1、BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06Construction products: Assessment of release of dangerous substances Analysis of inorganic substances in eluatesPD CEN/TS 17195:2018TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 17195 Ju
2、ly 2018 ICS 91.100.01 English Version Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in eluates Produits de construction - Evaluation de lmission de substances dangereuses - Analyse des substances inorganiques dans les luats Bauprodukte - Bewe
3、rtung der Freisetzung von gefhrlichen Stoffen - Analyse von anorganischen Stoffen in Eluaten This Technical Specification (CEN/TS) was approved by CEN on 9 March 2018 for provisional application. The period of validity of this CEN/TS is limited initially to three years. After two years the members o
4、f CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available promptly at national level in a
5、n appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus,
6、Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
7、 Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. C
8、EN/TS 17195:2018 ENational forewordThis Published Document is the UK implementation of CEN/TS 17195:2018.The UK participation in its preparation was entrusted to Technical Committee B/557, Construction products - Assessment of dangerous substances.A list of organizations represented on this committe
9、e can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2018 Published by BSI Standards Limited 2018ISBN 978 0 539 01866 0ICS 91.100.01C
10、ompliance with a British Standard cannot confer immunity from legal obligations.This Published Document was published under the authority of the Standards Policy and Strategy Committee on 31 July 2018.Amendments/corrigenda issued since publicationDate Text affectedPUBLISHED DOCUMENTPD CEN/TS 17195:2
11、018TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 17195 July 2018 ICS 91.100.01 English Version Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in eluates Produits de construction - Evaluation de lmission de subs
12、tances dangereuses - Analyse des substances inorganiques dans les luats Bauprodukte - Bewertung der Freisetzung von gefhrlichen Stoffen - Analyse von anorganischen Stoffen in Eluaten This Technical Specification (CEN/TS) was approved by CEN on 9 March 2018 for provisional application. The period of
13、validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to announce the existence of this CEN/TS in
14、the same way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached. CEN
15、members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Po
16、rtugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploit
17、ation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TS 17195:2018 EPD CEN/TS 17195:2018CEN/TS 17195:2018 (E) 2 Contents Page European foreword . 3 Introduction 4 1 Scope 5 2 Normative references 5 3 Terms and definitions . 6 4 Abbreviations . 8 5 Sample pre-t
18、reatment . 8 6 Selection of suitable analytical test method 9 6.1 Table of test methods 9 6.2 General validation information . 9 7 Method performance 11 8 Expression of results . 11 9 Test report 11 10 Test performance . 12 Annex A (informative) Validation of analytical methods for eluates of waste
19、. 13 A.1 General . 13 A.2 Interlaboratory study . 13 Annex B (informative) Additional validation data for Ba, Cd, Cr, Mo, Sb and Se in eluates using hydride generation 19 B.1 General . 19 B.2 Round robin samples 19 B.3 Results of the round robin test 20 B.4 Conclusion from the round robin test 24 Bi
20、bliography . 25 PD CEN/TS 17195:2018CEN/TS 17195:2018 (E) 3 European foreword This document (CEN/TS 17195:2018) has been prepared by Technical Committee CEN/TC 351 “Construction products: Assessment of release of dangerous substances”, the secretariat of which is held by NEN. Attention is drawn to t
21、he possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all such patent rights. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Associat
22、ion. A similar standard has been developed for eluates from different types of waste, see Annex A. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croati
23、a, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey
24、 and the United Kingdom. PD CEN/TS 17195:2018CEN/TS 17195:2018 (E) 4 Introduction Following an extended evaluation of available methods for content analysis in construction products (CEN/TR 16045, 1) it was concluded that eluate analysis methods are very similar to analytical methods used to determi
25、ne content after digestion of a solid matrix. This document has been adopted from the work carried out in the context of CEN/TC 292 and is very similar to EN 16192 Characterization of waste Analysis of waste eluates 2. This Technical Specification is part of a modular horizontal approach which was a
26、dopted in CEN/TC 351. Horizontal means that the methods can be used for a wide range of materials and products with certain properties. Modular means that a test standard developed in this approach concerns a specific step in assessing a property and not the whole chain of measurement (from sampling
27、 to analyses). Beneficial features of this approach are that modules can be replaced by better ones without jeopardizing the standard chain and duplication of work of in different Technical Committees for Products can be avoided as far as possible. The modules that relate to the standards developed
28、in CEN/TC 351 are specified in CEN/TR 16220 3, which distinguishes between the modules. This Technical Specification belongs to the analytical step. The use of modular horizontal standards implies the drawing of test schemes as well. Before executing a test on a certain construction product to deter
