1、BRITISH STANDARD BS EN ISO 1060-2:1999 Plastics Homopolymer and copolymer resins of vinyl chloride Part 2: Preparation of test samples and determination of properties The European Standard EN ISO 1060-2:1999 has the status of a British Standard ICS 83.080.20BSEN ISO 1060-2:1999 This British Standard
2、, having been prepared under the directionof the Sector Committeefor Materials and Chemicals, waspublished underthe authorityof the Standards Committee and comesinto effect on 15 August 1999 BSI 03-2000 ISBN 0 580 32844 9 National foreword This British Standard is the English language version of EN
3、ISO 1060-2:1999. It is identical with ISO 1060-2:1998. The UK participation in its preparation was entrusted to Technical Committee PRI/82, Thermoplastic Materials, which has the responsibility to: aid enquirers to understand the text; present to the responsible international/European committee any
4、enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references Att
5、ention is drawn to the fact that CEN and CENELEC Standards normally include an annex which lists normative references to international publications with their corresponding European publications. The British Standards which implement international or European publications referred to in this documen
6、t may be found in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of Brit
7、ish Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, pages i and ii, theENISOtitle page, page 2, the ISO title page, pa
8、ges ii to iv, pages 1 to 4 and a back cover. This standard has been updated (see copyright date) and may have had amendments incorporated. This will be indicated in the amendment table on the inside front cover. Amendments issued since publication Amd. No. Date CommentsBSEN ISO 1060-2:1999 BSI 03-20
9、00 i Contents Page National foreword Inside front cover Foreword 2 Foreword iii Text of ISO 1060-2 1ii blankEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 1060-2 May 1999 ICS 83.080.20 English version Plastics Homopolymer and copolymer resins of vinyl chloride Part 2: Preparation of test s
10、amples and determination of properties (ISO 1060-2:1998) Plastiques Rsines dhomopolymres et de copolymres de chlorure de vinyle Partie2:Prparation des chantillons pour essai et dtermination des proprits (ISO1060-2:1998) Kunststoffe Homo-und Copolymere des Vinylchlorids Teil 2: Herstellung von Probek
11、rpern und Bestimmung von Eigenschaften (ISO 1060-2:1998) This European Standard was approved by CEN on 18 April 1999. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without a
12、ny alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made b
13、y translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, CzechRepublic, Denmark, Finland, France, Germany, Greece, Iceland, Ire
14、land, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom. CEN European Committee for Standardization Comit Europen de Normalisation Europisches Komitee fr Normung Central Secretariat: rue de Stassart 36, B-1050 Brussels 1999 CEN All rights of exploitation
15、 in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 1060-2:1999 EEN ISO 1060-2:1999 BSI 03-2000 2 Foreword The text of the International Standard from Technical Committee ISO/TC 61 “Plastics” of the International Organization for Standardization (ISO) has been
16、taken over as an European Standard by Technical Committee CEN/TC 249 “Plastics”, the, secretariat of which is held by IBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 1999, and confli
17、cting national standards shall be withdrawn at the latest by November 1999. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, CzechRepublic, Denmark, Finland, France, Ger
18、many, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the UnitedKingdom. Endorsement notice The text of the International Standard ISO 1060-2:1998 has been approved by CEN as a European Standard without any modification. NOTENormative refere
19、nces to International Standards are listed in Annex ZA (normative).EN ISO 1060-2:1999 ii BSI 03-2000 Contents Page Foreword iii 1 Scope 1 2 Normative references 1 3 Preparation of test samples 2 4 Conditioning of test samples 2 5 Determination of properties 2 Annex ZA (normative) Normative reference
