1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 13604:2013Copper and copper alloys Semiconductor devices,electronic and vacuum productsmade from high conductivitycopperBS EN 13604:2013 BRITISH STANDARDNational forewordTh
2、is British Standard is the UK implementation of EN 13604:2013. Itsupersedes BS EN 13604:2002 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee NFE/34, Copper and copper alloys.A list of organizations represented on this committee can beobtained on request
3、 to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2013. Published by BSI StandardsLimited 2013ISBN 978 0 580 74206 4ICS 29.050; 77.150.30Compliance with a Briti
4、sh Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 June 2013.Amendments issued since publicationDate Text affectedBS EN 13604:2013EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 136
5、04 June 2013 ICS 77.150.30 Supersedes EN 13604:2002English Version Copper and copper alloys - Semiconductor devices, electronic and vacuum products made from high conductivity copper Cuivre et alliages de cuivre - Produits en cuivre de haute conductivit pour application dans les tubes lectroniques,
6、semi-conducteurs et vide Kupfer und Kupferlegierungen - Produkte aus hochleitfhigem Kupfer fr Elektronenrhren, Halbleiterbauelemente und fr die Anwendung in der Vakuumtechnik This European Standard was approved by CEN on 25 April 2013. CEN members are bound to comply with the CEN/CENELEC Internal Re
7、gulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN me
8、mber. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
9、 CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Polan
10、d, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form a
11、nd by any means reserved worldwide for CEN national Members. Ref. No. EN 13604:2013: EBS EN 13604:2013EN 13604:2013 (E) 2 Contents Page Foreword 3 1 Scope 4 2 Normative references 4 3 Terms and definitions .5 4 Designations 5 4.1 Material .5 4.2 Symbol 5 4.3 Number .5 4.4 Material condition 5 4.5 Pr
12、oduct .6 5 Ordering information .7 6 Requirements .8 6.1 Composition .8 6.2 Mechanical properties .8 6.3 Electrical properties 8 6.4 Freedom from hydrogen embrittlement 8 6.5 Scale adhesion .9 6.6 Grain size 9 6.7 Tolerances of dimensions and form 9 6.8 Surface condition.9 7 Sampling 10 7.1 General
13、. 10 7.2 Analysis . 10 7.3 Mechanical, electrical and other tests 10 8 Test methods . 10 8.1 Analysis . 10 8.2 Tensile test 11 8.3 Hardness test 11 8.4 Bend test 11 8.5 Electrical test . 11 8.6 Hydrogen embrittlement test . 11 8.7 Scale adhesion test 11 8.8 Estimation of average grain size . 11 8.9
14、Retests . 12 8.10 Rounding of results 12 9 Declaration of conformity and inspection documentation . 12 9.1 Declaration of conformity 12 9.2 Inspection documentation . 12 10 Marking, packaging, labelling 12 Annex A (normative) Reference chart for microscopic examination at magnification 100 15 Annex
15、B (informative) Characteristics of coppers for electrical purposes 16 Bibliography . 18 Figures Figure A.1 Reference chart for microscopic examination at magnification 100 15 Tables Table 1 Composition of Cu-OFE and Cu-PHCE . 13 Table 2 Electrical properties (at 20 C) . 14 Table B.1 Particular chara
16、cteristics of coppers for electrical purposes 17 BS EN 13604:2013EN 13604:2013 (E) 3 Foreword This document (EN 13604:2013) has been prepared by Technical Committee CEN/TC 133 “Copper and copper alloys”, the secretariat of which is held by DIN. This European Standard shall be given the status of a n
17、ational standard, either by publication of an identical text or by endorsement, at the latest by December 2013, and conflicting national standards shall be withdrawn at the latest by December 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of
18、 patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 13604:2002. In comparison with EN 13604:2002, the following changes have been made: Normative references have been updated. Editorial modifications have been ma
19、de. Within its programme of work, Technical Committee CEN/TC 133 requested CEN/TC 133/WG 4 “Extruded and drawn products, forgings and scrap“ to prepare the revision of the following standard: EN 13604:2002, Copper and copper alloys Products of high conductivity copper for electronic tubes, semi-cond
