1、BRITISH STANDARD BS EN 13121-1:2003 GRP tanks and vessels for use above ground Part 1: Raw materials Specification conditions and acceptance conditions The European Standard EN 13121-1:2003 has the status of a British Standard ICS 23.020.10 BS EN 13121-1:2003 This British Standard was published unde
2、r the authority of the Standards Policy and Strategy Committee on 30 May 2003 BSI 30 May 2003 ISBN 0 580 41954 1 National foreword This British Standard is the official English language version of EN 13121-1:2003. The UK participation in its preparation was entrusted by Technical Committee PRI/5, UK
3、 Steering Committee for CEN/TC210, to Subcommittee PRI/5/1, Glass reinforced tanks and vessels, which has the responsibility to: A list of organizations represented on this subcommittee can be obtained on request to its secretary. Cross-references The British Standards which implement international
4、or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to in
5、clude all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enq
6、uiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 21 and a back
7、 cover. The BSI copyright date displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date CommentsEUROPEANSTANDARD NORMEEUROPENNE EUROPISCHENORM EN131211 May2003 ICS23.020.10 Englishversion GRPtanksandvesselsforuseabovegroundPart1:Raw ma
8、terialsSpecificationconditionsandacceptanceconditions RservoirsetrcipientsenPRVpourapplicationshorssol Partie1:MatirespremiresConditionsdespcifications etconditionsdutilisation OberirdischeGFKTanksundBehlterTeil1: AusgangsmaterialienSpezifikationsund Annahmebedingungen ThisEuropeanStandardwasapprove
9、dbyCENon17March2003. CENmembersareboundtocomplywiththeCEN/CENELECInternalRegulationswhichstipulatetheconditionsforgivingthisEurope an Standardthestatusofanationalstandardwithoutanyalteration.Uptodatelistsandbibliographicalreferencesconcernings uchnational standardsmaybeobtainedonapplicationtotheMana
10、gementCentreortoanyCENmember. ThisEuropeanStandardexistsinthreeofficialversions(English,French,German).Aversioninanyotherlanguagemadebytra nslation undertheresponsibilityofaCENmemberintoitsownlanguageandnotifiedtotheManagementCentrehasthesamestatusasthe official versions. CENmembersarethenationalsta
11、ndardsbodiesofAustria,Belgium,CzechRepublic,Denmark,Finland,France,Germany,Greece, Hungary,Iceland,Ireland,Italy,Luxembourg,Malta,Netherlands,Norway,Portugal,Slovakia,Spain,Sweden,SwitzerlandandUn ited Kingdom. EUROPEANCOMMITTEEFORSTANDARDIZATION COMITEUROPENDENORMALISATION EUROPISCHESKOMITEEFRNORMU
12、NG ManagementCentre:ruedeStassart,36B1050Brussels 2003CEN Allrightsofexploitationinanyformandbyanymeansreserved worldwideforCENnationalMembers. Ref.No.EN131211:2003EEN131211:2003(E) 2 Contents page Foreword. 4 Introduction 5 1 Scope 5 2 Normativereferences . 5 3 Terms,definitions,symbolsandabbreviat
