LPG but may also be applied for LPG. However fordedicated LPG cylinders, EN 1439, Transportable refillable welded steel cylinders for liquefied petroleum gas(LPG) Procedure for checking before, during and after filling prepared by CEN/TC
22、286 Liquefied petroleumgas equipment and accessories, should be consulted.2 Normative referencesThis European Standard incorporates by dated or undated reference, provisions from other publications.These normative references are cited at the appropriate places in the text and the publications are li
23、stedhereafter. For dated references, subsequent amendments to or revisions of any of these publications apply tothis European Standard only when incorporated in it by amendment or revision. For undated references thelatest edition of the publication referred to applies (including amendments).EN ISO
24、11114-1, Transportable gas cylinders Compatibility of cylinder and valve materials with gascontents Part 1: Metallic materials (ISO 11114-1:1997).3 Terms and definitionsFor the purposes of this European Standard, the following terms and definitions apply:3.1gassubstance, which:a) at 50 C has a vapou
25、r pressure greater than 300 kPa (3 bar); orb) is completely gaseous at 20 C at the standard pressure of 101,3 kPaNOTE Hydrogen fluoride and hydrogen cyanide are listed in Table 3 together with other liquids which may be filledinto gas receptacles.3.2single component gassubstance as defined in 3.1 wh
26、ich is technically pure in the gas receptacle. A single component gas dissolvedunder pressure falls within this categoryNOTE A single component gas may contain other components deriving from its production process or added topreserve the stability of the product provided that the level of these comp
27、onents does not change its classification or itsconditions of carriage, such as filling ratio, filling pressure or test pressure.EN 13096:2003 (E)63.3gas receptacles3.3.1cylinderstransportable pressure receptacles of a capacity not exceeding 150 litres3.3.2tubesseamless transportable pressure recept
28、acles of a capacity exceeding 150 litres and of not more than3 000 litres3.3.3pressure drumswelded transportable pressure receptacles of a capacity exceeding 150 litres and of not more than1 000 litres, (e.g. cylindrical receptacles equipped with rolling hoops, receptacles on skids and receptacleseq
29、uipped in frames)3.3.4bundles of cylinders (also known as frames)transportable assemblies of cylinders which are interconnected by a manifold and held firmly together3.4compressed gasesgases having a critical temperature less than or equal to - 50 C3.5liquefied gases3.5.1liquefied gasesgases having
30、a critical temperature above - 50 C3.5.2high pressure liquefied gasgas which has a critical temperature above - 50 C and equal to or below + 65 C3.5.3low pressure liquefied gasgas which has a critical temperature above + 65 C3.6dissolved gasgas which is dissolved under pressure in a liquid (solvent)
31、. The liquid (solvent) may be supported in a porousmass.3.7critical temperaturetemperature above which the substance cannot exist in the liquid state3.8filling degree (filling ratio)mass of gas in kg which can be filled into 1 litre of cylinder water capacity. Normally applied to liquefied gasesonly
32、NOTE The water capacity stamped on the cylinder may apply to the minimum designed water capacity withoutinternal fittings, in which case, the net water capacity should be ascertained.EN 13096:2003 (E)73.9filling degree reference temperature(s)temperature at which the liquid density is to be evaluate
33、d for calculating the filling degree (see 4.3 and 4.4.)3.10developed pressurepressure achieved by the contents of a gas cylinder filled according to the standard when raised to thereference temperature for developed pressureNOTE All pressures are given in bar gauge1)unless otherwise stated.3.11devel
34、oped pressure reference temperaturethat chosen to represent the expected maximum temperature in normal serviceNOTE All pressures are given in bar gauge unless otherwise stated.3.12settled pressure (P15)pressure of the content of the cylinder at + 15 CNOTE All pressures are given in bar gauge unless
35、otherwise stated.3.13test pressure (Ph)pressure at which the receptacle is hydraulically or pneumatically testedNOTE 1 The test pressure should not be exceeded under any foreseeable normal conditions (for example duringfilling).NOTE 2 All pressures are given in bar1)gauge unless otherwise stated.3.1
