1、BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06Construction products: Assessment of release of dangerous substances Analysis of inorganic substances in digests and eluates Analysis by Inductively Coupled Plasma Mass Spectrometry (ICP-MS)PD CEN/TS 17200:2018TECHNICAL
2、 SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 17200 July 2018 ICS 91.100.01 English Version Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma - Mass Spectrome
3、try (ICP-MS) Produits de construction: valuation des missions de substances dangereuses - Analyse des substances inorganiques dans les digestats et les luats - Analyse par spectromtrie de masse avec plasma couplage inductif Bauprodukte: Beurteilung der Freisetzung von gefhrlichen Stoffen - Analyse v
4、on anorganischen Stoffen in Aufschlusslsungen und Eluaten - Analyse mit induktiv gekoppeltem Plasma - Massenspektrometrie (ICP-MS) This Technical Specification (CEN/TS) was approved by CEN on 2 April 2018 for provisional application. The period of validity of this CEN/TS is limited initially to thre
5、e years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS ava
6、ilable promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached. CEN members are the national standards bodies of Austria
7、, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain,
8、Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation in any form and by any means reserved worldwid
9、e for CEN national Members. Ref. No. CEN/TS 17200:2018 ENational forewordThis British Standard is the UK implementation of CEN/TS 17200:2018.The UK participation in its preparation was entrusted to Technical Committee B/557, Construction products - Assessment of dangerous substances.A list of organi
10、zations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2018 Published by BSI Standards Limited 2018
11、ISBN 978 0 580 85059 2ICS 91.100.01Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 July 2018.Amendments/corrigenda issued since publicationDate Text affectedP
12、UBLISHED DOCUMENTPD CEN/TS 17200:2018TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 17200 July 2018 ICS 91.100.01 English Version Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis
13、by Inductively Coupled Plasma - Mass Spectrometry (ICP-MS) Produits de construction: valuation des missions de substances dangereuses - Analyse des substances inorganiques dans les digestats et les luats - Analyse par spectromtrie de masse avec plasma couplage inductif Bauprodukte: Beurteilung der F
14、reisetzung von gefhrlichen Stoffen - Analyse von anorganischen Stoffen in Aufschlusslsungen und Eluaten - Analyse mit induktiv gekoppeltem Plasma - Massenspektrometrie (ICP-MS) This Technical Specification (CEN/TS) was approved by CEN on 2 April 2018 for provisional application. The period of validi
15、ty of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to announce the existence of this CEN/TS in the sa
16、me way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached. CEN member
17、s are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal
18、, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation
19、in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TS 17200:2018 EPD CEN/TS 17200:2018CEN/TS 17200:2018 (E) 2 Contents Page European foreword . 4 Introduction 5 1 Scope 6 2 Normative references 6 3 Terms and definitions . 7 4 Symbols and abbreviations . 9 5 Princi
20、ple . 9 6 Interferences 9 6.1 General 9 6.2 Spectral interferences . 9 6.2.1 Isobaric elemental interferences 9 6.2.2 Isobaric molecular and doubly charged ion interferences . 10 6.3 Non spectral interferences . 10 7 Reagents 10 8 Apparatus 13 9 Procedure 14 9.1 Test sample 14 9.2 Test portion 14 9.
21、3 Instrument set up . 14 9.4 Calibration 15 9.4.1 Calibration function 15 9.4.2 Standard addition calibration . 15 9.4.3 Determination of correction factors . 16 9.4.4 Variable isotope ratio . 16 9.5 Sample measurement . 16 10 Calculation 16 10.1 Calculation for digests of construction products 16 1
22、0.2 Calculation for eluates of construction products . 17 11 Expression of results . 17 12 Performance characteristics 17 12.1 General . 17 12.2 Blank . 17 12.3 Calibration check . 17 12.4 Internal standard response 17 12.5 Interference . 17 12.6 Recovery 17 12.7 Precision 17 13 Test report 18 PD CE
23、N/TS 17200:2018CEN/TS 17200:2018 (E) 3 Annex A (informative) Method detection limit (MDL) and precision data for soil, sludge and biowaste 20 Annex B (informative) Validation results for construction products . 28 B.1 Introduction 28 B.2 Performance data . 28 Bibliography . 29 PD CEN/TS 17200:2018CE
24、N/TS 17200:2018 (E) 4 European foreword This document (CEN/TS 17200:2018) has been prepared by Technical Committee CEN/TC 351 “Construction products - Assessment of release of dangerous substances”, the secretariat of which is held by NEN. Attention is drawn to the possibility that some of the eleme
25、nts of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all such patent rights. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association. A similar document has been deve
26、loped for drinking water, surface water and waste water and different types of waste respectively, see Annex A. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to announce this Technical Specification: Austria, Belgium, Bul
27、garia, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switze
28、rland, Turkey and the United Kingdom. PD CEN/TS 17200:2018CEN/TS 17200:2018 (E) 5 Introduction Following an extended evaluation of available methods for content and eluate analysis in construction products (CEN/TR 16045; 1) it was concluded that multi element analysis methods have preference over me
29、thods developed for single elements or small groups of elements. This implies that for inorganic substances ICP methods are preferred for the analysis of extracts obtained from digestion or eluates obtained from leaching. This standard has been adopted from the work carried out in the context of CEN