20、uctor devices and vacuum applications. The two copper grades Cu-OFE (CW009A) and Cu-PHCE (CW022A) specified in this European Standard are those which are especially suitable for electronic, semiconductor and vacuum applications. Annex A (normative) is the reference for microscopic examination. Annex
21、 B (informative) gives guidance on the characteristics of coppers for electrical purposes. This is one of a series of European Standards for copper products for electrical purposes. Other copper products are specified as follows: EN 13599, Copper and copper alloys Copper plate, sheet and strip for e
22、lectrical purposes EN 13600, Copper and copper alloys Seamless copper tubes for electrical purposes EN 13601, Copper and copper alloys Copper rod, bar and wire for general electrical purposes EN 13602, Copper and copper alloys Drawn, round copper wire for the manufacture of electrical conductors EN
23、13605, Copper and copper alloys Copper profiles and profiled wire for electrical purposes According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Cze
24、ch Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdo
25、m. BS EN 13604:2013EN 13604:2013 (E) 4 1 Scope This European Standard specifies the composition, property requirements including electrical properties and tolerances on dimensions and form of semiconductor devices, electronic and vacuum products in two copper grates Cu-OFE (CW009A) and Cu-PHCE (CW02
26、2A), in the form of wrought products, e.g. plate, sheet, strip, seamless tube, rod, bar, wire, profiles. The sampling procedures, the methods of test for verification of conformity to the requirements of this European Standard, and the delivery conditions are also specified. This European Standard a
27、pplies to the wrought copper products as delivered to the device manufacturer, i.e. for further fabrication. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edit
28、ion cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1655, Copper and copper alloys Declarations of conformity EN 1976, Copper and copper alloys Cast unwrought copper products EN 10204, Metallic materials Types of inspection
29、documents EN 13599, Copper and copper alloys Copper plate, sheet and strip for electrical purposes EN 13600, Copper and copper alloys Seamless copper tubes for electrical purposes EN 13601, Copper and copper alloys Copper rod, bar and wire for general electrical purposes EN 13602, Copper and copper
30、alloys Drawn, round copper wire for the manufacture of electrical conductors EN 13605, Copper and copper alloys Copper profiles and profiled wire for electrical purposes EN ISO 2624, Copper and copper alloys Estimation of average grain size (ISO 2624) EN ISO 2626, Copper Hydrogen embrittlement test
31、(ISO 2626) EN ISO 6506-1, Metallic materials Brinell hardness test Part 1: Test method (ISO 6506-1) EN ISO 6507-1, Metallic materials Vickers hardness test Part 1: Test method (ISO 6507-1) EN ISO 6892-1, Metallic materials Tensile testing Part 1: Method of test at room temperature (ISO 6892-1) EN IS
32、O 7438, Metallic materials Bend test (ISO 7438) IEC 60468, Method of measurement of resistivity of metallic materials ISO 1811-2, Copper and copper alloys Selection and preparation of samples for chemical analysis Part 2: Sampling of wrought products and castings ISO 4746, Oxygen-free copper Scale a
33、dhesion test ISO 7801, Metallic materials Wire Reverse bend test BS EN 13604:2013EN 13604:2013 (E) 5 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 13599, EN 13600, EN 13601, EN 13602 and EN 13605 apply. 4 Designations 4.1 Material The material is de
34、signated either by symbol or by number (see Table 1). 4.2 Symbol The material symbol designation is based on the designation system given in ISO 1190-1. NOTE Although material symbol designations used in this standard might be the same as those in other standards using the designation system given i
35、n ISO 1190-1, the detailed composition requirements are not necessarily the same. 4.3 Number The material number designation is in accordance with the system given in EN 1412. 4.4 Material condition The material condition depends on the product and is fully described in the corresponding standards:
36、EN 13599 for plate, sheet and strip; EN 13600 for tube; EN 13601 for rod and bar; EN 13602 for wire; EN 13605 for profile and profiled wire. For the purposes of this standard, the following designations, which are in accordance with the system given in EN 1173, apply for the material condition: M Ma
37、terial condition for the product as manufactured without specified mechanical properties; D Material condition for the product as drawn without specified mechanical properties; H. Material condition designated by the minimum value of hardness requirement for the product with mandatory hardness requi
38、rements; R. Material condition designated by the minimum value of tensile strength requirement for the product with mandatory tensile strength requirement (and other tensile property requirements, dependent on product); A. Material condition designated by the minimum value of elongation requirement
39、for the product with manda-tory elongation requirements. Products in the H. condition may be specified to Vickers or Brinell hardness, dependent on the product. The material condition designation H. is the same for both hardness test methods. BS EN 13604:2013EN 13604:2013 (E) 6 Exact conversion betw
40、een the material conditions designated H. and R., or R. and A., dependent on the product, is not possible. Material condition is designated by only one of the above designations. 4.5 Product The product designation provides a standardised pattern of designation from which a rapid and unequivocal des
41、cription of a product can be conveyed in communication. It provides mutual comprehension at the international level with regard to products which meet the requirements of the relevant European Standard. The product designation is no substitute for the full content of the standard. The product design
42、ation for products to this standard shall consist of: denomination (Plate, Sheet, Strip, Tube, Rod, Bar, Wire, Profile or Profiled wire); number of this European Standard (EN 13604); material designation, either symbol or number (see Table 1); other information dependent on copper product for electr
43、ical purposes (see 6.2). The derivation of a product designation is shown in Example 1 and another typical product designation is shown in Example 2. EXAMPLE 1 Rod for electrical purposes conforming to this standard, in material designated either Cu-OFE or CW009A, in material condition R250, round,
44、nominal diameter 15 mm, tolerance Class A, will be designated as follows: Rod EN 13604 Cu-OFE R250 RND15A or Rod EN 13604 CW009A R250 RND15A Denomination Number of this European Standard Material designation Material condition designation Cross-sectional shape, nominal dimension in millimetres, tole
45、rance class BS EN 13604:2013EN 13604:2013 (E) 7 EXAMPLE 2 Strip for electrical purposes conforming to this standard, in material designated either Cu-PHCE or CW022A, in material condition R290, nominal thickness 2 mm, nominal width 1 000 mm, will be designated as follows: Strip EN 13604 Cu-PHCE R290
46、 2 x 1 000 or Strip EN 13604 CW022A R290 2 x 1 000 5 Ordering information In order to facilitate the enquiry, order and confirmation of order procedures between the purchaser and the supplier, the purchaser shall state on his enquiry and order the ordering information for the relevant copper product
47、 for electrical purposes from: plate, sheet and strip in EN 13599; seamless tubes in EN 13600; rod, bar and wire in EN 13601; drawn, round wire in EN 13602; profiles and profiled wire in EN 13605; except that the number of this European standard (EN 13604) shall be substituted, or if there is no cor
48、responding product standard, the details shall be agreed between the purchaser and the supplier. For material conditions other than annealed, the electrical properties shall be agreed between the purchaser and the supplier (see 6.3). In addition, the purchaser shall also state on the enquiry and ord
49、er any of the following, if required: a) dependent on product, test method to be used for the measurement of hardness, i.e. Vickers or Brinell (see 8.3); b) whether scale adhesion test is required for Cu-OFE (CW009A) (see 6.5); c) whether a grain size determination is required (see 6.6); d) whether special surface conditions are required (see 6.8); e) the inspection lot size if different from the sampling rate for mechanical and electrical tests