36、4pressure relief devicedevice which is fitted to the cylinder or cylinder valve and designed to relieve gas pressure in the event ofabnormal conditions resulting in the development of excessive pressure inside the receptacle3.15compatibilityterm relating to the interaction of gas and receptacles/cyl
37、inder equipment (parts in contact with gas) under theconditions of use. Hence the term compatible implies a satisfactory gas/cylinder/cylinder equipmentcombination.3.16tare weightsum of the masses of the receptacles and other fittings not removed during the receptacle filling operation,such as valve
38、, dip tube and any permanently or semi permanently fixed valve protection device4 Principles and requirements for filling gas receptacles4.1 General requirements (all gases and gas receptacles)The gas to be filled shall be compatible with the receptacles, the cylinder valve and any other fittings th
39、at maybe in contact with the gas (see EN ISO 11114-1).1)1 bar = 105Pa = 0,1 MPaEN 13096:2003 (E)8The receptacles when presented for filling shall be within the specified period for periodic inspection and test.The receptacles and cylinder valve shall be in a serviceable condition.The receptacles sha
40、ll be equipped with a suitable valve with the appropriate valve outlet.The receptacles shall be correctly identified for the intended gas.Filling degrees specified in this standard are maximum values and hence the filling mass charged into thereceptacle shall take account of the accuracy of the fill
41、ing procedure and weighing equipment. The tare weightof the receptacle shall be identified.4.2 For compressed gasesThe maximum settled pressure shall be the lower of the following values:a) two thirds of the test pressure; orb) the pressure, which, when the receptacle content is raised to the refere
42、nce temperature at 65 Cproduces a developed pressure that does not exceed the receptacle test pressure.4.3 For low pressure liquefied gasesThe maximum permissible mass of contents per litre capacity (filling factor) equals 0,95 times the density ofthe liquid phase at 50 C; in addition, the vapour ph
43、ase shall not disappear below 60 C. The test pressureshall be at least equal to the vapour pressure of the liquid at 65 C, minus 100 kPa (1 bar).For pure gases with sufficient data the maximum filling degree (FD) shall be determined as follows:()124,00032,0 dBPFD -where:FD = max. permissible filling
44、 degree (in kg/l)BP = boiling point (in Kelvin)dl= density of the liquid at boiling point (in kg/l)Data for low pressure liquefied gases are given in Table 1.4.4 For high pressure liquefied gasesThe maximum permissible mass of contents per litre capacity shall be such that the degree of filling shal
45、l besuch that the internal pressure at 65 C does not exceed the test pressure of the receptacles.For gases and gas mixtures with insufficient data, the maximum permissible filling degree (FD) shall bedetermined as follows:hgPdFD - 4105,8whereFD = max. permissible filling degree (in kg/l)dg= gas dens
46、ity (at 15 C, 1 bar) (in kg/m)EN 13096:2003 (E)9Ph= minimum test pressure (in bar)If the density of the gas is unknown, the maximum permissible filling degree shall be determined as follows:338103-RMMPFDhwhereFD = max. permissible filling degree (in kg/l)Ph = minimum test pressure (in bar)MM = molar
47、 mass (in g/mol)R = 8,31451 10 bar l mol-1K-1(gas constant)Data for high pressure liquefied gases are given in Table 1. Receptacles of other test pressures may be usedprovided the filling degrees are adjusted accordingly.4.5 For dissolved gasesIf receptacles are filled with gases dissolved under pre
48、ssure, the test pressure shall correspond to thatpressure resulting from a reference temperature of 65 C and prescribed concentration of the gas in thesolvent. For acetylene the minimum test pressure shall amount to 60 bar.4.6 In cases where the reference temperatures are to be deliberately exceeded
49、4.6.1 The maximum anticipated temperature shall be established. The suitability of the receptacles andvalve materials shall be checked for operation at the maximum anticipated temperature. In such cases thefilling degrees for high pressure and low pressure liquefied gases shall be appropriately calculated and shallbe lower than those given in this standard.4.6.2 For compressed gases, a filling pressure shall be chosen to ensure the developed pressure at themaximum anticipated temperature does not exceed the cylinder te
