1、| | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BRITISH STANDARD BS EN ISO 15252-2:2000 Th
2、e European Standard EN ISO 15252-2:1999 has the status of a British Standard ICS 83.080.10 NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW Plastics Epoxy powder moulding compounds (EP-PMCs) Part 2: Preparation of test specimens and determination of propertiesThis British Stand
3、ard, having been prepared under the direction of the Sector Committee for Materials and Chemicals, was published under the authority of the Standards Committee and comes into effect on 15 January 2000 BSI 01-2000 ISBN 0 580 35889 5 BS EN ISO 15252-2:2000 Amendments issued since publication Amd. No.
4、Date Comments National foreword This British Standard is the English language version of EN ISO 15252-2:1999. It is identical with ISO 15252-2:1999. The UK participation in its preparation was entrusted to Technical Committee PRI/42, Fibre reinforced thermosetting plastics and prepregs, which has th
5、e responsibility to: aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the
6、UK. A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references Attention is drawn to the fact that CEN and CENELEC Standards normally include an annex which lists normative references to international publications with their corresponding Euro
7、pean publications. The British Standards which implement these international or European publications may be found in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A Br
8、itish Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a fr
9、ont cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii and iii, a blank page, pages 1 to 11 and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued.EN ISO 15252-2:1999 Referencenumber I
10、SO15252-2:1999(E) INTERNATIONAL STANDARD ISO 15252-2 Firstedition 1999-11-15 PlasticsEpoxypowdermoulding compounds(EP-PMCs) Part2: Preparationoftestspecimensand determinationofproperties Plastiques Poudres mouler base dpoxydes (EP-PMC) Partie 2: Prparation des prouvettes et dtermination des proprits
11、 EN ISO 15252-2:1999ISO-252512:(9991E) ISO9991 Allrgihtsresvrede.lnUesstorehwisescepfieid,noraptofthisilbupctaoinmaybeudorpercedorutziliedinnayformorbynaysnaem,electcinor ormecinahcal,inclidungtohpociypongnadmicrfoilm,wituohteprmissioninwritingfromeitehrISOattherddaessleboworISOsmemebrydob inthectnu
12、oryofthertseuqee.r ISOcirypohgtfofice aCsesoptale56 121-HC1veneGa20 leT.+41224790111 aFx+41223741097 E-mailcirypothgiso.ch Webwww.iso.ch ii DPFdcsilremia ihTsPDFfilemayctnoainemeddebdtyfepaces.InaccnadrocewithAebodslicensinglopicy,thisfilemaybepirntedorivewedubtslahlton beidetedlnuessthetyfepaceswhi
13、chareemeddebdraelicensedtonadintslaledonthecomputerfrepormingtheideting.Inodwlnidaongthis feli,trapiesaccepttierehnthesersnoptilibiyofontinfrnignigAebodslicsneniglopicy.hTeISOtneCarlSecterairatacceptsnollibaiityinthis .aera AbodeisatdaremarkofAbodeStsyemsInctaropro.de teDailsofthesfotwraepudorctsuse
14、dtocrtaeetihsPDFfilecanbefnuodintheGarenelInfolerativetothefile;theP-FDcerationrapamteers weretpoimizedforpirtning.EvreycraeahseebntakentoensruethatthefileissuitlbaeforusebyISOmemebridobse.Inthelnuikleyetnev tahtaplboremleratingtoitisfdnuo,lpaeseifnormthetneCarlSecterairatattheserddasgivenlebow. EN
15、ISO 15252-2:1999ISO15252-2:1999(E)iii Foreword ISO(theInternationalOrganizationforStandardization)isaworldwidefederationofnationalstandardsbodies(ISO memberbodies).TheworkofpreparingInternationalStandardsisnormallycarriedoutthroughISOtechnical committees.Eachmemberbodyinterestedinasubjectforwhichate
16、chnicalcommitteehasbeenestablishedhas therighttoberepresentedonthatcommittee.Internationalorganizations,governmentalandnon-governmental,in liaisonwithISO,alsotakepartinthework.ISOcollaboratescloselywiththeInternationalElectrotechnical Commission(IEC)onallmattersofelectrotechnicalstandardization. Int
17、ernationalStandardsaredraftedinaccordancewiththerulesgivenintheISO/IECDirectives,Part3. DraftInternationalStandardsadoptedbythetechnicalcommitteesarecirculatedtothememberbodiesforvoting. PublicationasanInternationalStandardrequiresapprovalbyatleast75%ofthememberbodiescastingavote. Attentionisdrawnto
18、thepossibilitythatsomeoftheelementsofthispartofISO15252maybethesubjectof patentrights.ISOshallnotbeheldresponsibleforidentifyinganyorallsuchpatentrights. InternationalStandardISO15252-2waspreparedbyTechnicalCommitteeISO/TC61, Plastics, Subcommittee SC12, Thermosetting materials. ISO15252consistsofth
19、efollowingparts,underthegeneraltitle Plastics Epoxy powder moulding compounds (EP-PMCs): Part 1: Designation system and basis for specifications Part 2: Preparation of test specimens and determination of properties Part 3: Requirements for selected moulding compounds EN ISO 15252-2:1999EN ISO 15252-