30、/TC 400 (project HORIZONTAL) and is very similar to EN 16171, Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma mass spectrometry (ICP-MS) 2. This Technical Specification is part of a modular horizontal approach which was adopted in CEN/TC 351. Horizontal
31、 means that the methods can be used for a wide range of materials and products with certain properties. Modular means that a test standard developed in this approach concerns a specific step in assessing a property and not the whole chain of measurement (from sampling to analyses). Beneficial featur
32、es of this approach are that modules can be replaced by better ones without jeopardizing the standard chain and duplication of work of in different Technical Committees for Products can be avoided as far as possible. The modules that relate to the standards developed in CEN/TC 351 are specified in C
33、EN/TR 16220, Construction products: Assessment of release of dangerous substances Complement to sampling 3 which distinguishes between the modules. This Technical Specification belongs to the analytical step. The use of modular horizontal standards implies the drawing of test schemes as well. Before
34、 executing a test on a certain construction product to determine certain characteristics it is necessary to draw up a protocol in which the adequate modules are selected and together form the basis for the entire test procedure. PD CEN/TS 17200:2018CEN/TS 17200:2018 (E) 6 1 Scope This Technical Spec
35、ification specifies the method for the determination of major, minor and trace elements in aqua regia and nitric acid digests and in eluates of construction products by Inductively Coupled Plasma - Mass Spectrometry (ICP-MS). It refers to the following 67 elements: Aluminium (Al), antimony (Sb), ars
36、enic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), cesium (Cs), chromium (Cr), cobalt (Co), copper (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), gold (Au), hafnium (Hf), holmium (Ho), indium (I
37、n), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), lutetium (Lu), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr), rubidium (Rb), rhenium (Re), rhodium (Rh),
38、 ruthenium (Ru), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulphur (S), tellurium (Te), terbium (Tb), thallium (Tl), thorium (Th), thulium (Tm), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), ytterbium (Yb), yttrium (Y), z
39、inc (Zn), and zirconium (Zr). NOTE 1 Construction products include e.g. mineral-based products (S); bituminous products (B); metals (M); wood-based products (W); plastics and rubbers (P); sealants and adhesives (A); paints and coatings (C), see also CEN/TR 16045 1. The working range depends on the m
40、atrix and the interferences encountered. NOTE 2 The limit of detection of most elements will be affected by their natural abundance, ionization behaviour, on abundance of isotope(s) free from isobaric interferences and by contamination (e.g. handling and airborne). Handling contaminations are in man
41、y cases more important than airborne ones. The limit of detection will be higher in cases where the determination is likely to be interfered (see Clause 4) or in case of memory effects (see e.g. EN ISO 17294-1:2006, 8.2). The method in this Technical Specification is applicable to construction produ
42、cts and validated for the product types listed in Annex B. 2 Normative references The following documents are referred to in the text in such a way that some or all of their content constitutes requirements of this document. For dated references, only the edition cited applies. For undated reference
43、s, the latest edition of the referenced document (including any amendments) applies. CEN/TS 16637-2, Construction products Assessment of release of dangerous substances Part 2: Horizontal dynamic surface leaching test CEN/TS 16637-3, Construction products Assessment of release of dangerous substance
44、s Part 3: Horizontal up-flow percolation test CEN/TS 17196, Construction products: Assessment of release of dangerous substances Digestion by aqua regia for subsequent analysis of the major, minor and trace elements EN ISO 3696:1995, Water for analytical laboratory use Specification and test methods
45、 (ISO 3696:1987) EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories (ISO/IEC 17025) EN ISO 17294-1:2006, Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS) Part 1: General guidelines (ISO 17294-1:2004) PD CEN/TS 17200:201
46、8CEN/TS 17200:2018 (E) 7 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. ISO and IEC maintain terminological databases for use in standardization at the following addresses: IEC Electropedia: available at http:/www.electropedia.org/ ISO Online br
47、owsing platform: available at http:/www.iso.org/obp 3.1 digest solution resulting from acid digestion of a sample SOURCE: EN 16687:2015, 3.2.8 3.2 eluate solution obtained from a leaching test SOURCE: EN 16687:2015, 4.2.7 3.3 analyte determinand element, ion or substance to be determined by an analy
48、tical method SOURCE: EN 16687:2015, 4.1.11 3.4 sample portion of material selected from a larger quantity of material Note 1 to entry: The manner of selection of the sample should be prescribed in a sampling plan. Note 2 to entry: The term “sample” is often accompanied by a prefix (e.g. laboratory s
49、ample, test sample) specifying the type of sample and/or the specific step in the sampling process to which the obtained material relates. SOURCE: EN 16687:2015, 3.1.5 3.5 laboratory sample sample or subsample(s) sent to or received by the laboratory Note 1 to entry: When the laboratory sample is further prepared by subdividing, cutting, sawing, coring, mixing, drying, grinding, and curing or by combinations of these operations, the result is the test sample. When no preparation of the laboratory sample is requi