13、ions. 7 3.1 Termsanddefinitions. 7 3.2 Symbolsandabbreviations . 7 4 Thermosettingresins 8 4.1 General . 8 4.2 Unsaturatedpolyesterresins . 10 4.3 Vinylesterresins. . 10 4.4 Vinylesterurethaneresins . 10 4.5 Epoxyresins 10 4.6 Furaneresins. 10 4.7 Phenolicresins. . 10 4.8 Characterisationofthermoset
14、tingresinsintheuncuredstate . 10 4.9 Characterisationofthermosettingresinsinthecuredstate. .11 5 Curingagentsforunsaturatedpolyesterandvinylesterresins 11 5.1 General . 11 5.2 Initiators . 12 5.3 Accelerators,organometallic . 12 5.4 Promotors 12 5.5 Inhibitors 12 6 Reinforcingmaterials . 12 6.1 Gene
15、ral . 12 6.2 Surfacenonwovens . . 12 6.3 Choppedstrandmats . 13 6.4 Continuousstrandmats . 13 6.5 Wovenfabrics/Wovenrovingfabrics 13 6.6 Rovingsforwindingandforchoppingapplications. 13 7 Additives 13 7.1 General . 13 7.2 Thixotropicagents 13 7.3 Conductivefillers 14 7.4 Fireretardants . 14 7.5 Paraf
16、finwax . 14 7.6 Aggregatesandfillers 14 7.7 Ultravioletabsorbers . 14 7.8 Pigments 14 7.9 Surfaceactiveagents . 14 8 Thermoplasticliningmaterials 14 8.1 General . 14 8.2 Mechanicalandthermalproperties. 15 8.3 Weldingconsumables . . 17 8.4 Dimensionalstability . . 17 9 Materialconformancedocumentatio
17、n 17 9.1 General . 17 9.2 Unsaturatedpolyester,vinylesterandvinylesterurethaneresins 17 9.3 Epoxyresinsandhardeners 17 9.4 Furaneandphenolicresins . 18EN131211:2003(E) 3 9.5 Curingagentsandadditives. 18 9.6 Surfacenonwovens . 18 9.7 Choppedstrandmats . .18 9.8 Wovenfabrics/Wovenrovingfabrics .18 9.9
18、 Rovingsforwindingandforchoppingapplications. .18 9.10 Thermoplasticlinings 19 AnnexZA (informative) RelationshipbetweenthisEuropeanStandardandtheEssentialRequirements ofEUDirective97/23/EC. .20 Bibliography 21EN131211:2003(E) 4 Foreword Thisdocument(EN131211:2003)hasbeenpreparedbyTechnicalCommittee
19、CEN/TC210,“GRPtanksandves sels“,thesecretariatofwhichisheldbyDIN. This.EuropeanStandardshallbegiventhestatusofanationalstandard,eitherbypublicationofanidenticaltextor byendorsement,atthelatestbyNovember2003,andconflictingnationalstandardsshallbewithdrawnatthelatest byNovember2003. Thisdocumenthasbee
20、npreparedunderamandategiventoCENbytheEuropeanCommissionandtheEuropean FreeTradeAssociationandsupportsessentialrequirementsofEUdirective(s). ForrelationshipwithEUDirective(s),seeinformativeAnnexZA,whichisanintegralpartofthisdocument. AccordingtotheCEN/CENELECInternalRegulations,thenationalstandardsor
21、ganizationsofthefollowingcoun triesareboundtoimplementthisEuropeanStandard:Austria,Belgium,CzechRepublic,Denmark,Finland, France,Germany,Greece,Hungary,Iceland,Ireland,Italy,Luxembourg,Malta,Netherlands,Norway,Portugal, Slovakia,Spain,Sweden,SwitzerlandandtheUnitedKingdom.EN131211:2003(E) 5 Introduc
22、tion EN13121consistsofthefollowingpartsunderthegeneraltitle“GRPtanksandvesselsforuseaboveground“: Part1RawmaterialsSpecificationconditionsandacceptanceconditions Part2CompositematerialsChemicalresistance Part3Designandworkmanship Part4Delivery,installationandmaintenance ThesefourPartstogetherdefinet