20、2:1999INTERNATIONAL STANDARD ISO 15252-2:1999(E) ISO 9991 All irhgts seredevr 1 Plastics Epoxy powder moulding compounds (EP-PMCs) Part 2: Preparation of test specimens and determination of properties 1 Scope This part of ISO 15252 specifies the methods of preparation of test specimens and the test
21、methods to be used in determining the properties of epoxy powder moulding compounds (EP-PMCs). Requirements for handling test material and for conditioning both the test material before moulding and the specimens before testing are given here. Procedures and conditions for the preparation of test sp
22、ecimens and procedures for measuring properties of the materials from which these specimens are made are given. Properties and test methods which are suitable and necessary to characterize PMCs are listed. The properties have been selected from the general test methods in ISO 10350-1. Other test met
23、hods in wide use for, or of particular significance to, PMCs are also included in this part of ISO 15252, as are the designatory properties found in ISO 15252-1. In order to obtain reproducible and comparable test results, it is necessary to use the methods of preparation and conditioning, the speci
24、men dimensions and the test procedures specified herein. Values determined will not necessarily be identical to those obtained using specimens of different dimensions or prepared using different procedures. 2 Normative references The following normative documents contain provisions which, through re
25、ference in this text, constitute provisions of this part of ISO 15252. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. However, parties to agreements based on this part of ISO 15252 are encouraged to investigate the possibility of applying the
26、 most recent editions of the normative documents indicated below. For undated references, the latest edition of the normative document referred to applies. Members of ISO and IEC maintain registers of currently valid International Standards. ISO 60:1977, Plastics Determination of apparent density of
27、 material that can be poured from a specified funnel. ISO 62:1999, Plastics Determination of water absorption. ISO 75-2:1993, Plastics Determination of temperature of deflection under load Part 2: Plastics and ebonite. ISO 120:1977, Plastics Phenol-formaldehyde mouldings Determination of free ammoni
28、a and ammonium compounds Colorimetric comparison method. ISO 171:1980, Plastics Determination of bulk factor of moulding materials. ISO 178:1993, Plastics Determination of flexural properties. EN ISO 15252-2:1999 1ISO -252512:(9991E) 2 ISO 9991 All irhgts seredevr ISO 179-1: 1) , Plastics Determinat
29、ion of Charpy impact properties Part 1: Non-instrumented impact test. ISO 291:1997, Plastics Standard atmospheres for conditioning and testing. ISO 295: 2) , Plastics Compression moulding of test specimens of thermosetting materials. ISO 472:1999, Plastics Vocabulary. ISO 527-1:1993, Plastics Determ
30、ination of tensile properties Part 1: General principles. ISO 527-2:1993, Plastics Determination of tensile properties Part 2: Test conditions for moulding and extrusion plastics. ISO 899-1:1993, Plastics Determination of creep behaviour Part 1: Tensile creep. ISO 1183:1987, Plastics Methods for det
31、ermining the density and relative density of non-cellular plastics. ISO 2039-1:1993, Plastics Determination of hardness Part 1: Ball indentation method. ISO 2577:1984, Plastics Thermosetting moulding materials Determination of shrinkage. ISO 2818:1994, Plastics Preparation of test specimens by machi
32、ning. ISO 3167:1993, Plastics Multipurpose test specimens. ISO 3671:1976, Plastics Aminoplastic moulding materials Determination of volatile matter. ISO 4589-2:1996, Plastics Determination of burning behaviour by oxygen index Part 2: Ambient-temperature test. ISO 4614:1977, Plastics Melamine-formald
33、ehyde mouldings Determination of extractable formaldehyde. ISO 6603-2: 3) , Plastics Determination of puncture impact behaviour of rigid plastics Part 2: Instrumented impact testing. ISO 7808:1992, Plastics Thermosetting moulding materials Determination of transfer flow. ISO 8256:1990, Plastics Dete
34、rmination of tensile-impact strength. ISO 10350-1:1998, Plastics Acquisition and presentation of comparable single-point data Part 1: Moulding materials. ISO 10724-1:1998, Plastics Injection moulding of test specimens of thermosetting powder moulding compounds (PMCs) Part 1: General principles and m
