BS PD CEN TR 16741-2015 Textiles and textile products Guidance on health and environmental issues related to chemical content of textile products intended for clothing interior tex.pdf

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1、BSI Standards PublicationPD CEN/TR 16741:2015Textiles and textile products Guidance on health andenvironmental issues relatedto chemical content of textileproducts intended for clothing,interior textiles and upholsteryPD CEN/TR 16741:2015 PUBLISHED DOCUMENTNational forewordThis Published Document is

2、 the UK implementation of CEN/TR16741:2015.The UK participation in its preparation was entrusted to TechnicalCommittee TCI/80, Chemical testing of textiles.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include al

3、l the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2015. Published by BSI StandardsLimited 2015ISBN 978 0 580 85884 0ICS 59.080.01Compliance with a British Standard cannot confer immunity fromlegal obligations.This Published D

4、ocument was published under the authority of theStandards Policy and Strategy Committee on 31 August 2015.Amendments issued since publicationDate Text affectedPD CEN/TR 16741:2015TECHNICAL REPORT RAPPORT TECHNIQUE TECHNISCHER BERICHT CEN/TR 16741 August 2015 ICS 59.080.01 English Version Textiles an

5、d textile products - Guidance on health and environmental issues related to chemical content of textile products intended for clothing, interior textiles and upholstery Textiles et produits textiles - Guide sur les consquences environnementales et sur la sant lies aux substances chimiques prsentes d

6、ans les produits textiles destins lhabillement, aux textiles dintrieur et lameublement Textilien und textile Erzeugnisse - Anleitung fr Gesundheits-und Umweltfragen in Bezug auf den Chemikaliengehalt von Textilerzeugnissen fr Bekleidung, Heimtextilien und Polstermbel This Technical Report was approv

7、ed by CEN on 14 May 2015. It has been drawn up by the Technical Committee CEN/TC 248. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Icel

8、and, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Manag

9、ement Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TR 16741:2015 EPD CEN/TR 16741:2015CEN/TR 16741:2015 (E) 2 Contents Page European foreword .4 Introduction .5 1 Scope 6 2 Terms a

10、nd definitions .6 3 General recommendations .7 3.1 CMR chemicals 7 3.2 PBT and vPvB substances .7 3.3 SVHC (“Substances of Very High Concern”) 7 4 Specific criteria for textile products 8 4.1 Formaldehyde . 14 4.1.1 General . 14 4.1.2 Why is it a critical substance? 14 4.1.3 Regulation/Specific test

11、s method . 15 4.2 Chlorophenols (pentachlorophenol, isomers of tetrachlorophenol) 15 4.2.1 General . 15 4.2.2 Why is PCP a critical substance? . 15 4.2.3 Regulation/Specific tests method . 15 4.3 Orthophenylphenol (OPP) 16 4.3.1 General . 16 4.3.2 Why is it a critical substance? 16 4.3.3 Tests metho

12、d . 16 4.4 Heavy metals . 16 4.4.1 General . 16 4.4.2 Extractable heavy metals . 17 4.4.3 Total heavy metal 17 4.4.4 Antimony -Sb . 17 4.4.5 Arsenic As 18 4.4.6 Barium Ba . 19 4.4.7 Cadmium Cd . 20 4.4.8 Chromium Cr 21 4.4.9 Cobalt Co 22 4.4.10 Copper Cu . 23 4.4.11 Lead Pb . 24 4.4.12 Mercury Hg .

13、26 4.4.13 Nickel Ni 27 4.4.14 Selenium Se 30 4.5 Flame retardants . 30 4.5.1 General . 30 4.5.2 Why is it a critical substance? 30 4.5.3 Regulation/Specific test methods . 31 4.6 Carcinogenic dyes, suspected dyes and derived substances 31 4.6.1 General . 31 4.6.2 Carcinogenic amines derived from azo

14、 colorants 32 4.6.3 Carcinogenic colorants and colorants suspected to be carcinogenic, mutagenic or toxic to reproduction . 32 4.6.4 Sensitizing colorants 33 4.7 Sensitizing substances (others than colorants) 34 4.8 Pesticides, herbicides and fungicides . 34 4.8.1 General . 34 PD CEN/TR 16741:2015CE

15、N/TR 16741:2015 (E) 3 4.8.2 Why is it a critical substance? . 35 4.8.3 Regulation/Specific test methods 35 4.9 Chloroorganics including carriers (chlorinated benzenes, chlorinated toluenes and chlorinated naphtalenes) 37 4.9.1 General . 37 4.9.2 Why is it a critical substance? . 37 4.9.3 Regulation/

