1、| | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BRITISH STANDARD BS EN ISO 14528-3:2000 Th
2、e European Standard EN ISO 14528-3:1999 has the status of a British Standard ICS 83.080.10 NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW Plastics Melamine-formaldehyde powder moulding compounds (MF-PMCs) Part 3: Requirements for selected moulding compoundsThis British Standa
3、rd, having been prepared under the direction of the Sector Committee for Materials and Chemicals, was published under the authority of the Standards Committee and comes into effect on 15 January 2000 BSI 01-2000 ISBN 0 580 35881 X BS EN ISO 14528-3:2000 Amendments issued since publication Amd. No. D
4、ate Comments National foreword This British Standard is the English language version of EN ISO 14528-3:1999. It is identical with ISO 14528-3:1999. The UK participation in its preparation was entrusted to Technical Committee PRI/42, Fibre reinforced thermosetting plastics and prepregs, which has the
5、 responsibility to: aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the U
6、K. A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references Attention is drawn to the fact that CEN and CENELEC Standards normally include an annex which lists normative references to international publications with their corresponding Europ
7、ean publications. The British Standards which implement these international or European publications may be found in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A Bri
8、tish Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a fro
9、nt cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii and iii, a blank page, pages 1 to 5 and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued.EN ISO 14528-3:1999 Referencenumber ISO
10、14528-3:1999(E) INTERNATIONAL STANDARD ISO 14528-3 Firstedition 1999-11-15 PlasticsMelamine-formaldehydepowder mouldingcompounds(MF-PMCs) Part3: Requirementsforselectedmoulding compounds Plastiques Poudres mouler base de mlamine-formaldhyde (MF-PMC) Partie 3: Exigences relatives certaines poudres mo
11、uler EN ISO 14528-3:1999ISO-825413:(9991E) ISO9991 Allrgihtsresvrede.lnUesstorehwisescepfieid,noraptofthisilbupctaoinmaybeudorpercedorutziliedinnayformorbynaysnaem,electnoric ormecinahcal,inclidungtohpociypongnadmicrfoilm,wituohteprmissioninwritingfromeitehrISOattherddaessleboworISOsmemebrydob inthe
12、ctnuoryofthertseuqee.r ISOcirypohgtfofice aCsesoptale56 121-HC1veneGa20 leT.+41224790111 aFx+41223741097 E-mailcirypothgiso.ch Webwww.iso.ch ii DPFdcsilremia ihTsPDFfilemayctnoainemeddebdtyfepaces.InaccnadrocewithAebodslicensinglopicy,thisfilemaybepirntedorivewedubtslahlton beidetedlnuessthetyfepace
13、swhichareemeddebdraelicensedtonadintslaledonthecomputerfrepormingtheideting.Inodwlnidaongthis feli,trapiesaccepttierehnthesersnoptilibiyofontinfrnignigAebodslicsneniglopicy.hTeISOtneCarlSecterairatacceptsnollibaiityinthis .aera AbodeisatdaremarkofAbodeStsyemsInctaropro.de teDailsofthesfotwraepudorct
14、susedtocrtaeetihsPDFfilecanbefnuodintheGarenelInfolerativetothefile;theP-FDcerationrapamteers weretpoimizedforpirtning.EvreycraeahseebntakentoensruethatthefileissuitlbaeforusebyISOmemebridobse.Inthelnuikleyetnev tahtaplboremleratingtoitisfdnuo,lpaeseifnormthetneCarlSecterairatattheserddasgivenlebow.
15、 EN ISO 14528-3:1999ISO14528-3:1999(E)iii Foreword ISO(theInternationalOrganizationforStandardization)isaworldwidefederationofnationalstandardsbodies(ISO memberbodies).TheworkofpreparingInternationalStandardsisnormallycarriedoutthroughISOtechnical committees.Eachmemberbodyinterestedinasubjectforwhic
16、hatechnicalcommitteehasbeenestablishedhas therighttoberepresentedonthatcommittee.Internationalorganizations,governmentalandnon-governmental,in liaisonwithISO,alsotakepartinthework.ISOcollaboratescloselywiththeInternationalElectrotechnical Commission(IEC)onallmattersofelectrotechnicalstandardization.
