1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationPD CEN/TR 15990:2010Data Sheets Footwear TestsMaterials and Test AdhesivesIncorporating corrigendum November 2010National forewordThis Published Document is the UK implementation
2、 of CEN/TR 15990:2010, incorporating corrigendum November 2010.The start and finish of text introduced or altered by CEN corrigendum November 2010 is indicated in the text by tags .The UK participation in its preparation was entrusted to Technical Committee PRI/52, Adhesives.A list of organizations
3、represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. BSI 2011 ISBN 978 0 580 73895 1 ICS 61.060; 83.180 This Published Document was publish
4、ed under the authority of the Standards Policy and Strategy Committee on 31 July 2010.Amendments issued since publication Date Text affected31 March 2011 I mplementation of CEN corrigendum November 2010PD CEN/TR 15990:2010 PUBLISHED DOCUMENTTECHNICAL REPORT RAPPORT TECHNIQUE TECHNISCHER BERICHT CEN/
5、TR 15990 July 2010 ICS 61.060; 83.180 English Version Data Sheets - Footwear Tests Materials and Test Adhesives Fiches techniques - Matriaux et colles pour essais des articles chaussants Datenbltter - Schuh-Testwerkstoffe und Schuh-Testklebstoffe This Technical Report was approved by CEN on 28 Decem
6、ber 2009. It has been drawn up by the Technical Committee CEN/TC 193. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Mal
7、ta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of expl
8、oitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TR 15990:2010: EIncorporating corrigendum November 2010PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 2 Contents Page Foreword 3Introduction .41 Scope 62 Normative references 63 Test materials .73.1 Test mater
9、ial L173.2 Test material L273.3 Test material SBR 83.4 Test material NBR 93.5 Test material SBS . 103.6 Test material PVC . 113.7 Test material EVA . 114 Test adhesives 124.1 Test adhesive CR1 124.2 Test adhesive CR2 134.3 Test adhesive PU1 144.4 Test adhesive PU2 144.5 Test adhesive PUD1 . 154.6 Te
10、st adhesive PUD2 . 15PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 3 Foreword This document (CEN/TR 15990:2010) has been prepared by Technical Committee CEN/TC 193 “Adhesives”, the secretariat of which is held by AENOR. Attention is drawn to the possibility that some of the elements of this document may
11、 be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 4 Introduction For testing adhesive bonds some important European Standards have been developed by CEN/TC 193/Working Group 5 “A
12、dhesives for Leather and Footwear“ in close cooperation with European Shoe Institutes and the “Association of European Adhesive and Sealant Manufacturers (FEICA)“: EN 1392:2006, Adhesives for leather and footwear materials Solvent-based and dispersion adhesives Testing of bond strength under specifi
13、ed conditions EN 15062:2006, Adhesives for leather and footwear materials Solvent-based and dispersion adhesives Testing ageing of bonds under specified conditions EN 15307:2007, Adhesives for leather and footwear materials Sole-upper bonds Minimum strength requirement These European Standards inten
14、d to serve: the manufactures of shoe materials for testing the bondability of their products; the adhesive manufactures to determine the bond properties of their adhesives; the shoe industry to test the suitability of the materials and/or adhesives before applying in their production line and for qu
15、ality control. In the footwear industry a large number of different solvent or dispersion adhesives are applied for sole-upper bonding offering a broad range of technical effects. The most important and most often adhesives used are based on polyurethane and polychloroprene. For research, developmen
16、t and quality certification purposes some simply formulated 1- and 2-part “reference test adhesives“ have been developed which can be considered as typical adhesives of these types. In footwear manufacture also a great number of the different sole and upper materials are used. From the most importan
17、t and most often applied some materials have been selected as “reference test materials“. The annexed data sheets offer for each of these reference test adhesives and reference test materials some information and specify some properties. CEN/TC193 Working Group 5 takes care for a continuous updating
18、 of these data sheets. For further information on a reference test adhesive or a reference test material (e.g. on availability and supply) please contact the European Shoe Institute mentioned in its data sheet: INSTITUTO TECNOLGICO DEL CALZADO Y CONEXAS (INESCOP) Polig. Ind. Campo Alto - Aptdo. 253
