1、BS ISO10307-1:2009ICS 75.160.20NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDPetroleum products Total sediment inresidual fuel oilsPart 1: Determination by hot filtrationThis British Standardwas published under theauthority of the StandardsPolicy and StrategyC
2、ommittee on 31 March2009 BSI 2009ISBN 978 0 580 60751 6Amendments/corrigenda issued since publicationDate CommentsBS ISO 10307-1:2009National forewordThis British Standard is the UK implementation of ISO 10307-1:2009. Itsupersedes BS 2000-375:1999 which is withdrawn.The UK participation in its prepa
3、ration was entrusted to TechnicalCommittee PTI/13, Petroleum testing and terminology.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisionsof a contract. Users are responsible for its
4、correct application.Compliance with a British Standard cannot confer immunityfrom legal obligations.BS ISO 10307-1:2009INTERNATIONALSTANDARDISO10307-1Second edition2009-02-01Reference numberISO 10307-1:2009(E) ISO 2009Petroleum products Total sediment in residual fuel oils Part 1:Determination by ho
5、t filtrationProduits ptroliers Insolubles existants dans les fuel-oils rsiduels Partie 1: Dtermination par filtration chaudBS ISO 10307-1:2009ISO 10307-1:2009(E)ii ISO 2009 All rights reservedPDF disclaimerThis PDF file may contain embedded typefaces. In accordance with Adobes licensing policy, this
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10、9 01 11Fax + 41 22 749 09 47E-mail copyrightiso.orgWeb www.iso.orgPublished in SwitzerlandBS ISO 10307-1:2009ISO 10307-1:2009(E) ISO 2009 All rights reserved iiiForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies(ISO member bodies).
11、 The work of preparing International Standards is normally carried out through ISOtechnical committees. Each member body interested in a subject for which a technical committee has beenestablished has the right to be represented on that committee. International organizations, governmental andnon-gov
12、ernmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the InternationalElectrotechnical Commission (IEC) on all matters of electrotechnical standardization.International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.The
13、 main task of technical committees is to prepare International Standards. Draft International Standardsadopted by the technical committees are circulated to the member bodies for voting. Publication as anInternational Standard requires approval by at least 75 % of the member bodies casting a vote.At
14、tention is drawn to the possibility that some of the elements of this document may be the subject of patentrights. ISO shall not be held responsible for identifying any or all such patent rights.ISO 10307-1 was prepared by Technical Committee ISO/TC 28, Petroleum products and lubricants.This second
15、edition cancels and replaces the first edition (ISO 10307-1:1993), which has been technicallyrevised. It also incorporates the Technical Corrigendum ISO 10307-1:1993/Cor.1:1997.ISO 10307 consists of the following parts, under the general title Petroleum products Total sediment inresidual fuel oils:
16、Part 1: Determination by hot filtration Part 2: Determination using standard procedures for ageingBS ISO 10307-1:2009.iv BS ISO 10307-1:2009INTERNATIONAL STANDARD ISO 10307-1:2009(E) ISO 2009 All rights reserved 1Petroleum products Total sediment in residual fuel oils Part 1:Determination by hot fil
17、trationWARNING The use of this part of ISO 10307 could involve hazardous materials, operations andequipment. The document does not purport to address all of the safety problems associated with itsuse. It is the responsibility of the user of this part of ISO 10307 to establish appropriate safety andh
18、ealth practices, and determine the applicability of regulatory limitations prior to use.1ScopeThis part of ISO 10307 specifies a method for the determination of total sediment in residual fuel oils having amaximum viscosity of at , and for blends of distillate fuels containing residual components.Th
19、e maximum total sediment covered by the precision evaluations of this method is for residualfuels and for distillate fuels containing residual components. Some fuels could exceed themaximum filtration time specified in this method due to factors other than the presence of significant quantitiesof in
20、soluble organic or inorganic material.For the determination of sediment insoluble in toluene, see ISO 37351).NOTE 1 The method can also be used for the assessment of total sediment after regimes of fuel pre-treatment designed toaccelerate the ageing process (see ISO 10307-2).NOTE 2 Significant amoun