16、Specific tests method 37 4.10 Phthalates. 38 4.10.1 General . 38 4.10.2 Why is it critical? . 38 4.10.3 Regulations / Specific test method 38 4.11 Organotin compounds 39 4.11.1 General . 39 4.11.2 Why is it critical? . 39 4.11.3 Regulations / Specific test method 39 4.12 Perfluorooctanesulfonates (P

17、FOS) and perfluorooctanoic acid (PFOA) . 40 4.12.1 General . 40 4.12.2 Why is it a critical substance? . 40 4.12.3 Regulations/Test method 41 4.13 Dimethylfumarate (DMFu) . 41 4.13.1 General . 41 4.13.2 Why is it a critical substance? . 41 4.13.3 Regulation/Specific test methods 42 4.14 Alkyl phenol

18、 ethoxylates (APEO) . 42 4.14.1 General . 42 4.14.2 Why are APEO critical substances? 43 4.14.3 Regulations/Test methods 43 4.15 Residual solvents 43 4.15.1 General . 43 4.15.2 Why is it critical? . 43 4.15.3 Regulations / Specific test method 44 5 Others . 44 5.1 pH 44 5.1.1 General . 44 5.1.2 Why

19、is it critical? . 44 5.1.3 Regulation/Specific tests method 44 5.2 Colour fastness in relation to acidic and alkaline perspiration (recommendation for screening). 44 5.3 Polycyclic aromatic hydrocarbons (PAH) (screening when strong odour) 44 5.3.1 General . 44 5.3.2 Why is it critical? . 45 5.3.3 Re

20、gulations / Specific test method 45 Annex A (informative) Risk phrases 46 Annex B (informative) Criteria for the identification of persistent, bioaccumulative and toxic substances, and very persistent and very bioaccumulative substances . 47 B.1 General . 47 B.2 PBT substances . 47 B.3 vPvB substanc

21、es . 48 Bibliography 49 PD CEN/TR 16741:2015CEN/TR 16741:2015 (E) 4 European foreword This document (CEN/TR 16741:2015) has been prepared by Technical Committee CEN/TC 248 “Textiles and textile products”, the secretariat of which is held by BSI. Attention is drawn to the possibility that some of the

22、 elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. PD CEN/TR 16741:2015CEN/TR 16741:2015 (E) 5 Introduction In 2003, the company CREM (Consultancy and Research for Environmental Management, A

23、msterdam, The Netherlands) started reviewing a selected number of European standards to identify relevant environmental concerns which should be addressed. Horizontal requirements were drafted during the continuing work on draft standards. These horizontal requirements comprise, among others, CMR ch

24、emicals (carcinogenic, mutagenic and toxic to reproduction), PBTs and vPvB substances (persistent, bioaccumulative and toxic and very persistent and very bioaccumulative substances) and substances identified as causing serious and irreversible effects to humans or the environment equivalent to the e

25、ffects mentioned on a case-by-case basis, such as endocrine disrupters. CEN/TC248 has decided to adopt the proposal included in the study as a technical report with general requirements for textile products with direct skin contact. The working group extended the scope of the technical report to tex

26、tile products in the proximity of the human body . In this technical report, the wording textile product is used, as defined in the Textile Fibre Regulation (EU) No 1007/2011. In the parts where REACH is described, the wording textile article is used in the same meaning. Thus, in the context of this

27、 technical report textile product and textile article are the same. PD CEN/TR 16741:2015CEN/TR 16741:2015 (E) 6 1 Scope This Technical Report specifies environmental and health recommendations for textile products (including accessories) with direct skin contact and in the proximity of the human bod

28、y. This Technical Report facilitates the understanding of chemicals with intended uses in the manufacturing of goods in the fields of textile products intended to clothing, interior textiles and upholstery, to comply with the European chemical regulations and recommendations in force in EU. WARNING

29、This Technical Report is not intended to substitute the existing regulations. The reader is requested to check the current existing regulation. By suggesting that the textile market follows the ethos of this Technical Report, and thereby avoiding the use of unwanted substances in the manufacture of

30、textile products, the level of protection of human health and of environment will be increased. The distinguishing properties of the chemicals and the processes in which they are used (intended use substances) or they occur (unintended release substances) are described in this technical report. This

31、 Technical Report mentions, when relevant, the existing standardized test methods commonly in use, as well as, the related limit values which are generally accepted. Only the standard identification number is given in the main text and the related title is listed in Bibliography. NOTE 1 When limit v

32、alues are given, possible contamination by the external environment and inaccuracy in the measurement of very low concentration may be taken into consideration. The listed substances of this Technical Report can be categorised in two: one related to intended use, another one related to unintended re

33、lease. NOTE 2 Inclusion in the candidate list of EU REACH Regulation (EC) n1907/2006 has been mentioned in this Technical Report for some substances. This does not necessarily mean that a substance, for which such a note is not made, would not be included in the candidate list in the future (new sub