19、03600 Elda- Alicante Espaa Phone: +34 965 39 52 13; Fax: +34 965 38 10 45 E-Mail: inescopinescop.es or respectively PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 5 PRF- UND FORSCHUNGSINSTITUT e.V. (PFI) Marie-Curie-Strae 19 D-66953 Pirmasens Phone: +49 6331 24900; Fax: +49 6331 249060 E-Mail: infopfi-pi
20、rmasens.de or respectively Lederinstitut Gerberschule Reutlingen Erwin-Seiz-Str. 9, D-72764 Reutlingen Phone: +49 7121 16230; Fax: +49 7121 45493 SAFETY STATEMENT Persons using this document should be familiar with the normal laboratory practice, if applicable. This document does not purport to addr
21、ess all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any regulatory conditions. ENVIRONMENTAL STATEMENT It is understood that some of the material permitted in this sta
22、ndard may have negative environmental impact. As technological advantages lead to acceptable alternatives for these materials, they will be eliminated from this standard to the extent possible. At the end of the test, the user of the standard shall take care to carry out an appropriate disposal of t
23、he wastes, according to local regulation. PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 6 1 Scope For research, development and quality certification purposes, some simply formulated 1- and 2-part “reference test adhesives“ have been developed and, from the most important and most often applied, some ma
24、terials have been selected as “reference test materials“. This technical report offers for each of these reference test adhesives and reference test materials some information and specify some properties. CEN/TC 193/WG 5 takes care for a continuous updating of these data sheets. 2 Normative referenc
25、es The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1392, Adhesives for leather and footwear ma
26、terials Solvent-based and dispersion adhesives Testing of bond strength under specified conditions EN 12092, Adhesives Determination of viscosity EN ISO 868, Plastics and ebonite Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868:2003) EN ISO 1183-1, Plastics Met
27、hods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration method (ISO 1183-1:2004) EN ISO 2420, Leather Physical and mechanical tests Determination of apparent density (ISO 2420:2002) EN ISO 3376, Leather Physical and mechanical tests
28、Determination of tensile strength and percentage extension (ISO 3376:2002) EN ISO 4045, Leather Chemical tests Determination of pH (ISO 4045:2008) EN ISO 4047, Leather Determination of sulphated total ash and sulphated water-insoluble ash (ISO 4047:1977) EN ISO 4048, Leather Chemical tests Determina
29、tion of matter soluble in dichloromethane and free fatty acid content (ISO 4048:2008) EN ISO 5398-3, Leather Chemical determination of chromic oxide content Part 3: Quantification by atomic absorption spectrometry (ISO 5398-3:2007) ISO 34 (all parts), Rubber, vulcanized or thermoplastic Determinatio
30、n of tear strength ISO 37, Rubber, vulcanized or thermoplastic Determination of tensile stress-strain properties ISO 247, Rubber Determination of ash ISO 1407, Rubber Determination of solvent extract ISO 2781, Rubber, vulcanized or thermoplastic Determination of density ISO 4649, Rubber, vulcanized
31、or thermoplastic Determination of abrasion resistance using a rotating cylindrical drum device ISO 7619, Rubber, vulcanized or thermoplastic Determination of indentation hardness PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 7 3 Test materials 3.1 Test material L1 Description Chrome tanned cowhide upper
32、 leather, full grain Information Lederinstitut Gerberschule Reutlingen Erwin-Seiz-Str. 9, D-72764 Reutlingen Phone: +49 7121 16230; Fax: +49 7121 162311 Designation Test upper leather L 1 Thickness: 1,5 mm to 1,8 mm Colour: green brown Formulation Raw material: Cowhides of South Germany, weight clas
33、s 25 kg to 29,5 kg Manufacturing method: specified by Lederinstitut Gerberschule Reutlingen Table 1 Technical Data of Test Material L1 Technical Data Unit Nominal Tolerance Standard Apparent density g/m30,7 0,1 EN ISO 2420 Tensile strength N/mm2 21 - EN ISO 3376 Elongation at break % Max. 80 - EN IS
34、O 3376 Ashes at 800 C % 6,0 1,0 EN ISO 4047 Chrome oxide % - EN ISO 5398-3 pH-value - 3,5 - EN ISO 4045 Dichloro methane extract % 8,0 2,0 EN ISO 4048 Bonding properties: Test Adhesives PU 1, PU 2, CR 1, CR 2, PUD 1 and PUD 2 (according to EN 1392) 3.2 Test material L2 Description Vegetably tanned s
