1、BRITISH STANDARD AEROSPACE SERIES BS ISO 14952-3:2003 Space systems Surface cleanliness of fluid systems Part 3: Analytical procedures for the determination of nonvolatile residues and particulate contamination ICS 49.080; 49.140 BS ISO 14952-3:2003 This British Standard was published under the auth
2、ority of the Standards Policy and Strategy Committee on 27 February 2004 BSI 27 February 2004 ISBN 0 580 43464 8 National foreword This British Standard reproduces verbatim ISO 14952-3:2003 and implements it as the UK national standard. The UK participation in its preparation was entrusted to Techni
3、cal Committee ACE/68, Space systems and operations, which has the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international publications referred to in this document may b
4、e found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are
5、 responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and
6、keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the ISO title page, pages ii to v, a blank page, pages 1 to 15 and a back cover. The BSI copyright not
7、ice displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date Comments Reference number ISO 14952-3:2003(E) OSI 3002INTERNATIONAL STANDARD ISO 14952-3 First edition 2003-11-15 Space systems Surface cleanliness of fluid systems Part 3: A
8、nalytical procedures for the determination of nonvolatile residues and particulate contamination Systmes spatiaux Propret des surfaces en contact avec des fluides Partie 3: Modes opratoires analytiques pour la dtermination des residus non volatils et de la contamination particulaire BSISO149523:2003
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14、Foreword iv Introduction v 1 Scope 1 2 Normative references. 1 3 Terms and definitions. 1 4 Acceptance inspection. 2 4.1 General. 2 4.2 Visual inspection. 2 4.3 Acidity and alkalinity test. 2 4.4 Acceptance inspection of items cleaned in a controlled environment . 2 4.5 Acceptance inspection of item
15、s cleaned in the field 6 4.6 Acceptance inspection of packaging materials. 7 4.7 Acceptance inspection of items by functional test .9 5 Sampling and analytical practices 9 5.1 Cleanliness level test methods 9 5.2 Microscopic particle population 12 5.3 Gravimetric NVR analysis method 12 5.4 Aqueous u
16、ltrasonic sampling and total carbon (TC) NVR analysis 13 Annex A (informative) Sensitivity factor calculation. 15 BSISO149523:2003ISO 14952-3:2003(E) iv I SO 3002 All irhgts seredevrForeword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodi
17、es (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations
18、, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the IS
19、O/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the
20、member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 14952-3 was prepared by Technical Committee ISO/TC 20, Aircraft and
21、 space vehicles, Subcommittee SC 14, Space systems and operations. ISO 14952 consists of the following parts, under the general title Space systems Surface cleanliness of fluid systems: Part 1: Vocabulary Part 2: Cleanliness levels Part 3: Analytical procedures for the determination of nonvolatile r
22、esidues and particulate contamination Part 4: Rough-cleaning processes Part 5: Drying processes Part 6: Precision-cleaning processes BSISO149523:2003IS-25941 O3:(3002E) I SO 3002 All irhgts seredevr vIntroduction This part of ISO 14952 defines sampling and analytical methods to verify cleanliness le
23、vels for parts and components used in space fluid systems. It can be used to determine the cleanliness level of precision- cleaned parts and components used in ground support equipment, launch vehicles and spacecraft. BSISO149523:2003BSISO149523:2003INTENRATIONAL TSANDADR IS-25941 O3:(3002E)I SO 300
24、2 All irhgts seredevr 1Space systems Surface cleanliness of fluid systems Part 3: Analytical procedures for the determination of nonvolatile residues and particulate contamination 1 Scope This part of ISO 14952 provides sampling and analytical test methods to validate the cleanliness levels of parts
25、 and components that have been precision cleaned, and identifies processes that may be used for the verification of cleanliness in ground support equipment, launch vehicles and spacecraft. This part of ISO 14952 is used to sample and verify the level of cleanliness of parts and components that have
26、been precision cleaned and applies equally to parts, components and systems in ground support equipment, launch vehicles and spacecraft. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited appl
27、ies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 2210:1972, Liquid halogenated hydrocarbons for industrial use Determination of residue on evaporation ISO 5789:1979, Fluorinated hydrocarbons for industrial use Determination of non-vol
28、atile residue ISO 5884:1987, Aerospace Fluid systems and components, Methods for system sampling and measuring the solid particle contamination of hydraulic fluids ISO 14951-3:1999, Space systems Fluids characteristics Part 3: Nitrogen ISO 14951-4:1999, Space systems Fluids characteristics Part 4: H
29、elium ISO 14951-10:1999, Space systems Fluids characteristics Part 10: Water ISO 14952-1:2003, Space systems Surface cleanliness of fluid systems Part 1: Vocabulary ISO 14952-5:2003, Space systems Surface cleanliness of fluid systems Part 5: Drying processes 3 Terms and definitions For the purposes
30、of this document, the terms and definitions given in ISO 14952-1 apply. BSISO149523:2003ISO 14952-3:2003(E) 2 I SO 3002 All irhgts seredevr4 Acceptance inspection 4.1 General Unless otherwise specified by the customer, acceptance inspection shall be performed as specified in 4.2 to 4.7. 4.2 Visual i
