1、BSI Standards PublicationCopper and copper alloys Compendium of compositions and productsPD CEN/TS 13388:2015National forewordThis Published Document is the UK implementation of CEN/TS 13388:2015.It supersedes PD CEN/TS 13388:2013 which is withdrawn.The UK participation in its preparation was entrus
2、ted to TechnicalCommittee NFE/34, Copper and copper alloys.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisions ofa contract. Users are responsible for its correct application. The B
3、ritish Standards Institution 2015.Published by BSI Standards Limited 2015ISBN 978 0 580 87727 8ICS 77.120.30; 77.150.30Compliance with a British Standard cannot confer immunity fromlegal obligations.This Published Document was published under the authority of theStandards Policy and Strategy Committ
4、ee on 31 May 2015.Amendments/corrigenda issued since publicationDate Text affectedPUBLISHED DOCUMENTPD CEN/TS 13388:2015TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 13388 May 2015 ICS 77.120.30; 77.150.30 Supersedes CEN/TS 13388:2013English Version Copper and copper
5、 alloys - Compendium of compositions and products Cuivre et alliages de cuivre - Inventaire des compositions et des produits Kupfer und Kupferlegierungen - bersicht ber Zusammensetzungen und Produkte This Technical Specification (CEN/TS) was approved by CEN on 21 March 2015 for provisional applicati
6、on. The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to announce the existence
7、of this CEN/TS in the same way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an E
8、N is reached. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands,
9、Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of e
10、xploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TS 13388:2015 EPD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 3 Table 12.3 Ingots and castings Copper-tin alloys Composition and casting processes 41 Table 12.4 Ingots and castings Copper-tin-lead alloys Co
11、mposition and casting processes ) . 42 Table 12.5 Ingots and castings Copper-aluminium alloys Composition and casting processes 44 Table 12.6 Ingots and castings Copper-manganese-aluminium alloys Composition and casting processes . 45 Table 12.7 Ingots and castings Copper-nickel alloys Composition a
12、nd casting processes 45 Table 13 Scrap Composition 46 Table 14 Composition of copper alloy according to EN 50149:2012 50 PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 4 Foreword This document (CEN/TS 13388:2015) has been prepared by Technical Committee CEN/TC 133 “Copper and copper alloys”, the secretar
13、iat of which is held by DIN. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes CEN/TS 13388:2013. In comparison
14、 with CEN/TS 13388:2013, the following changes were made: a) modifications regarding materials and compositions from EN 12420:2014, EN 13600:2013, EN 13601:2013 and EN 13602:2013 considered; b) last paragraph of the “Scope” deleted; c) 3.5 “Composition of filler metals” deleted; d) 4.4 “Filler metal
15、s” deleted; e) Clause 5 “Copper and copper alloys standardised by other CEN Technical Committees” deleted; f) Clause 6 “Copper and copper alloys registered by CEN/TC 133” deleted. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are b
16、ound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
17、Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 5 Introduction CEN/TC 133 “Copper and copper alloys” was established in 1988 to prepare and maintain standards in the field of unwrought, wrought and cast produ
18、cts made from copper and copper alloys. Its responsibilities included developing, defining, specifying and giving guidance on, as appropriate, material compositions, designations, terminology, dimensions and tolerances, mechanical and physical characteristics, conditions of delivery and methods of t
19、esting peculiar to copper and copper alloys. During the development of standards for copper and copper alloy products, the experts realized the necessity and seized the opportunity: a) to coordinate and in some cases also to rationalize the composition limits which already existed for the various pr