21、ts of sediment in a residual fuel oil can cause fouling of facilities for handling and presentproblems in burner mechanisms. Sediment can accumulate in storage tanks, on filter screens or on burner parts, resultingin obstruction to flow of oil from the tank to the burner.NOTE 3 For the purposes of t
22、his International Standard, the terms “ ” and “ ” are used to representmass and volume fractions of a material, respectively. These expressions are deprecated under the International Systemand according to ISO 31-0, Quantities and units Part 0: General principles, which specifies that mass and volum
23、efractions be expressed as “mass fraction of xx %” (symbol ) and “volume fraction of xx %” (symbol ).2 Normative referencesThe following referenced documents are indispensable for the application of this document. For datedreferences, only the edition cited applies. For undated references, the lates
24、t edition of the referenced document(including any amendments) applies.ISO 3170:2004, Petroleum liquids Manual samplingISO 3171:1988, Petroleum liquids Automatic pipeline samplingISO 6353-2:1983, Reagents for chemical analysis Part 2: Specifications First seriesISO 6353-3:1987, Reagents for chemical
25、 analysis Part 3: Specifications Second series1) ISO 3735, Crude petroleum and fuel oils Determination of sediment Extraction method.55 mm2/s 100C0,50 % (m/m)0,40 % (m/m)% (m/m) % (V/V) BS ISO 10307-1:2009ISO 10307-1:2009(E)2 ISO 2009 All rights reserved3 Terms and definitionsFor the purposes of thi
26、s document, the following terms and definitions apply.3.1 total sedimentsum of insoluble organic and inorganic material, separated from the bulk of the sample by filtration through aspecified filter, and also insoluble in a predominantly paraffinic solvent4PrincipleAn aliquot of the oil sample is fi
27、ltered through the prescribed apparatus (Clause 6) at , and after solventwashing and drying the total sediment on the filter is weighed. The test is carried out in duplicate.5MaterialsDuring the analysis, unless otherwise stated, use only reagents as specified in ISO 6353-2 and ISO 6353-3, iflisted
28、there. If not listed, then use reagents of a recognized analytical grade.5.1 Heptane, CH3(CH2)5CH3.WARNING Heptane is a toxic volatile hydrocarbon, and shall only be used with adequate ventilation.Avoid inhalation of vapour or mist and prolonged skin contact.5.2 Toluene, C6H5CH3.WARNING Toluene is a
29、 toxic, volatile hydrocarbon which is absorbed by inhaling the vapour orthrough skin contact with the liquid. Use only in adequate ventilation and avoid skin contact.5.3 Wash solvent, consisting of heptane (5.1) and toluene (5.2).6 Apparatus6.1 Filtration apparatus, an example of which is shown in F
30、igure 1 and the arrangement of which is shown inFigure 2. Its construction is with steam coils attached, suitably supported, above a vacuum flask appropriatelyprotected against the effects of implosion.NOTE Other apparatus configurations have been shown to be satisfactory, provided that the dimensio
31、nal requirements andheating-medium capacity are strictly adhered to.6.2 Temperature measuring device, capable of measuring the temperature in the range from towith an accuracy of .6.3 Oven, capable of maintaining a temperature of and evaporating the solvent without risk offire or explosion.6.4 Stirr
32、ing rod, glass or PTFE (polytetrafluoroethylene), approximately in length and indiameter.6.5 Glass beaker, capacity, either squat form with lip or conical.6.6 Small dishes, such as watch glasses or Petri dishes.6.7 Magnetic stirrer/hotplate, or other suitable heating device, capable of being control
33、led by a surface-temperature-measuring device (6.13), and polytetrafluoroethylene (PTFE)-coated stirring bars, length .6.8 Steam generator, to provide a source of steam at . Alternative heating media to steam areacceptable where steam is either not available or not available at the specified tempera
34、ture.100C85 % (V/V) 15 % (V/V)95C105C 0,5C110C 1C150 mm 3mm30 ml25 mm100C 1CBS ISO 10307-1:2009ISO 10307-1:2009(E) ISO 2009 All rights reserved 36.9 Vacuum source, capable of providing the specified absolute pressure of (vacuum).6.10 Vacuum gauge, capable of recording the absolute pressure or vacuum