23、heresponsibilitiesofthetankorvesselmanufacturers,thematerialsmanufactur ersorsuppliersandthepurchasers. ThedesignandmanufactureofGRPtanksandvesselsinvolveanumberofdifferentmaterialssuchasresins, plasticsandreinforcingfibresandanumberofdifferentmanufacturingmethods.Itisimplicitthattanksandvessels con
24、formingtothisEuropeanStandardshouldbemadeonlybymanufacturersandoperatorswhoarecompetent andsuitablyequippedtofulfilallrequirements,usingmaterialsmanufacturedbycompetentandexperiencedmate rialmanufacturers. Part1ofthisstandardspecifiestherequirementsforspecificationconditionsandacceptanceconditionsfo
25、rraw materialsresins,curingagents,thermoplasticlinings,reinforcingmaterialsandadditivesintermsofboth materialtechnicalpropertiesandthemanufacturingprocess.Theserequirementsarenecessaryinordertoestab lishthechemicalresistancepropertiesdeterminedinPart2andthemechanical,thermalanddesignproperties deter
26、minedinPart3.TogetherwiththeworkmanshipprinciplesdeterminedinPart3,specificationconditionsand acceptanceconditionsforrawmaterialsensurethatthetankorvesselwillbeabletomeetitsdesignrequirements, particularlyintermsofitschemical/thermalresistanceandpressureandloadsupportingrequirements.Part4of thisstan
27、dardspecifiesrequirementsfordelivery,handlingandinstallationandrecommendationsformaintenance ofGRPtanksandvessels. 1Scope ThisEuropeanStandardgivesrequirementsforspecificationandacceptanceconditionsofrawmaterialsforGRP tanksandvesselswithorwithoutliningforstorageorprocessingoffluids,factorymadeorsit
28、ebuilt,nonpressur isedorpressurised,foruseaboveground. 2 Normativereferences ThisEuropeanStandardincorporatesbydatedorundatedreference,provisionsfromotherpublications.These normativereferencesarecitedattheappropriateplacesinthetextandthepublicationsarelistedhereafter.For datedreferences,subsequentam
29、endmentstoorrevisionsofanyofthesepublicationsapplytothisEuropean Standardonlywhenincorporatedinitbyamendmentorrevision.Forundatedreferencesthelatesteditionofthe publicationreferredtoapplies(includingamendments). EN59, GlassreinforcedplasticsMeasurementofhardnessbymeansofaBarcolimpressor. EN10204:199
30、1, MetallicproductsTypesofinspectiondocuments. prEN131212:1999, GRPtanksandvesselsforuseabovegroundPart2:CompositematerialsChemical resistance. prEN131213:2001, GRPtanksandvesselsforuseabovegroundPart3:Designandworkmanship. EN29092, TextilesNonwovensDefinition. ENISO752, PlasticsDeterminationoftempe
31、ratureofdeflectionunderloadPart2:Plasticsandebonite (ISO752:1993). ENISO178, PlasticsDeterminationofflexuralproperties(ISO178:2001).EN131211:2003(E) 6 ENISO306, PlasticsThermoplasticmaterialsDeterminationofVicatsofteningtemperature(VST) (ISO306:1994). ENISO472:2001, PlasticsVocabulary(ISO472:1999).