20、oduct forms; b) to establish unique, new and identifiably European designations for copper and copper alloys, including a numerical option to be particularly convenient for computerized handling; c) to confirm, clarify and redefine where necessary, the terminology which already existed in common usa
21、ge, at the international level or in customs nomenclature. CEN/TC 133 decided, in view of the new form of presentation and new parameters for the description and provision of information on copper and copper alloy products, to prepare and publish the present consolidation and summary of essential de
22、tails. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 6 1 Scope This Technical Specification provides a summary of material designations, compositions and the product forms in which they are available, for coppers and copper alloys standardized in European Standards by CEN/TC 133 “Copper and copper alloy
23、s”. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any a
24、mendments) applies. EN 1976, Copper and copper alloys Cast unwrought copper products EN 1982:2008, Copper and copper alloys Ingots and castings 3 Compositions of coppers and copper alloys standardised by CEN/TC 133 3.1 Composition of coppers The symbol and number designations and compositions of cop
25、per grades are given in the following tables: Table 1.1 Composition of copper cathodes according to EN 1978:1998, Cu-CATH-1 (CR001A) and Cu-CATH-2 (CR002A) Table 1.2 Composition of unalloyed copper grades made from Cu-CATH-1 (CR001A) according to EN 1978 Table 1.3 Composition of unalloyed copper gra
26、des, other than those made from Cu-CATH-1 (CR001A) according to EN 1978 Table 1.4 Composition of phosphorus-containing copper grades Table 1.5 Composition of silver-containing copper grades (silver-bearing coppers) 3.2 Composition of copper alloys The symbol and number designations and compositions
27、of copper alloys are given in the following tables: Table 2 Composition of copper alloys, low alloyed (less than 5 % alloying elements) Table 3 Composition of copper-aluminium alloys Table 4 Composition of copper-nickel alloys Table 5 Composition of copper-nickel-zinc alloys Table 6 Composition of c
28、opper-tin alloys Table 7 Composition of copper-zinc alloys, binary Table 8 Composition of copper-zinc-lead alloys Table 9 Composition of copper-zinc alloys, complex PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 7 3.3 Composition of master alloys The symbol and number designations and compositions of mas
29、ter alloys in accordance with EN 1981:2003 are given in Table 11. 3.4 Composition of ingots and castings The symbol and number designations and compositions of ingots and castings in accordance with EN 1982:2008 are given in the following tables: Table 12.1 Ingots and castings Copper and copper-chro
30、mium alloys Compositions and casting processes Table 12.2 Ingots and castings Copper-zinc alloys Composition and casting processes Table 12.3 Ingots and castings Copper-tin alloys Composition and casting processes Table 12.4 Ingots and castings Copper-tin-lead alloys Composition and casting processe
31、s Table 12.5 Ingots and castings Copper-aluminium alloys Composition and casting processes Table 12.6 Ingots and castings Copper-manganese-aluminium alloys Composition and casting processes Table 12.7 Ingots and castings Copper-nickel alloys Composition and casting processes 3.5 Composition of coppe
32、r and copper alloy scrap The symbol and number designations and compositions of copper and copper alloy scrap in accordance with EN 12861:1999 are given in Table 13. 4 Available product forms of copper and copper alloys 4.1 Wrought coppers and copper alloys The product forms and applicable standards
33、 are given in Table 10. 4.2 Master alloys The product forms are given in Table 11. 4.3 Ingots and castings The product forms are given in Tables 12.1 to 12.7. 4.4 Scrap The product forms are given in Table 13. 4.5 Copper and copper alloy grooved contact wires The product forms are given in Table 14.
34、 PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 8 Table 1.1 Composition of copper cathodes according to EN 1978:1998, Cu-CATH-1 (CR001A) and Cu-CATH-2 (CR002A) Material designation Composition in % (mass fraction) Element Cu Ag As Bi Cd Co Cr Fe Mn Ni P Pb S Sb Se Si Sn Te Zn Sum of elements listed in th