35、 as specified in 6.9.6.11 Glass-fibre filters, nominal porosity , diameter .EXAMPLE Whatman GF/A.2)6.12 High-speed mixer, of any convenient type with a minimum speed of .6.13 Surface-temperature-measuring device, capable of measuring the temperature up to .6.14 Cooling vessel, for cooling the filter
36、s before weighing while keeping them protected from contaminationfrom the atmosphere. A desiccator-type vessel without drying agent is found suitable.6.15 Graduated syringe or wash bottle, minimum capacity , graduated at intervals.6.16 Forceps, spade-ended.6.17 General-purpose temperature-measuring
37、device, capable of measuring the temperature in the rangefrom to with an accuracy of .7 SamplingUnless otherwise specified, samples shall be taken in accordance with ISO 3170 and ISO 3171.8 Sample preparationMix the whole sample thoroughly using a high-speed mixer (6.12), if practicable, for . A sam
38、ple taken on aglass or PTFE rod (6.4) dipped to the bottom of the container shall show a homogeneous appearance. For fuelswith a high wax content (high pour point) or of very high viscosity, heat the sample before stirring. Thetemperature, as measured with the general-purpose temperature-measuring d
39、evice (6.17), shall be eitherto above the pour point for low-viscosity fuels, or at a temperature sufficient to reduce the viscosityto between and for high-viscosity fuels. The temperature shall not exceed duringthis preparation stage.9 Filter preparationFor each test, dry two filters (6.11) for in
40、the oven (6.3) at . Allow to cool in the cooling vessel(6.14) to room temperature for . Weigh each filter to the nearest .NOTE 1 For convenience, the filters can be placed on numbered small dishes (6.6) during drying and cooling.NOTE 2 It has been shown that the same level of results is achieved by
41、the use of a fine wire mesh support screen (seeFigure 1) in combination with a third, disposable filter. This third filter can be placed below the two test filters on the supportscreen and the same pre-drying regime followed as for the test filters, but without weighing the third filter before place
42、ment,discarding it when filtration is complete.The glass-fibre filters are fragile, and need to be handled with care. Before use, check each against abackground light for consistency and the possible presence of small defects (holes).2) Whatman GF/A is an example of a suitable product available comm
43、ercially. This information is given for theconvenience of users of this part of ISO 10307 and does not constitute an endorsement by ISO of this product.40 kPa2 kPa 61,3 kPa0,001 6 mm 47 mmcircleR400 r/min200C25 ml 0,5 ml0C 100C 0,5C30 s15C 18C150 mm2/s 250 mm2/s 80C20 min 110C20 min 0,000 1 gBS ISO
44、10307-1:2009ISO 10307-1:2009(E)4 ISO 2009 All rights reservedDimensions in millimetresKey1 heating/cooling coils (copper)2 cup (brass)3filters4 sintered disc or fine wire mesh5 funnel, brassaSmooth face.bDiameter, : exterior ; interior .cSee Clause 9, Note 2.Figure 1 Detail of filtration cell4,8 mm
45、2,9 mmBS ISO 10307-1:2009ISO 10307-1:2009(E) ISO 2009 All rights reserved 510 Procedure10.1 GeneralThe determination shall be carried out in duplicate.10.2 Assembly of apparatusBefore use, check that the filter support screen is clean, and if necessary clean it by boiling in a high-boilingaromatic s
46、olvent such as toluene (5.2). Renew the filter support screen if more than of the sinter area (i.e.a significant number of pores visible to the naked eye) is blocked by a particulate content after such cleaning.The filtration unit (6.1) shall be clean and dry before assembly. Stack the two previousl
47、y dried and weighedfilters on top of the sinter support with the mesh imprint side down using forceps (6.16). Apply slight vacuum toKey1 heating device2 steam generator3vent4steam5 filtration cells6 heating/cooling coils7 cold water supply for cooling8 drain line9 vacuum gauge10 vacuum pump11 vacuum
48、 flask (protected against implosion)T temperature sensoraSee Figure 1.Figure 2 Arrangement of filtration apparatus2%BS ISO 10307-1:2009ISO 10307-1:2009(E)6 ISO 2009 All rights reservedaid the centralization of the filters and place the top portion of the filtration apparatus carefully on the filters
49、before clamping. Shut off the vacuum suction and press steam, or the alternative heating medium (see 6.8), atthrough the unit for prior to addition of the test portion and throughout the addition andfiltration stages.10.3 Addition of test portionPour into a beaker (6.5) with stirring bar approximately of the residual fuel sample or approximatelyof the blended distillate fuel sample prepared as in Clause 8, and