32、ENISO527 2,PlasticsDeterminationoftensilepropertiesPart2:Testconditionsformouldingandextrusion plastics(ISO5272:1993includingCorr1:1994). ENISO868, PlasticsandeboniteDeterminationofindentationhardnessbymeansofadurometer(Shorehard ness)(ISO868:2003). ENISO1133 ,PlasticsDeterminationofthemeltmassflowr
33、ate(MFR)andthemeltvolumeflowrate(MVR)of thermoplastics(ISO1133:1997). ENISO11631:1999, PlasticsUnplasticizedpoly(vinylchloride)(PVCU)mouldingandextrusionmaterials Part1:Designationsystemandbasisforspecifications(ISO11631:1995). ENISO1675, PlasticsLiquidresinsDeterminationofdensitybythepyknometermeth
34、od(ISO1675:1985). ENISO1889 ReinforcementyarnsDeterminationoflineardensity(ISO1889:1997). ENISO2114:2000 ,Plastics(polyesterresins)andpaintsandvarnishes(binders)Determinationofpartialacid valueandtotalacidvalue(ISO2114:2000). ENISO2535:2002, PlasticsUnsaturatedpolyesterresinsMeasurementofgeltimeatam
35、bienttemperature (ISO2535:2001). ENISO2554, PlasticsUnsaturatedpolyesterresinsDeterminationofhydroxylvalue(ISO2554:1997). ENISO2555, PlasticsResinsintheliquidstateorasemulsionsordispersionsDeterminationofapparent viscositybytheBrookfieldTestmethod(ISO2555:1989). ENISO2592:2001, Determinationofflasha
36、ndfirepointsClevelandopencupmethod(ISO2592:2000). ENISO3001, PlasticsEpoxycompoundsDeterminationofepoxyequivalent(ISO3001:1999). ENISO3219, PlasticsPolymers/resinsintheliquidstateorasemulsionsordispersionsDeterminationof viscosityusingarotationalviscometerwithdefinedshearrate(ISO3219:1993). ENISO325
37、1:2003, Paints,varnishesandplasticsDeterminationofnonvolatilemattercontent(ISO3251:2003). ENISO3344, ReinforcementproductsDeterminationofmoisturecontent(ISO3344:1997). ENISO67212, PlasticsDeterminationofdynamicmechanicalpropertiesPart2:Torsionpendulummethod (ISO67212:1994,includingTechnicalCorrigend
38、um1:1995). ENISO90731, TextilesTestmethodsfornonwovensPart1:Determinationofmassperunitarea. ENISO90732, TextilesTestmethodsfornonwovensPart2:Determinationofthickness(ENISO9073 2:1995). ENISO90733, TextilesTestmethodsfornonwovensPart3:Determinationoftensilestrengthandelongation. ENISO9702, PlasticsAm
39、ineepoxidehardenersDeterminationofprimary,secondaryandtertiaryamine groupnitrogencontent(ISO9702:1996). ENISO9771, PlasticsPhenolicresinsDeterminationofthepseudoadiabatictemperatureriseofliquidresols whencuredunderacidconditions(ISO 9771:1995). ISO1183, PlasticsMethodsfordeterminingthedensityandrela
40、tivedensityofnoncellularplastics. ISO1887, TextileglassDeterminationofcombustiblemattercontent. ISO2113, ReinforcementfibresWovenfabricsBasisforaspecification. ISO2211, LiquidchemicalproductsMeasurementofcolourinHazenunits(platinumcobaltscale). ISO2559, TextileglassMats(madefromchoppedorcontinuousst
41、rands)Designationandbasisforspecifi cations. ISO2797, TextileglassRovingsBasisforaspecification. ISO3374, ReinforcementproductsMatsandfabricsDeterminationofmassperunitarea. ISO5661, PetroleumproductsHydrocarbonliquidsDeterminationofrefractiveindex.EN131211:2003(E) 7 ISO6271, ClearliquidsEstimationof
42、colourbytheplatinumcobaltscale. ISO113592, PlasticsThermomechanicalanalysis(TMA)Part2:Determinationofcoefficientoflinearthermal expansionandglasstransitiontemperature. 3 Terms,definitions,symbolsandabbreviations 3.1Termsanddefinitions ForthepurposesofthisEuropeanStandardthetermsanddefinitionsgivenin
43、prEN 13 1213:2001andEN ISO472:2001apply. 3.2Symbolsandabbreviations ForthepurposesofthisEuropeanStandard,thesymbolsandabbreviationsgiveninTable1apply. Table1Symbolsandabbreviations Symbol/abbreviation Unit Abbreviation HDT C Heatdeflectiontemperature MFR g/10min Meltflowrate T g C Glasstransitiontemperature e t % Elongationatbreakintension s f MPa Flexuralstrength s t MPa Tensilestrength ShD ShoreHardnessD r g/ml Density E t MPa Modulusofelasticityintension E f MPa ModulusofelasticityinflexureEN131211:2003(E) 8 4Thermosetting resins 4.1General TheresinsusedforGRPtanksorvesselsareliquid