20、s to international publications with their relevant European publications 4 Table 1 Properties and test procedures 3 Descriptors: Plastics, thermoplastic resins, vinyl resins, homopolymers, copolymers, vinyl chloride, tests, determination, properties, test specimens, specimen preparation.EN ISO 1060
21、-2:1999 BSI 03-2000 iii Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in
22、 a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commiss
23、ion (IEC) on all matters of electrotechnical standardization. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75% of the member bodies casting a vote. Internationa
24、l Standard ISO 1060-2 was prepared by Technical Committee ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic materials. This third edition cancels and replaces the second edition (ISO 1060-2:1985) and includes the following main changes: a) the list of test methods in Table 1 has been revised; b)
25、 the preparation of standard pastes has been included. ISO 1060 consists of the following parts, under the general title Plastics Homopolymer and copolymer resins of vinyl chloride: Part 1: Designation system and basis for specifications; Part 2: Preparation of test samples and determination of prop
26、erties.iv blankEN ISO 1060-2:1999 BSI 03-2000 1 1 Scope This part of ISO 1060 specified the methods of preparation of test samples and the test methods to be used in determining the properties of PVC resins. Requirements for handling test material and for conditioning the material before testing are
27、 given here. In addition, properties and test methods which are suitable and necessary to characterize PVC resins are listed. In order to obtain reproducible and comparable test results, it is necessary to use the methods of sample preparation and conditioning and the test procedures specified herei
28、n. Values determined will not necessarily be identical to those obtained using different test samples, or test samples prepared using different procedures. 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this part of I
29、SO 1060. At the time of publication, the editions indicated were valid. All standards are subject to revision, and parties to agreements based on this part of ISO 1060 are encouraged to investigate the possibility of applying the most recent editions of the standards indicated below. Members of IEC
30、and ISO maintain registers of currently valid International Standards. ISO 60:1977, Plastics Determination of apparent density of material that can be poured from a specified funnel. ISO 1068:1975, Plastics Homopolymer and copolymer resins of vinyl chloride Determination of compacted apparent bulk d
31、ensity. ISO 1158:, Plastics Vinyl chloride homopolymers and copolymers Determination of chlorine content 1) . ISO 1159:1978, Plastics Vinyl chloride-vinyl acetate copolymers Determination of vinyl acetate. ISO 1264:1980, Plastics Homopolymer and copolymer resins of vinyl chloride Determination of pH
32、 of aqueous extract. ISO 1265:1979, Plastics Polyvinyl chloride resinsDetermination of number of impurities and foreign particles. ISO 1269:1980, Plastics Homopolymer and copolymer resins of vinyl chloride Determination of volatile matter (including water). ISO 1385-1:1977, Phthalate esters for indu
33、strial use Methods of test Part 1: General. ISO 1624:1978, Plastics Vinyl chloride homopolymer and copolymer resins Sieve analysis in water. ISO 1628-2:, Plastics Determination of the viscosity of polymers in dilute solution using capillary viscometers Part 2: Poly(vinyl chloride) resins 2) . ISO 25
34、55:1989, Plastics Resins in the liquid state or as emulsions or dispersions Determination of apparent viscosity by the Brookfield Test method. ISO 2591-1:1988, Test sieving Part 1: Methods using test sieves of woven wire cloth and perforated metal plate. ISO 3219:1993, Plastics Polymers/resins in th
35、e liquid state or as emulsions or dispersions Determination of viscosity using a rotational viscometer with defined shear rate. ISO 3451-5:1989, Plastics Determination of ash Part 5: Poly(vinyl chloride). ISO 4574:1978, Plastics PVC resins for general use Determination of hot plasticizer absorption.