35、is table other than copper Symbol Number Cu-CATH-1 CR001A min. max. 0,002 5 0,000 5a0,000 20baca0,001 0caca0,000 5 0,001 5d0,000 4a0,000 20bcc0,000 20bc0,006 5 Cu-CATH-2 CR002A min. 99,90e max. 0,000 5 0,005 0,03 excluding Ag a(As + Cd + Cr + Mn + P + Sb) maximum 0,001 5 %. b(Bi + Se + Te) maximum 0
36、,000 3 %, of which (Se + Te) maximum 0,000 30 %. c(Co + Fe + Ni + Si + Sn + Zn) maximum 0,002 0 %. dThe sulfur content shall be determined on a cast sample. eIncluding silver up to a maximum of 0,015 %. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 9 Table 1.2 Composition of unalloyed copper grades made
37、 from Cu-CATH-1 (CR001A) according to EN 1978 Material designation Composition in % (mass fraction) Symbol Number Element Cu Ag As Bi Cd Co Cr Fe Mn Ni O P Pb unwrought copper wrought copper Cu-ETP1 CR003A CW003A min. max. 0,002 5 0,000 5a 0,000 20b a c a 0,001 0c a c 0,040 a 0,000 5 Cu-OF1 CR007A C
38、W007A min. max. 0,002 5 0,000 5a 0,000 20b a c a 0,001 0c a c d a 0,000 5 Cu-OFE CR009A CW009A min. max. 99,99 0,002 5 0,000 5 0,000 20 0,000 1 0,001 0 0,000 5 0,001 0 d 0,000 3 0,000 5 Cu-PHCE CR022A CW022A min. max. 99,99 0,002 5 0,000 5 0,000 20 0,000 1 0,001 0 0,000 5 0,001 0 d0,001 0,006 0,000
39、5 Material designation Composition in % (mass fraction) Symbol Number Element S Sb Se Si Sn Te Zn Elements listed in this table other than copper unwrought copper wrought copper total excluding Cu-ETP1 CR003A CW003A min. max. 0,001 5 0,000 4a 0,000 20b c c 0,000 20b c 0,006 5 O Cu-OF1 CR007A CW007A
40、min. max. 0,001 5 0,000 4a 0,000 20b c c 0,000 20b c 0,006 5 O Cu-OFE CR009A CW009A min. max. 0,001 5 0,000 4 0,000 20 0,000 2 0,000 20 0,000 1 Cu-PHCE CR022A CW022A min. max. 0,001 5 0,000 4 0,000 20 0,000 2 0,000 20 0,000 1 a(As + Cd + Cr + Mn + P + Sb) max. 0,001 5 %. b(Bi + Se + Te) max. 0,000 3
41、 %, of which (Se + Te) max. 0,000 30 %. c(Co + Fe + Ni + Si + Sn + Zn) max. 0,002 0 %. dThe oxygen content shall be controlled by the manufacturer so that the material conforms to the hydrogen embrittlement requirements of EN 1976. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 10 Table 1.3 Composition o
42、f unalloyed copper grades, other than those made from Cu-CATH-1 (CR001A) according to EN 1978 Material designation Composition in % (mass fraction) Symbol Number Other elements (see note) unwrought copper wrought copper Element CuaBi O Pb total excluding Cu-ETP CR004A CW004A min. max. 99,90 0,000 5
43、0,040b 0,005 0,03 Ag, O Cu-FRHC CR005A CW005A min. max. 99,90 0,040b 0,06 dAg, O Cu-FRTP CR006A CW006A min. max. 99,90 0,100 0,05 Ag, Ni, O Cu-OF CR008A CW008A min. max. 99,95 0,000 5 c 0,005 0,03 Ag NOTE The total of other elements (than copper) is defined as the sum of Ag, As, Bi, Cd, Co, Cr, Fe,
44、Mn, Ni, O, P, Pb, S, Sb, Se, Si, Sn, Te and Zn, subject to the exclusion of any individual elements indicated. aIncluding silver, up to a maximum of 0,015 %. bOxygen content up to 0,060 % is permitted, subject to agreement between the purchaser and the supplier. cThe oxygen content shall be controll
45、ed by the manufacturer so that the material conforms to the hydrogen embrittlement requirements of EN 1976. dHigher total impurities content is permitted, subject to agreement between the purchaser and the supplier. Table 1.4 Composition of phosphorus-containing copper grades Material designation Co
46、mposition in % (mass fraction) Symbol Number Other elements (see note) unwrought copper wrought copper Element CuaBi P Pb total excluding Cu-PHC CR020A CW020A min. max. 99,95 0,000 5 0,001 0,006 0,005 0,03bAg, P Cu-HCP CR021A CW021A min. max. 99,95 0,000 5 0,002 0,007 0,005 0,03bAg, P Cu-DLP CR023A
47、CW023A min. max. 99,90 0,000 5 0,005 0,013 0,005 0,03 Ag, Ni, P Cu-DHP CR024A CW024A min. max. 99,90 0,015 0,040 c Cu-DXP CR025A min. max. 99,90 0,000 5 0,04 0,06 0,005 0,03 Ag, Ni, P NOTE The total of other elements (than copper) is defined as the sum of Ag, As, Bi, Cd, Co, Cr, Fe, Mn, Ni, O, P, Pb, S, Sb, Se, Si, Sn, Te and Zn, subject to the exclusion of any individual elements indicated. aIncluding silver, up to a maximum of 0,015 %. bThe oxygen content shall be controlled by the manufacturer so that the material conforms to the hydrogen embrittlement requirements of EN 1976. cIf req