17、 InternationalStandardsaredraftedinaccordancewiththerulesgivenintheISO/IECDirectives,Part3. DraftInternationalStandardsadoptedbythetechnicalcommitteesarecirculatedtothememberbodiesforvoting. PublicationasanInternationalStandardrequiresapprovalbyatleast75%ofthememberbodiescastingavote. Attentionisdra
18、wntothepossibilitythatsomeoftheelementsofthispartofISO14528maybethesubjectof patentrights.ISOshallnotbeheldresponsibleforidentifyinganyorallsuchpatentrights. InternationalStandardISO14528-3waspreparedbyTechnicalCommitteeISO/TC61, Plastics, Subcommittee SC12, Thermosetting materials. Afteratransition
19、periodof,atthemost,fouryears,thethreepartsofISO14528(seebelow),togetherwiththe threepartsofISO14527,willreplaceISO2112:1990,ofwhichtheyconstituteatechnicalrevision. ISO14528consistsofthefollowingparts,underthegeneraltitle Plastics Melamine-formaldehyde powder moulding compounds (MF-PMCs): Part 1: De
20、signation system and basis for specifications Part 2: Preparation of test specimens and determination of properties Part 3: Requirements for selected moulding compounds AnnexAofthispartofISO14528isforinformationonly. EN ISO 14528-3:1999EN ISO 14528-3:1999INTERNATIONAL STANDARD ISO 14528-3:1999(E) IS
21、O 9991 All irhgts seredevr 1 Plastics Melamine-formaldehyde powder moulding compounds (MF-PMCs) Part 3: Requirements for selected moulding compounds 1 Scope This part of ISO 14528 specifies the requirements for the physical and chemical properties of melamine- formaldehyde powder moulding compounds
22、(MF-PMCs) and compression- or injection-moulded test specimens produced from them. It is limited to those powder moulding compounds whose composition and properties are significantly different. It is further limited to those moulding compounds which are of general technical and/or economic importanc
23、e. The properties which are used to characterize the moulding compounds, the test methods and the test conditions are selected from those given in ISO 14528-2. The moulding compounds are divided into types according to their composition and properties. The various types are designated using the desi
24、gnation system defined in ISO 14528-1. 2 Normative references The following normative documents contain provisions which, through reference in this text, constitute provisions of this part of ISO 14528. For dated references, subsequent amendments to, or revisions of, any of these publications do not
25、 apply. However, parties to agreements based on this part of ISO 14528 are encouraged to investigate the possibility of applying the most recent editions of the normative documents indicated below. For undated references, the latest edition of the normative document referred to applies. Members of I
26、SO and IEC maintain registers of currently valid International Standards. ISO 472:1999, Plastics Vocabulary. ISO 2112:1990, Plastics Aminoplastic moulding materials Specification. ISO 14528-1:1999, Plastics Melamine-formaldehyde powder moulding compounds (MF-PMCs) Part 1: Designation system and basi
27、s for specifications. ISO 14528-2:1999, Plastics Melamine-formaldehyde powder moulding compounds (MF-PMCs) Part 2: Preparation of test specimens and determination of properties. 3 Terms and definitions For the purposes of this part of ISO 14528, the terms and definitions given in ISO 472, ISO 14528-
28、1 and ISO 14528-2 apply. EN ISO 14528-3:1999 1ISO -825413:(9991E) 2 ISO 9991 All irhgts seredevr 4 Requirements 4.1 Property values In order for a melamine-formaldehyde powder moulding compound to be considered as complying with this part of ISO 14528, it shall meet the requirements given in the app
29、ropriate table (Table 1 or 2). Tables 1 and 2 give the mean value obtained for the set of test specimens used to determine a particular property. Individual values of properties 2.1, 2.2, 2.3 and 2.4 shall be within 10 % of the mean value, and individual values of properties 3.1 and 3.2 shall be wit
30、hin 5 C of the mean value. No specific limits are placed on rheological and processing properties. However, suitable rheological and processing properties are essential for the satisfactory use of a moulding compound. The test methods and test conditions used shall be as agreed between the intereste
31、d parties. In addition, for some applications, it may be useful for information to be made available on other properties, for example: cure time; particle size; moisture content. If this is so, these properties and test methods, as well as the test conditions to be used, shall be as agreed between t
32、he interested parties. 4.2 Filler/reinforcement type and content In order for a melamine-formaldehyde powder moulding compound to be considered as complying with this part of ISO 14528, the nature, form and content by mass of its filler/reinforcement shall be as given in the designation of the mould