35、oling leather, butt Information Lederinstitut Gerberschule Reutlingen Erwin-Seiz-Str. 9, D-72764 Reutlingen Phone: +49 7121 16230; Fax: +49 7121 162311 Designation Test upper leather L 2 PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 8 Thickness: 3,8 mm to 4,5 mm Colour: brown Formulation Raw material: M
36、anufacturing method: specified by Lederinstitut Gerberschule Reutlingen Table 2 Technical Data of Test Material L2 Technical Data Unit Nominal Tolerance Standard Apparent density g/m3Max. 1,15 - EN ISO 2420 Tensile strength N/mm2 19 - EN ISO 3376 Elongation at break % Max. 30 - EN ISO 3376 Ashes at
37、800 C % Max. 1,3 - EN ISO 4047 pH-value - 3,5 - EN ISO 4045 Dichloro methane extract % Max. 2,0 - EN ISO 4048 Bonding properties: Test Adhesives PU 1, PU 2, CR 1, CR 2, PUD 1 and PUD 2 (according to EN 1392) 3.3 Test material SBR Description Synthetic rubber vulcanizate, transparent Information Prf-
38、 und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens Designation Durotrans1Formulation SBR: silica zinc oxide colour pigments 1Durotrans is the tradename of a product supplied by ContiTech Formteile/Schuhbedarf, D-Hannover. This information is given for the conven
39、ience of users of this CEN Report and does not constitute an endorsement by CEN. Equivalent products may be used if they can be shown to lead to the same results. PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 9 Table 3 Technical Data of Test Material SBR Technical Data Unit Nominal Tolerance Standard Ra
40、w density g/m31,17 0,02 ISO 2781 Tensile strength N/mm2 13 - ISO 37 Elongation at break % 500 - ISO 37 Hardness ShoreA 70 3 EN ISO 868 Abrasion mm3 210 30 ISO 4649 Ashes at 950 C % 31,0 2,0 ISO 247 Acetone extract % 6,0 0,5 ISO 1407 Bonding properties: Test Adhesives PU 2 and CR 2 (according to EN 1
41、392 with halogenation) 3.4 Test material NBR Description Oil-resistant, vulcanised nitrile-butadiene soling material Information Prf- und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens Designation CMKX Thickness: 4,0 mm Surface: ripped pattern Colour: dark brown
42、Formulation NBR, 33 % ACN silica plasticizer, reinforcing resin, zinc oxide colour pigments PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 10 Table 4 Technical Data of Test Material NBR Technical Data Unit Nominal Tolerance Standard Raw density g/m31,25 0,02 ISO 2781 Tensile strength N/mm222,0 3,0 ISO 37
43、 Elongation at break % 400 80 ISO 37 Hardness ShoreA 80 3 EN ISO 868 Abrasion mm3150 30 ISO 4649 Ashes at 950 C % 32,0 2,2 ISO 247 Acetone extract % 14,0 1,0 ISO 1407 Bonding properties: Test Adhesives PU 1 and PU 2 (according to EN 1392) 3.5 Test material SBS Description Thermoplastic styrene-butad
44、iene-styrene soling material Information Prf- und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens Designation SBS R 6 Neu - granules SBS R 6 Neu - test sheet Formulation styrene-butadiene-styrene block copolymer polystyrene, silica, plasticizer, Table 5 Technical
45、Data of Test Material SBS Technical Data Unit Nominal Tolerance Standard Raw density g/m30,95 0,03 ISO 2781 Tensile strength N/mm24,0 0,5 ISO 37 Elongation at break % 500 50 ISO 37 Hardness ShoreA 60 2 EN ISO 868 Abrasion mm3150 10 ISO 4649 Ashes at 950 C % 7,6 0,3 ISO 247 Acetone extract % 9,5 0,3
46、ISO 1407 Bonding properties: Test Adhesives PU 1 and PU 2 (according to EN 1392 with halogenation) PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 11 3.6 Test material PVC Description Plasticized polyvinyl chloride soling material Information INSTITUTO TECNOLGICO DEL CALZADO Y CONEXAS (INESCOP) Polig. Ind
47、. Campo Alto - Aptdo. 253 03600 Elda- Alicante Espaa Designation Black PVC Thickness: 5,0 mm Surface: smooth Colour: black Formulation PVC plastiziser dop (36 %), stabilizer, carbon black Table 6 Technical Data of Test Material PVC Technical Data Unit Nominal Tolerance Standard Raw density g/m31,23
48、0,03 ISO 2781 Tensile strength N/mm212,9 1,0 ISO 37 Elongation at break % 300 20 ISO 37 Tear strength N/mm 24,1 1,0 ISO 34 Hardness ShoreA 78 3 EN ISO 868 Abrasion mm3123 10 ISO 4649 Ashes at 950 C % 2,6 0,1 ISO 247 Acetone extract % 53 1,0 ISO 1407 Bonding properties: Test Adhesives PU 1 and PU 2 (
49、according to EN 1392) 3.7 Test material EVA Description Vulcanizate of ethylene-vinylacetate-copolymer and polyisoprene Information Prf- und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens PD CEN/TR 15990:2010CEN/TR 15990:2010 (E) 12 Designation Lunalight2Formulation ethylene-vinylacetate-copolymer polyisoprene silica, colour pigments blowing agent crosslinking agent Table 7