31、nspection 4.2.1 The surfaces of all items that will contact the service medium shall be visually inspected for the presence of moisture, corrosion, scale, dirt, grease and other foreign matter. An external light source or borescope may be required to examine internal surfaces. 4.2.2 Items having lim
32、ited accessibility for visual inspection shall be accepted or rejected on the basis of the quality assurance inspections of 4.3, 4.4 and 4.5. The presence of visible contamination that discloses a particle population greater than the level specified shall be cause for rejection. Discoloration of a s
33、urface due to welding and passivation shall be permitted provided no weld scale or other contaminants remain. 4.3 Acidity and alkalinity test All surfaces that have been cleaned shall be tested for acidity and alkalinity with pH paper while the surfaces are wet from the final water rinse. Dry surfac
34、es of completed items shall be wetted with a few drops of high purity water, with a pH range of 5,0 to 8,0, meeting the requirements of ISO 14951-10, to permit testing as required. When tested, the pH shall range from 5,0 to 8,0. 4.4 Acceptance inspection of items cleaned in a controlled environment
35、 4.4.1 General Items cleaned in a controlled environment, except those processed to level visually clean (VC) and/or level visually clean and inspected with the aid of an ultraviolet (UV) light, shall be tested for conformance to the applicable cleanliness level by the test fluid-flush procedure giv
36、en in 4.4.2 to 4.5.4. 4.4.2 Test fluids The test fluids shall not react with, combine with, etch, or otherwise cause immediate or latent degradation of the item being tested, and shall be selected from those specified in Table 1, unless otherwise approved by the customer. The test fluid shall meet t
37、he following requirements. a) The test fluid shall be filtered to remove particulates greater than 1 m and shall not exceed 10 mg/l of nonvolatile residue (NVR) (see ISO 5789). For particle analysis where NVR analysis is not required, the maximum allowable NVR level of the test solvent shall not exc
38、eed 50 mg/l. b) Isopropanol and ethanol shall not be used as the test fluid for oxidizer systems and hardware unless the softgoods are removed or are applied with a suitable pretreatment process. Softgoods for oxidizer systems should be cleaned with a waterbased process and blown dry with Type A nit
39、rogen conforming to ISO 14951-3. If the softgoods are cleaned with isoproanol or ethanol purge, the softgoods shall be purged with Type A nitrogen conforming to ISO 14951-3, until the methane hydrocarbon equivalent of the effluent gas does not exceed that of the source gas. Alternatively, the softgo
40、ods may be vacuum dried as described in ISO 14952-5:2003, 5.2. c) Subtraction of the test fluid blank particle count from the test sample particle count shall not be allowed. d) The quality of the test fluids shall be verified at least once a day prior to use. e) Some test fluids may have low thresh
41、old limit values; therefore, chemical hygiene tables should be consulted prior to use. BSISO149523:2003ISO 14952-3:2003(E) I SO 3002 All irhgts seredevr 3f) The NVR of the flushing solvent should be less than or equal to the NVR of the cleanliness level being verified. g) The test fluids shall be co
42、mpatible with the fluid used in the system or components being tested. WARNING Halogenated solvents shall not be used on titanium alloys. 4.4.3 Test fluid volume for analysis The test fluid volume required for analysis shall be dependent upon the analytical method employed. The standard test sample
43、shall be 500 ml of test fluid to ensure that all critical surfaces are flushed. The 500-ml sample of test fluid shall represent a minimum surface area of 0,1 m 2to a maximum of 0,5 m 2 . For very large items, the volume of flushing solvent should correlate to a minimum sampling area. In cases where
44、all critical surfaces can be sampled with 100 ml of test fluid and the analytical method requires 100 ml or less of test fluid, a 100 ml sample of test fluid shall be allowed to represent 0,1 m 2of critical surface area, if approved by the customer. Table 1 Solvents, maximum allowable nonvolatile re
45、sidue Maximum allowable NVR Test fluid Solvent General use mg/l Oxidizer mg/l Perfluoro-n-butyl methyl ether (C 4 F 9 OCH 3 ) 10 10 Tetrachloroethylene a10 10 Perfluoro-n-butyl methyl ether (20 % to 80 % by mass) and perfluoroisobutyl methyl ether (20 % to 80 % by mass) 10 10 Isopropanol 10 not allo
46、wed Ethanol 10 not allowed Azeotrope of HFC 43-10 MEE (62 % by mass ) and trans- 1,2-dichloroethylene (38 % by mass) a10 10 HCFC - 225 ca/cb a10 10 HCFC-141b a10 10 HFC 43-10 MEE a10 10 HFE 7100 10 10 HFE 71DE 10 10 aThese solvents have low threshold limit values and may pose a hazard in controlled
47、areas or cleanrooms.4.4.4 Test fluid-flush procedure (solvent) The fluid-flush procedure shall be as follows. a) Ascertain the test procedure and total volume of test fluid necessary to flush the cleaned item or items in accordance with Method I (see 5.1.1). b) Flush all critical surfaces uniformly
48、with the test fluid. Tubing, piping and hoses shall be flushed in accordance with either Method I or Method II (see 5.1.1 and 5.1.2). Where flushing does not reach all interior surfaces, the test fluid shall be introduced and the item shall be manually shaken or rolled until all interior surfaces ar
49、e wetted. Large, difficult-to-flush items may be positioned so that the vessel can be filled from the bottom and overflowed from the top. BSISO149523:2003IS-25941 O3:(3002E) 4 I SO 3002 All irhgts seredevrc) Catch the test fluid in a precision-cleaned container. d) Immediately upon the completion of step c), dry the tested items in accordance with the applicable drying procedure. Some analytica