33、ing compound (see ISO 14528-1:1999, subclause 4.2). EN ISO 14528-3:1999 2ISO -825413:(9991E) ISO 9991 All irhgts seredevr 3 Table 1 Property requirements for MF-PMCs containing (LD+MD) or (WD+MD) as filler 1234 Type: PMC ISO 14528-MF. . . Property Unit Pro- cess- ing a Max. or min. (LD25+MD20) to (L
34、D35+MD10) (LD20+MD25),X,N to (LD30+MD15),X,N (LD20+MD25),X,N,M to (LD30+MD15),X,N,M (WD30+MD15) to (WD40+MD05) 1 Rheological and processing properties 1.1 To be agreed between the interested parties 2 Mechanical properties 2.1 Stress at break, B MPa Q M W W 40 50 40 50 40 50 40 50 2.2 Flexural stren
35、gth, fM MPa Q M W W 80 90 80 100 90 100 70 90 2.3 Charpy impact strength, a cU kJ/m 2 Q M W W 5,0 6,0 5,0 6,0 6,0 8,0 5,0 6,0 2.4 Charpy notched impact strength, a cA kJ/m 2 Q M W W 1,2 1,4 1,2 1,4 1,4 1,5 1,2 1,3 3 Thermal properties 3.1 Temperature of deflection under load, T f 1,8 C Q/M W 155 155
36、 155 155 3.2 Temperature of deflection under load, T f 8,0 C Q/M W 110 110 110 110 3.3 Flammability (glow bar), BH Q/M u BH 2-10 BH 2-10 BH 2-10 BH 2-10 4 Electrical properties 4.1 Dissipation factor, tan 100 Q / Mu 4.2 Volume resistivity, e cm Q/M W 4.3 Surface resistivity, e Q/M W 10 10 10 10 10 1
37、0 10 10 4.4 Proof tracking index, PTI Q/M W 600 600 600 600 5 Other properties 5.1 mg u 200 200 200 200 5.2 Water absorption, W w 24 %b y mass Q/M u 5.3 5.4 5.5 Extractable formaldehyde with water, m E/W F with acetic acid, m E/AA F with ethyl alcohol, m E/AL F g/ml Q/M u 33 a Q = Compression mouldi
38、ng M = Injection moulding NOTE 1 See ISO 14528-2:1999, Tables 3 and 4, columns 3, 4, and 7, for the methods to be used for the preparation of test specimens and the determination of properties. NOTE 2 In view of the differences between the property-value limits for compression-moulding and injection
39、-moulding materials, the likely variations in test results and the wide range of properties covered, it should not be assumed that materials having the same designation are exactly equivalent. EN ISO 14528-3:1999 3ISO -825413:(9991E) 4 ISO 9991 All irhgts seredevr Table 2 Property requirements for M
40、F-PMCs containing (SS+MD) or (GF+MD) as filler 5678 Type: PMC ISO 14528-MF. . . Property Unit Pro- cess- ing a Max. or min. (SS30+MD15) to (SS40+MD05) (GF20+MD25) to (GF30+MD15) 1 Rheological and processing properties 1.1 To be agreed between the interested parties 2 Mechanical properties 2.1 Stress
41、 at break, B MPa Q M W W 35 45 40 50 2.2 Flexural strength, fM MPa Q M W W 60 80 90 100 2.3 Charpy impact strength, a cU kJ/m 2 Q M W W 9,0 15,0 5,0 7,0 2.4 Charpy notched impact strength, a cA kJ/m 2 Q M W W 6,5 6,5 2,0 2,5 3 Thermal properties 3.1 Temperature of deflection under load, T f 1,8 C Q/
42、M W 155 180 3.2 Temperature of deflection under load, T f 8,0 C Q/M W 110 130 3.3 Flammability (glow bar), BH Q/M u BH 2-10 BH 1 4 Electrical properties 4.1 Dissipation factor, tan 100 Q / Mu 4.2 Volume resistivity, e cm Q/M W 4.3 Surface resistivity, e Q/M W 10 8 10 10 4.4 Proof tracking index, PTI
43、 Q/M W 600 600 5 Other properties 5.1 mg u 150 150 5.2 Water absorption, W w 24 %b y mass Q/M u 5.3 5.4 5.5 Extractable formaldehyde with water, m E/W F with acetic acid, m E/AA F with ethyl alcohol, m E/AL F g/ml Q/M u a Q = Compression moulding M = Injection moulding NOTE 1 See ISO 14528-2:1999, T
44、ables 3 and 4, columns 3, 4, and 7, for the methods to be used for the preparation of test specimens and the determination of properties. NOTE 2 In view of the differences between the property-value limits for compression-moulding and injection-moulding materials, the likely variations in test resul
45、ts and the wide range of properties covered, it should not be assumed that materials having the same designation are exactly equivalent. EN ISO 14528-3:1999 4ISO -825413:(9991E) ISO 9991 All irhgts seredevr 5 Annex A (informative) Comparison of designations Table A.1 Comparison of designations used
46、for MF-PMCs in national and international standards 1234 National or international standard Type: PMC ISO 14528-MF. . . ISO 14528-3:1999 (LD25+MD20) to (LD35+MD10) (LD20+MD25),X,N to (LD30+MD15),X,N (LD20+MD25),X,N,M to (LD30+MD15),X,N,M (WD30+MD15) to (WD40+MD05) ISO 2112:1990 MF B10 MF B11 MF B12
47、MF B20 ASTM D 704-94 BS 1322:1992 DIN 7708-3:1975 152 152.7 152.7 150 JIS K 6917:1995 MM-E MM-G MM-T NF Table A.1 Comparison of designations used for MF-PMCs in national and international standards (continued) 5678 National or international standard Type: PMC ISO 14528-MF. . . ISO 14528-3:1999 (SS30
48、+MD15) to (SS40+MD05) (GF20+MD25) to (GF30+MD15) ISO 2112:1990 MF D10 ASTM D 704-94 BS 1322:1992 DIN 7708-3:1975 154 JIS K 6917:1995 NF EN ISO 14528-3:1999 5BS EN ISO 14528-3:2000 BSI 389 Chiswick High Road London W4 4AL | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | |
49、 | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BSI British Standards Institution BSI is the independent national body responsible for preparing British Standards. It presents the UK view on standards in Europe and at the international