29、mine certain characteristics it is necessary to draw up a protocol in which the adequate modules are selected and together form the basis for the entire test procedure. PD CEN/TS 17195:2018CEN/TS 17195:2018 (E) 5 1 Scope This Technical Specification specifies analytical methods for the determination
30、 of major, minor and trace elements and of anions in aqueous eluates from construction products. It refers to the following 67 elements: Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), cesium (Cs), chromium (
31、Cr), cobalt (Co), copper (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), gold (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), lutetium (Lu), magnesium (Mg), manganese (Mn), mercury (Hg)
32、, molybdenum (Mo), neodymium (Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr), rubidium (Rb), rhenium (Re), rhodium (Rh), ruthenium (Ru), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulphur (S)
33、, tellurium (Te), terbium (Tb), thallium (Tl), thorium (Th), thulium (Tm), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), ytterbium (Yb), yttrium (Y), zinc (Zn), and zirconium (Zr) and to the following four anions: Cl-, Br-, F-, SO42-. The Technical Specification also describes ho
34、w to measure general parameters like pH, electrical conductivity, DOC/TOC. The methods in this Technical Specification are applicable to construction products. NOTE Construction products include e.g. mineral-based products (S); bituminous products (B); metals (M); wood-based products (W); plastics a
35、nd rubbers (P); sealants and adhesives (A); paints and coatings (C), see also CEN/TR 16045. The selection of analytical methods to be applied is based on the required sensitivity of the method, which is provided for all substance - analytical procedure combinations. 2 Normative references The follow
36、ing documents are referred to in the text in such a way that some or all of their content constitutes requirements of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. CEN/TS
37、17197, Construction products: Assessment of release of dangerous substances Analysis of major, minor and trace elements in digests and eluates by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) CEN/TS 17200, Construction products: Assessment of release of dangerous substances Anal
38、ysis of major, minor and trace elements in digests and eluates by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) EN 1484, Water analysis Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) EN 27888, Water quality Determination of electrical conduc
39、tivity (ISO 7888) EN ISO 5667-3, Water quality Sampling Part 3: Preservation and handling of water samples (ISO 5667-3) EN ISO 10304-1, Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate a
40、nd sulfate (ISO 10304-1) PD CEN/TS 17195:2018CEN/TS 17195:2018 (E) 6 EN ISO 10523, Water quality Determination of pH (ISO 10523) EN ISO 12846, Water quality Determination of mercury Method using atomic absorption spectrometry (AAS) with and without enrichment (ISO 12846) EN ISO 15586, Water quality
41、Determination of trace elements using atomic absorption spectrometry with graphite furnace (ISO 15586) EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories (ISO/IEC 17025) EN ISO 17852, Water quality Determination of mercury Method using atomic fluorescen
42、ce spectrometry (ISO 17852) ISO 10359-1, Water quality Determination of fluoride Part 1: Electrochemical probe method for potable and lightly polluted water ISO 17378-1, Water quality Determination of arsenic and antimony Part 1: Method using hydride generation atomic fluorescence spectrometry (HG-A
43、FS) ISO 17378-2, Water quality Determination of arsenic and antimony Part 2: Method using hydride generation atomic absorption spectrometry (HG-AAS) ISO/TS 13530, Water quality Guidance on analytical quality control for chemical and physicochemical water analysis ISO/TS 17379-1, Water quality Determ
44、ination of selenium Part 1: Method using hydride generation atomic fluorescence spectrometry (HG-AFS) ISO/TS 17379-2, Water quality Determination of selenium Part 2: Method using hydride generation atomic absorption spectrometry (HG-AAS) 3 Terms and definitions For the purposes of this document, the
45、 following terms and definitions apply. ISO and IEC maintain terminological databases for use in standardization at the following addresses: IEC Electropedia: available at http:/www.electropedia.org/ ISO Online browsing platform: available at http:/www.iso.org/obp 3.1 eluate solution obtained from a
46、 leaching test SOURCE: EN 12457-1:2002 4, 3.3, modified “recovered” replaced by “obtained 3.2 leachant liquid that is brought into contact with the test portion in the leaching procedure Note 1 to entry: Usually demineralized water is used as leachant for laboratory leaching tests. SOURCE: EN 16687:
47、2015 5 PD CEN/TS 17195:2018CEN/TS 17195:2018 (E) 7 3.3 leaching test laboratory test for the determination of the release of substances from a construction product into a leachant 3.4 sample portion of material selected from a larger quantity of material SOURCE: ISO 11074:2015 6, 4.1.16; modified “s
48、oil deleted”, Note deleted Note 1 to entry: The term “sample” is often accompanied by a prefix (e.g. laboratory sample, test sample) specifying the type of sample and/or the specific step in the sampling process to which the obtained material relates. SOURCE of note: EN 16687:2015 5, 3.2.1 3.5 labor
49、atory sample sample or subsample(s) sent to or received by the laboratory Note 1 to entry: When the laboratory sample is further prepared by subdividing, mixing, diluting, etc. or by combinations of these operations, the result is the test sample. When no preparation of the laboratory sample is required, the laboratory sample is the test sample. A test portion is removed from the test sample for the performance of the test/ analysis. SOURCE: IUPAC 2014 7, modified abridge