34、stances are regularly included in the list). NOTE 3 For filling material such as “feather wall and floor coverings are excluded SOURCE: EU fibre composition Regulation (EC) n1007/2011 2.3 fibres, yarn and fabric intended for use in textile clothing and accessories or interior textiles PD CEN/TR 1674

35、1:2015CEN/TR 16741:2015 (E) 7 Note 1 to entry: For textile clothing and accessories and for interior textiles: down, feathers, membranes and coatings need not be taken into account in the calculation of the percentage of textile fibres. 2.4 CMR chemical chemical (substance or substance mixtures) bel

36、onging to at least one of three different categories: Carcinogenic, Mutagenic and Reprotoxic (toxic to reproduction) Note 1 to entry: CMR chemicals are classified according to EU Classification Labelling Packaging Regulation (EC) n1272/2008 and are covered by the following R-phrases: R40, R45, R46 R

37、49, R60, R61, R62, R63 and R68 (see Annex A). 2.5 PBT and vPvB substances Persistent, Bio accumulative and Toxic substances and very Persistent and very Bio accumulative substances Note 1 to entry: The terms of PBT and vPvB substances are defined in EU REACH Regulation (EC) n1907/2006 2.6 Substances

38、 of Very High Concern (SVHC) substances which should be treated with equivalent concern as CMR chemical and PBT and vPvB substances. Note 1 to entry: These substances for which there is scientific evidence of probable serious effect to human health or the environment which give rise to an equivalent

39、 level of concern to CMR and/or PBT and/or vPvB substances. 3 General recommendations 3.1 CMR chemicals The product should not contain or release any carcinogenic, mutagenic or reprotoxic chemicals (CMR chemicals) in amounts exceeding 0,1 % by weight of the whole product. 3.2 PBT and vPvB substances

40、 The product should not contain any PBT and vPvB substances which meet the criteria in Annex XIII of EU REACH Regulation (EC) n1907/2006, in amounts exceeding 0,1 % by weight of the whole product. 3.3 SVHC (“Substances of Very High Concern”) SVHC are defined in Article 57 of EU REACH Regulation (EC)

41、 n1907/2006 and include substances which are: Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC. This directive was recently replaced by the new EU Classification Labelling Packaging Regulation (

42、EC) n1272/2008 on classification, labelling and packaging of chemical substances and mixtures, the so-called CLP Regulation. According to the new CLP Regulation these substances shall be classified as 1a or 1b. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (

43、vPvB) according to the criteria in Annex XIII of EU REACH Regulation (EC) n1907/2006, Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters, alle

44、rgenic substances and sensitizing substances) NOTE The list of identified substances of very high concern is updated regularly. The current listing can be found at http:/echa.europa.eu/candidate-list-table. The obligations relating to placing on the market articles containing SVHC PD CEN/TR 16741:20

45、15CEN/TR 16741:2015 (E) 8 substances can be reviewed on ECHA webpages. Uses of some SVHCs in the EU require authorization. More information on this can also be found at http:/echa.europa.eu/ . 4 Specific criteria for textile products The criteria are listed in Table 1 in relation to the type of fibr

46、es and in Table 2 in relation to the type of finishing and accessories. PD CEN/TR 16741:2015CEN/TR 16741:2015 (E) 9 Table 1 Criteria in relation to the type of fibres Type of fibres a)natural fibres man-made fibres Criteria Animal fibres Cellulose fibres Polyester Polyamide Acetate; Triacetate Acryl

47、ic Viscose Elastane Elastodiene Formaldehyde X X X Azo dyes X X X X X X X Extractable heavy metals Cd X X X X X X As X Hg X Ni X Cu X X Pb X X Cr X X Co X X X Sb X Chromium (VI) X X Chlorinated Phenols PCP, TeCP, TriCP X X X X X X X OPP X X X X X X X Carcinogenic dyes X X X X X X X Allergenic Disper

48、se dyes X X X X Chlorinated benzenes and toluenes X X X X PD CEN/TR 16741:2015CEN/TR 16741:2015 (E) 10 Organotin compounds X X X X X X X X Flame retardants X X X X X X X Acrylonitrile X Pesticides X X Herbicides X Dimethylformamide (DMF) X Dimethylfumarate (DMFu) X x X X X X X APEO X X X X X X X DMA

49、 X X X PFOSb)X X X X X X X PAH X X X X X X X a)In case of fibre blends, all criteria related to the fibre of the blends have to be considered. b)only for water-, oil- and dirt- repellent finish or coated PD CEN/TR 16741:2015CEN/TR 16741:2015 (E) 11 Table 2 Criteria in relation to the type of finishing and components used on textile products (buttons, slide fasteners, buckles, etc.) Crite

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