35、oulding of multipurpose test specimens. ISO 10724-2:1998, Plastics Injection moulding of test specimens of thermosetting powder moulding compounds (PMCs) Part 2: Small plates. ISO 11359-2:1999, Plastics Thermomechanical analysis (TMA) Part 2: Determination of coefficient of linear thermal expansion
36、and glass transition temperature. 1) To be published. (Revision of ISO 179:1993) 2) To be published. (Revision of ISO 295:1991) 3) To be published. (Revision of ISO 6603-2:1989) EN ISO 15252-2:1999 2ISO -252512:(9991E) ISO 9991 All irhgts seredevr 3 ISO 15062: 4) , Plastics Determination of the ther
37、mal-flow and cure behaviour of thermosetting materials by torque rheometry. ISO 15252-1:1999, Plastics Epoxy powder moulding compounds (EP-PMCs) Part 1: Designation system and basis for specifications. ISO 15252-3:1999, Plastics Epoxy powder moulding compounds (EP-PMCs) Part 3: Requirements for sele
38、cted moulding compounds. IEC 60093:1980, Methods of test for volume resistivity and surface resistivity of solid electrical insulating materials. IEC 60112:1979, Method for determining the comparative and the proof tracking indices of solid insulating materials under moist conditions. IEC 60167:1964
39、, Methods of test for the determination of the insulation resistance of solid insulating materials. IEC 60243-1:1998, Electrical strength of insulating materials Test methods Part 1: Tests at power frequencies. IEC 60250:1969, Recommended methods for the determination of the permittivity and dielect
40、ric dissipation factor of electrical insulating materials at power, audio and radio frequencies including metre wavelengths. IEC 60296:1982, Specification for unused mineral insulating oils for transformers and switchgear. IEC 60695-11-10:1999, Fire hazard testing Part 11-10: Test flames 50 W horizo
41、ntal and vertical flame test methods. IEC 60695-11-20:1999, Fire hazard testing Part 11-20: Test flames 500 W flame test methods. IEC 60707:1999, Flammability of solid non-metallic materials when exposed to flame sources List of test methods. 3 Terms and definitions For the purposes of this part of
42、ISO 15252, the terms and definitions given in ISO 472 and ISO 15252-1 apply, plus the following: 3.1 thermal flow parameter which characterizes the flow behaviour of plasticized thermosetting moulding compounds, e.g. when filling a mould cavity, and for which the minimum torque M B measured in accor
43、dance with ISO 15062 may be taken as a measure 4 Preparation of test specimens 4.1 General It is essential that specimens are always prepared by the same procedure (either injection moulding or compression moulding), using the same processing conditions. The procedure to be used for each test method
44、 is indicated in Tables 3 and 4 (M = injection moulding, Q = compression moulding). 4) To be published. EN ISO 15252-2:1999 3ISO -252512:(9991E) 4 ISO 9991 All irhgts seredevr The material shall be kept in moisture-proof containers until it is required for use. The moisture content of filled or rein
45、forced materials shall be expressed as a percentage of the total mass of the compound. 4.2 Pretreatment of the material Before processing by injection moulding, no treatment of the sample is normally necessary. If pretreatment is required, this shall be in accordance with the manufacturers recommend
46、ations. Before processing by compression moulding, treatment of the sample in accordance with ISO 295:, subclause 5.2 (preforming), 6.2 (drying), 6.3 (high-frequency preheating) or 6.4 (preplastification), is allowed. 4.3 Injection moulding Injection-moulded specimens shall be prepared in accordance
47、 with ISO 10724-1 and/or ISO 10724-2, using the conditions specified in Table 1. Table 1 Conditions for injection moulding of test specimens Type of PMC Melt temperature T M (range) C Mould temperature T C (range) C Average injection velocity, v I (range) mm/s Cure time t CR (range) s Injection EP-P
48、MC 100 to 110 160 to 180 50 to 150 (see text) The conditions may be selected from within the range specified in Table 1 provided that the statement in 4.1, first sentence, is observed and, in each specific case, definite values (not ranges) are laid down for the melt temperature T M , the mould temp
49、erature T C and th ecu reti met CR . T h ec u r et i m et CR may be selected as a function of the curing behaviour and the type of pretreatment of the EP-PMC under test, provided that it is the same for all specimens of the same thickness moulded from any one type of EP-PMC and is stated together with the test results. The cure time selected shall ensure that all the specimens are cured as completely