36、 ISO 4575:1985, Plastics Polyvinyl chloride pastes Determination of apparent viscosity using the Severs rheometer. ISO 4608:, Plastics Homopolymer and copolymer resins of vinyl chloride for general use Determination of plasticizer absorption at room temperature 3) . ISO 4610:1977, Plastics Vinyl chl
37、oride homopolymer and copolymer resins Sieve analysis using air-jet sieve apparatus. ISO 4612:, Plastics Preparation of PVC pastes for test purposes Planetary-mixer method 4) . ISO 6186:, Plastics Determination of pourability 5) . ISO 6401:1985, Plastics Homopolymer and copolymer resins of vinyl chl
38、oride Determination of residual vinyl chloride monomer Gas chromatographic method. ISO 11468:1997, Plastics Preparation of PVC pastes for test purposes Dissolver method. 1) To be published. (Revision of ISO 1158:1984) 2) To be published. (Revision of ISO 1628-2:1988) 3) To be published. (Revision of
39、 ISO 4608:1984) 4) To be published. (Revision of ISO 4612:1979) 5) To be published. (Revision of ISO 6186:1980)EN ISO 1060-2:1999 2 BSI 03-2000 3 Preparation of test samples 3.1 Sampling The sample of resin taken shall be generally representative of the resin whose properties are to be determined an
40、d be sufficiently large to provide the number of test samples required by the test methods concerned. 3.2 Preparation of standard pastes In order to carry out certain tests on paste resins, it is necessary to prepare standard pastes from the test sample concerned. For designation purposes, one of tw
41、o standard paste formulations, A and B, shall be used, but formulation A should be used in preference. Formulation B should be used when the resin to be designated does not form a paste with formulation A or if the temperature exceeds 35 C during the preparation of the paste. Formulation B should al
42、so be used when it is not possible to measure the viscosities of the paste at both shear rates with formulation A. The pastes shall be prepared in accordance with ISO4612 (method B) or ISO 11468 except in cases of dispute when they shall be prepared by method B of ISO 4612. When measured at 20 C by
43、the methods described in ISO 1385-1, the density, refractive index and dynamic viscosity of the DOP plasticizer used shall have the following values: 4 Conditioning of test samples Condition test samples prior to testing wherever specified in the test method or product specification. 5 Determination
44、 of properties In the determination of properties and the presentation of results, the standards, methods and special conditions listed in Table 1 shall apply. For the designation of general-purpose resins, retention on a 63 4m mesh sieve shall be determined in accordance with ISO 4610 while, for pa
45、ste resins and filler resins, it shall be determined in accordance with ISO 1624. Formulation A: 100 parts by mass of resin 60 parts by mass of bis-(2-ethylhexyl) phthalate (DOP) Formulation B: 100 parts by mass of resin 100 parts by mass of bis-(2-ethylhexyl) phthalate (DOP) density 0,982 g/cm 3to
46、0,984 g/cm 3 refractive index 1,486 to 1,487 dynamic viscosity 77 mPas to 83 mPasEN ISO 1060-2:1999 BSI 03-2000 3 Table 1 Properties and test procedures Property Standard Units Properties of powder Apparent density a Compacted apparent bulk density Impurities and foreign particles Sieve analysis in
47、water a Methods using test sieves of woven wire cloth Plasticizer absorption at room temperature a Sieve analysis using air-jet sieve apparatus a Hot plasticizer absorption Pourability ISO 60 ISO 1068 ISO 1265 ISO 1624 ISO 2591-1 ISO 4608 ISO 4610 ISO 4574 ISO 6186 g/ml g/ml number of specks per 100
48、 squares of grid % % or other appropriate unit parts per 100 parts of resin by mass % parts per 100 parts of resin by mass s Chemical properties Chlorine content Vinyl acetate content pH of aqueous extract Volatile matter (including water) Reduced viscosity a K value Ash Residual vinyl chloride mono
49、mer ISO 1158 ISO 1159 ISO 1264 ISO 1269 ISO 1628-2 ISO 3451-5 ISO 6401 % % % ml/g % mg/kg Viscosity of pastes The pastes used for all viscosity determinations shall be prepared in accordance with ISO 4612 or ISO11468 Apparent viscosity by the Brookfield test method Viscosity with a rotational viscometer working at defined shear rate ab Apparent viscosity using the Severs rheometer ISO 2555 ISO 3219 ISO 4575 Pas Pas Pas a Designato
